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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16
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NASA NTRS1986

The clumpy circumstellar medium around young supernova remnants

Each of the youngest supernova remnants known in the Milky Way, Cas A, Kepler's SNR, and Tycho's SNR, shows a different morphological structure caused by different conditions in the progenitor stars and their surroundings. In all three cases, however, the observed shells have a thickness of about 1/4 the radius, a sharp outer edge, and significant brightness irregularities. These features require that the circumstellar medium be highly clumped. To investigate the phenomenon, models of the expansion have been constructed using a one-dimensional spherical hydrodynamic code. As a supernova shock moves down the external density gradient of the star, material behind the shock begins to go into free expansion. Then as surrounding material is encountered a reverse shock moving back into the ejectum will be formed. Until the expansion has swept up about eight times the ejected mass when the situation can be considered as a point explosion in its surroundings, the dynamics are controlled by conditions between the shocks. The region is also where the synchrotron radio emission from relativistic electrons trapped in magnetic fields arises. Initial particles and fields are accelerated and amplified by eddy motion at the interface between the ejected and swept-up material and at the boundaries of clumps. Polarimetry shows that these SNR have a net radial orientation of their magnetic fields apparently from stretching by Rayleigh-Taylor instabilities at the contact surfaces. Without clumps the observed shell is much too narrow and steep on the inside.

Dickel, J. R.↗
NASA NTRS1987

Stability boundaries for command augmentation systems

The Stability Augmentation System (SAS) is a special case of the Command Augmentation System (CAS). Control saturation imposes bounds on achievable commands. The state equilibrium depends only on the open loop dynamics and control deflection. The control magnitude to achieve a desired command equilibrium is independent of the feedback gain. A feedback controller provides the desired response, maintains the system equilibrium under disturbances, but it does not affect the equilibrium values of states and control. The saturation boundaries change with commands, but the location of the equilibrium points in the saturated region remains unchanged. Nonzero command vectors yield saturation boundaries that are asymmetric with respect to the state equilibrium. Except for the saddle point case with MCE control law, the stability boundaries change with commands. For the cases of saddle point and unstable nodes, the region of stability decreases with increasing command magnitudes.

Shrivastava, P. C.↗
NASA NTRS1987

Potential surfaces for O atom-polymer reactions

Ab initio quantum chemistry methods are used to study the energetics of interactions of O atoms with organic compounds. Polyethylene (CH2)n has been chosen as the model system to study the interactions of O(3P) and O(1D) atoms with polymers. In particular, H abstraction is investigated and polyethylene is represented by a C3 (propane) oligomeric model. The gradient method, as implemented in the GRADSCF package of programs, is used to determine the geometries and energies of products and reactants. The saddle point, barrier geometry is determined by minimizing the squares of the gradients of the potential with respect to the internal coordinates. To correctly describe the change in bonding during the reaction at least a two configuration MCSCF (multiconfiguration self consistent field) or GVB (generalized valence bond) wave function has to be used. Basis sets include standard Pople and Dunning sets, however, increased with polarization functions and diffuse p functions on both the C and O atoms. The latter is important due to the O(-) character of the wave function at the saddle point and products. Normal modes and vibrational energy levels are given for the reactants, saddle points and products. Finally, quantitative energetics are obtained by implementing a small CAS (complete active space) approach followed by limited configuration interaction (CI) calculations. Comparisons are made with available experimental data.

Laskowski, B. C.↗
NASA NTRS1986

On the uniqueness of the constrained space orbital variation (CSOV) technique

Several CSOV analyses are performed for the 1Sigma(+) state of NiCO, and it is shown that the importance of the CO sigma donation, Ni pi back donation, and interunit polarizations are virtually independent of the order of the CSOV steps, provided that the open-shell 3d sigma and 4s Ni orbitals are orthogonalized to the CO. This order of orthogonalization is consistent with the polarization of the Ni observed in the unconstrained SCF wavefunction. If instead the CO is orthogonalized to the open-shell Ni orbitals, the frozen orbital repulsion and entire CSOV analysis becomes unphysical. A comparison of the SCF and CAS SCF descriptions for the NiCO 1Sigma(+) state shows the importance of the s to d promotion and sd hybridization in reducing the repulsion and increasing the Ni to CO pi bonding. For LiF, CSOV analyses starting from both the neutral and ionic asymptotes show the bonding to be predominantly Li(+) - F(-). These examples show the uniqueness of the CSOV decomposition.

Bauschlicher, C. W., Jr.↗
NASA NTRS1987

Observations of infrared emission from a fast-moving knot in Cassiopeia A

Broadband (10 microns) and spectroscopic (8.99, 10.52 and 12.81 microns) scans were made of the metal-rich knots in Cas A using instrumentation at the NASA IR Telescope Facility. The observations were performed to distinguish between thermal continuum emission and other features of the metal-rich knots. A faint, forbidden Si IV line was detected, and upper limits were set on the forbidden Ar III and forbidden Ne II emissions, which are now expected to be completely due to lines that may be accessible to the 12 microns sensor on the IRAS. The implications of the measurements for the interpretation of broadband data on metal-rich remnants are discussed.

Dinerstein, Harriet L.↗
NASA NTRS1987

Theoretical D(0) for NH(X3Sigma-)

A value of 3.37 + or - 0.03 eV is recommended for the D(0) of the X3Sigma(-) state of NH. The value of 3.34 eV computed directly from CAS SCF/MRSD CI calculations in a (5s4p3d2f1g/4s3p2d) contracted Gaussian basis has been corrected for basis set incompleteness based on analogous calculations on CH and OH where D(0) is accurately known. Equivalent full CI calculations on the ground states of CH, NH and OH in a (4s3p2d/2s1p) basis provide strong support for the 0.03 eV extrapolation of the D(0) for NH.

Bauschlicher, Charles W., Jr.↗
NASA NTRS1987

Nonvariability of the radial velocity of Eta Cassiopeiae A

Twenty-eight measurements of the radial velocity of the G0 V star Eta Cas A on 14 nights between December 11, 1986, and February 19, 1987 UT (inclusive) were made with an uncertainty per observation between + or - 10 and + or - 20 m/s. The velocity of the star never exceeded 30 m/s from the mean, even though the star was monitored on three occasions for three consecutive nights. The standard deviation of all 28 measurements is + or - 13.7 m/s.

Mcmillan, Robert S.↗
NASA NTRS1987

The infrared diagnostic of a dusty plasma with applications to supernova remnants

IRAS observations of infrared emission from supernova remnants constitute the first observational evidence of shock-heated dust in the interstellar medium. These observations can provide valuable information on the morphology of supernova remnants, and on their interaction with the ambient interstellar medium. In particular, they can be used to study the physical condition and the cooling rate of dusty astrophysical plasmas. In this paper, consideration is given to the possibilities and limitations of using the infrared observations as a diagnostic for the shocked gas, and as a means of determining remnant parameters. The paper presents improved calculations for the cooling rate of a dusty plasma by means of gas-grain collisions, and the equilibrium temperature of the dust for a variety of plasma conditions. These results are then used to define the density-temperature parameter space of the plasma, which, given its infrared spectrum, should be occupied by the observed remnant. This constraint can be used to estimate distances to supernova remnants and to set limits on various parameters that determine their evolution. The analysis is applied to the remnants Cas A and the Cygnus Loop.

Dwek, Eli↗
NASA NTRS1987

Accurate ab initio calculations for the ground states of N2, O2 and F2

Spectroscopic constants and dissociation energies for the ground states of N2, O2, and F2 determined at the CAS SCF MRCI correlation level are in excellent agreement with experiment when very large primitive valence and polarization one-particle Gaussian basis sets are employed. The dissociation energy (De) for N2 is larger than experiment unless the 2s electrons are correlated. The basis set requirement for an accurate determination of De is found to increase with the degree of multiple-bond character in the molecule.

Langhoff, Stephen R.↗
NASA NTRS1988

Radio and optical studies of supernova 1961V in NGC 1058

Radio observations of the Sc galaxy NGC 1058 at 20 cm and 6 cm reveal two radio sources. One of the sources is coincident with supernova 1961V and has a spectral index of -0.4 + or - 0.3. This is the second (and probably the third) detection of radio emission from a supernova decades after optical maximum. The absolute luminosity of SN 1961V at 20 cm is comparable to Cas A. A second source, about 2.3 arcsec to the west, has a spectral index of -0.3 + or - 0.3 and is likely to be the remnant of a supernova that was not optically detected. Optical images of NGC 1058 show two faint H II regions associated with the radio sources. Filter photometry in several bands indicates that these two H II regions are normal with respect to the many optically brighter, albeit radio-quiet, H II regions in NGC 1058.

Cowan, John J.↗
NASA NTRS1985

A survey of chemical information systems

A survey of the features, functions, and characteristics of a fairly wide variety of chemical information storage and retrieval systems currently in operation is given. The types of systems (together with an identification of the specific systems) addressed within this survey are as follows: patents and bibliographies (Derwent's Patent System; IFI Comprehensive Database; PULSAR); pharmacology and toxicology (Chemfile; PAGODE; CBF; HEEDA; NAPRALERT; MAACS); the chemical information system (CAS Chemical Registry System; SANSS; MSSS; CSEARCH; GINA; NMRLIT; CRYST; XTAL; PDSM; CAISF; RTECS Search System; AQUATOX; WDROP; OHMTADS; MLAB; Chemlab); spectra (OCETH; ASTM); crystals (CRYSRC); and physical properties (DETHERM). Summary characteristics and current trends in chemical information systems development are also examined.

Dominick, Wayne D.↗
NASA NTRS1989

X-ray halos around supernova remnants

The results are reported of an Einstein Observatory imaging proportional counter investigation of the X-ray halos of the four brightest young Galactic supernova remnants: the Crab Nebula, Cas A, Tycho's, and Kepler's supernova remnant. It is found that the size, shape, and rough intensity of each of these sources are consistent with the measured properties of the X-ray halos of compact Galactic X-ray sources, and as such are consistent with an origin due solely to the scattering of X-rays by interstellar grains.

Mauche, Christopher W.↗
NASA NTRS1989

A second supernova inside Puppis A?

Narrow-band images of an unusual swirl structure located near the center of the Puppis A supernova remnant are presented which reveal three overlapping filamentary systems of highly diverse composition. One is dominated by emission lines of nitrogen, one by oxygen, and one by sulfur. Spectra indicate that these small rings have high velocities and a corresponding kinematic age of less than 800 yr. Heavy-element abundances are extremely high and different in each system, some reminiscent of knots in Cas A, and others of circumstellar matter observed surrounding supernova 1987A. The youth and unusual chemistry lead to the suggestion that a second supernova has exploded within the shell of Puppis A, giving rise to the swirl structure.

Winkler, P. F.↗
NASA NTRS1989

Theoretical studies of the infrared emission from circumstellar dust shells - The infrared characteristics of circumstellar silicates and the mass-loss rate of oxygen-rich late-type giants

A simple analytic formula and a numerical radiative transfer program have been used to model the IR emission of spherically symmetric circumstellar dust shells in order to determine the IR absorption properties of circumstellar silicate grains and the mass-loss rates of the central stars. The correlation between the near-IR color temperature and the strength of the 10-micron emission or absorption feature is discussed, and it is shown that the near-IR absorption efficiency of circumstellar silicate grains is much higher than is expected from terrestrial minerals, possibly due to the presence of Fe(2+) color centers dissolved in the circumstellar silicates. Detailed models of the IR emission of R Cas, IRC 10011, and OH 26.5+0.6 are presented.

Schutte, W. A.↗
NASA NTRS1989

The chromosphere of Beta Cassiopeiae

High-resolution, long-wavelength IUE observations and ground-based photometry of the Delta Scuti star Beta Cas is reported. The ground-based observations were used together with previous results of Antonello et al. (1986) to ensure that the IUE observations were correctly phased relative to the photometric variation. Fluxes for the emission core of the Mg II k 2796-A line were obtained from the UV spectra over several cycles in 1986 and 1987. It is found that there is an increase in the emission during part of the cycle, but it occurs near minimum light in contrast to another Delta Scuti star, Rho Pup, and the classical Cepheids (where it occurs near maximum light). The mean level of chromospheric activity is comparable to other early F dwarfs.

Teays, Terry J.↗
NASA NTRS1990

A conflict analysis of 4D descent strategies in a metered, multiple-arrival route environment

A conflict analysis was performed on multiple arrival traffic at a typical metered airport. The Flow Management Evaluation Model (FMEM) was used to simulate arrival operations using Denver Stapleton's arrival route structure. Sensitivities of conflict performance to three different 4-D descent strategies (clear-idle Mach/Constant AirSpeed (CAS), constant descent angle Mach/CAS and energy optimal) were examined for three traffic mixes represented by those found at Denver Stapleton, John F. Kennedy and typical en route metering (ERM) airports. The Monte Carlo technique was used to generate simulation entry point times. Analysis results indicate that the clean-idle descent strategy offers the best compromise in overall performance. Performance measures primarily include susceptibility to conflict and conflict severity. Fuel usage performance is extrapolated from previous descent strategy studies.

Izumi, K. H.↗
NASA NTRS1990

The interstellar D1 line at high resolution

Observations at a resolving power or a velocity resolution are reported of the interstellar D(sub 1) line of Na I in the spectra of gamma Cas, delta Ori, epsilon Ori, pi Sco, delta Cyg, and alpha Cyg. An echelle grating was used in a double-pass configuration with a CCD detector in the coude spectrograph of the 2.7 m reflector at McDonald Observatory. At least 42 kinematically distinct clouds are detected along the light paths to the five more distant stars, in addition to a single cloud seen toward delta Cyg. The absorption lines arising in 13 of the clouds are sufficiently narrow and unblended to reveal clearly resolved hyperfine structure components split by 1.05 km/s. An additional 13 clouds apparently show comparably narrow, but more strongly blended, lines. For each individual cloud, upper limits T(sub max) and (v sub t)(sub max) on the temperature and the turbulent velocity, respectively, are derived by fitting the observed lines with theoretical absorption profiles.

Hobbs, L. M.↗
NASA NTRS1990

Pure-oxygen radiative shocks with electron thermal conduction

Steady state radiative shock models in gas composed entirely of oxygen are calculated with the purpose of explaining observations of fast-moving knots in Cas A and other oxygen-rich SNRs. Models with electron thermal conduction differ significantly from models in which conduction is neglected. Conduction reduces postshock electron temperatures by a factor of 7-10 and flattens temperature gradients. The O III ion, whose forbidden emission usually dominates the observed spectra, is present over a wide range of shock velocities, from 100 to 170 km/s. The electron temperature in the O III forbidden line formation region is 30,000 K, in agreement with the 20,000 K derived from observations. All models with conduction have extensive warm (T above 4000 K) photoionization zones, which provides better agreement with observed optical O I line strengths.

Borkowski, Kazimierz J.↗