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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

Integrated Direct Air Capture and H₂-Free CO₂ Valorization

This project advances fundamental understanding of a novel integrated direct air capture (DAC) and CO₂ conversion process that valorizes atmospheric CO₂ without external H₂. The research encompasses four critical components: (1) design of task-specific ionic liquids for efficient CO₂ capture under ambient conditions, (2) development of H₂-free tandem catalytic systems using ethane as a reductant, (3) advanced operando characterization to elucidate capture and conversion mechanisms, and (4) data science-driven predictive computation to accelerate material discovery. Over the project period, we developed five high-performance DAC sorbent systems—including CaO/superbase ionic liquid composites, Ni-MOF/Ionic Liquid (IL) hybrids, fluorinated covalent organic frameworks with ion-pair functional groups, defect-engineered UiO-66, and a validated kinetic model for humid-condition operation, achieving CO₂ capacities up to 1.86 mmol/g at 400 ppm with excellent cycling stability. For H₂-free conversion, we constructed atomically synergistic Zn–O–Cr binuclear catalytic sites that achieve 100% ethylene selectivity, ~9.6% ethane conversion, and 99% CO₂ utilization in equimolar co-conversion of ethane and CO₂. We further demonstrated downstream valorization pathways converting CO and C₂H₄ into polyketones and C₃ chemicals. These advances strengthen the scientific foundation for producing value-added materials from ambient CO₂.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Spatiotemporal Coherence of Mean and Extreme Aerosol Particle Events over Eastern North America as Observed from Satellite

Quantifying spatiotemporal scales of coherence and variability of aerosol particle properties provides (i) metrics for evaluating observational data sets and model simulations, (ii) inferences regarding dominant causes of variability, and (iii) information that is necessary to determine their climate forcing and air quality impacts. Accordingly, analyses of columnar aerosol optical depth (AOD) and Ångstrom exponent (AE) from the MODerate resolution Imaging Spectroradiometer (MODIS) on the Aqua and Terra satellites, and AErosol RObotic NETwork (AERONET) stations are used to evaluate the spatially averaged (Level-3) MODIS products, and to characterize the spatiotemporal scales of variability (and coherence) of aerosol particles over eastern North America (2000-2013). Results show a high degree of consistency in AOD retrievals from the different data sets but larger discrepancies in AE estimates, highest mean AOD and lowest day-to-day variability during the summer, and largest scales of spatial coherence in summer and fall. Consistent with the scales of spatial coherence from MODIS data, in both data sets power spectra indicate AOD variability is manifest primarily on synoptic and annual time scales. Conversely, AE variability in MODIS data is primarily focused on seasonal, semiannual, and annual time scales, and there is an additional mode of AE variability at approx. 30 days in the AERONET measurements. The frequency of cooccurrence of extreme AOD values (>local 90th percentile) decreases to below 50% at approx. 150 km from a central grid cell, but is above that expected by random chance over almost all of eastern North America, indicating supra-regional scale extreme events.

MODIS↗

Optical Frequency Optimization of a High Intensity Laser Power Beaming System Utilizing VMJ Photovoltaic Cells

An effective form of wireless power transmission (WPT) has been developed to enable extended mission durations, increased coverage and added capabilities for both space and terrestrial applications that may benefit from optically delivered electrical energy. The high intensity laser power beaming (HILPB) system enables long range optical 'refueling" of electric platforms such as micro unmanned aerial vehicles (MUAV), airships, robotic exploration missions and spacecraft platforms. To further advance the HILPB technology, the focus of this investigation is to determine the optimal laser wavelength to be used with the HILPB receiver, which utilizes vertical multi-junction (VMJ) photovoltaic cells. Frequency optimization of the laser system is necessary in order to maximize the conversion efficiency at continuous high intensities, and thus increase the delivered power density of the HILPB system. Initial spectral characterizations of the device performed at the NASA Glenn Research Center (GRC) indicate the approximate range of peak optical-to-electrical conversion efficiencies, but these data sets represent transient conditions under lower levels of illumination. Extending these results to high levels of steady state illumination, with attention given to the compatibility of available commercial off-the-shelf semiconductor laser sources and atmospheric transmission constraints is the primary focus of this paper. Experimental hardware results utilizing high power continuous wave (CW) semiconductor lasers at four different operational frequencies near the indicated band gap of the photovoltaic VMJ cells are presented and discussed. In addition, the highest receiver power density achieved to date is demonstrated using a single photovoltaic VMJ cell, which provided an exceptionally high electrical output of 13.6 W/sq cm at an optical-to-electrical conversion efficiency of 24 percent. These results are very promising and scalable, as a potential 1.0 sq m HILPB receiver of similar construction would be able to generate 136 kW of electrical power under similar conditions.

Raible, Daniel E.↗

FFT Computation with Systolic Arrays, A New Architecture

The use of the Cooley-Tukey algorithm for computing the l-d FFT lends itself to a particular matrix factorization which suggests direct implementation by linearly-connected systolic arrays. Here we present a new systolic architecture that embodies this algorithm. This implementation requires a smaller number of processors and a smaller number of memory cells than other recent implementations, as well as having all the advantages of systolic arrays. For the implementation of the decimation-in-frequency case, word-serial data input allows continuous real-time operation without the need of a serial-to-parallel conversion device. No control or data stream switching is necessary. Computer simulation of this architecture was done in the context of a 1024 point DFT with a fixed point processor, and CMOS processor implementation has started.

Boriakoff, Valentin↗

A modeling analysis program for the JPL Table Mountain Io sodium cloud data

The necessary personnel software base was established to accomplish the data processing requirements for this project. Conversion of software required in reformatting the raw Io sodium cloud data was completed and data processing activities were initiated. Slit spectra data acquired by the JPL Table Mountain Io sodium cloud observing program were reviewed and their scientific value assessed. The lifetime description for sodium atoms in the Io sodium cloud model was improved by incorporating the most recently available temperatures and densities for ions and electrons in the plasma torus.

Smyth, W. H.↗

Hydrogen turbine power conversion system assessment

A three part technical study was conducted whereby parametric technical and economic feasibility data were developed on several power conversion systems suitable for the generation of central station electric power through the combustion of hydrogen and the use of the resulting heat energy in turbogenerator equipment. The study assessed potential applications of hydrogen-fueled power conversion systems and identified the three most promising candidates: (1) Ericsson Cycle, (2) gas turbine, and (3) direct steam injection system for fossil fuel as well as nuclear powerplants. A technical and economic evaluation was performed on the three systems from which the direct injection system (fossil fuel only) was selected for a preliminary conceptual design of an integrated hydrogen-fired power conversion system.

Wright, D. E.↗

Deriving New Mixing Ratios for Venus Atmospheric Gases Using Data From the Pioneer Venus Large Probe Neutral Mass Spectrometer

We present the first published method to convert data obtained by the Pioneer Venus Large Probe Neutral Mass Spectrometer (LNMS) into units of mixing ratio (ppm) and volume percent (v%) against CO 2 and N 2 , the dominant Venus atmospheric gases, including conversion to density (kg m −3 ). These unit conversions are key to unlocking the untapped potential of the data, which represents a significant challenge given the scant calibration data in the literature. Herein, we show that our data treatments and conversions yield mixing ratios and volume percent values for H 2 O, N 2 , and SO 2 that are within error to those reported for the gas chromatograph (LGC) on the Pioneer Venus Large Probe (PVLP). For the noble gases, we developed strategies to correct for instrument biases by treating the data as a relative scale and using PVLP and Venera-based measurements as calibration points. Together, these methods, conversions, calibrations, and comparisons afford novel unit conversions for the LNMS data and yield unified measures for Venus’ atmosphere from the LNMS and LGC on the PVLP. - Conversion into mixing ratio (ppm), volume percent (v%), and density (kg m −3 ). - Mixing ratios are expressed against CO 2 and N 2 . - LNMS and LGC measurements on the PVLP are consistent.

Venus↗

Anion Data for the East River Watershed, Colorado (2014-2025)

The anion data for the East River Watershed, Colorado, consist of fluoride, chloride, sulfate, nitrate, and phosphate concentrations collected at multiple, long-term monitoring sites that include stream, groundwater, and spring sampling locations. These locations represent important and/or unique end-member locations for which solute concentrations can be diagnostic of the connection between terrestrial and aquatic systems. Such locations include drainages underlined entirely or largely by shale bedrock, land covered dominated by conifers, aspens, or meadows, and drainages impacted by historic mining activity and the presence of naturally mineralized rock. Developing a long-term record of solute concentrations from a diversity of environments is a critical component of quantifying the impacts of both climate change and discrete climate perturbations, such as drought, forest mortality, and wildfire, on the riverine export of multiple anionic species. Such data may be combined with stream gauging stations co-located at each monitoring site to directly quantify the seasonal and annual mass flux of these anionic species out of the watershed. This data package contains (1) a zip file (anion_data_2014_2025.zip) containing a total of 386 files: 387 data files of anion data from across the Lawrence Berkeley National Laboratory (LBNL) Watershed Function Scientific Focus Area (SFA) which is reported in .csv files per location and a locations.csv (1 file) with latitude and longitude for each location; (2) a file-level metadata (v7_20260901_flmd.csv) file that lists each file contained in the dataset with associated metadata; (3) a data dictionary (v7_20260901_dd.csv) file that contains terms/column_headers used throughout the files along with a definition, units, and data type; and (4) a anion MDL fact sheet (anion_MDLs_202608 in PDF and docx formats). Missing values within the anion data files are noted as either "-9999" or "0.0" for not detectable (N.D.) data. There are a total of 47 locations containing anion data. Update on 2022-06-10: versioned updates to this dataset was made along with these changes: (1) updated anion data for all locations up to 2021-12-31, (2) removal of units from column headers in datafiles, (3) added row underneath headers to contain units of variables, (4) restructure of units to comply with CSV reporting format requirements, and (5) the addition of the file-level metadata (flmd.csv) and data dictionary (dd.csv) were added to comply with the File-Level Metadata Reporting Format. Update on 2022-09-09: Updates were made to reporting format specific files (file-level metadata and data dictionary) to correct swapped file names, add additional details on metadata descriptions on both files, add a header_row column to enable parsing, and add version number and date to file names (v2_20220909_flmd.csv and v2_20220909_dd.csv). Update on 2022-12-20: Updates were made to both the data files and reporting format specific files. Conversion issues affecting ER-PLM locations for anion data was resolved for the data files. Additionally, the flmd and dd files were updated to reflect the updated versions of these files. Available data was added up until 2022-03-14. Update on 2023-08-08: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until 2023-05-19. The file level metadata and data dictionary files were updated to reflect the additional data added. Update on 2024-03-11: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until 2023-09-11. Further, revisions to the data files were made to remove incorrect data points (from 1970 and 2001). The reporting format specific files were updated to reflect the additional data added. Update on 2025-05-15: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until the end of WY2024 (September 30, 2024). International Generic Sample Numbers (IGSNs), when registered, were added to the data files. The reporting format specific files were updated to reflect the additional data added. Update on 2026-09-01: Updates were made to both the data files and reporting format specific files. New available anion data was added, up until the end of WY2025 (September 30, 2025). An anion MDL document was included in this update.

54 ENVIRONMENTAL SCIENCES↗

Large-scale spatially explicit analysis of carbon capture at cellulosic biorefineries

The large-scale production of cellulosic biofuels would involve spatially distributed systems including biomass fields, logistics networks and biorefineries. Better understanding of the interactions between landscape-related decisions and the design of biorefineries with carbon capture and storage (CCS) in a supply chain context is needed to enable efficient systems. Here we analyse the cost and greenhouse gas mitigation potential for cellulosic biofuel supply chains in the US Midwest using realistic spatially explicit land availability and crop productivity data and consider fuel conversion technologies with detailed CCS design for their associated CO 2 streams. Optimization methods identify trade-offs and design strategies leading to systems with attractive environmental and economic performance. Strategic and operational decisions depend on underlying spatial features and are sensitive to biofuel demand and CCS incentives. US CCS incentives neglect to motivate greenhouse gas mitigation from all supply chain emission sources, which leverage spatial interactions between CCS, electricity prices and the biomass landscape.

09 BIOMASS FUELS↗

Automating Traffic Microsimulation from SYNCHRO UTDF to SUMO

Modern transportation research relies on seamlessly integrating traffic signal data with robust network representation and simulation tools. This study presents utdf2gmns, an open-source Python tool that automates conversion of the Universal Traffic Data Format, including network representation, signalized intersections, and turning volumes into the General Modeling Network Specification (GMNS) Standard. The resulting GMNS-compliant network can be converted for microsimulation in SUMO. By automatically extracting intersection control parameters and aligning them with GMNS conventions, utdf2gmns minimizes manual preprocessing and data loss. utdf2gmns also integrates with the Sigma-X engine to extract and visualize key traffic control metrics, such as phasing diagrams, turning volumes, volume-tocapacity ratios, and control delays. This streamlined workflow enables efficient scenario testing, accurate model building, and consistent data management. Validated through case studies, utdf2gmns reliably models complex urban corridors, promoting reproducibility and standardization. Documentation is available on GitHub and PyPI, supporting easy integration and community engagement.

Luo, Roy [ORNL] (ORCID:0009000312909983)↗

Analysis of carbon capture at cellulosic biorefineries

The large-scale production of cellulosic biofuels would involve spatially distributed systems including biomass fields, logistics networks and biorefineries. Better understanding of the interactions between landscape-related decisions and the design of biorefineries with carbon capture and storage (CCS) in a supply chain context is needed to enable efficient systems. Here we analyse the cost and greenhouse gas mitigation potential for cellulosic biofuel supply chains in the US Midwest using realistic spatially explicit land availability and crop productivity data and consider fuel conversion technologies with detailed CCS design for their associated CO2 streams.

carbon capture and storage (CCS)↗

Digital processing of radiographic images

Some techniques are presented and the software documentation for the digital enhancement of radiographs. Both image handling and image processing operations are considered. The image handling operations dealt with are: (1) conversion of format of data from packed to unpacked and vice versa; (2) automatic extraction of image data arrays; (3) transposition and 90 deg rotations of large data arrays; (4) translation of data arrays for registration; and (5) reduction of the dimensions of data arrays by integral factors. Both the frequency and the spatial domain approaches are presented for the design and implementation of the image processing operation. It is shown that spatial domain recursive implementation of filters is much faster than nonrecursive implementations using fast fourier transforms (FFT) for the cases of interest in this work. The recursive implementation of a class of matched filters for enhancing image signal to noise ratio is described. Test patterns are used to illustrate the filtering operations. The application of the techniques to radiographic images of metallic structures is demonstrated through several examples.

Bond, A. D.↗

State resource management and role of remote sensing

Remote sensing by satellite can provide valuable information to state officials when making decisions regarding resources management. Portions of California's investment for Prosperity program which seem likely candidates for remote sensing include: (1) surveying vegetation type, age, and density in forests and wildlife habitats; (2) controlling fires through chaparal management; (3) monitoring wetlands and measuring ocean biomass; (4) eliminating ground water overdraught; (5) locating crops in overdraught areas, assessing soil erosion and the areas of poorly drained soils and those affected by salt; (6) monitoring coastal lands and resources; (7) changes in landscapes for recreational purposes; (8) inventorying irrigated lands; (9) classifying ground cover; (10) monitoring farmland conversion; and (11) supplying data for a statewide computerized farmlands data base.

Johnson, H. D.↗

Present state of boron-carbon thermoelectric materials

Boron-carbon p-type thermoelectric materials show promise for use in advanced thermal-to-electric space power conversion systems. Here, recent data on the thermoelectric properties of boron-carbon materials, such as B9C, B13C2, B15C2, and B4C, are reviewed. In particular, attention is given to the effect of the compositional homogeneity and residual impurity content on the Seeback coefficient, electrical resistivity, and thermal conductivity of these materials. The effect of carbon content for a given level of impurity and degree of homogeneity is also discussed.

Elsner, N. B.↗

Carbon kinetic isotope effect in the reaction of CH4 with HO

The carbon kinetic isotope effect in the CH4 + HO reaction is measured experimentally and the use of carbon isotope ratios to diagnose atmospheric methane is examined. The chemical, photolysis, and analytical experimental conditions and procedures are described. It is determined that the CH4 + HO reaction has a carbon kinetic isotope effect of 1.010 + or 0.007 for k(12)k(13) (rate constants ratio) at 297 + or - 3 K. This value is compared with the data of Rust and Stevens (1980). Causes for the poor correlation between the data at high methane conversions are discussed. It is supposed that the difference between the k(12) and k(13) values is due to a difference in the activation energy of the two reactions.

Davidson, J. A.↗

Computer processing of tunable diode laser spectra

A computer-controlled tunable diode laser spectrometer and spectral analysis software are described. The three-channel system records simultaneously the transmission of a subject gas, a temperature-stabilized etalon, and a calibration gas. The software routines are applied to diode laser spectra of HNO3 and NO2 to illustrate the procedures adopted for conversion of raw spectral data to useful transmission and harmonic spectra. Extraction of line positions, absorption intensities, collisional broadening coefficients, and gas concentrations from recorded spectra is also described.

May, Randy D.↗

Computer modeling of solar wind interaction with Venus and Mars

The fundamental ideas, successes, and shortcomings of fluid models based on MHD theory for the interaction of the solar wind and a planetary magnetic field and/or atmosphere are reviewed, with special attention to applications to Venus and Mars. An account, including new quantitative results, is given of a number of enhancements of a basic gasdynamic convected field approximation to the magnetohydrodynamic model that incorporate features of solar wind flow past a planet not treated previously. These permit solutions to be calculated for 3D, as opposed to axisymmetric, obstacle shapes, the effects of a magnetic barrier region just exterior to the ionopause, the complete MHD equations for the special case in which the interplanetary magnetic field is aligned with the flow, the effects of mass loading by pickup of ions newly created by photoionization of atmospheric neutrals, and for the unsteady effects associated with the passage of an interplanetary shock wave. Particular emphasis is placed on the information furnished by these models that can be compared with observations, and conversely on the observational data that provide critical tests of the models.

Spreiter, John R.↗