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At least 289 records · Page 16

Mechanical Properties of Air Plasma Sprayed Environmental Barrier Coating (EBC) Materials

Development work in Environmental Barrier Coatings (EBCs) for Ceramic Matrix Composites (CMCs) has focused considerably on the identification of materials systems and coating architectures to meet application needs. The evolution of these systems has occurred so quickly that modeling efforts and requisite data for modeling lag considerably behind development. Materials property data exists for many systems in the bulk form, but the effects of deposition on the critical properties of strength and fracture behavior are not well studied. We have plasma sprayed bulk samples of baseline EBC materials (silicon, ytterbium disilicate) and tested the mechanical properties of these materials to elicit differences in strength and toughness. We have also endeavored to assess the mixed-mode fracture resistance, Gc, of silicon in a baseline EBC applied to SiCSiC CMC via four point bend test. These results are compared to previously determined properties of the comparable bulk material.

Ceramic Matrix Composites (CMC's)↗

Engineering the fracture resistance of 2H-transition metal dichalcogenides using vacancies: An in-silico investigation based on HRTEM images

Vacancy engineering of 2H-transition metal dichalcogenides (2H-TMDs) has recently attracted great attention due to its potential to fine-tune the phonon and opto-electric properties of these materials. From a mechanical perspective, this symmetry-breaking process typically reduces the overall crack resistance of the material and adversely affects its reliability. However, vacancies can trigger the formation of heterogeneous phases that synergistically improve fracture properties. In this study, using MoSe2 as an example, we characterize the types and density of vacancies that can emerge under electron irradiation and quantify their effect on fracture. Molecular dynamic (MD) simulations, employing a re-parameterized Tersoff potential capable of accurately capturing bond dissociation and structural phase changes, reveal that isolated transition metal monovacancies or chalcogenide divacancies tend to arrest the crack tip and hence enhance the monolayer toughness. In contrast, isolated chalcogenide monovacancies do not significantly affect toughness. The investigation further reveals that selenium vacancy lines, formed by high electron dose rates, alter the crack propagating direction and lead to multiple crack kinking. Using atomic displacements and virial stresses together with a continuum mapping, displacement, strain, and stress fields are computed to extract mechanistic information, e.g., conditions for crack kinking and size effects in fracture events. The study also reveals the potential of specific defect patterns, “vacancy engineering,” to improve the toughness of 2H-TMDs materials.

36 MATERIALS SCIENCE↗

Ultrasonic nondestructive evaluation, microstructure, and fracture toughness interrelations

Ultrasonic techniques for mechanical property characterizations are reviewed and conceptual models are advanced for explaining and interpreting the empirically based results. At present, the technology is generally empirically based and is emerging from the research laboratory. Advancement of the technology will require establishment of theoretical foundations for the experimentally observed interrelations among ultrasonic measurements, mechanical properties, and microstructure. Conceptual models are applied to ultrasonic assessment of fracture toughness to illustrate an approach for predicting correlations found among ultrasonic measurements, microstructure, and mechanical properties.

Vary, Alex↗

Fracture of Charring Avcoat With Meshfree Material Response-Coupled Fracture Approach

Fracture of thermal protection systems (TPS) is typically unfavorable, but often unavoidable. TPS can fracture during entry, manufacturing or from impact. Many NASA missions use ablative materials for TPS, including the fore-body for Dragonfly (PICA) and Orion for Artemis-I (Avcoat). The material response to thermal and mechanical loads during entry is integral to TPS sizing, design and analysis. The fracture of TPS also depends, and can be caused by, the change of material properties during entry. Simulations that resolve fracture of TPS due to thermo-mechanical forces can identify TPS failure mechanisms and be applied to conditions inaccessible to ground testing. We present simulation work using a mesh-free/Lagrangian approach to solving continuum mechanics, coupled to material response. Two different materials are simulated under different model entry-like boundary conditions. The dynamic crack structure is analyzed and compared across simulations. Crack analyses inform the role of design features, such as entry trajectories and manufacturing-influenced material properties, play in TPS fracture.

Andrew P Santos↗

PYSIMFRAC: A Python library for synthetic fracture generation and analysis

In this paper, we introduce PYSIMFRAC, an open-source python library for generating 3-D synthetic fracture realizations, integrating with fluid simulators, and performing analysis. PYSIMFRAC allows the user to specify one of three fracture generation techniques (Box, Gaussian, or Spectral) and perform statistical analysis including the autocorrelation, moments, and probability density functions of the fracture surfaces and aperture. This analysis and accessibility of a python library allows the user to create realistic fracture realizations and vary properties of interest. In addition, PYSIMFRAC includes integration examples to two different pore-scale simulators and the discrete fracture network simulator, dfnWorks. The capabilities developed in this work provides opportunity for quick and smooth adoption and implementation by the wider scientific community for accurate characterization of fluid transport in geologic media. We present PYSIMFRAC along with integration examples and discuss the ability to extend PYSIMFRAC from a single complex fracture to complex fracture networks.

58 GEOSCIENCES↗

Characterization of Al-Cu-Mg-Ag Alloy RX226-T8 Plate

Aluminum-copper-magnesium-silver (Al-Cu-Mg-Ag) alloys that were developed for thermal stability also offer attractive ambient temperature strength-toughness combinations, and therefore, can be considered for a broad range of airframe structural applications. The current study evaluated Al-Cu-Mg-Ag alloy RX226-T8 in plate gages and compared performance with sheet gage alloys of similar composition. Uniaxial tensile properties, plane strain initiation fracture toughness, and plane stress tearing resistance of RX226-T8 were examined at ambient temperature as a function of orientation and thickness location in the plate. Properties were measured near the surface and at the mid-plane of the plate. Tensile strengths were essentially isotropic, with variations in yield and ultimate tensile strengths of less than 2% as a function of orientation and through-thickness location. However, ductility varied by more than 15% with orientation. Fracture toughness was generally higher at the mid-plane and greater for the L-T orientation, although the differences were small near the surface of the plate. Metallurgical analysis indicated that the microstructure was primarily recrystallized with weak texture and was uniform through the plate with the exception of a fine-grained layer near the surface of the plate. Scanning electron microscope analysis revealed Al-Cu-Mg second phase particles which varied in composition and were primarily located on grain boundaries parallel to the rolling direction. Fractography of toughness specimens for both plate locations and orientations revealed that fracture occurred predominantly by transgranular microvoid coalescence. Introduction High-strength, low-density Al-Cu-Mg-Ag alloys were initially developed to replace conventional 2000 (Al-Cu-Mg) and 7000 (Al-Zn-Cu-Mg) series aluminum alloys for aircraft structural applications [1]. During the High Speed Civil Transport (HSCT) program, improvements in thermal stability were demonstrated for candidate aircraft wing and fuselage skin materials through the addition of silver to Al-Cu-Mg alloys based on Al 2519 chemistry [2]. Thermal stability of the resulting Al-Cu-Mg-Ag alloys, C415-T8 and C416-T8, was due to co-precipitation of the thermally stable . (AlCu) and ' (Al2Cu) strengthening phases [1-4]. The strength and toughness behavior was investigated for these alloys produced as 0.090-inch thick rolled sheet in the T8 condition and after various thermal exposures. The mechanical properties were shown to be competitive with conventional aircraft alloys, 2519-T8 and 2618-T8 [2]. During the Integral Airframe Structure (IAS) program, advanced aluminum alloys were examined for use in an integrally stiffened airframe structure where the skin and stiffeners would be machined from plate and extruded frames would be mechanically attached (see Figure 1) [5]. Advantages of integrally stiffened structure include reduced part count, and reduced assembly times compared to conventional built-up airframe structure. The near-surface properties of a thick plate are of significance for a machined integrally stiffened airframe structure since this represents the skin location. Properties measured at the mid-plane of the plate are more representative of the stiffener web. RX226 was developed to exploit strength-toughness improvements and thermal stability benefits of Al-Cu-Mg-Ag alloys in plate gages. This study evaluated the microstructure and properties of three gages of plate produced in the T8 condition.

Lach, Cynthia L.↗

Modeling brittle fracture due to anisotropic thermal expansion in polycrystalline materials

Here, this work investigated brittle fracture of polycrystalline materials due to thermal stresses arising from anisotropic thermal expansion. We used phase-field fracture simulations with the properties of alpha-uranium (α-U) and assumed a linear elastic mechanical response. Three-dimensional simulations were used to predict fracture for various conditions and crystallographic textures. We found that fracture was more pronounced during cooling than during heating because the anisotropy increased with temperature. We also found that the total crack surface area increased with increasing average misorientation, while the net shape change of the material decreased with increasing misorientation. Two-dimensional simulations in which one crystallographic coefficient of thermal expansion (CTE) was set to zero indicated that the expansion behavior in the crystallographic direction with the smallest CTE was the primary cause of fracture.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Tritium Aging Effects on Fracture Toughness of Stainless Steel Weldments

The long-term embrittlement effects of tritium and decay helium on the structural properties of stainless steels have been studied for years at Savannah River to provide required data for establishing safe operating conditions and lifetimes of pressure vessels used to contain tritium gas. In this study, the fracture toughness properties of the longest-aged tritium-precharged stainless-steel base metals and weldments tested at Savannah River were measured and compared to earlier results. The fracture toughness values were the lowest recorded here for tritium-exposed stainless steel. As-forged and as-welded specimens were thermally precharging with tritium gas at 34.5 MPa and 623 K, then aged for up to 17 years to buildin decay helium prior to testing. ASTM J-Integral fracture mechanics analyses, transmission electron microscopy (TEM), and small angle neutron scattering (SANS) examinations were conducted to characterize the effects of tritium and its radioactive decay product, helium-3. Results show that the fracture toughness values were reduced to less than 2-4% of the as-forged values for specimens with more than 1300 appm helium from tritium decay. The trend of decreasing fracture toughness values with increasing helium content was consistent with earlier observations, and the data show that Type 304L stainless steel is more resistant to tritium-induced cracking than Type 21-6-9 stainless at similar decay helium levels. The fracture toughness properties of long-aged weldments were also affected, but the reductions were not as severe over time because weldments did not retain as much tritium as did the base metals. TEM observations were used to characterize the effects of decay helium bubbles on the deformation substructures, but nanometer-sized helium bubbles were not easily resolved because of high dislocation densities within the forged microstructures. SANS results are presented that suggest the technique can provide information on decay helium bubble size, spacing, and distribution in these steels.

36 MATERIALS SCIENCE↗

Modeling Graphite Behavior (Fracture and Oxidation)

Purpose of this work Oxidation modeling Oxidation of full-scale components Local properties in oxidized components Graphite fracture strength Phase field fracture modeling Microstructurally informed fracture model IG-110 tensile results and comparison to experiment Work in progress and future work

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Insights into the hydro-mechanical behavior of a decimeter-scale fracture using the mini-SIMFIP probe

ABSTRACT: Understanding hydro-mechanical couplings in fractured rocks is essential for predicting the rock mass response during high-pressure fluid injection, including the stimulation of enhanced geothermal systems. However, fluid-driven fracture dislocations are challenging to measure due to the need for local displacement data at high fluid pressures. In this study, fluid-driven displacement across a decimeter-scale laboratory fracture was investigated using the mini-SIMFIP (step rate injection method for fracture in-situ properties) probe, which is a smaller version of the SIMFIP tool (Guglielmi et al., 2014). The mini-SIMFIP probe is able to resolve the full 3D displacement vector of a fracture. The probe was installed in one of two boreholes across a decimeter-scale saw-cut granite fracture. Two pressure step injection tests were conducted under the same isotropic stress conditions. By varying injection between the boreholes, we estimated the aperture profile across the fracture. The results show a consistent pressure-dependent opening as long as steady-state flow was maintained. At a certain pressure step, steady-state conditions were no longer achievable and the fracture opened rapidly. The pressure-opening relationship diverged between the two tests and indicated a homogenization of the aperture profile and an increase in the non-linearity of the flow regime.

Osten, J↗

Fracto-emission from fiber-reinforced and particulate filled composites

Fracto-emission (FE) in the emission of particles and photons during and following crack propagation. The types of particles observed include electrons (EE), positive ions (PIE), photons (phE), and excited and ground state neutral emission (NE). In this paper work is presented on the characterization of the various FE components and measurements relating FE to the fracture events and material properties involved. FE characteristics measured include total emission, time dependence relative to crack propagation, species of neutral and ionic components, energy of charged species, and time correlations between pairs of FE components. Experiments on fracture of epoxy, single fibers, fiber/epoxy strands, particulate filled epoxy, and multi-ply fiber/epoxy systems will be presented.

Dickinson, J. T.↗

Ion Size Effects on the Thermodynamic, Kinetic, and Mechanical Properties during Ion Exchange in Solid-State Electrolytes

Ion exchange offers a pathway to impose residual compressive stresses to mitigate the electro-chemo-mechanical cracking of solid-state electrolytes such as lithium lanthanum zirconium oxide. This study uses a coupled multiscale framework (integrating density functional theory (DFT), molecular dynamics (MD), and continuum modeling) to examine how exchange ion size influences stress, diffusion, fracture toughness, and electronic properties. Larger isovalent ions (Na + , Ag + , K + ) were exchanged with Li + , with DFT confirming their preference for octahedral 96h sites and a linear relationship between ion size and chemical free expansion coefficient. MD simulations reveal stress and concentration effects on exchange ion diffusivity at elevated temperatures, with Na + and Ag + maintaining favorable mobility while K + showing concentration-dependent clustering. Continuum modeling predicts the range of fracture strength improvements and the required ion exchange concentration profile. It was shown that a 5% surface exchange concentration can induce ∼0.6 GPa of surface compressive stress using Na + and ∼1.0 GPa of surface compressive stress using Ag + . On the other hand, larger ion exchange species may penalize Li + diffusivity by increasing the activation volume and activation energy. Interestingly, Na + has a negligible penalty on Li-ion diffusivity. The room temperature Li + ion diffusivity is reduced by ∼40% with Ag + ion exchange. Electronic band structure analysis shows no size-dependent change in the bandgap, though Ag + introduces localized defect states near the valence band maximum. This study highlights ion size as a key factor in optimizing LLZO properties, offering a framework to improve the solid-state battery performance.

Jagad, Harsh D. [Brown Univ., Providence, RI (Unit↗

Investigation of fracture in porous materials: a phase-field fracture study informed by ReaxFF

Microscopic features (e.g, pore shapes, sizes, and distribution) in porous material substantially affect the overall mechanical properties such as stiffness and strength. In turn, these material properties determine the macroscopic behaviors of fracture in the porous material. In certain cases, macroscopic properties can be derived from the porous skeleton and void ratio (i.e., porosity), but in many other cases, such derivation is a challenging task. This paper presents a numerical investigation of microporosity and micropore shapes effect on the macrofracture behavior in porous amorphous silica. For this study, we extend the recently-proposed combined molecular dynamic (MD) and phase-field (PF) fracture modeling approach by including different pore shapes in the atomistic domain. In the MD simulations, we adopt ReaxFF to evaluate the material properties, where four different micropore cases are considered. Based on the material properties derived from MD simulations, the macrofracture propagation of porous media is studied using hybrid PF simulation. In the characterization of the pore structure, the concept of pore ligament is proposed to relate the pore shape and the critical energy release rate. Two classical fracture problems were used to evaluate the effect of pore shape on the macrofracture behavior. The results of the case study show that although the micropore shapes change the macrofracture behaviors, these effects vary with the geometry and loading conditions of macroscopic boundary value problems. Furthermore, the case study also shows that the influence of micropore structure can be captured at the macroscopic level through the material properties derived from the MD simulations.

42 ENGINEERING↗

Whisker-reinforced ceramic composites for heat engine components

Much work was undertaken to develop techniques of incorporating SiC whiskers into either a Si3N4 or SiC matrix. The result was the fabrication of ceramic composites with ever-increasing fracture toughness and strength. To complement this research effort, the fracture behavior of whisker-reinforced ceramics is studied so as to develop methodologies for the analysis of structural components fabricated from this toughened material. The results, outlined herein, focus on the following areas: the use of micromechanics to predict thermoelastic properties, theoretical aspects of fracture behavior, and reliability analysis.

Duffy, Stephen F.↗

Fracture toughness of fibrous composite materials

Laminates with various proportions of 0 deg, 45 deg, and 90 deg plies were fabricated from T300/5208 and T300/BP-907 graphite/epoxy prepreg tape material. The fracture toughness of each laminate orientation or lay-up was determined by testing center-cracked specimens, and it was also predicted with the general fracture-toughness parameter. The predictions were good except when crack-tip splitting was large, at which time the toughness and strengths tended to be underpredicted. By using predictions, a parametric study was also made of factors that influence fracture toughness. Fiber and matrix properties as well as lay-up were investigated. Without crack-tip splitting, fracture toughness increases in proportion to fiber strength and fiber volume fraction, increases linearly with E(22)/E(11), is largest when the modulus for non-0 deg fibers is greater than that of 0 deg fibers, and is smallest for 0(m)/90(p)(s) lay-ups. (The E(11) and E(22) are Young's moduli of the lamina parallel to and normal to the direction of the fibers, respectively). For a given proportion of 0 deg plies, the most notch-sensitive lay-ups are 0(m)/90(p)(s) and the least sensitive are 0(m)/45(n)(s) and alpha(s). Notch sensitivity increases with the proportion of 0 deg plies and decreases with alpha. Strong, tough matrix materials, which inhibit crack-tip splitting, generally lead to minimum fracture toughness.

Poe, C. C., Jr.↗

Hydraulic Modeling of Induced and Propagated Fractures: Analysis of Flow and Pressure Data From Hydromechanical Experiments in the COSC-1 Deep Borehole in Crystalline Rock Near Åre, Sweden

To characterize the coupled hydromechanical behavior of rock fractures, the step-rate injection method for fracture in-situ properties (SIMFIP) was conducted with a specialized downhole probe developed by Guglielmi et.al. In June 2019, a field campaign was carried out near Åre, Sweden, where the SIMFIP probe was applied in the Collisional Orogeny in the Scandinavian Caledonides-1 scientific borehole to understand the dynamics of injection-induced fracture initiation, fracture opening, and shearing due to water injection-withdrawal in a borehole interval isolated by two packers. Three intervals were investigated at ~500 m depth: (a) an unfractured section (intact rock), (b) a section with non-conductive fractures, and (c) a section with hydraulically conductive fractures. Pressure, injection flow rate, and borehole wall displacement were simultaneously measured during the tests. In the present study, the geometry of the induced fracture and deformation of existing fractures at different time stages of the tests are determined based on a hydrologic model by using the measured pressure and flow data during each time stage of the experiment. A numerical model for the fluid flow within the fracture and the packed-off borehole interval is implemented within COMSOL Multiphysics. By matching model simulations with observed data for all three sections, estimates of the induced and propagated fractures' radius and aperture at successive time stages have been obtained in each case. We could also determine the non-linear relationship between fracture aperture and pressure for values above fracture opening pressures. The model results provide insights for the understanding of pressure-induced fracture initiation and propagation in crystalline rock.

58 GEOSCIENCES↗