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At least 289 records · Page 16

Efficiency of silicon solar cells containing chromium

Efficiency of silicon solar cells containing about one quadrillon atoms cu cm of chromium is improved about 26% by thermal annealing of the silicon wafer at a temperature of 200 C to form chromium precipitates having a diameter of less than 1 Angstrom. Further improvement in efficiency is achieved by scribing laser lines onto the back surface of the wafer at a spacing of at least 0.5 mm and at a depth of less than 13 micrometers to preferentially precipitate chromium near the back surface and away from the junction region of the device. This provides an economical way to improve the deleterious effects of chromium, one of the impurities present in metallurgical grade silicon mateial.

Salama, A. M.↗

Phase partitioning, crystal growth, electrodeposition and cosmic ray experiments in microgravity

Five experiments are contained in one Get Away Special Canister (5 cu ft). The first utilizes microgravity to separate biological cells and to study the mechanism of phase partitioning in 12 separate cuvettes. Two experiments are designed to grow organic crystals by physical vapor transport. One experiment consists of eight electroplating cells with various chemicals to produce surfaces electroplated in microgravity. Some of the surfaces have micron sized particles of hard materials co-deposited during electrodeposition. The fifth experiment intercepts cosmic ray particles and records their paths on photographic emulsions. The first four experiments are controlled by an on-board C-MOS controller. The fifth experiment is totally passive. These are the first in Space. Their purpose is to create new commercial products with microgravity processing.

Wessling, Francis C.↗

Reaction of nonaqueous halogen solutions with YBa2Cu3O(7-x)

The reaction of the surfaces of the new high-temperature superconductor YBa2Cu3O(7-x) with nonaqueous halogen solutions is investigated, and the species formed in the reactions are identified. Treatment of films with HF/EtOH (EtOH = HI in absolute ethanol) results in the formation of an oxyfluoride with Y:Ba:Cu relative concentrations of 1:4:3. Results of X-ray photoelectron spectroscopy of HF-treated films are consistent with the formation of CuF, a compound which does not exist in bulk form. Treatment of films with HCl/EtOH results primarily in the formation of BaCl2, with smaller amounts of YCl3, CuCl, and CuCl2. Treatment with Br2/EtOH or HBr/EtOH results in the formation of YBr3, BaBr2, and CuBr with relative concentrations of 1:4:3.

Vasquez, R. P.↗

Metallic Foams

The formation of metallic foams by use of a blowing agent in the melt was investigated. It was attempted to produce a metallic foam by melting a mixture of Cu powder and graphite in a SPAR rocket. The graphite combines with the oxide on the copper to form Co and acts as a blowing agent. No foam was formed, and it could not be determined whether the foam fails to form, forms but was lost to surface tension instabilities, or is destroyed by incomplete solidification before reentry.

Pond, R. B.↗

Superconductivity applications for infrared and microwave devices II; Proceedings of the Meeting, Orlando, FL, Apr. 4, 5, 1991

Topics discussed include thin-film technology, microwave transmission lines and resonators, microwave devices and circuits, infrared detectors and bolometers, and superconducting junctions. Papers are presented on possible enhancement in bolometric response using free-standing film of YBa2Cu3O(x), aging and surface instability in high-Tc superconductors, epitaxial Tl2Ba2CaCu2O8 thin films on LaAlO3 and their microwave device properties, the performance of stripline resonators using sputtered YBCO films, and a coplanar waveguide microwave filter of YBa2Cu3O7. Attention is also given to the performance characteristics of Y-Ba-Cu-O microwave superconducting detectors, high-Tc bolometer developments for planetary missions, infrared detectors from YBaCuO thin films, high-temperature superconductor junction technology, and submillimeter receiver components using superconducting tunnel junctions.

Heinen, Vernon O.↗

Active Flow Separation Control on a NACA 0015 Wing Using Fluidic Actuators

Results are presented from a recent set of wind tunnel experiments using sweeping jet actuators to control ow separation on the 30% chord trailing edge ap of a 30 deg. swept wing model with an aspect ratio (AR) of 4.35. Two sweeping jet actuator locations were examined, one on the flap shoulder and one on the trailing edge flap. The parameters that were varied included actuator momentum, freestream velocity, and trailing edge flap deflection (Delta f ) angle. The primary focus of this set of experiments was to determine the mass flow and momentum requirements for controlling separation on the flap, especially at large flap deflection angles which would be characteristic of a high lift system. Surface pressure data, force and moment data, and stereoscopic particle image velocimetry (PIV) data were acquired to evaluate the performance benefits due to applying active flow control. Improvements in lift over the majority of the wing span were obtained using sweeping jet actuator control. High momentum coefficient, Cu, levels were needed when using the actuators on the ap because they were located downstream of separation. Actuators on the flap shoulder performed slightly better but actuator size, orientation, and spacing still need to be optimized.

Melton, Latunia P.↗

Transmutations Observed from Pressure Cycling Palladium Silver Metals with Deuterium Gas

Hydrogen, deuterium, and helium gases were separately cycled through a Johnson-Mattheypurifier containing coiled palladium silver alloy tubing: Pd25Ag (75 wt% Pd and 25 wt% Ag).During the cycling of D2 gas, evidence of anomalous heat production was observed. However,during the cycling of H2 and He,very little (H2) or no (He) unusual heat events were observed.After cycling the D2 gas through the coiled tubing for several months, Pd25Ag samples showedan increase in Cu and Fe compared with the amounts in unexposed Pd25Ag. Chromium,manganese, and zinc were detected in gas-cycled Pd25Ag samples, whereas they were notdetected in unexposed Pd25Ag samples. In particular, Zn was present in the gas-cycled Pd25Agmaterial in larger quantities than either Cr or Mn. Although a small amount of Cu was present inthe Pd25Ag coil before the D2 gas cycling, 7 times more was present after the cycling. Multiplematerial characterization techniques were used to obtain both pre-test and post-test elementalcomposition. The results indicate that novel post-test elements, primarily on the surface, werecreated by unknown nuclear mechanisms at low energy.

Gustave C Fralick↗

Particle track record of the Luna missions.

Measurements are reported of particle-track densities in 100 to 200-micron crystalline grains taken from one level of the soil column returned from the lunar highlands between Mare Fecunditatis and Mare Crisium by Luna 20 and from two levels in the soil column from Mare Fecunditatis by Luna 16. Ninety-three percent of the grains from Luna 16 have very high densities, greater than 10 to the 8th power per cu cm and the lower-track density grains are all in the deeper soil level. In contrast, most Luna 20 grains show densities less than 10 to the 8th power per cu cm. Track density gradients and exposure times have been measured for six Luna 16 grains with a wide spread in absolute track densities. The more extensive track counts in crystals strengthens an earlier conclusion that the Luna 16 soil has received long irradiations very close to the surface. Two possible histories are that the highly irradiated soil blanket at the Luna 16 site is either well mixed and thin, or else has accumulated by transport from surrounding higher regions.

Comstock, G. M.↗

Improvement of thermal contact resistance by carbon nanotubes and nanofibers

Interfacial thermal resistance results of various nanotube and nanofiber coatings, prepared by chemical vapor deposition (CVD) methods, are reported at relatively low clamping pressures. The five types of samples examined include multi-walled and single-walled nanotubes growth by CVD, multi-walled nanotubes grown by plasma enhanced CVD (PECVD) and carbon nanofibers of differing aspect ratio grown by PECVD. Of the samples examined, only high aspect ratio nanofibers and thermally grown multi-walled nanotubes show an improvement in thermal contact resistance. The improvement is approximately a 60% lower thermal resistance than a bare Si-Cu interface and is comparable to that attained by commercially available thermal interface materials.

Evaluation Studies↗

A Perspective on Multi-Source Energy Harvesting Technology Using Piezoelectric and Thermoelectric Materials

Energy harvesting using various locally available energy sources such as vibration energy, heat, sound, or magnetic field have become attractive topics for supplying power to modular electronic devices making them run independently in extreme environments. In this paper, we will be discussing the perspectives on thermoelectric (TE) and piezoelectric materials and devices, and then the concept of multi-source energy harvester using piezoelectric and thermoelectric devices and integration of them into a reliable and independent power source. TE materials having low thermal conductivity and high figure-of-merit ( zT ) are developed to convert even a small temperature gradient efficiently into electrical energy with the state-of-the-art conversion efficiency of ~15% and output power of ~56 W from single device. The piezoelectric device architecture is configured using high performance piezoelectric ceramics (Cu-Mn-PIN-PMN-PT). These ceramics exhibit high piezoelectric coefficient with high mechanical quality factor and low dielectric loss factor. Using these piezoelectric materials, power density as high a 2 mW/cm 2 is demonstrated in 1-1.5 g vibration environments. The piezoelectric device is attached on the surface of TE module to capture both the vibration and thermal energy sources to realize dual mode energy harvester. The multi-energy transfer strategy opens opportunities for a future generation of wireless and modular electronic devices. These devices would be useful in powering wearable electronic devices, micro sensor chargers, etc. in extreme environmental conditions using body heat/thermal sources and induced motion/vibrations.

Piezoelectric↗

Laboratory observations of electron temperature in the wake of a sphere in a streaming plasma

A parametric study was performed of electron-temperature variation in the wake of a conducting sphere in a streaming plasma. The flow conditions were varied as follows: the ambient electron temperatures in the range from 850 to 2450 K; the ambient electron densities in the range from 0.0005 to 0.00007 per cu cm; and body potentials relative to plasma potential in the range from +1.7 to -2.8 V for an ion-beam energy of approximately 4 eV. Electron-temperature enhancements were observed which ranged up to 200 per cent above ambient in the nearest proximity of the body surface. The magnitude of the enhancement depends upon the ambient density, temperature, and body potential.

Oran, W. A.↗

Current-driven resistive ballooning modes in axially bounded solar flare plasmas

The most unstable current-driven resistive modes of an axially bounded coronal loop are found in computer simulations to exhibit the spatial structure of ballooning modes. The observed modes are not confined to mode rational surfaces, but instead have broad radial extent. A theory assuming ballooning mode spatial structure predicts that a minimum current should be required for linear instability, and that, when the mode is unstable, the linear growth rate scales linearly with the resistivity eta below a critical resistivity, and scales as cu root of eta for larger resistivities. Both predictions are borne out by simulation results. Both theory and simulation analyses of the mode suggest that the strong radial structure of the mode near the ends of the system is the primary contributing factor to the instability of the mode. A helical current sheet is formed in the nonlinear evolution of the mode near the edge of the current channel and is accompanied by a strong radial gradient in the current and partial current reversal.

Otani, Niels F.↗

Kinetics of the reaction OH + HO2 yields H2O + O2 from 254 to 382 K

The discharge-flow resonance fluorescence technique has been used to determine the absolute rate constant for the reaction OH + HO2 yields H2O + O2 from 254 to 382 K at a total pressure of 1 Torr. Pseudo-=first-order conditions were used with HO2 in large excess over OH. The rate constant was obtained directly from observed decays of OH and measured concentrations of HO2. Since the observed rate constant was found to be very sensitive to small background concentrations of O and H atoms, NO2 was used to remove both atom species from the system. With added NO2 the result at 299 K is (1.1 + or - 0.3) x 10 to the -10th cu cm/molecule where the error limits are one standard deviation and include an estimate of overall experimental uncertainty. The temperature dependence expressed in Arrhenius form is (4.8 + or - 0.8) x 10 to the -11th exp (250 + or - 50)/T. The results are independent of the type of reactor surface and the precursor used to produce OH and HO2. The present results agree well with earlier measurements near 1-atm total pressure and suggest that this rate constant exhibits little or no pressure dependence between 1 and 1000 Torr.

Keyser, Leon F.↗

Ignition propagation and heat effects of propellant chips embedded in castable inhibitor using a laser flux test bomb

A castable inhibitor is applied to the aft face of the Space Shuttle Redesigned Solid Rocket Motor (RSRM) forward segment propellant grain to control propellant surface burn area. During fabrication, the propellant surface is trimmed prior to the inhibitor application. This produces a potential for small propellant chips to remain undetected on the propellant surface and contaminate the inhibitor during application. The concern was that undetected propellant chips in the inhibitor might provide a fuse path for premature propellant ignition underneath the inhibitor. To evaluate the fuse path potential, testing was performed on inhibitor samples with embedded propellant. The internal motor environment was simulated with a calibrated CO2 laser beam directed onto a sample which was placed in a 4100 kPa (600 psi) nitrogen pressurized bomb (laser bomb). The testing showed definitive results pertaining to fuse path formation. Embedded propellant chips did not autoignite until the receding heat affected inhibitor surface reached, or passed, the propellant chip. Samples with embedded propellant chips in alignment did not propagate ignition from one chip to another with separation distances as small as 0.010 cm(0.004 inc) and some as little as 0.0051 cm (0.002 in). Propellant chips with volumes approximately less than 0.025 cu cm (0.0015 cu in) (which did not propagate ignition) did not increase the inhibitor material decomposition depth more than the resulting void cavity of the burned out propellant chip. In addition, the depth of this void cavity did not increase until it was overtaken by the surrounding material decomposition depth. This was due, in part, to the retention of the protective inhibitor char layer. Samples with embedded propellant strings, whose thicknesses were below 0.023 cm (0.009 in), did not propagate ignition. Propellant string thicknesses above 0.038 cm (0.015 in) did propagate ignition. Test sample char and heat affected layer measurements and observations compared well with those from the Space Shuttle Solid Rocket Motor (SRM) Technical Evaluation Motor no. 9(TEM-9).

Bolton, Douglas E., Jr.↗

Ignition and combustion of bulk metals under elevated, normal and reduced gravity conditions

This research effort is aimed at providing further insight into this multi-variable dependent phenomena by looking at the effects of gravity on the ignition and combustion behavior of metals. Since spacecraft are subjected to higher-than-1g gravity loads during launch and reentry and to zero-gravity environments while in orbit, the study of ignition and combustion of bulk metals at different gravitational potentials is of great practical concern. From the scientific standpoint, studies conducted under microgravity conditions provide simplified boundary conditions since buoyancy is removed, and make possible the identification of fundamental ignition mechanisms. The effect of microgravity on the combustion of bulk metals has been investigated by Steinberg, et al. on a drop tower simulator. However, no detailed quantitative work has been done on ignition phenomena of bulk metals at lower or higher-than-normal gravitational fields or on the combustion characteristics of metals at elevated gravity. The primary objective of this investigation is the development of an experimental system capable of providing fundamental physical and chemical information on the ignition of bulk metals under different gravity levels. The metals used in the study, iron (Fe), titanium (Ti), zirconium (Zr), magnesium (Mg), zinc (Zn), and copper (Cu) were selected because of their importance as elements of structural metals and their simple chemical composition (pure metals instead of multi-component alloys to avoid complication in morphology and spectroscopic studies). These samples were also chosen to study the two different combustion modes experienced by metals: heterogeneous or surface oxidation, and homogeneous or gas-phase reaction. The experimental approach provides surface temperature profiles, spectroscopic measurements, surface morphology, x-ray spectrometry of metals specimens and their combustion products, and high-speed cinematography of the heating, ignition and combustion stages of the metal specimen. This paper summarizes the results obtained to date from experiments conducted under normal and high-gravity conditions.

Abbud-Madrid, Angel↗

Joining and Testing Composite Plates to Ti Tubes

The joining of metal tubes to composite plates is required for heat-rejection components in several space applications. Currently a number of different braze compositions are being evaluated as to their effectiveness. Such tube-plate configurations cannot be represented by traditional methods of testing, e.g., lap joints. The joined region is not between two flat surfaces, but rather between a flat surface and a curved surface. Therefore, several tests have been employed to ascertain the effectiveness of the different braze approaches in tension that are both simple and representative of the actual system and relatively straightforward in analysis. The results of these "tube-tests" will be discussed for the three different braze compositions, Cu-ABA, Ti-Cu-Sil, and Ti-Cu-Ni. In addition, fracture analysis of the failed joints was performed and offers insights into the cause of joint failure and the distinctions which need to be made between the "strength" of a joint versus the "load carrying ability" of a joint.

Morscher, Gregory N.↗

Titan Airship Surveyor

Saturn's moon Titan is considered to be one of the prime candidates for studying prebiotic materials - the substances that precede the formation of life but have disappeared from the Earth as a result of the evolution of life. A unique combination of a dense, predominantly nitrogen, atmosphere (more than four times that of the Earth), low gravity (six times less than on the Earth) and small temperature variations makes Titan the almost ideal planet for studies with lighter-than-air aerial platforms (aerobots). Moreover, since methane clouds and photochemical haze obscure the surface, low-altitude aerial platforms are the only practical means that can provide global mapping of the Titan surface at visible and infrared wavelengths. One major challenge in Titan exploration is the extremely cold atmosphere (approx. 90 K). However, current material technology the capability to operate aerobots at these very low temperatures. A second challenge is the remoteness from the Sun (10 AU) that makes the nuclear (radioisotopic) energy the only practical source of power. A third challenge is remoteness from the Earth (approx. 10 AU, two-way light-time approx. 160 min) which imposes restrictions on data rates and makes impractical any meaningful real-time control. A small-size airship (approx. 25 cu m) can carry a payload approximately 100 kg. A Stirling engine coupled to a radioisotope heat source would be the prime choice for producing both mechanical and electrical power for sensing, control, and communications. The cold atmospheric temperature makes Stirling machines especially effective. With the radioisotope power source the airship may fly with speed approximately 5 m/s for a year or more providing an excellent platform for in situ atmosphere measurements and a high-resolution remote sensing with unlimited access on a global scale. In a station-keeping mode the airship can be used for in situ studies on the surface by winching down an instrument package. Floating above the surface allows relatively simple means for flight control. Mission requirements and possible methods of navigation, control, data acquisition, and communications are discussed. The presentation describes also the state-of-the art and current progress in aerial deployed aerobots.

Kerzhanovich, V.↗

Iron abundance and magnetic permeability of the moon

A larger set of simultaneous data from the Apollo 12 lunar surface magnetometer and the Explorer 35 Ames magnetometer are used to construct a whole-moon hysteresis curve, from which a new value of global lunar permeability is determined to be mu = 1.012 + or - 0.006. The corresponding global induced dipole moment is 2.1 x 10 to the 18th power gauss-cu cm for typical inducing fields of .0001 gauss in the lunar environment. From the permeability measurement, lunar free iron abundance is determined to be 2.5 + or - 2.0 wt. %. Total iron abundance (sum of iron in the ferromagnetic and paramagnetic states) is calculated for two assumed compositional models of the lunar interior: a free iron/orthopyroxene lunar composition and a free iron/olivine composition. The overall lunar total iron abundance is determined to be 9.0 + or - 4.7 wt. %. Other lunar models with a small iron core and with a shallow iron-rich layer are discussed in light of the measured global permeability.

Parkin, C. W.↗