SEARCH · Search NASA

Results for “Chemical Engineering”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 289 records · Page 16

All sources NASA NTRS DOE OSTI

NASA NTRS2007

RESOLVE - Starting Point for Partnerships in Lunar and Mars Resource Characterization

The mystery and controversy surrounding the possibility of finding water/ice at the lunar poles of the Moon based on the interpretation of neutron spectrometer data from Lunar Prospector and radar data from Clementine raises questions that both Science and the Human Exploration proponents want answered. From the Science perspective, the determination of lunar volatiles and in particular the increased hydrogen concentration detected at the lunar poles was identified as an important objectives for lunar exploration and understanding the history of the Moon, Sun, and the solar system. From the Human Exploration perspective, the potential for large concentrations of accessible water opens up possibilities for utilizing in-situ resources, known as In-Situ Resource Utilization (ISRU), to implement a sustained and affordable human exploration program of the Moon and beyond through production of propellants, fuel cell reagents, and life support consumables for lunar surface operations and mobility, and Earth-Moon transportation. Both the Science and Human Exploration proponents agree that a mission to the lunar poles to obtain ground truth data is the only means to conclusively answer the questions of whether water/ice exists, how much, what form, and where did it come from. In 2005, NASA initiated the Regolith and Environment Science & Oxygen and Lunar Volatiles Extraction (RESOLVE) project, and is currently developing hardware under the NASA Exploration Technology Development Program (ETDP). The purpose of the project was to begin developing technologies and operations that would answer the fundamental science questions, such as What resources are available on the Moon, where are they, what form, and where did they come from? as well as critical engineering questions, such as How will we mine these resources, what chemical extraction processes are the most practical and efficient, and what are the engineering challenges to be faced in this environment? .

Sanders, Gerald B.↗

NASA NTRS1973

Research in the aerospace physical sciences

Research efforts are reported in various areas including dynamics of thin films, polymer chemistry, mechanical and chemical properties of materials, radar system engineering, stabilization of lasers, and radiation damage of organic crystals. Brief summaries of research accomplished and literature citations are included.

Whitehurst, R. N.↗

NASA NTRS1973

On the Design and Test of a Liquid Injection Electric Thruster

A liquid injection electric thruster (LINJET) was designed and tested. The results of the tests were very encouraging with thruster performance levels well in excess of design goals. Supporting activities to the engine design and test included a five-million pulse life test on the main capacitor, a 46-million pulse test on the trigger electronics, design and fabrication of a zero resistance torque connector for use with the torsional pendulum thrust stand, design and fabrication of a logic box for control of engine firing, and a physical and chemical properties characterization of the perfluorocarbon propellant. While the results were encouraging, testing was limited, as many problems existed with the design. The most significant problem was involved with excessive propellant flow which contributed to false triggering and shorting. Low power active thermal control of the propellant storage cavity, coupled with a re-evaluation of the injection ring pore size and area exposed to the main capacitor discharge are areas that should be investigated should this design be carried forward.

Jones, T. A.↗

NASA NTRS1977

Site Alteration Effects from Rocket Exhaust Impingement During a Simulated Viking Mars Landing. Part 2: Chemical and Biological Site Alteration

Chemical and biological alteration of a Mars landing site was investigated experimentally and analytically. The experimental testing was conducted using a specially designed multiple nozzle configuration consisting of 18 small bell nozzles. The chemical test results indicate that an engine using standard hydrazine fuel will contaminate the landing site with ammonia (50-500ppm), nitrogen (5-50ppm), aniline (0.01-0.5ppm), hydrogen cyanide (0.01-0.5ppm), and water. A purified fuel, with impurities (mostly aniline) reduced by a factor of 50-100, limits the amount of hydrogen cyanide and aniline to below detectable limits for the Viking science investigations and leaves the amounts of ammonia, nitrogen, and water in the soil unchanged. The large amounts of ammonia trapped in the soil will make interpretation of the organic analysis investigation results more difficult. The biological tests indicate that the combined effects of plume gases, surface heating, surface erosion, and gas composition resulting from the retrorockets will not interfere with the Viking biology investigation.

Husted, R. R.↗

NASA NTRS1978

An assessment of the effect of supersonic aircraft operations on the stratospheric ozone content

An assessment of the potential effect on stratospheric ozone of an advanced supersonic transport operations is presented. This assessment, which was undertaken because of NASA's desire for an up-to-date evaluation to guide programs for the development of supersonic technology and improved aircraft engine designs, uses the most recent chemical reaction rate data. From the results of the present assessment it would appear that realistic fleet sizes should not cause concern with regard to the depletion of the total ozone overburden. For example, the NOx emission of one type designed to cruise at 20 km altitude will cause the ozone overburden to increase by 0.03% to 0.12%, depending upon which vertical transport is used. These ozone changes can be compared with the predictions of a 1.74% ozone decrease (for 100 Large SST's flying at 20 km) made in 1974 by the FAA's Climatic Impact Assessment Program.

Poppoff, I. G.↗

NASA NTRS1984

Tribological applications of surface analysis

For some years, surface analysis was used in fundamental studies of solid-solid contacts existing in tribological systems. Analysis was used to detect material transfer in sliding contacts. The effects of surface films on the adhesion of contacts was monitored. Finally electron spectroscopic analysis of interfaces has shed some light on the fundamental electronic nature of the interfacial bond. More recently, surface analysis was applied to many tribological engineering problems. In particular, identification of chemical films formed during the sliding contact of lubricated systems and study of the surface chemistry of lubricant additives were active areas of research. One or more of four properties of the analytical technique will be important in determining its utility. The four are: lateral resolution, specimen damage, depth resolution and the availability of chemical information. In each of the applications discussed here, the important factors are brought out.

Wheeler, D. R.↗

NASA NTRS1992

Program For Simulation Of Trajectories And Events

Universal Simulation Executive (USE) program accelerates and eases generation of application programs for numerical simulation of continuous trajectories interrupted by or containing discrete events. Developed for simulation of multiple spacecraft trajectories with events as one spacecraft crossing the equator, two spacecraft meeting or parting, or firing rocket engine. USE also simulates operation of chemical batch processing factory. Written in Ada.

Gottlieb, Robert G.↗

NASA NTRS1991

Catalysis and biocatalysis program

The annual report presents the fiscal year (FY) 1990 research activities and accomplishments for the Catalysis and Biocatalysis Program of the Advanced Industrial Concepts Division (AICD), Office of Industrial Technologies of the Department of Energy (DOE). The mission of the AICD is to create a balanced program of high risk, long term, directed interdisciplinary research and development that will improve energy efficiency and enhance fuel flexibility in the industrial sector. The Catalysis and Biocatalysis Program's technical activities were organized into five work elements: the Molecular Modeling and Catalysis by Design element; the Applied Microbiology and Genetics element; the Bioprocess Engineering element; the Separations and Novel Chemical Processes element; and the Process Design and Analysis element.

Source record↗

NASA NTRS1992

Engineering design constraints of the lunar surface environment

Living and working on the lunar surface will be difficult. Design of habitats, machines, tools, and operational scenarios in order to allow maximum flexibility in human activity will require paying attention to certain constraints imposed by conditions at the surface and the characteristics of lunar material. Primary design drivers for habitat, crew health and safety, and crew equipment are: ionizing radiation, the meteoroid flux, and the thermal environment. Secondary constraints for engineering derive from: the physical and chemical properties of lunar surface materials, rock distributions and regolith thicknesses, topography, electromagnetic properties, and seismicity. Protection from ionizing radiation is essential for crew health and safety. The total dose acquired by a crew member will be the sum of the dose acquired during EVA time (when shielding will be least) plus the dose acquired during time spent in the habitat (when shielding will be maximum). Minimizing the dose acquired in the habitat extends the time allowable for EVA's before a dose limit is reached. Habitat shielding is enabling, and higher precision in predicting secondary fluxes produced in shielding material would be desirable. Means for minimizing dose during a solar flare event while on extended EVA will be essential. Early warning of the onset of flare activity (at least a half-hour is feasible) will dictate the time available to take mitigating steps. Warning capability affects design of rovers (or rover tools) and site layout. Uncertainty in solar flare timing is a design constraint that points to the need for quickly accessible or constructible safe havens.

Morrison, D. A.↗

NASA NTRS1993

Evaluation of the Munich Method for modeling rocket engine performance

A new procedure, dubbed the Munich Method, has been proposed recently for the modeling of rocket engine performance. The author of the Munich Method claims it to be an extension and improvement of the thermodynamic procedures used to model rocket engines in the NASA-Lewis chemical equilibrium program. An examination of the Munich Method shows that it contains several flaws. If these defects are corrected then the Munich Method will produce results identical to those generated by the NASA-Lewis Code.

Zeleznik, Frank J.↗

NASA NTRS1951

Theoretical performance of lithium and fluorine as a rocket propellant

Theoretical performance for liquid lithium and liquid fluorine as a rocket propellant was calculated with assumptions both of equilibrium and frozen composition during expansion. Parameters included were specific impulse, combustion-chamber temperature, nozzle-exit temperature, composition, mean molecular weight, characteristic velocity, coefficient of thrust, and ratio of nozzle-exit area to throat area. For chamber pressure of 300 pounds per square inch absolute and expansion to 1 atmosphere, the maximum equilibrium specific impulse calculated was 335.5 pound-seconds per pound. The effect of ionization on calculated performance was shown to be negligible by comparison of values of various parameters calculated both with and without ionized products of combustion.

FUELS -ROCKETS (INCLUDES FUELS AND OXIDANT)↗

NASA NTRS1954

Study of the physical properties of petrolatum-stabilized magnesium-hydrocarbon slurry fuels

Magnesium-hydrocarbon slurries containing a moderate proportion of petrolatum have physical properties such that they offer promise as experimental aircraft fuels. The settling of the magnesium is greatly retarded by the petrolatum, and the slurries can easily be remixed to their original condition after storage. Successive batches which have closely similar properties can be prepared readily. The apparent viscosity of these slurries increased rapidly with increasing magnesium concentration, with increasing petrolatum concentration, and with decreasing temperature. As the apparent viscosity increased, the extent of settling and the ease of remixing both decreased. Although no quantitative correlation was found between the properties of the slurry and those of the petrolatum, and no one petrolatum gave slurries which were best in all respects, one of the five petrolatum used was judged to be superior to the others.

FUELS - PROPERTIES, PHYSICAL AND CHEMICAL↗

NASA NTRS1996

Inlet and Propulsion Integration of Scram Propelled Vehicles

The material to be presented in these two lectures begins with cycle considerations of the turbojet engine combined with a ramjet engine to provide thrust over the range of Mach 0 to 5. We will then examine in some detail the aerodynamic behavior that occurs in the inlet operating near the peak speed. Following that, we shall view a numerical simulation through a baseline scramjet engine, starting at the entrance to the inlet, proceeding into the combustor and through the nozzle. In the next segment, we examine a combined rocket and ramjet propulsion system. Analysis and test results will be examined with a view toward evaluation of the concept as a practical device. Two other inlets will then be reviewed: a Mach 12 inlet and a Mach 18 configuration. Finally, we close our lectures with a discussion of the Detonation Wave engine, and inspect the physical and chemical behavior obtained from numerical simulation. A few final remarks will be made regarding the application of CFD for hypersonic propulsion components.

Povinelli, Louis A.↗

NASA NTRS1999

Novel optical methodologies in studying mechanical signal transduction in mammalian cells

For the last 3 decades evidence has been accumulating that some types of mammalian cells respond to their mechanically active environment by altering their morphology, growth rate, and metabolism. The study of such responses is very important in understanding, physiological and pathological conditions ranging from bone formation to atherosclerosis. Obtaining this knowledge has been the goal for an active research area in bioengineering termed cell mechanotransduction. The advancement of optical methodologies used in cell biology research has given the tools to elucidate cellular mechanisms that would otherwise be impossible to visualize. Combined with molecular biology techniques, they give engineers invaluable tools in understanding the chemical pathways involved in mechanotransduction. Herein we briefly review the current knowledge on mechanical signal transduction in mammalian cells, focusing on the application of novel optical techniques in the ongoing research.

NASA Discipline Cell Biology↗

NASA NTRS2005

Non-contact Creep Resistance Measurement for Ultra-high temperature Materials

Continuing pressures for higher performance and efficiency in propulsion are driving ever more demanding needs for high-temperature materials. Some immediate applications in spaceflight include combustion chambers for advanced chemical rockets and turbomachinery for jet engines and power conversion in nuclear-electric propulsion. In the case of rockets, the combination of high stresses and high temperatures make the characterization of creep properties very important. Creep is even more important in the turbomachinery, where a long service life is an additional constraint. Some very high-temperature materials are being developed, including platinum group metals, carbides, borides, and silicides. But the measurement of creep properties at very high temperatures is itself problematic, because the testing instrument must operate at such high temperatures. Conventional techniques are limited to about 1700 C. A new, containerless technique for measuring creep deformation has been developed. This technique is based on electrostatic levitation (ESL) of a spherical sample, which is heated to the measurement temperature and rotated at a rate such that the centrifugal acceleration causes creep deformation. Creep of samples has been demonstrated at up to 2300 C in the ESL facility at NASA MSFC, while ESL itself has been applied at over 3000 C, and has no theoretical maximum temperature. The preliminary results and future directions of this NASA-funded research collaboration will be presented.

Hyers, Robert W.↗

NASA NTRS2005

Hydrogen Sensors Boost Hybrids; Today's Models Losing Gas?

Advanced chemical sensors are used in aeronautic and space applications to provide safety monitoring, emission monitoring, and fire detection. In order to fully do their jobs, these sensors must be able to operate in a range of environments. NASA has developed sensor technologies addressing these needs with the intent of improving safety, optimizing combustion efficiencies, and controlling emissions. On the ground, the chemical sensors were developed by NASA engineers to detect potential hydrogen leaks during Space Shuttle launch operations. The Space Shuttle uses a combination of hydrogen and oxygen as fuel for its main engines. Liquid hydrogen is pumped to the external tank from a storage tank located several hundred feet away. Any hydrogen leak could potentially result in a hydrogen fire, which is invisible to the naked eye. It is important to detect the presence of a hydrogen fire in order to prevent a major accident. In the air, the same hydrogen-leak dangers are present. Stress and temperature changes can cause tiny cracks or holes to form in the tubes that line the Space Shuttle s main engine nozzle. Such defects could allow the hydrogen that is pumped through the nozzle during firing to escape. Responding to the challenges associated with pinpointing hydrogen leaks, NASA endeavored to improve propellant leak-detection capabilities during assembly, pre-launch operations, and flight. The objective was to reduce the operational cost of assembling and maintaining hydrogen delivery systems with automated detection systems. In particular, efforts have been focused on developing an automated hydrogen leak-detection system using multiple, networked hydrogen sensors that are operable in harsh conditions.

Source record↗

NASA NTRS2010

Integrated System Health Management (ISHM) Implementation in Rocket Engine Testing

A pilot operational ISHM capability has been implemented for the E-2 Rocket Engine Test Stand (RETS) and a Chemical Steam Generator (CSG) test article at NASA Stennis Space Center. The implementation currently includes an ISHM computer and a large display in the control room. The paper will address the overall approach, tools, and requirements. It will also address the infrastructure and architecture. Specific anomaly detection algorithms will be discussed regarding leak detection and diagnostics, valve validation, and sensor validation. It will also describe development and use of a Health Assessment Database System (HADS) as a repository for measurements, health, configuration, and knowledge related to a system with ISHM capability. It will conclude with a discussion of user interfaces, and a description of the operation of the ISHM system prior, during, and after testing.

Figueroa, Fernando↗

NASA NTRSDate not supplied

Supercritical Water Oxidation (SCWO) for the treatment of spacecraft waste.

Supercritical water oxidation (SCWO) is a powerful waste treatment that has been considered as a substitute or complement to other potential spacecraft waste handling methods including jettisoning, compacted sealed storage, drying, and others. Combustible trash and garbage is mixed with water and then heated and pressurized above the critical point of water (705 °F and 218 atmospheres). The waste is nearly all oxidized to produce carbon dioxide, water and nitrogen. NOx is not formed. The combustion energy can be used to heat the input stream. SCWO is relatively complex, expensive, and hazardous compared to other methods. Oxidation of compounds containing chlorine and sulfur produces hydrochloric and sulfuric acid which can cause corrosion in the reactor. Neutralizing these acids produces salts which can precipitate and cause clogging. The major engineering challenges to implementing SCWO are chemical corrosion and fouling due to the deposition of salts. SCWO was first proposed for general waste treatment and for spacecraft in the 1980’s and extensive research has been carried out.

Harry W Jones↗