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At least 289 records · Page 16

Effects of C/O Ratio and Temperature on Sooting Limits of Spherical Diffusion Flames

Limiting conditions for soot particle inception in spherical diffusion flames were investigated numerically. The flames were modeled using a one-dimensional, time accurate diffusion flame code with detailed chemistry and transport and an optically thick radiation model. Seventeen normal and inverse flames were considered, covering a wide range of stoichiometric mixture fraction, adiabatic flame temperature, residence time and scalar dissipation rate. These flames were previously observed to reach their sooting limits after 2 s of microgravity. Sooting-limit diffusion flames with scalar dissipation rate lower than 2/s were found to have temperatures near 1400 K where C/O = 0.51, whereas flames with greater scalar dissipation rate required increased temperatures. This finding was valid across a broad range of fuel and oxidizer compositions and convection directions.

Lecoustre, V. R.↗

Opposed-Flow Flame Spread in a Narrow Channel Apparatus over Thin PMMA Sheets

Flame spread tests have been conducted over polymethylmethacrylate (PMMA) samples in San Diego State University's Narrow Channel Apparatus (SDSU NCA). The Narrow Channel Apparatus (NCA) has the ability to suppress buoyant flow in horizontally spreading flames, and is currently being investigated as a possible replacement or complement to NASA's current material flammability test standard for non-metallic solids, NASA-STD-(I)-6001B Test 1. The buoyant suppression achieved with a NCA allows for tests to be conducted in a simulated microgravity atmosphere-a characteristic that Test 1 lacks since flames present in Test 1 are buoyantly driven. The SDSU NCA allows for flame spread tests to be conducted with varying opposed flow oxidizer velocities, oxygen percent by volume, and total pressure. Also, since the test sample is placed symmetrically between two confining plates so that there is a gap above and below the sample, this gap can be adjusted. This gap height adjustment allows for a compromise between heat loss from the flame to the confining boundaries and buoyancy suppression achieved by those boundaries. This article explores the effect gap height has on the flame spread rate for 75 μm thick PMMA at 1 atm pressure and 21% oxygen concentration by volume in the SDSU NCA. Flame spread results from the SDSU NCA for thin cellulose fuels have previously been compared to results from tests in actual microgravity at various test conditions with the same sample materials and were found to be in good agreement. This article also presents results from the SDSU NCA for PMMA at 1 atm pressure, opposed oxidizer velocity ranging from 3 to 35 cm/s, oxygen concentration by volume at 21%, 30 %, and 50% and fuel thicknesses of 50 and 75 μm. These results are compared to results obtained in actual microgravity for PMMA obtained at the 4.5s drop tower of MGLAB in Gifu, Japan, and the 5.2s drop tower at NASA's Zero-Gravity Research Facility in Cleveland, OH. This comparison confirms that at 1 atm pressure, the SDSU NCA successfully simulates microgravity for not only thin cellulose fuels, but also for thin PMMA sheets as well. This further supports the idea that the NCA is a viable option to complement or replace NASA's Test 1 for material flammability testing. Tests with thick fuels will be conducted in the future to further characterize the SDSU NCA.

flame spread↗

Effects of Confinement on Flame Spread in Microgravity

Solid fuel combustion experiments aboard the ISS examine the effects of confinement on a concurrent, purely-forced-flow flame spread in microgravity environment. The results for a thin, cotton-fiberglass-blended textile fabric fuel are presented. Flat baffles of differing materials are used to alter the radiative boundary conditions with transparent polycarbonate, black anodized aluminum (reflectance ~ 0), and highly polished aluminum (reflectance ~ 1). The baffles are parallel to the fuel sheet and placed symmetrically on each side. The inter-baffle distance is varied to change the boundary conditions for the flow. In all tests, samples are ignited at the upstream leading edge and allowed to burn to completion. Results show that the flame reaches a steady length and spread rate at low flow speeds (< 15 cm/s) for all tested inter-baffle distances. As the distance decreases, the flame length and spread rate first increase then decrease showing an optimal inter-baffle distance. For all baffle types, the flame either fails to ignite or extinguishes before reaching the end of the sample when the inter-baffle distance is too small (~ 1 cm). This is attributed to the reduction of oxygen supply to the flame zone and heat loss to the baffles. The results also show at the same inter-baffle distance, flame length and spread rate are highest for polished aluminum baffles, and lowest for transparent polycarbonate baffles. The differences are most prominent at intermediate tested baffle distances. While the radiative heat feedback from the baffles is expected to increase when the baffle distance decreases, the combustion is limited by the reduced oxygen supply. Near this limit, flame lengths and spread rates are similar for all baffle types.

Microgravity↗

Experimental investigation of flow turbulence effects on premixed methane-air flames

An experimental assessment of a novel technique for measuring turbulent flame speeds was conducted. Unconfined, V-shaped, methane-air flames stabilized in grid turbulence were investigated. Local flame speeds were measured employing hot film and laser anemometry and fine wire thermocouples. The measurement instrumentation was extended to provide mean and fluctuating temperature information about turbulent flames. The flames in grid turbulence exhibited an increase in flame speed with increased length scale and velocity fluctuations. At high combustor velocities, stabilizer wake turbulence dominated the flame properties.

Smith, K. O.↗

Effect of pressure on structure and NO sub X formation in CO-air diffusion flames

A study was made of nitric oxide formation in a laminar CO-air diffusion flame over a pressure range from 1 to 50 atm. The carbon monoxide (CO) issued from a 3.06 mm diameter port coaxially into a coflowing stream of air confined within a 20.5 mm diameter chimney. Nitric oxide concentrations from the flame were measured at two carbon monoxide (fuel) flow rates: 73 standard cubic/min and 146 sccm. Comparison of the present data with data in the literature for a methane-air diffusion flame shows that for flames of comparable flame height (8 to 10 mm) and pseudoequivalence ratio (0.162), the molar emission index of a CO-air flame is significantly greater than that of a methane-air flame.

Maahs, H. G.↗

An experimental study on extinction and stability of stretched premixed flames

Law et al. (1981) and Ishizuka et al. (1982) have experimentally investigated the effects of flame stretch, preferential diffusion, and downstream heat loss on the extinction and stability of propane/air flames. The obtained results suggest that in the case of rich propane/air mixtures downstream heat loss, in addition to flame stretch, is needed for flame extinction. In the case of lean mixtures, flames can be extinguished by flame stretch alone. The data obtained in connection with the present study provide convincing evidence regarding the correctness of the previous results on the nature of flame extinction due to stretch. It is found that, in accordance with theoretical predictions, extinction by stretch alone is possible only when there is a deficiency regarding the less mobile reactant.

Ishizuka, S.↗

The mechanisms of flame holding in the wake of a bluff body

The flame holding mechanism for lean methane and lean propane air flames is examined under conditions where the recirculation zone is absent. The holding process is studied in detail in an attempt to determine the mechanism of flame holding and also the conditions where this mechanism is viable and when it fails and blow off occurs. Inverted flames held in the wake of a flat strip are studied. The velocity flow field is determined using a Laser Doppler Velocimetry technique. Equation of continuity is used to calculate the flame temperature from the change in area of flow streamlines before and after the flame. For methane air flame the controlling factor for blow off is incomplete reaction due to higher blowing rate leading to reduced residence time in the reaction zone.

Strehlow, R. A.↗

Buoyancy Effects upon Vapor Flame and Explosion Processes

The objective of this microgravity project is to develop an experimental and theoretical analyses critical to the understanding of the coupling of buoyancy and turbulence generation and its effect on fuel-air mixing, flame intensity and flame propagation in jet diffusion flames. The experiment is designed to examine certain effects of buoyancy acting on a diffusion flame in which the flame is directed either upward or downward. This change from negative to positive g is observed to significantly alter the flame shape although all other operating conditions are the same for both configurations. However, to perform this experiment a significant coaxial secondary air flow is needed in order to prevent flow reversal when the flame is inverted. The theoretical analysis that has been developed handles the secondary air flow and the extreme change in gravity vector direction. Thus the data will provide a measure of credibility of the analysis which will then be used to assist in the design of the actual zero-g experiment.

Edelman, R. B.↗

Effects of H2O, CO2, and N2 Air Contaminants on Critical Airside Strain Rates for Extinction of Hydrogen-Air Counterflow Diffusion Flames

Coaxial tubular opposed jet burners (OJB) were used to form dish shaped counterflow diffusion flames (CFDF), centered by opposing laminar jets of H2, N2 and both clean and contaminated air (O2/N2 mixtures) in an argon bath at 1 atm. Jet velocities for flame extinction and restoration limits are shown versus wide ranges of contaminant and O2 concentrations in the air jet, and also input H2 concentration. Blowoff, a sudden breaking of CFDF to a stable ring shape, occurs in highly stretched stagnation flows and is generally believed to measure kinetically limited flame reactivity. Restore, a sudden restoration of central flame, is a relatively new phenomenon which exhibits a H2 dependent hysteresis from Blowoff. For 25 percent O2 air mixtures, mole for mole replacement of 25 percent N2 contaminant by steam increased U(air) or flame strength at Blowoff by about 5 percent. This result is consistent with laminar burning velocity results from analogous substitution of steam for N2 in a premixed stoichiometric H2-O2-N2 (or steam) flame, shown by Koroll and Mulpuru to promote a 10 percent increase in experimental and calculated laminar burning velocity, due to enhanced third body efficiency of water in: H + O2 + M yields HO2 + M. When the OJB results were compared with Liu and MacFarlane's experimental laminar burning velocity of premixed stoichiometric H2 + air + steam, a crossover occurred, i.e., steam enhanced OJB flame strength at extinction relative to laminar burning velocity.

Pellett, G. L.↗

Radiation from Gas-Jet Diffusion Flames in Microgravity Environments

This paper presents the first demonstration of quantitative flame-radiation measurement in microgravity environments, with the objective of studying the influences and characteristics of radiative transfer on the behavior of gas-jet diffusion flames with possible application to spacecraft fire detection. Laminar diffusion flames of propane, burning in quiescent air at atmospheric pressure, are studied in the 5.18-Second Zero-Gravity Facility of NASA Lewis Research Center. Radiation from these flames is measured using a wide-view angle, thermopile-detector radiometer, and comparisons are made with normal-gravity flames. The results show that the radiation level is significantly higher in microgravity compared to normal-gravity environments due to larger flame size, enhanced soot formation, and entrapment of combustion products in the vicinity of the flame. These effects are the consequences of the removal of buoyancy which makes diffusion the dominant mechanism of transport. The results show that longer test times may be needed to reach steady state in microgravity environments.

Bahadori, M. Yousef↗

Effects of Radiative and Diffusive Transport Processes on Premixed Flames near Flammability Limits

A study of the mechanisms of flammability limits and the dynamics of flame extinguishment in premixed gas flames is described, a novel feature of which is the use of diluent gases having a wide range of radiative and diffusive transport properties. This feature enables an assessment of the importance of volumetric heat losses and Lewis number effects on these mechanisms. Additionally, effects of flame dynamics and flame front curvature are studied by employing spherically expanding flames obtained in a microgravity environment whereby natural convection is eliminated. New diagnostics include chamber pressure measurements and the first reported species concentration measurements in a microgravity combustion experiment. The limit mechanisms and extinguishment phenomena are found to be strongly influenced by the combined effects of radiant heat loss, Lewis number and flame curvature. Two new and as yet not well understood phenomena are reported: 'double flames' in rich H2-O2-CO2 mixtures and an 'inverse flammability region' in rich C3H8-O2-CO2 mixtures.

Abbud-Madrid, Angel↗

Ignition and subsequent flame spread over a thin cellulosic material

Both ignition and flame spread on solid fuels are processes that not only are of considerable scientific interest but that also have important fire safety applications. Both types of processes, ignition and flame spread, are complicated by strong coupling between chemical reactions and transport processes, not only in the gas phase but also in the condensed phase. In most previous studies, ignition and flame spread were studied separately with the result that there has been little understanding of the transition from ignition to flame spread. In fire safety applications this transition is crucial to determine whether a fire will be limited to a localized, temporary burn or will transition into a growth mode with a potential to become a large fire. In order to understand this transition, the transient mechanisms of ignition and subsequent flame spread must be studied. However, there have been no definitive experimental or modeling studies, because of the complexity of the flow motion generated by buoyancy near the heated sample surface. One must solve the full Navier-Stokes equations over an extended region to represent accurately the highly unstable buoyant plume and entrainment of surrounding gas from far away. In order to avoid the complicated nature of the starting plume problem under normal gravity, previous detailed radiative ignition models were assumed to be one-dimensional or were applied at a stagnation point. Thus, these models cannot be extended to include the transition to flame spread. The mismatch between experimental and calculated geometries means that theories cannot be compared directly with experimental results in normal gravity. To overcome the above difficulty, theoretical results obtained without buoyancy can be directly compared with experimental data measured in a microgravity environment. Thus, the objective of this study is to develop a theoretical model for ignition and the transition to flame spread and to make predictions using the thermal and chemical characteristics of a cellulosic material which are measured in normal gravity.

Nakabe, Kazuyoshi↗

Computational predictions of flame spread over alcohol pools

The effects of buoyancy and thermocapillarity on pulsating and uniform flame spread above n-propanol fuel pools have been studied using a numerical model. Data obtained indicate that the existence of pulsating flame spread is dependent upon the formation of a gas-phase recirculation cell which entrains evaporating fuel vapor in front of the leading edge of the flame. The size of the recirculation cell which is affected by the extent of liquid motion ahead of the flame, is shown to dictate whether flame spread is uniform or pulsating. The amplitude and period of the flame pulsations are found to be proportional to the maximum extent of the flow head. Under conditions considered, liquid motion was not affected appreciably by buoyancy. Horizontal convection in the liquid is the dominant mechanism for transporting heat ahead of the flame for both the pulsating and uniform regimes.

Schiller, D. N.↗

Direct simulations of premixed turbulent flames with nonunity Lewis numbers

A principal effect of turbulence on premixed flames in the flamelet regime is to wrinkle the flame fronts. For nonunity Lewis numbers, Le is not equal to 1, the local flame structure is altered in curved regions. This effect is examined using direct numerical simulations of 3D isotropic turbulence with constant density, single-step Arrhenius kinetics chemistry. Simulations of Lewis numbers 0.8, 1.0, and 1.2 are compared. At the local level, curvature effects dominated changes to the flame structure while strain effects were insignificant. A strong Lewis-number-dependent correlation was found between surface curvature and the local flame speed. The correlation was positive for Le less than 1 and negative for Le greater than 1. At the global level, strain-related effects were more significant than curvature effects. The turbulent flame speed changed significantly with Lewis number, increasing as Le decreased. This was found to be due to strain effects that have a nonzero mean over the flame surface, rather than to curvature effects that have a nearly zero mean. The mean product temperature was also found to vary with Lewis number, being higher for Le greater than 1 and lower for Le less than 1.

Rutland, C. J.↗

Analytical and Numerical Modeling of Flame-Balls in Hydrogen-Air Mixtures

Flame-balls are stationary spherical premixed flames observed in certain near-limit mixtures. It is believed that radiative heat losses are an important stabilizing influence. Numerical solutions of flame balls are constructed for hydrogen-air mixtures using an accurate description of the chemical kinetics, diffusive transport, and radiation losses. A lean limit equivalence ratio of 0.0866 is predicted and a rich limit of 2,828. For any equivalence ratio between the two limits there are two solutions. One is characterized by a small flame, incomplete reactant consumption, and negligible radiation losses. The other by a large flame, complete consumption of one of the reactants, and significant radiation losses. The maximum temperature varies between 1200 and 900 K as the two solution branches are traversed. Much of our discussion is a reprise and modification of previously published analytical results, for these provide physical insight into the nature of the solutions, and suggest that a portion of the large flame branch near the lean limit is stable and so corresponds to observable flames.

Buckmaster, J.↗

Numerical simulations of turbulent premixed H2/O2/N2 flames with complex chemistry

Premixed stoichiometric H2/O2/N2 flames propagating in two-dimensional turbulence were studied using direct numerical simulation (simulations in which all fluid and thermochemical scales are fully resolved) including realistic chemical kinetics and molecular transport. Results are compared with earlier zero-chemistry (flame sheet) and one-step chemistry simulations. Consistent with the simpler models, the turbulent flame with realistic chemistry aligns preferentially with extensive strain rates in the tangent plane and flame curvature probability density functions are close to symmetric with near-zero means. By contrast to simple-chemistry results with non-unity Lewis numbers (ratio of thermal to species diffusivity), local flame structure does not correlate with curvature but rather with tangential strain rate. Turbulent straining results in substantial thinning of the flame relative to the steady unstrained laminar case. Heat release and H2O2 contours remain thin and connected ('flamelet-like') while species including H-atom and OH are more diffuse. Peak OH concentration occurs well behind the peak heat-release zone. The feasibility of incorporating realistic chemistry into full turbulence simulations to address issues such as pollutant formation in hydrocarbon-air flames is suggested.

Baum, M.↗

Flame spreading over a thin solid in low-speed concurrent flow- Drop tower experimental results and comparison with theory

Flame spread over thin paper samples in low-speed concurrent flow is experimentally investigated in a 5.18 s drop tower. In the experiment, the oxygen molar percentage is varied from 30% down to the flame extinction limits and the forced flow velocity from 5.29 cm/s down to the quenching limits. Motion pictures are taken to observe flame shape, color, size, and spread rates. These quantities are compared with a theoretical model describing concurrent flame spread over thin solids in low-speed flows. The paper also discusses the similarity and difference between concurrent-flow and opposed-flow flame spread in microgravity and between low-speed and high-speed concurrent-flow flame spread. Finally the limitations of using a drop tower for flame spread research is assessed.

Grayson, G. D.↗

An innovative approach to the development of a portable unit for analytical flame characterization in a microgravity environment

The availability of manned laboratory facilities in space offers wonderful opportunities and challenges in microgravity combustion science and technology. In turn, the fundamentals of microgravity combustion science can be studied via spectroscopic characterization of free radicals generated in flames. The laser-induced fluorescence (LIF) technique is a noninvasive method of considerable utility in combustion physics and chemistry suitable for monitoring not only specific species and their kinetics, but it is also important for imaging of flames. This makes LIF one of the most important tools for microgravity combustion science. Flame characterization under microgravity conditions using LIF is expected to be more informative than other methods aimed at searching for effects like pumping phenomenon that can be modeled via ground level experiments. A primary goal of our work consisted in working out an innovative approach to devising an LIF-based analytical unit suitable for in-space flame characterization. It was decided to follow two approaches in tandem: (1) use the existing laboratory (non-portable) equipment and determine the optimal set of parameters for flames that can be used as analytical criteria for flame characterization under microgravity conditions; and (2) use state-of-the-art developments in laser technology and concentrate some effort in devising a layout for the portable analytical equipment. This paper presents an up-to-date summary of the results of our experiments aimed at the creation of the portable device for combustion studies in a microgravity environment, which is based on a portable UV tunable solid-state laser for excitation of free radicals normally present in flames in detectable amounts. A systematic approach has allowed us to make a convenient choice of species under investigation, as well as the proper tunable laser system, and also enabled us to carry out LIF experiments on free radicals using a solid-state laser tunable in the UV.

Dubinskiy, Mark A.↗