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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

Options for Martian propellant production

A quantitative evaluation methodology for utilizing in-situ resources on Mars for the production of useful substances. The emphasis is on the chemical processes. Various options considering different feedstock (mostly, carbon dioxide, water, and iron oxides) are carefully examined for the product mix and the energy needs. Oxygen, carbon monoxide, alcohols, and other chemicals are the end products. The chemical processes involve electrolysis, methanation, and variations. It is shown that maximizing the product utility is more important than the production of oxygen, methane, or alcohols. An important factor is the storage of the chemicals produced. The product utility is dependent, to some extent, upon the mission. A combination of the stability, the enthalpy of formation, and the mass fraction of the products is seen to yield a fairly good quantitative feel for the overall utility and maximum mission impact.

Dowler, Warren↗

Nanomaterials for Space Exploration Applications

Nano-engineered materials are multi-functional materials with superior mechanical, thermal and electrical properties. Nanomaterials may be used for a variety of space exploration applications, including ultracapacitors, active/passive thermal management materials, and nanofiltration for water recovery. Additional applications include electrical power/energy storage systems, hybrid systems power generation, advanced proton exchange membrane fuel cells, and air revitalization. The need for nanomaterials and their growth, characterization, processing and space exploration applications is discussed. Data is presented for developing solid-supported amine adsorbents based on carbon nanotube materials and functionalization of nanomaterials is examined.

Moloney, Padraig G.↗

Characterization of Heat Melt Compactor (HMC) Product Water

The Heat Melt Compactor (HMC) is designed to sterilize and process wastes produced during space missions. Benefits of the HMC include reduction of biohazards to the crew, reduction in volume of wastes that would otherwise require storage, production of radiation shielding tiles, and recovery of water and other resources. Water reuse is critical onboard spacecrafts; it reduces the need for resupply missions and saves valuable storage space. The main sources of water in HMC batches are food, beverages, shampoo, disinfecting wipes, toothpaste, and diapers. Water reclaimed by the HMC was analyzed for concentrations of Na+, NH4+, K+, Mg2+, Ca2+, Cl-­‐, NO2-­‐, Br-­‐, NO3-­‐, PO43-­‐, SO42-­‐, total organic carbon (TOC), total inorganic carbon (TIC), % total solids, and pH. The data are discussed in relation to the current water input characteristics established for the International Space Station Water Processor Assembly system. Batches with higher than average amounts of food produced HMC product water with higher sulfate content, and batches with higher proportions of disinfectant wipes and food yielded HMC product water with higher ammonium concentration. We also compared theoretical chemical composition of HMC product water based on food labels and literature values to experimental results.

Heat Melt Compactor↗

Low-cost, focused-science Mars mission

The Mars Orbiter Water Mission (MOWM) is discussed as an example of a low-cost, low-risk focused-science Mars mission which might be implemented in the near term within recently imposed fiscal constraints. MOWM is designed to act as a follow-on to the Viking results in the areas of comparative climatology and water, carbon dioxide and dust inventories. The STS-compatible space vehicle would be based on proven earth-orbiting satellite hardware, fulfilling requirements for both spinning and despun components, operation with nonoptimum solar cell orientation, PAM-A upper stage compatibility, and data storage for delayed transmission. Study results have shown the technical and economic feasibility of missions based on any of four submitted designs which meet these requirements, and of low-cost, well-focused science objective Mars missions in general.

Stuart, J. R.↗

An Advanced Helium Buffer Seal for the SSME, ATD Oxygen Pump

The present configuration of Helium Buffer Seal on the ATD oxygen pump consists of a pair of opposed carbon rings are forced axially against their containment housings. Leakage occurs through the clearance between the rings and the shaft. The total helium leakage through both sides is approximately 239 SCFM. A reduction in leakage to 50 SCFM will result in less helium storage and consequently permit a substantial increase in payload. Under Phase 1 NASA SBIR, a solid T-Ring seal was analyzed and designed that could satisfy the criteria of reducing leakage to 50 SCFM or less. The design makes maximum use of available length and employs a mid length row of hydrostatic orifaces that feed buffer helium directly into a 2 to 3 mil clearance region. The flow splits into opposite paths to buffer oxygen gas on one side and hydrogen gas on the turbine side. The seal employs opposed hydrostatic tapered land secondary seals that provide friction free support of the primary seal and allows the primary seal to follow rotor excursion and maintain concentric operating clearance . The predicted performance of the T-seal is excellent with operation at a safe film thickness of 2 to 2.5 mils and leakage less than 50 SCFM.

Shapiro, Wilbur↗

Interfacial Structure and Capacitance of Li-doped Ionic Liquid Electrolytes from Molecular Simulations

Ionic liquids have been proposed as candidate electrolytes for high-energy density, rechargeable batteries, supercapacitors, and hybrid energy storage devices. Though Li-salt is often present in these systems, its influence on interfacial properties is largely uncharacterized. We, thereby, present an extensive computational analysis, supported by experimental comparisons, of the properties of a representative set of these electrolytesat an ideal carbon interface as a function of Li-salt doping and voltage. We have performed polarizable molecular (MD) dynamics simulations, using the APPLEP force field, to evaluate electric double layer (EDL) capacitance and distribution of Li+ in the EDL. Differential capacitance exhibits the characteristic camel profile and is insensitive to Li-doping. Li+ localizes in the second molecular layer of the EDL, which is a result of confinement from free energy barriers associated with ion layering. Joint MDelectronic structure computations show the electrochemical window of the electrolytes to be a weak function of Li-doping. Estimates of supercapacitor specific energy are made using the computed window and capacitance. The magnitude and trends in specific energy are in good agreement with experiment.

batteries↗

Quantifying Grassland-to-Woodland Transitions and the Implications for Carbon and Nitrogen Dynamics in the Southwest United States

Replacement of grasslands and savannas by shrublands and woodlands has been widely reported in tropical, temperate and high-latitude rangelands worldwide (Archer 1994). These changes in vegetation structure may reflect historical shifts in climate and land use; and are likely to influence biodiversity, productivity, above- and below ground carbon and nitrogen sequestration and biophysical aspects of land surface-atmosphere interactions. The goal of our proposed research is to investigate how changes in the relative abundance of herbaceous and woody vegetation affect carbon and nitrogen dynamics across heterogeneous savannas and shrub/woodlands. By linking actual land-cover composition (derived through spectral mixture analysis of AVIRIS, TM, and AVHRR imagery) with a process-based ecosystem model, we will generate explicit predictions of the C and N storage in plants and soils resulting from changes in vegetation structure. Our specific objectives will be to (1) continue development and test applications of spectral mixture analysis across grassland-to-woodland transitions; (2) quantify temporal changes in plant and soil C and N storage and turnover for remote sensing and process model parameterization and verification; and (3) couple landscape fraction maps to an ecosystem simulation model to observe biogeochemical dynamics under changing landscape structure and climatological forcings.

Wessman, Carol A.↗

Prokaryotic and Fungal Characterization of the Facilities Used to Assemble, Test, and Launch the OSIRIS-REx Spacecraft

To characterize the ATLO (Assembly, Test, and Launch Operations) environment of the OSIRIS-REx spacecraft, we analyzed 17 aluminum witness foils and two blanks for bacterial, archaeal, fungal, and arthropod DNA. Under NASA’s Planetary Protection guidelines, OSIRIS-REx is a Category II outbound, Category V unrestricted sample return mission. As a result, it has no bioburden restrictions. However, the mission does have strict organic contamination requirements to achieve its primary objective of returning pristine carbonaceous asteroid regolith to Earth. Its target, near-Earth asteroid (101955) Bennu, is likely to contain organic compounds that are biologically available. Therefore, it is useful to understand what organisms were present during ATLO as part of the larger contamination knowledge effort—even though it is unlikely that any of the organisms will survive the multi-year deep space journey. Even though these samples of opportunity were not collected or preserved for DNA analysis, we successfully amplified bacterial and archaeal DNA (16S rRNA gene) from 16 of the 17 witness foils containing as few as 7 ± 3 cells per sample. Fungal DNA (ITS1) was detected in 12 of the 17 witness foils. Despite observing arthropods in some of the ATLO facilities, arthropod DNA (COI gene) was not detected. We observed 1,009 bacterial and archaeal sOTUs (sub-operational taxonomic units, 100% unique) and 167 fungal sOTUs across all of our samples (25–84 sOTUs per sample). The most abundant bacterial sOTU belonged to the genus Bacillus. This sOTU was present in blanks and may represent contamination during sample handling or storage. The sample collected from inside the fairing just prior to launch contained several unique bacterial and fungal sOTUs that describe previously uncharacterized potential for contamination during the final phase of ATLO. Additionally, fungal richness (number of sOTUs) negatively correlates with the number of carbon-bearing particles detected on samples. The total number of fungal sequences positively correlates with total amino acid concentration. These results demonstrate that it is possible to use samples of opportunity to characterize the microbiology of low-biomass environments while also revealing the limitations imposed by sample collection and preservation methods not specifically designed with biology in mind.

Aaron B. Regberg↗

Production of gaseous fuel by pyrolysis of municipal solid waste

Pilot plant tests were conducted on a simulated solid waste which was a mixture of shredded newspaper, wood waste, polyethylene plastics, crushed glass, steel turnings, and water. Tests were conducted at 1400 F in a lead-bath pyrolyser. Cold feed was deaerated by compression and was dropped onto a moving hearth of molten lead before being transported to a sealed storage container. About 80 percent of the feed's organic content was converted to gaseous products which contain over 90 percent of the potential waste energy; 12 percent was converted to water; and 8 percent remained as partially pyrolyzed char and tars. Nearly half of the carbon in the feed is converted to benzene, toluene and medium-quality fuel gas, a potential credit of over $25 per ton of solid waste. The system was shown to require minimal preprocessing and less sorting then other methods.

Crane, T. H.↗

Testing balloon gas

In the generation, storage, and use of hydrogen for balloon purposes it is necessary to be able to determine, first, its lifting power, and, secondly, its purity. The lifting power may be determined directly from the specific gravity. Contamination by other gases may be determined by analysis for oxygen, carbon dioxide, etc., by the usual methods of gas analysis. The determination of oxygen is important, since the presence of oxygen in amounts beyond certain limits will make the compressing, handling, and use of the gas hazardous. If the specific gravity of the gas is known, however, it may not be necessary to analyze the gas for oxygen and other gases, because the specific gravity in itself is a delicate criterion of the purity of hydrogen. Report describes a simple, portable apparatus for testing hydrogen, with special reference to its use in balloons.

Edwards, Junius David↗

Merging IceSAT GLAS and Terra MODIS Data in Order to Derive Forest Type Specific Tree Heights in the Central Siberian Boreal Forest

Mapping of boreal forest's type, biomass, and other structural parameters are critical for understanding of the boreal forest's significance in the carbon cycle, its response to and impact on global climate change. We believe the nature of the forest structure information available from MISR and GLAS can be used to help identify forest type, age class, and estimate above ground biomass levels beyond that now possible with MODIS alone. The ground measurements will be used to develop relationships between remote sensing observables and forest characteristics and provide new information for understanding forest changes with respect to environmental change. Lidar is a laser altimeter that determines the distance from the instrument to the physical surface by measuring the time elapsed between the pulse emission and the reflected return. Other studies have shown that the returned signal may identify multiple returns originating from trees, building and other objects and permits the calculation of their height. Studies using field data have shown that lidar data can provide estimates of structural parameters such as biomass, stand volume and leaf area index and allows remarkable differentiation between primary and secondary forest. NASA's IceSAT Geoscience Laser Altimeter System (GLAS) was launched in January 2003 and collected data during February and September of that year. This study used data acquired over our study sites in central Siberia to examine the GLAS signal as a source of forest height and other structural characteristics. The purpose of our Siberia project is to improve forest cover maps and produce above-ground biomass maps of the boreal forest in Northern Eurasia from MODIS by incorporating structural information inherent in the Terra MISR and ICESAT Geoscience Laser Altimeter System (GLAS) instruments. A number of forest cover classifications exist for the boreal forest. We believe the limiting factor in these products is the lack of structural information, particularly in the vertical dimension. The emphasis of this project is to improve upon satellite maps of boreal forest structure parameters (i.e. height and biomass) using temporal, multi-angle, and vertical profile information of GLAS data. The existing and near future lidar data is useful for demonstrating these techniques and pursuing current estimates. Future lidar missions may be several years in the future, so we will work other new data sets that may aide in biomass estimates such as ALOS PALSAR We will continue this work to produce an accurate map of current above ground forest phytomass/carbon storage possible for the study area. We plan to develop, test, and integrate remote sensing methods for extracting forest canopy structure measures. We are compiling our field measurements and will compare them with the remote sensing methods where possible. We also be able to produce a realistic error bound on the remotely sensed carbon estimates.

Ranson, K. Jon↗

Physical-Chemical Solid Waste Processing for Space Missions at Ames Research Center

As space missions become longer in duration and reach out to more distant locations such as Mars, solids waste processing progresses from storage technologies to reclamation technologies. Current low Earth orbit technologies consist of store-and dispose to space or return to Earth. Fully regenerative technologies recycle wastes. The materials reclaimed from waste can be used to provide the basic materials to support plant growth for food including carbon dioxide, water, and nutrients. Other products can also be reclaimed from waste such as hydrocarbons and activated carbon. This poster describes development at Ames Research Center of a process to make activated carbon from space mission wastes and to make an incineration system that produces clean flue gas. Inedible biomass and feces contain hydrocarbons in a form that can be pyrolyzed and converted to activated carbon. The activated carbon can then be used to clean up contaminants from various other life support systems; in particular, the activated carbon can be used regeneratively to remove NOx from incinerator flue gas. Incinerator flue gas can also be cleaned up by the use of reductive and oxidative catalysts. A catalytic incinerator flue gas cleanup system has been developed at ARC that produces flue gas clean enough (with the exception of carbon dioxide) to meet the Space Minimum Allowable Concentration limits for human exposure.

Fisher, John W.↗

Assessment of Service Life for Regenerative ECLSS Resin Beds

The International Space Station (ISS) Water Processor Assembly (WPA) and Oxygen Generation Assembly (OGA) manage and process water at various levels of cleanliness for multiple purposes. The effluent of theWPA and the influent of the OGA require water at very high levels of purity. The bulk of the water purification that occurs in both systems is performed by consumable activated carbon and ion exchange resin beds. Replacement beds must be available on orbit in order to continue the ISS critical processes of water purification and oxygen generation. Various hurdles exist in order to ensure viable spare resin beds. These include the characteristics of resin beds such as: storage environment, shelf life requirements, microbial growth, and variations in the levels and species of contaminants the beds are required to remove. Careful consideration has been given to match water models, bed capacities and spares traffic models to ensure that spares are always viable. The results of these studies and considerations, in particular, how shelf life requirements affect resin bed life management, are documented in this paper.

Cloud, Dale L.↗

Converging Climate Sensitivities of European Forests Between Observed Radial Tree Growth and Vegetation Models

The impacts of climate variability and trends on European forests are unevenly distributed across different bioclimatic zones and species. Extreme climate events are also becoming more frequent and it is unknown how they will affect feed backs of CO2 between forest ecosystems and the atmosphere. An improved understanding of species differences at the regional scale of the response of forest productivity to climate variation and extremes is thus important for forecasting forest dynamics. In this study, we evaluate the climate sensitivity of above ground net primary production (NPP) simulated by two dynamic global vegetation models (DGVM; ORCHIDEE and LPJ-wsl) against tree ring width (TRW) observations from about1000 sites distributed across Europe. In both the model simulations and the TRW observations, forests in northern Europe and the Alps respond positively to warmer spring and summer temperature, and their overall temperature sensitivity is larger than that of the soil-moisture-limited forests in central Europe and Mediterranean regions. Compared with TRW observations, simulated NPP from ORCHIDEE and LPJ-wsl appear to be overly sensitive to climatic factors. Our results indicate that the models lack biological processes that control time lags, such as carbohydrate storage and remobilization, that delay the effects of radial growth dynamics to climate. Our study highlights the need for re-evaluating the physiological controls on the climate sensitivity of NPP simulated by DGVMs. In particular, DGVMs could be further enhanced by a more detailed representation of carbon reserves and allocation that control year-to year variation in plant growth.

Zhang, Zhen↗

Optimization of thermal protection systems for the space shuttle vehicle. Volume 1: Final report

A study performed to continue development of computational techniques for the Space Shuttle Thermal Protection System is reported. The resulting computer code was used to perform some additional optimization studies on several TPS configurations. The program was developed in Fortran 4 for the CDC 6400, and it was converted to Fortran 5 to be used for the Univac 1108. The computational methodology is developed in modular fashion to facilitate changes and updating of the techniques and to allow overlaying the computer code to fit into approximately 131,000 octal words of core storage. The program logic involves subroutines which handle input and output of information between computer and user, thermodynamic stress, dynamic, and weight/estimate analyses of a variety of panel configurations. These include metallic, ablative, RSI (with and without an underlying phase change material), and a thermodynamic analysis only of carbon-carbon systems applied to the leading edge and flat cover panels. Two different thermodynamic analyses are used. The first is a two-dimensional, explicit precedure with variable time steps which is used to describe the behavior of metallic and carbon-carbon leading edges. The second is a one-dimensional implicity technique used to predict temperature in the charring ablator and the noncharring RSI. The latter analysis is performed simply by suppressing the chemical reactions and pyrolysis of the TPS material.

Source record↗

Potential propellant storage and feed systems for space station resistojet propulsion options

The resistojet system has been defined as part of the baseline propulsion system for the initial Operating Capability Space Station. The resistojet propulsion module will perform a reboost function using a wide variety of fluids as propellants. There are many optional propellants and propellant combinations for use in the resistojet including (but not limited to): hydrazine, hydrogen, oxygen, nitrogen, water, carbon dioxide, and methane. Many different types of propulsion systems have flown or have been conceptualized that may have application for use with resistojets. This paper describes and compares representative examples of these systems that may provide a basis for space station resistojet system design.

Bader, Clayton H.↗

A Revolution in the Making: Advances in Materials That May Transform Future Exploration Infrastructures and Missions

The NASA Strategic Plan identifies the long-term goal to provide safe and affordable space access, orbital transfer, and interplanetary transportation capabilities to enable research, human exploration, and the commercial development of space; and to conduct human and robotic missions to planets and other bodies in our solar system. Numerous scientific and engineering breakthroughs will be required to develop the technology necessary to achieve this goal. Critical technologies include advanced vehicle primary and secondary structure, radiation protection, propulsion and power systems, fuel storage, electronics and devices, sensors and science instruments, and medical diagnostics and treatment. Advanced materials with revolutionary new capabilities are an essential element of each of these technologies. This paper discusses those materials best suited for aerospace vehicle structure and highlights the enormous potential of one revolutionary new material, carbon nanotubes.

Harris, Charles E.↗

Long term variability of transmission of thin In-Sn and Sn-C films for EUV instrumentation

The transmission variability is reported for two filters in the EUV, where the filters were supported on an 80% transmission nickel mesh and fabricated by means of a vacuum deposition technique. The first film consisted of 2500 A-thick indium, deposited on 500 A-thick tin, and had its primary bandpass in the 740-960 A range. The second consisted of 1800 A-thick tin and 2000 A-thick carbon, with a bandpass of 500-750 A. At the end of 10 months, the transmission of both filters was measured to check variations. It is demonstrated that the EUV transmission of such filters can change over the typical lifetime of satellite missions, and that such variation depends on the storage environment. The use of vacuum, rather than dry nitrogen storage is recommended.

Chakrabarti, S.↗