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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Formation of Na2SO4 and K2SO4 in flames doped with sulfur and alkali chlorides and carbonates

High pressure, free-jet expansion, mass spectrometric sampling was used to identify directly and to measure reaction products formed in doped methane-oxygen flames. Flames were doped with SO2 or CH3SH and sodium or potassium chlorides or carbonates. Gaseous NA2SO4 or K2S04 molecules were formed in residence times on the order of msec for each combination of dopants used. Composition profiles of combustion products were measured and compared with equilibrium thermodynamic calculations of product composition.

Fryburg, G. C.↗
NASA NTRS1977

Burner rig alkali salt corrosion of several high temperature alloys

The hot corrosion of five alloys was studied in cyclic tests in a Mach 0.3 burner rig into whose combustion chamber various aqueous salt solutions were injected. Three nickel-base alloys (IN-792, IN-738, and IN-100), a cobalt-base alloy (MM-509), and an iron-base alloy (304 stainless steel) were studied at temperatures of 700, 800, 900, and 1000 C with various salt concentrations and compositions. The relative resistance of the alloys to hot corrosion attack was found to vary with temperature and with both the concentration and composition of the injected salt solution. Results indicate that the corrosion of these alloys is a function of both the presence of salt condensed as a liquid on the surface and of the composition of the gas phases present.

Deadmore, D.↗
NASA NTRS1977

Formation of Na2SO4 and K2SO4 in flames doped with sulfur and alkali chlorides and carbonates

High pressure, free-jet expansion, mass spectrometric sampling was used to identify directly and to measure reaction products formed in doped methane-oxygen flames. Flames were doped with SO2 or CH3SH and sodium or potassium chlorides or carbonates. Gaseous Na2SO4 or K2SO4 molecules were formed in residence times on the order of 1 msec for each combination of dopants used. Composition profiles of combustion products were measured and compared with equilibrium thermodynamic calculations of product composition.

Fryburg, G. C.↗
NASA NTRS1979

Thermally stimulated conductivity studies of trapping centers in alkali-borosilicate glasses

Thermally stimulated conductivity studies have been performed on unirradiated borosilicate glasses made to contain various amounts of sodium, lithium, nickel, and iron oxides. Measurements were made between 77 and 570 K. All the samples gave one or more conductivity peaks below room temperature. Analysis of the initial-rise slope of the conductivity peaks of the various samples gave trapping-level energies ranging from 0.1 to 1.9 eV. The shape and temperature of the maximum of most of the peaks changed on each measurement cycle. A few samples exhibited a common peak that formed on annealing.

Catchings, R. M.↗
NASA NTRS1980

Structure of complexes between aluminum chloride and other chlorides, 2: Alkali-(chloroaluminates). Gaseous complexes

The structural chemistry of complexes between aluminum chloride and other metal chlorides is important both for practice and theory. Condensed-phase as well as vapor-phase complexes are of interest. Structural information on such complexes is reviewed. The first emphasis is given to the molten state because of its practical importance. Aluminum chloride forms volatile complexes with other metal chlorides and these vapor-phase complexes are dealt with in the second part. Finally, the variations in molecular shape and geometrical parameters are summarized.

Hargittai, M.↗
NASA NTRS1980

Computational study of alkali-metal-noble gas collisions in the presence of nonresonant lasers - Na + Xe + h/2/pi/omega sub 1 + h/2/pi/omega sub 2 system

The collision of Na with Xe in the presence of both the rhodamine-110 dye laser and the Nd-glass laser is investigated within a quantum-mechanical close-coupled formalism, utilizing ab initio potential curves and transition dipole matrix elements. Both one- and two-photon processes are investigated; the Na + Xe system is not asymptotically resonant with the radiation fields, so that these processes can only occur in the molecular collision region. The one-photon processes are found to have measurable cross sections at relatively low intensities; even the two-photon process has a significant section for field intensities as low as 10 MW/sq cm.

Devries, P. L.↗
NASA NTRS1981

High temperature alkali corrosion in high velocity gases

The effects of potential impurities in coal derived liquids such as Na, K, Mg, Ca and Cl on the accelerated corrosion of IN-100, U-700, IN-792 and Mar-M509 were investigated using a Mach 0.3 burner rig for times to 1000 hours in one hour cycles. These impurities were injected in combination as aqueous solutions into the combustor of the burner rig. The experimental matrix utilized was designed statistically. The extent of corrosion was determined by metal recession. The metal recession data were fitted by linear regression to a polynomial expression which allows both interpolation and extrapolation of the data. As anticipated, corrosion increased rapidly with Na and K, and a marked maximum in the temperature response was noted for many conditions. In contrast, corrosion decreased somewhat as the Ca, Mg and Cl contents increased. Extensive corrosion was observed at concentrations of Na and K as low as 0.1 PPM at long times.

Lowell, C. E.↗
NASA NTRS1980

Moon and earth - Compositional differences inferred from siderophiles, volatiles, and alkalis in basalts

A comparison of RNAA analyses of 18 trace elements in 25 low-Ti lunar and 10 terrestrial oceanic basalts indicated that the volatiles such as Ag, Bi, and Br are depleted in lunar basalts by nearly constant factors of 0.026 relative to terrestrial basalts. This constancy is not consistent with models that derive the moon's volatiles from partial recondensation of the earth's mantle or from partial degassing of a captured body; it is consistent with models which derive planetary volatiles from a thin veneer of C-chondrite material. Chalcogens (Se and Te) have almost constant and identical abundances in lunar and terrestrial basalts; siderophiles show abundant Ni in lunar basalts, while Ir, Re, Ge, and Au are depleted.

Wolf, R.↗
NASA NTRS1984

Research on oxidation by air and tempering of Raney nickel electrocatalysts for the H2 anodes of alkali combustion materials cells

The controlled oxidation in air of Raney nickel electrocatalysts was studied, with special attention paid to the quantitative analysis of nickel hydroxide. The content of the latter was determined through X-ray studies, thermogravimetric measurements, and spectral photometric examinations. The dependence of the content on the drying of activated catalyst is determined. The influence of nickel hydroxide on the electrochemical parameters of the catalyst, such as diffusion polarization, is studied, including a measurement of the exchange current density using the potential drop method. Conservation by oxidation in air with ancillary stabilization of the oxide in an H2 flow at 300 C is explored, including reduction by H2, the influence of tempering time, and structural studies on conserved and stabilized catalyst, long term research on the catalyst, including the influence of aging on the reduced catalyst, and the results of impedance measurements are presented.

Selbach, H. J.↗
NASA NTRS1986

Origin of the earth's moon - Constraints from alkali volatile trace elements

Although the moon is depleted in volatile elements compared to the earth, these depletions are not in accord with simple volatility. For example, the Cs/Rb ratios of the earth and moon inferred from basalt are approximately one seventh and one half of the CI ratio, respectively. Volatility considerations alone predict that the lunar Cs/Rb ratio should be equal to or lower than the terrestrial ratio if the moon was derived entirely from earth mantle material. Thus hypotheses such as rotational fission which invoke derivation of lunar material entirely from the earth's mantle may be excluded. The collisional ejection hypothesis of lunar origin requires at least 18 percent of lunar material to be derived from a projectile with dehydrated CI composition to match the lunar Cs/Rb ratio, and 25-50 percent to match both the lunar Cs/Rb ratio and absolute concentrations of Cs and Rb. It remains to be demonstrated that this relatively large contribution of projectile material is consistent with other elemental abundances and element ratios in the moon.

Kreutzberger, M. E.↗
NASA NTRS1986

Nonlinear infrared generation in alkali metal vapors: Steady state susceptibilities and dynamic behavior. Effective relaxation rates and preliminary Raman gain predictions for the Cs system

Effective relaxation rates for atomic cesium pumped by doubled Alexandrite radiation are presented. Laser radiation levels are 8S 1/2 and 9S 1/2; resonance levels 3 = 8P 1/2 and 8P 1/2, respectively. In addition, Raman gain is represented in two graphs which plot chi per atom (10 to the -13 power) at Raman peak versus the infrared wave number per centimeter and the corresponding doubled Alexandrite wave number. One graph covers resonance level 8P, the other 9P; in both cases cesium is pumped with a peak pulse height of 0.5 MW in a 200 micron diameter spot size.

Lawandy, N. M.↗
NASA NTRS1986

The role of oxygen in porous molybdenum electrodes for the alkali metal thermoelectric converter

A model for chemical reactions in porous molybdenum electrodes is presented which is based on thermochemical and kinetic data, known sodium-molybdenum-oxygen chemistry, X-ray diffraction analysis of molybdenum and molybdenum oxide electrodes, and the electrochemical behavior of the cell. Enhanced sodium transport through the electrode in its optimum performance state is found to be due to the high sodium ion conductivity of molten Na2MoO4 in the pores, and the electrical conduction to the molybdenum matrix by Na2Mo3O6. The decline of electrode performance is shown to be due to a combination of loss mechanisms for the Na-Mo-O compounds including reduction at short circuit, disproportionation of Na2Mo3O6 at open circuit, and the evaporation of Na2MoO4 at elevated temperature. It is suggested that operation of the cell at moderate voltage of about 0.5 V corresponding to maximum power may be a more stable condition for the porous electrode than open-circuit stand or short-circuit, where degradation reactions are heightened.

Williams, R. M.↗
NASA NTRS1986

Theoretical study of the X1Sigma(+) states of the alkali hydrides NaH-CsH

By means of near Hartree-Fock quality Slater basis sets, and the incorporation of electron correlation through the coupled-pair formalism, theoretical potentials are obtained for the X1Sigma(+) states of NaH, KH, and RbH. Electric dipole moment functions are given for NaH-RbH, as well as vibrationally averaged dipole moments, Einstein coefficients, and radiative lifetimes for the first 10 vibrational levels; an extensive study is made of the computational requirements for an accurate permanent dipole moment of KH.

Langhoff, Stephen R.↗
NASA NTRS1987

Quantum efficiencies of imaging detectors with alkali halide photocathodes. I - Microchannel plates with separate and integral CsI photocathodes

Measurements and comparisons have been made of the quantum efficiencies of microchannel plate (MCP) detectors in the far-UV (below 2000-A) wavelength range using CsI photocathodes (a) deposited on the front surfaces of microchannel plates and (b) deposited on solid substrates as opaque photocathodes with the resulting photoelectrons input to microchannel plates. The efficiences were measured in both pulse-counting and photodiode modes of operation. Typical efficiencies are about 15 percent at 1216 A for a CsI-coated MCP compared with 65 percent for an opaque CsI photocathode MCP detector. Special processing has yielded an efficiency as high as 20 percent for a CsI-coated MCP. This may possibly be further improved by optimization of the tilt angle of the MCP channels relative to the front face of the MCP and incident radiation. However, at present there still remains a factor of at least 3 quantum efficiency advantage in the separate opaque CsI photocathode configuration.

Carruthers, George R.↗
NASA NTRS1988

The band systems of alkali vapors

A number of band edges of the molecules, Na2, K2, NaK, NaCs, LiK, LiRb, LiCs, and NaRb are arranged in edge schemes. The vibrational quanta of the base terms and the upper terms can be approximately determined. Viewpoints are produced for interpreting electron terms. The terms Na2 are interpreted as terms of a photo-electron.

Weizel, W.↗