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At least 289 records · Page 16

Climatic influence of background and volcanic stratosphere aerosol models

A simple modelization of the earth atmosphere system including tropospheric and stratospheric aerosols has been derived and tested. Analytical expressions are obtained for the albedo variation due to a thin stratospheric aerosol layer. Also outlined are the physical procedures and the respective influence of the main parameters: aerosol optical thickness, single scattering albedo and asymmetry factor, and sublayer albedo. The method is applied to compute the variation of the zonal and planetary albedos due to a stratospheric layer of background H2SO4 particles and of volcanic ash.

Deschamps, P. Y.↗

Erosion and transport of eolian materials on Mars

An abrasion chamber was constructed to produce grain to grain impacts and to eliminate, as far as possible, grain to wall impact. Quartz, basalt, olivine, and volcanic ash were used as abrasives to determine particle longevity on Mars during eolian abrasion. The various abrasion velocities, measured velocity or particles, calculated velocity of collision, time during which abrasion took place, the charge (material) in grams, and the percent remaining after completion are tabulated. The tests show that if coarse sand-sized particles of the composition presumably present on Mars are moved at the wind velocities given, almost complete destruction can occur in geologically insignificant time periods. Grain to rock collisions are not necessary for almost complete destruction; grain to grain collisions are sufficient.

Krinsley, D.↗

Micronized coal burner facility

A combustor or burner system in which the ash resulting from burning a coal in oil mixture is of submicron particle size is described. The burner system comprises a burner section, a flame exit nozzle, a fuel nozzle section, and an air tube by which preheated air is directed into the burner section. Regulated air pressure is delivered to a fuel nozzle. Means are provided for directing a mixture of coal particles and oil from a drum to a nozzle at a desired rate and pressure while means returns excess fuel to the fuel drum. Means provide for stable fuel pressure supply from the fuel pump to the fuel nozzle.

Calfo, F. D.↗

Abrasion by aeolian particles: Earth and Mars

Estimation of the rate of aeolian abrasion of rocks on Mars requires knowledge of: (1) particle flux, (2) susceptibilities to abrasion of various rocks, and (3) wind frequencies on Mars. Fluxes and susceptibilities for a wide range of conditions were obtained in the laboratory and combined with wind data from the Viking meteorology experiment. Assuming an abundant supply of sand-sized particles, estimated rates range up to 2.1 x 10 to the minus 2 power cm of abrasion per year in the vicinity of Viking Lander 1. This rate is orders of magnitude too great to be in agreement with the inferred age of the surface based on models of impact crater flux. The discrepancy in the estimated rate of abrasion and the presumed old age of the surface cannot be explained easily by changes in climate or exhumation of ancient surfaces. The primary reason is thought to be related to the agents of abrasion. At least some sand-sized (approx. 100 micrometers) grains appear to be present, as inferred from both lander and orbiter observations. High rates of abrasion occur for all experimental cases involving sands of quartz, basalt, or ash. However, previous studies have shown that sand is quickly comminuted to silt- and clay-sized grains in the martian aeolian regime. Experiments also show that these fine grains are electrostatically charged and bond together as sand-sized aggregates. Laboratory simulations of wind abrasion involving aggregates show that at impact velocities capable of destroying sand, aggregates from a protective veneer on the target surface and can give rise to extremely low abrasion rates.

Greeley, R.↗

Non-noble metal based metallization systems

The results of efforts to produce a nonsilver metallization system for silicon photovoltaic cells are given. The system uses a metallization system based on molybdenum, tin, and titanium hydride. The initial work in this system was done using the MIDFILM process. The MIDFILM process attains a line resolution comparable to photoresist methods with a process related to screen printing. The surface to be processed is first coated with a thin layer of photopolymer material. Upon exposure to ultraviolet light through a suitable mask, the polymer in the non-pattern area crosslinks and becomes hard. The unexposed pattern areas remain tacky. The conductor material is then applied in the form of a dry mixture of metal which adheres to the tacky pattern area. The assemblage is then fired to ash the photopolymer and sinter the conductor powder.

Garcia, A., III↗

Recent comet impacts on the moon: The evidence from spectral reflectance studies

The results of analyses of near infrared reflectance spectra are inconsistent with numerous previous interpretations of the Reiner Gamma Formation. These include: (1) nue ardente or volcanic ash deposits, (2) volcanically derived sublimates, (3) high albedo volcanic deposits, and (4) highlands debris emplaced as impact ejecta. These results, strongly suggest that the selective preservation of high albedo features (formed by secondaries) by a local magnetic field enhancement is not a viable hypothesis. The results are generally consistent with, but place constraints on, the cometary impact hypothesis of Schultz and co-workers. While the presence of a magnetized component was not detected in either the bright or dark portions of the Reiner Gamma Formation, this material may be present in amounts under the current detection limits.

Hawke, B. R.↗

Chronology, morphology and stratigraphy of pumiceous pyroclastic-flow (ignimbrite) deposits from the eruption of Mount St. Helens on 18 May 1983

Between 1217 and 1620 hours (PDT), on May 18, 1980, the magmatic eruption column of Mount St. Helens formed an ash fountain and pyroclastic flows dominated the eruption process over tephra ejection. Eurption-rate pulsations generally increased to a maximum at 1600 to 1700 hrs. After 1620 hrs, the eruption assumed an open-vent discharge with strong, vertical ejection of tephra. Relative eruption rates (relative mass flux rates) of the pyroclastic flows were determined by correlating sequential photographs and SLAR images, obtained during the eruption, with stratigraphy and surface morphology of the deposits.

Criswell, C. W.↗

Sputtered coatings for protection of spacecraft polymers

Kapton polyimide oxidizes at significant rates (4.3x10(-24) gram/incident oxygen atom) when exposed in low Earth orbit to the ram atomic oxygen flux. Ion beam sputter deposited thin films of Al2O3 and SiO2 as well as a codeposited mixture of predominantly SiO2 with a small amount of polytetrafluoroethylene were evaluated and found to be effective in protecting Kapton from oxidation in both laboratory plasma ashing tests as well as in space on board shuttle flight STS-8. A protective film of or = 96 percent SiO2 and or = 4 percent polytetrafluoroethylene was found to be very flexible compared to the pure metal oxide coatings and resulted in mass loss rates that were 0.2 percent of that of the unprotected Kapton. The optical properties of Kapton for wavelengths investigated between 0.33 and 2.2 microns were not significantly altered by the presence of the coatings or changed by exposure of the coated Kapton to the low Earth orbital ram environment.

Banks, B. A.↗

Development of carbon slurry fuels for transportation (hybrid fuels, phase 2)

Slurry fuels of various forms of solids in diesel fuel are developed and evaluated for their relative potential as fuel for diesel engines. Thirteen test fuels with different solids concentrations are formulated using eight different materials. A variety of properties are examined including ash content, sulfur content, particle size distribution, and rheological properties. Attempts are made to determine the effects of these variations on these fuel properties on injection, atomization, and combustion processes. The slurries are also tested in a single cylinder CLR engine in both direct injection and prechamber configurations. The data includes the normal performance parameters as well as heat release rates and emissions. The slurries perform very much like the baseline fuel. The combustion data indicate that a large fraction (90 percent or more) of the solids are burning in the engine. It appears that the prechamber engine configuration is more tolerant of the slurries than the direct injection configuration.

Ryan, T. W., III↗

El Chichon - Composition of plume gases and particles

Aircraft measurements were made of trace gases, atmospheric particles, and condensed acid volatiles in the plume of El Chichon volcano, Chiapas, Mexico, in November 1982. Hydrogen sulfide was the primary gaseous sulfur species in the plume at the time of collection. Concentrations of 28 elements were determined by neutron activation analysis of particulate material from the plume. The volatile elements sulfur, chlorine, arsenic, selenium, bromine, antimony, iodine, tungsten, and mercury were enriched relative to bulk pyroclastic material by factors of 60 to 20,000. Arsenic, antimony, and selenium were associated predominantly with small (not greater than 3 micrometer) particles. Calcium and sodium were present almost exclusively on larger particles and aluminum and manganese were bimodally distributed. Ashladen particulate material injected into the stratosphere during the early violent eruptions was enriched by factors of 10 to 30 relative to ash in some of the same elements observed in the quiescent plume.

Kotra, J. P.↗

The faint young sun-climate paradox - Crustal influences

The various mechanisms which have been proposed to compensate for the climatic effects of a 30 percent increase in the solar constant during the past 4.5 billion years are examined. Mechanisms besides the greenhouse effect could have provided significant compensation during the second half of this period. It is proposed that the development of continents during the past 2.5 billion years caused a secular evolution of the atmosphere-ocean heat transport system. As a result, past climates were less susceptible to complete freeze-over. The lower albedo of water would be another factor in this effect insofar as the early earth had smaller land masses. A complete or nearly complete freeze-over may have occurred as past glaciations were widespread. Climate models then suggest that the earth would have remained frozen through the present epoch and into a distant future. It is suggested that volcanic influences could allow a passage from the frozen branch onto the unfrozen branch of climate models should conditions on earth be suitable for that climate change. A broad equatorial belt of volcanic ash is one scenario which would allow a transfer from the frozen earth state into the unfrozen one.

Schatten, K. H.↗

Size-specific composition of aerosols in the El Chichon volcanic cloud

A NASA U-2 research aircraft flew sampling missions in April, May, July, November, and December 1982 aimed at obtaining in situ data in the stratospheric cloud produced from the March-April 1982 El Chichon eruptions. Post flight analyses provided information on the aerosol composition and morphology. The particles ranged in size from smaller than 0.05 m to larger than 20 m diameter and were quite complex in composition. In the April, May, and July samples the aerosol mass was dominated by magmatic and lithic particles larger than about 3 m. The submicron particles consisted largely of sulfuric acid. Halite particles, believed to be related to a salt dome beneath El Chichon, were collected in the stratosphere in April and May. On the July 23 flight, copper-zinc oxide particles were collected. In July, November, and December, in addition to the volcanic ash and acid particles, carbon-rich particles smaller than about 0.1 m aerodynamic diameter were abundant.

Woods, D. C.↗

The Effect of Particle Density on Aeolian Transport

A set of experiments using a wide range of particle densities was performed in an open-circuit, terrestrial-atmospheric-pressure wind tunnel at Arizona State University. The results show that saltation flux equations derived for typical geologic material overpredict the flux of low-density particles. Walnut shells (approximately 1.1 g/cc) were used in the experiment and correspond to volcanic ash or ice. Less mass is transported by the wind in the case of low particle density because the style of transport is different. There is a direct, counter-intuitive relationship between particle density and transport height. Measurements of the vertical distribution of material show that the low-density walnut shells travel in a zone within 10 cm of the surface while high-density (approximately 4.5 g/cc) chromite particles travel as 50 cm. Furthermore, the overall saltation rate of the chromite is approximately four times greater than the walnut shells at the same freestream wind speed, even though the wind is much further above threshold for the walnut shells.

Williams, S. H.↗

Development of acceptance criteria for batches of silane primer for external tank thermal protection system bonding applications

Concluding tests for the thermogravimetric and FTIR analyses of DC 1200 silane primers are discussed as well as methods for HPLC and GC analyses and for determining titanium and silicon by atomic absorption spectroscopy. Tables summarizes results obtained for residue, ash, titanium, silicone, Si/Ti ratio, OH-absorption, the lap-shear test, and the GC headspace for alcohols.

Mikes, F.↗

The salutary effect of dietary calcium on bone mass in a rat model of simulated weightlessness

Whether supplementation of dietary calcium reduces the differences in bone mass of unweighed limbs and normally weighted limbs, and whether parathyroid hormone (PTH) and 1,25-dihydroxyvitamin D (1,25(OH)2D) respond differently to dietary calcium in unweighted animals in comparison with pair-fed controls was studied. The hind limbs of rats were unweighted by a tail suspension method and diets containing 0.1% to 2.4% calcium. After 2 weeks serum calcium, phosphorus, PTH and 1,25(OH)2D intestinal calcium transport were determined and bone mass, ash weight, and calcium in the tibia, L-1 vertebra, and humerus were measured. No significant differences in body weights were observed among the various groups. Suspended rats maintained constant levels of serum calcium and phosphate over the wide range of dietary calcium. Serum PTH and 1,25(OH)2D and intestinal calcium transport fell as dietary calcium was increased. Bone calcium in the tibia and vertebra from suspended rats remained less than that from pair-fed control. It is suggested that although no striking difference between suspended and control animals was observed in response to dieteary calcium, increasing dietary calcium may reduce the negative impact of unloading on the calcium content of the unweighted bones. The salutary effect of high dietary calcium appears to be due to inhibition of bone resorption rather than to stimulation of bone formation.

Bikle, D. D.↗

Ion beam sputter-deposited thin film coatings for protection of spacecraft polymers in low Earth orbit

Ion beam sputter-deposited thin films of Al2O3, SiO2, and a codeposited mixture of predominantly SiO2 with small amounts of a fluoropolymer were evaluated both in laboratory plasma ashing tests and in space on board shuttle flight STS-8 for effectiveness in preventing oxidation of polyimide Kapton. Measurements of mass loss and optical performance of coated and uncoated polyimide samples exposed to the low Earth orbital environment are presented. Optical techniques were used to measure loss rates of protective films exposed to atomic oxygen. Results of the analysis of the space flight exposed samples indicate that thin film metal oxide coatings are very effective in protecting the polyimide. Metal oxide coatings with a small amount of fluoropolymer codeposited have the additional benefit of great flexibility.

Banks, B. A.↗

STS 8 Orbiter mission window pitting and the possible association with the El Chichon eruption of March and April 1982

The possibility that the pitting that occurred in the STS-8 Orbiter windows was caused by dust from the El Chichon volcano eruption in March-April 1982 is considered. The pit density was more than 30/sq cm, most being 2.5-5 microns deep, and showed no evidence of impact melting. An 'alley' of higher incidence of pits in one window coincided with the line of a seam between TPS tiles. The particles causing the sandblasting were concluded to have arrived in parallel and could not be attributed to the ET, SRBs or a dust storm. The sulfuric gas-rich El Chichon plume injected sufficient material into the atmosphere so that the globe was soon encircled. Most of the resulting particulates (480-8400 tons) stayed in the Northern Hemisphere, and H2SO4 and ash concentrations were high during the STS-8 mission. The Orbiter cut through the debris layer at 19.8 km altitude at a 10 deg angle of attack, which matches the particle crater impact angle in the Orbiter windows. Since the passage was at night, larger H2SO4 droplets may have coalesced and formed larger particles on available solid nuclei, thus producing the 20-40 microns cratering observed in the windows.

Cour-Palais, B. G.↗

Accurate stratospheric particle size distributions from a flat plate collection surface

Flat plate particle collections have revealed the presence of a remarkable variety of both terrestrial and extraterrestrial material in the stratosphere. It is found that the ratio of terrestrial to extraterrestrial material and the nature of the material collected may vary significantly over short time scales. These fluctuations may be related to massive injections of volcanic ash, emissions from solid fuel rockets, or variations in the micrometeoroid flux. The variations in particle number density can be of great importance to the earth's atmospheric radiation balance, and, therefore, its climate. With the objective to assess the number density of solid particles in the stratosphere, an examination has been conducted of all particles exceeding 1 micron in average diameter for a representative suite of particles obtained from a single flat plate collection surface. Attention is given to solid particle size distributions in the stratosphere, and the origin of important stratospheric particle types.

Zolensky, M. E.↗