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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

Effects of curvilinear motion in large-amplitude bending of C3

The geometry of the bending of a linear triatomic molecule is analyzed, and an expression for the average rotational constant is derived. A harmonic oscillator model of C3 is fitted to the observed rotational constant within 0.6%. The bond distance between atoms at zero bending is 1.287 A according to this model; this is noticeably larger than the average internuclear distance of 1.277 A for the vibrational ground state. The first order perturbation solutions for the vibrational energy levels, taking into account the effect of a quartic perturbation potential, closely match observed levels. For a square well potential model of C3, the effect of curvilinear motion in bending is similar to that found for the harmonic oscillator model, though the decreases in energy are about twice as large. In both models, the average energy decrease is relatively constant at approximately 10% over a wide range of vibrational quantum number.

Hansen, C. F.↗

Active control of gust- and interference-induced vibration of tilt-rotor aircraft

An active control system to suppress the response of the blade bending modes of a tilt-rotor aircraft to axial gusts and wing/rotor interference is described. The use of blade-mounted accelerometers as sensors is shown to permit the measurement and control of tilt-rotor blade modal responses and their associated vibratory loads directly. The feedback of modal acceleration, in addition to modal rate and displacement, is demonstrated to provide a control phase lead, in comparison with feedback of modal rate and displacement only, which makes higher system gains achievable.

Ham, Norman D.↗

Gas-phase preparation of the dibenzo[ e,l ]pyrene (C 24 H 14 ) butterfly molecule via a phenyl radical-mediated ring annulation

A high temperature phenyl-mediated addition–cyclization–dehydrogenation mechanism to form peri-fused polycyclic aromatic hydrocarbon (PAH) derivatives—illustrated through the formation of dibenzo[e,l]pyrene (C 24 H 14 )—is explored through a gas-phase reaction of the phenyl radical (C 6 H 5 ˙) with triphenylene (C 18 H 12 ) utilizing photoelectron photoion coincidence spectroscopy (PEPICO) combined with electronic structure calculations. Low-lying vibrational modes of dibenzo[e,l]pyrene exhibit out-of-plane bending and are easily populated in high temperature environments such as combustion flames and circumstellar envelopes of carbon stars, thus stressing dibenzo[e,l]pyrene as a strong target for far-IR astronomical surveys.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Structural analysis of wind turbine rotors for NSF-NASA Mod-0 wind power system

Preliminary estimates are presented of vibratory loads and stresses in hingeless and teetering rotors for the proposed NSF-NASA Mod-0 wind power system. Preliminary blade design utilizes a tapered tubular aluminum spar which supports nonstructural aluminum ribs and skin and is joined to the rotor hub by a steel shank tube. Stresses in the shank of the blade are calculated for static, rated, and overload operating conditions. Blade vibrations were limited to the fundamental flapping modes, which were elastic cantilever bending for hingeless rotor blades and rigid-body rotation for teetering rotor blades. The MOSTAB-C computer code was used to calculate aerodynamic and mechanical loads. The teetering rotor has substantial advantages over the hingeless rotor with respect to shank stresses, fatigue life, and tower loading. The hingeless rotor analyzed does not appear to be structurally stable during overloads.

Spera, D. A.↗

Comprehensive analysis of helicopters with bearingless rotors

A modified Galerkin method is developed to analyze the dynamic problems of multiple-load-path bearingless rotor blades. The development and selection of functions are quite parallel to CAMRAD procedures, greatly facilitating the implementation of the method into the CAMRAD program. A software is developed implementing the modified Galerkin method to determine free vibration characteristics of multiple-load-path rotor blades undergoing coupled flapwise bending, chordwise bending, twisting, and extensional motions. Results are in the process of being obtained by debugging the software.

Murthy, V. R.↗

Modified Composite Struts Would Damp Vibrations

Composite-material (fiber/matrix laminate) struts damping longitudinal vibrations fabricated more easily in proposed new design. Prior design described in "Composite Struts Would Damp Vibrations" (NPO-17914). New design similar except pattern of fibers includes rounded bends (instead of sharp bends) in fibers.

Chen, Gun-Shing↗

Structural Dynamic Analysis of a Spacecraft Multi-DOF Shaker Table

Finite element enforced response analysis was performed on a multiple degree of freedom expander head shaker table to aid in the design of the table structure and vibration control system. The payload for this shaker system is a spacecraft with a multitude of flexible modes across a broad frequency band. A Craig-Bampton representation of the spacecraft was used to expedite analysis of multiple shaker table designs. The analysis examines the required forces in the actuators for a constant amplitude base acceleration sine sweep test, the resulting forces in the spacecraft and table attachment restraints, and the resulting accelerations on the spacecraft structure. The results show the spacecraft response at low frequencies is very high near the tip due to the low order spacecraft bending and axial modes. The high response can be addressed by notching the input vibration levels to avoid overtesting the spacecraft. At frequencies above 25 Hz, the spacecraft modal effective masses are very small, and the response of the shaker table dominates the response. Anti-resonances of the shaker table in the frequency range of interest reduce the acceleration output and require much higher actuator forces to achieve the acceleration specification. These effects may require stiffening the shaker structure to move the modes out of the test frequency range or increasing the shaker table damping.

Pray, Carl↗

Experiments concerning the laser-enhanced reaction between vibrationally excited O3 and NO

The enhancement in reaction rate between O3 and NO is studied for the case of O3 vibrationally excited by a CO2 laser. Chemiluminescence observations of a vibrationally excited and an electronically excited nitrogen dioxide reaction product provide information on the separate contributions to the overall reaction rate of these two reactive channels. The contribution of the stretching and bending modes of O3 to the reaction rate enhancement is also discussed. In addition, consideration is given to the nonreactive vibrational deactivation of vibrationally excited O3.

Hui, K.-K.↗

Vibrational spectroscopy analysis of silica and silicate glass networks

Vibrational spectroscopy has been widely used to investigate various structural aspects of the glass network, and there are a plethora of papers reporting subtle but consistent changes in infrared and Raman spectral features of glass upon alterations of glass compositions, thermal histories, mechanical stresses, or surface treatments. However, interpretations of such spectral features are still obscured due to the lack of well-established physical principles accurately describing vibrational modes of the non-crystalline glass network. Due to the non-equilibrium nature of the glass network, three-dimensionally connected without any long-range orders, vibrational spectral features of glass cannot be interpreted using the analogy with those of isolated molecular moieties or crystalline counterparts. Here, this feature article explains why such comparisons are outdated and describes the recent advances made from theoretical calculations of vibrational spectral features of amorphous networks or comparisons of computational results with experimental data. For the interpretation of vibrational spectral features of silica and silicate glasses, the following empirical relationships are suggested: (i) the intensity-weighted peak position of the Si-O-Si stretch mode negatively correlates with the weighted average of the Si-O bond length distribution, and (ii) the broad band of the Si-O-Si bending mode negatively correlates with the Si-O-Si bond angle distribution. Selected examples of vibrational spectroscopic imaging of surface defects are discussed to deliberate the implication of these findings in the structure-property relationship of silica and silicate glass materials. Unanswered questions and continuing research challenges are identified.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Photodetachment spectroscopy and resonant photoelectron imaging of the 2-naphthoxide anion via dipole-bound excited states

We report a photodetachment spectroscopy and high-resolution resonant photoelectron imaging study of cryogenically-cooled 2-naphthoxide anions (C 10 H 7 O - ). The photodetachment spectrum revealed a dipole-bound state (DBS) 202(4) cm -1 below the detachment threshold and thirty-eight resonances corresponding to the vibrational levels of the DBS. By tuning the detachment laser to these above-threshold resonances, we obtained thirty-eight resonantly-enhanced photoelectron spectra, which were highly non-Franck-Condon as a result of mode-selective vibrational auto-detachment from the DBS. The resonances were assigned by comparing the resonant and non-resonant photoelectron spectra, assisted by the computed vibrational frequencies. Specifically, vibrational features with low Franck-Condon factors or from Franck-Condon-forbidden vibrational modes were significantly enhanced in the resonant photoelectron spectra, resulting in much richer spectroscopic information. The electron affinity of the 2-naphthoxy radical was measured accurately to be 19,387(4) cm -1 or 2.4037(5) eV. In addition, a total of seventeen vibrational frequencies were obtained for the 2-naphthoxy radical. In particular, seven Franck-Condon-forbidden out-of-plane bending modes, including the two lowest frequency modes (ν 48 at 102 cm -1 and ν47 at 171 cm -1 ), were observed, demonstrating the advantages of combining photodetachment spectroscopy and resonant photoelectron spectroscopy in obtaining vibrational information for polar radical species via DBS.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Photomechanical vibration of thin crystals of polar semiconductors

It was found that thin crystals of polar (non-centrosymmetric) semiconductors constitute a new type of photosensitive system in which incident illumination is converted into mechanical energy: thus, illumination-induced elastic deformation (bending) was observed on thin (00.1) CdS and (111) GaAs crystals; furthermore, by employing chopped light the crystals were excited to their resonant vibration (photomechanical vibration); the dependence of the amplitude of this vibration on the energy of the incident radiation was found to be similar to the dependence of the surface photovoltage on the energy of the incident radiation (surface photovoltage spectrum). The present findings are consistent with a model based on light-induced modulation of the piezoelectric surface stresses.

Lagowski, J.↗

Two Mathematical Models of Nonlinear Vibrations

Two innovative mathematical models of nonlinear vibrations, and methods of applying them, have been conceived as byproducts of an effort to develop a Kalman filter for highly precise estimation of bending motions of a large truss structure deployed in outer space from a space-shuttle payload bay. These models are also applicable to modeling and analysis of vibrations in other engineering disciplines, on Earth as well as in outer space.

Brugarolas, Paul↗

Study of T53 engine vibration

Vibration characteristics for overhauled T53 engines, including rejection rate, principal sources of vibration, and normal procedures taken by the overhaul center to reduce engine vibration are summarized. Analytical and experimental data were compared to determine the engine's dynamic response to unbalance forces with results showing that the engine operates through bending critical speeds. Present rigid rotor balancing techniques are incapable of compensating for the flexible rotor unbalance. A comparison of typical test cell and aircraft vibration levels disclosed significant differences in the engine's dynamic response. A probable spline shift phenomenon was uncovered and investigated. Action items to control costs and reduce vibration levels were identified from analytical and experimental studies.

Walter, T. J.↗

Towards complete assignment of the infrared spectrum of the protonated water cluster H + (H 2 O) 21

The spectroscopic features of protonated water species in dilute acid solutions have been long sought after for understanding the microscopic behavior of the proton in water with gas-phase water clusters H + (H 2 O) n extensively studied as bottom-up model systems. We present a new protocol for the calculation of the infrared (IR) spectra of complex systems, which combines the fragment-based Coupled Cluster method and anharmonic vibrational quasi-degenerate perturbation theory, and demonstrate its accuracy towards the complete and accurate assignment of the IR spectrum of the H + (H 2 O) 21 cluster. The site-specific IR spectral signatures reveal two distinct structures for the internal and surface four-coordinated water molecules, which are ice-like and liquid-like, respectively. The effect of inter-molecular interaction between water molecules is addressed, and the vibrational resonance is found between the O-H stretching fundamental and the bending overtone of the nearest neighboring water molecule. The revelation of the spectral signature of the excess proton offers deeper insight into the nature of charge accommodation in the extended hydrogen-bonding network underpinning this aqueous cluster.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Determination of the durability of the fiberoptics in rocket engine environments

The results of a testing program in which selected optical fibers were exposed to extreme environments representative of those experienced on rocket engines are discussed. Included in the experiment are cold-bend testing, a moisture embrittlement test, a thermal cycling test, temperature extremes testing, vibration testing, and shock testing. Two of the fibers selected, the titanium-carbide-coated and the aluminum-jacketed silica samples succeeded in passing all the tests without a failure.

Delcher, R.↗