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At least 289 records · Page 16

Derivation of Midinfrared (5-25 micrometers) Optical Constants of Some Silicates and Palagonite

The midinfrared 2000-400/ cm (5-25 microns) optical constants (real (n) and imaginary (k) indices of refraction) are presented for: (1) pyrophyllite; (2) kaolinite; (3) serpentine; (4) montmorillonite; (5) saponite; (6) palagonite; and (7) orthopyroxene. Comparison of the values derived here with those previously presented for serpentine, montmorillonite, and palagonite is generally quite good and discrepancies between values are probably due to either chemical differences between the actual samples or different techniques used to derive the values. For montmorillonite, saponite, and palagonite we were able to derive optical constants in the region of the H2O-bending fundamental near 6 microns. We find that if a pellet of pure material can be produced with a mirror-like surface then the optical constants of clays and other noncohesive materials can be readily derived.

Roush, T.↗

Thermal emission measurements 2000-400 cm(exp -1) (5-25 microns) of Hawaiian palagonitic soils and their implications for Mars

The thermal emission of two palagonitic soils, common visible and near infrared spectral analogs for bright soils on Mars, was measured over the wavelength range of 5 to 25 microns (2000 to 400 cm(exp -1) for several particle size separates. All spectra exhibit emissivity features due to vibrations associated with H2O and SiO. The maximum variability of emissivity is approx. = 20% in the short wavelength region (5 to 6.5 microns, 2000 to 1500 cm(exp -1)), and is more subdued, < 4%, at longer wavelengths. The strengths of features present in infrared spectra of Mars cannot be solely provided by emissivity variations of palagonite; some other material or mechanism must provide additional absorption(s).

Roush, Ted L.↗

Mars Comm/Nav MicroSat Network Using the Multi-Mission Bus Launched Piggyback by Ariane 5

Recently, NASA's Jet Propulsion Laboratory completed a Mars Exploration Program Architecture Definition Study with strong international participation. The recommendations of this study include establishment of a low cost in-situ communications and navigation satellite network to provide enabling and enhancing support for the international exploration of Mars. This would be the first step toward establishing a "virtual presence throughout the solar system" as called for in NASA's Strategic Plan. Response to the proposed comm/nav satellite network has been very favorably received, as reflected by the inclusion of a line item in NASA's budget submittal to Congress, which provides funding for implementation of the network with first launch in the 2003 opportunity. Funding has already been provided for a phase A study being conducted this year. This paper presents the planned implementation of the comm/nav network, which will utilize microsats based on a multi-mission spacecraft bus being designed for launch by the Ariane 5 as a secondary payload. A companion paper at this conference, entitled "The Multi-Purpose Mars Micro-Mission System Design Utilizing Ariane 5 Piggyback Launch", describes the multimission bus design. This paper addresses the application of the multi-mission bus to the comm/nav microsat mission. Following an introduction, which provides the background that has led to the proposed comm/nav network, the paper discusses the projected user needs with emphasis on the various possible robotic missions (landers, rovers, ascent vehicles, balloons, aircraft, etc.) progressing toward eventual piloted missions. Next, the paper describes the concept for an evolving network of comm/nav microsats and the expected capability to satisfy the user needs. Results of communications and navigation performance analysis are summarized for attractive satellite constellation configurations. The important comm/nav microsat functional requirements on the multi-mission spacecraft bus are described with discussion of the mission-system tradeoffs for the driving requirements. The functional design of the in-situ communications / navigation package, which constitutes the payload of the microsat, is also described. The paper also includes discussion of technologies which are of specific importance to the implementation of the comm/nav microsat network.

Hastrup, R. C.↗

STS-111 Flight Day 5 Highlights

On Flight Day 5 of STS-111, the crew of Endeavour (Kenneth Cockrell, Commander; Paul Lockhart, Pilot; Franklin Chang-Diaz, Mission Specialist; Philippe Perrin, Mission Specialist) and the Expedition 5 crew (Valery Korzun, Commander; Peggy Whitson, Flight Engineer; Sergei Treschev, Flight Engineer) and Expedition 4 crew (Yury Onufrienko, Commander; Daniel Bursch, Flight Engineer; Carl Walz, Flight Engineer) are aboard the docked Endeavour and International Space Station (ISS). The ISS cameras show the station in orbit above the North African coast and the Mediterranean Sea, as Chang-Diaz and Perrin prepare for an EVA (extravehicular activity). The Canadarm 2 robotic arm is shown in motion in a wide-angle shot. The Quest Airlock is shown as it opens to allow the astronauts to exit the station. As orbital sunrise approaches, the astronauts are shown already engaged in their EVA activities. Chang-Diaz is shown removing the PDGF (Power and Data Grapple Fixture) from Endeavour's payload bay as Perrin prepares its installation position in the ISS's P6 truss structure; The MPLM is also visible. Following the successful detachment of the PDGF, Chang-Diaz carries it to the installation site as he is transported there by the robotic arm. The astronauts are then shown installing the PDGF, with video provided by helmet-mounted cameras. Following this task, the astronauts are shown preparing the MBS (Mobile Base System) for grappling by the robotic arm. It will be mounted to the Mobile Transporter (MT), which will traverse a railroad-like system along the truss structures of the ISS, and support astronaut activities as well as provide an eventual mobile base for the robotic arm.

Source record↗

STS-109 Mission Highlights Resource Tape: Flight Days 4 & 5 - Part 2 of 4

This video, Part 2 of 4, shows the activities of the STS-109 crew (Scott Altman, Commander; Duane Carey, Pilot; John Grunsfeld, Payload Commander; Nancy Currie, James Newman, Richard Linnehan, Michael Massimino, Mission Specialists) during flight days 4 and 5. The activities from other flights days can be seen on 'STS-109 Mission Highlights Resource Tape' Part 1 of 4 (internal ID 2002139471), 'STS-109 Mission Highlights Resource Tape' Part 3 of 4 (internal ID 2002139476), and 'STS-109 Mission Highlights Resource Tape' Part 4 of 4 (internal ID 2002137577). The primary activities during these days were EVAs (extravehicular activities) to replace two solar arrays on the HST (Hubble Space Telescope). Footage from flight day 4 records an EVA by Grunsfeld and Linnehan, including their exit from Columbia's payload bay airlock, their stowing of the old HST starboard rigid array on the rigid array carrier in Columbia's payload bay, their attachment of the new array on HST, the installation of a new starboard diode box, and the unfolding of the new array. The pistol grip space tool used to fasten the old array in its new location is shown in use. The video also includes several shots of the HST with Earth in the background. On flight day 5 Newman and Massimino conduct an EVA to change the port side array and diode box on HST. This EVA is very similar to the one on flight day 4, and is covered similarly in the video. A hand operated ratchet is shown in use. In addition to a repeat of the previous tasks, the astronauts change HST's reaction wheel assembly, and because they are ahead of schedule, install installation and lubricate an instrument door on the telescope. The Earth views include a view of Egypt and Israel, with the Nile River, Red Sea, and Mediterranean Sea.

Source record↗

STS-113 Flight Day 5 Highlights

This video shows the activities of the STS-113 crew (Jim Wetherbee, Commander; Paul Lockhart, Pilot; Michael Lopez-Alegria, John Herrington, Mission Specialists) during flight day 5. The crew is seen together with the Expedition 5 (Valeri Korzun, Commander; Peggy Whitsun, ISS Science Officer/Flight Engineer; Sergei Treschev, Flight Engineer) and Expedition 6 (Kenneth Bowersox, Commander; Donald Pettit, Nikolai Budarin, Flight Engineers) crews of the ISS (International Space Station) preparing for an EVA (extravehicular activity) the following day, and performing tasks on board the ISS. The changing of valves on the ISS carbon dioxide removal assembly is shown. The STS-113 crew is seen together answering numerous questions from the general public, with Lopez-Alegria answering all but one. There is also a clip of Jay Leno congratulating Wetherbee on his fiftieth birthday. Inside views of the Endeavour orbiter and the ISS modules are shown, as well as a view of the coast of Chile.

Source record↗

Efficient Synthesis of 4,8-Ditoluoyl-1,5-Dihydroxynaphthalene

4,8-Ditoluoyl-1,5-dihydroxynaphthalene was synthesized in quantitative yield from the corresponding methylenequinone via base-catalyzed hydration. Alkaline treatment gives the title compound in one step with a 99% yield, an improvement of 80% compared to the acidic, two step literature method for preparing 4,8-dibenzoyl-1,5-dihydroxynaphthalene.

Tyson, Daniel S.↗

5' modification of duplex DNA with a ruthenium electron donor-acceptor pair using solid-phase DNA synthesis

Incorporation of metalated nucleosides into DNA through covalent modification is crucial to measurement of thermal electron-transfer rates and the dependence of these rates with structure, distance, and position. Here, we report the first synthesis of an electron donor-acceptor pair of 5' metallonucleosides and their subsequent incorporation into oligonucleotides using solid-phase DNA synthesis techniques. Large-scale syntheses of metal-containing oligonucleotides are achieved using 5' modified phosporamidites containing [Ru(acac)(2)(IMPy)](2+) (acac is acetylacetonato; IMPy is 2'-iminomethylpyridyl-2'-deoxyuridine) (3) and [Ru(bpy)(2)(IMPy)](2+) (bpy is 2,2'-bipyridine; IMPy is 2'-iminomethylpyridyl-2'-deoxyuridine) (4). Duplexes formed with the metal-containing oligonucleotides exhibit thermal stability comparable to the corresponding unmetalated duplexes (T(m) of modified duplex = 49 degrees C vs T(m) of unmodified duplex = 47 degrees C). Electrochemical (3, E(1/2) = -0.04 V vs NHE; 4, E(1/2) = 1.12 V vs NHE), absorption (3, lambda(max) = 568, 369 nm; 4, lambda(max) = 480 nm), and emission (4, lambda(max) = 720 nm, tau = 55 ns, Phi = 1.2 x 10(-)(4)) data for the ruthenium-modified nucleosides and oligonucleotides indicate that incorporation into an oligonucleotide does not perturb the electronic properties of the ruthenium complex or the DNA significantly. In addition, the absence of any change in the emission properties upon metalated duplex formation suggests that the [Ru(bpy)(2)(IMPy)](2+)[Ru(acac)(2)(IMPy)](2+) pair will provide a valuable probe for DNA-mediated electron-transfer studies.

Non-NASA Center↗

Oligomerization of deoxyguanosine 5'-phosphoro-2-methylimidazolide on a polycytidylate template

The oligomerization of deoxyguanosine 5'-phosphoro-2-methylimidazolide on a polycytidylate template is much less efficient than the oligomerization of the corresponding activated ribonucleotide. Nonetheless oligomers containing up to eight nucleotide residues are detected. The products are 3'-5'-linked oligodeoxyribonucleotides capped at the 5'-terminus with a pyrophosphate-linked monomer.

NASA Discipline Exobiology↗

Space Technology 5: Enabling Future Micro-Sat Constellation Science Missions

The Space Technology 5 (ST-5) Project is part of NASA s New Millennium Program. ST-5 will consist of a constellation of three micro-satellites, each approximately 25 kg in mass. The mission goals are to demonstrate the research-quality science capability of the ST-5 spacecraft; to operate the three spacecraft as a constellation; and to design, develop and flight-validate three capable micro-satellites with new technologies. ST-5 is designed to measurably raise the utility of small satellites by providing high functionality in a low mass, low power, and low volume package. The whole of ST-5 is greater than the sum of its parts: the collection of components into the ST-5 spacecraft allows it to perform the functionality of a larger scientific spacecraft on a micro-satellite platform. The ST-5 mission was originally designed to be launched as a secondary payload into a Geosynchronous Transfer Orbit (GTO). Recently, the mission has been replanned for a Pegasus XL dedicated launch into an elliptical polar orbit. A three-month flight demonstration phase, beginning in March 2006, will validate the ability to perform science measurements, as well as the technologies and constellation operations. ST- 5 s technologies and concepts will then be transferred to future micro-sat science missions.

Carlisle, Candace C.↗

Prebiotic synthesis of 5-substituted uracils: a bridge between the RNA world and the DNA-protein world

Under prebiotic conditions, formaldehyde adds to uracil at the C-5 position to produce 5-hydroxymethyluracil with favorable rates and equilibria. Hydroxymethyluracil adds a variety of nucleophiles, such as ammonia, glycine, guanidine, hydrogen sulfide, hydrogen cyanide, imidazole, indole, and phenol, to give 5-substituted uracils with the side chains of most of the 20 amino acids in proteins. These reactions are sufficiently robust that, if uracil had been present on the primitive Earth, then these substituted uracils would also have been present. The ribozymes of the RNA world would have included many of the functional groups found in proteins today, and their catalytic activities may have been considerably greater than presently assumed.

NASA Program NSCORT↗

Blockade of 5-hydroxytryptamine3 receptors prevents cisplatin-induced but not motion- or xylazine-induced emesis in the cat

5-Hydroxytryptamine3 antagonists have been reported to prevent emesis elicited by cisplatin and radiation. This study investigated the possibility that drugs with this mechanism of action may be useful in preventing emesis elicited by other stimuli. The drugs ICS 205-930 (0.1 and 1.0 mg/kg) and MDL 72222 (0.1 and 1.0 mg/kg) were administered SC to cats before challenging them with either provocative motion or an emetic dose of xylazine. In no instance was a significant reduction in emesis evident. Zacopride was also administered before motion testing (0.01 to 10.0 mg/kg) and found to not have efficacy. To test the possibility that species or route of administration were factors in the negative results, 1.0 mg/kg of ICS 205-930 was administered SC before IV infusion of 7.5 mg/kg of cisplatin. There was a total suppression of emesis for the duration of the six-hour observation periods. This result verifies other work which found 5-hydroxytryptamine3 antagonists to be effective in preventing emesis elicited by cancer chemotherapeutic treatments. However, there is no evidence that they are effective in other syndromes, such as motion sickness and xylazine-induced emesis.

NASA Discipline Number 16-10↗

Design and Development of the Space Technology 5 (ST5) Solar Arrays

The National Aeronautics and Space Administration's (NASA's) Space Technology 5 (ST5) is designed to flight-test the concept of miniaturized 'small size" satellites and innovative technologies in Earth's magnetosphere. Three satellites will map the intensity and direction of the magnetic fields within the inner magnetosphere. Due to the small area available for the solar arrays, and to meet the mission power requirements, very high-efficiency multijunction solar cells were selected to power the spacecraft built by NASA Goddard Space Flight Center (GSFC). This was done in partnership with the Air Force Research Lab (AFRL) through the Dual-Use Science and Technology (DUS&T) program. Emcore's InGaP/lnGaAs/Ge Advanced triple-junction (ATJ) solar cells, exhibiting an average air mass zero (AMO) efficiency of 28.0% (one-sun, 28 C), were used to populate the arrays. Each spacecraft employs 8 identical solar panels (total area of about 0.3 square meters), with 15 large-area solar cells per panel. The requirement for power is to support on-orbit average load of 13.5 W at 8.4 V, with plus or minus 5% off pointing. The details of the solar array design, development and qualification considerations, as well as ground electrical performance & shadowing analysis results are presented.

Lyons, John↗

The Conference Proceedings of the 2003 Air Transport Research Society (ATRS) World Conference, Volume 5

The UNO Aviation Institute Monograph Series began in 1994 as a key component of the education outreach and information transfer missions of the Aviation Institute and the NASA Nebraska Space Grant & EPSCoR Programs. The series is an outlet for aviation materials to be indexed and disseminated through an efficient medium. Publications are welcome in all aspects of aviation. Publication formats may include, but are not limited to, conference proceedings, bibliographies, research reports, manuals, technical reports, and other documents that should be archived and indexed for future reference by the aviation and world wide communities. The Conference proceedings of the 2003 Air Transport Research Society (ATRS) world conference, volume 5 is presented. The topics include: 1) The Temporal Configuration of Airline Networks in Europe; 2) Determination and Applications of Environmental Costs at Different Sized Airports-Aircraft Noise and Engine Emissions; 3) Cost Effective Measures to Reduce CO2 Emissions in the Air Freight Sector; 4) An Assessment of the Sustainability of Air Transport System: Quantification of Indicators; 5) Regulation, Competition and Network Evolution in Aviation; 6) Regulation in the Air: Price and Frequency Cap; 7) Industry Consolidation and Future Airline Network Structures in Europe; 8) Application of Core Theory to the U.S. Airline Industry; 9) Air Freight Transshipment Route Choice Analysis; 10) A Fuzzy Approach of the Competition on Air Transport Market; and 11) Developing Passenger Demand Models for International Aviation from/to Egypt: A Case Study of Cairo Airport and Egyptair.

Bowen, Brent↗

Space Technology 5: Enabling Future Micro-Sat Constellation Science Missions

The Space Technology 5 (ST-5) Project is part of NASA s New Millennium Program. ST-5 will consist of a constellation of three micro-satellites, each approximately 25 kg in mass. The mission goals are to demonstrate the research-quality science capability of the ST-5 spacecraft, to operate the three spacecraft as a constellation; and to design, develop and flight-validate three capable micro-satellites with new technologies. ST-5 is designed to measurably raise the utility of small satellites by providing high functionality in a low mass, low power, and low volume package. The whole of ST-5 is greater than the sum of its parts: the collection of components into the ST-5 spacecraft allows it to perform the functionality of a larger scientific spacecraft on a micro-satellite platform. The ST-5 mission was originally designed to be launched as a secondary payload into a Geosynchronous Transfer Orbit (GTO). Recently, the mission has been replanned for a Pegasus XL dedicated launch into an elliptical polar orbit. A three-month flight demonstration phase, beginning in March 2006, will validate the ability to perform science measurements, as well as the technologies and constellation operations. ST- 5 s technologies and concepts will then be transferred to future micro-sat science missions.

Carlisle, Candace C.↗

Electrochemical Evaluation of LaNi(sub 5-x)Ge(sub x) Metal Hydride Alloys

We report a detailed evaluation of Ge-substituted LaNi(sub 5) for electrochemical application as a negative electrode inalkaline rechargeable cells. Alloys with small substitutions of Ge for Ni show operating pressures, chargeability, cyclic lifetime, and kinetics for hydrogen absorption and desorption all superior to those found in many substituted LaNi(sub 5) alloys.

alkaline cells recharchable cells rechargeable bat↗

Kinetics of Hydrogen Diffusion in LaNi(sub 5-x)Sn(sub x) Alloys

Solid-state diffusion of hydrogen in metal hydride (MH) alloys is recognized as the rate determining step in the discharge of MH alloys in alkaline Ni-MH rechargeable cells. In our pursuit of new ternary solutes in LaNi(sub 5) for extended cycle lifetimes, we have observed noticeable improvement in the cycle life with small substitutions of Sn and Ge for Ni. Furthermore, these substituents also facilitate enhanced charge transfer kinetics for hydriding-dehydriding process. In this paper, we report our studies on the kinetics of hydrogen diffusion in LaNi(sub 5-x) Sn(sub x) alloys by electrochemical pulse techniques, chronoamperometry and chronocoulometry.

electrochemical cycling↗

Integration and Testing Challenges of Small Satellite Missions: Experiences from the Space Technology 5 Project

The Space Technology 5(ST5) payload was successfully carried into orbit on an OSC Pegasus XL launch vehicle, which was carried aloft and dropped from the OSC Lockheed L-1011 from Vandenberg Air Force Base March 22,2006, at 9:03 am Eastern time, 6:03 am Pacific time. In order to reach the completion of the development and successful launch of ST 5, the systems integration and test(I&T) team determined that a different approach was required to meet the project requirements rather than the standard I&T approach used for single, room-sized satellites. The ST5 payload, part of NASA's New Millennium Program headquartered at JPL, consisted of three micro satellites (approximately 30 kg each) and the Pegasus Support Structure (PSS), the system that connected the spacecrafts to the launch vehicle and deployed the spacecrafts into orbit from the Pegasus XL launch vehicle. ST5 was a technology demonstration payload, intended to test six (6) new technologies for potential use for future space flights along with demonstrating the ability of small satellites to perform quality science. The main technology was a science grade magnetometer designed to take measurements of the earth's magnetic field. The three spacecraft were designed, integrated, and tested at NASA Goddard Space Flight Center with integration and environmental testing occurring in the Bldg. 7-1 0-15-29. The three spacecraft were integrated and tested by the same I&T team. The I&T Manager determined that there was insufficient time in the schedule to perform the three I&T spacecraft activities in series used standard approaches. The solution was for spacecraft #1 to undergo integration and test first, followed by spacecraft #2 and #3 simultaneously. This simultaneous integration was successful for several reasons. Each spacecraft had a Lead Test Conductor who planned and coordinated their spacecraft through its integration and test activities. One team of engineers and technicians executed the integration of all three spacecraft, learning and gaining knowledge and efficiency as spacecraft #1 integration and testing progressed. They became acutely familiar with the hardware, operation and processes for I&T, thus each team member had the experience and knowledge to safely execute I&T for spacecraft #2 and #3 together. The integration team was very versatile and each member could perform many different activities or work any spacecraft, when needed. Daily meetings between the three Lead TCs and technician team allowed the team to plan and implement activities efficiently. The three (3) spacecraft and PSS were successfully integrated and tested, shipped to the launch site, and ready for launch per the I&T schedule that was planned three years previously.

Sauerwein, Timothy A.↗