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At least 289 records · Page 16

Modification of microstructure and properties of Ti-47Al-2Cr-4Nb-0.3W alloys fabricated by SPS with trace multilayer graphene addition

Highlights: • The TiAl alloys with different content addition of multilayer graphene were fabricated. • When the graphene content is 0.8 at.%, the mean grain size decreases to 8.2 μm. • The bending and fracture strength increase to 1000 MPa and 2347 MPa, respectively. • The friction coefficient decreased from 0.6 to 0.4, with a decrease by 1/3. - Abstract: In this paper, Ti-47Al-2Cr-4Nb-0.3W alloys with trace multilayer graphene addition were fabricated by spark plasma sintering to enhance both mechanical properties and tribological property simultaneously. With the addition of multilayer graphene, bending strength, compressive strength and tribological property of TiAl alloys are all improved. When graphene content increases from zero to 0.8 at.%, the mean grain size decreases from 14.8 ± 1.4 μm to 8.2 ± 0.8 μm. The bending strength reaches almost 1000 MPa and the fracture strength increases to 2347 ± 12 MPa, an increase of 15% compared with TiAl alloy. The friction coefficient also decreases from about 0.6 to 0.4, a decrease by 1/3 compared with TiAl alloy. The reasons for the improved mechanical properties and tribological property are the in-situ reaction plate-shape Ti{sub 2}AlC phase, fine needle-like Ti{sub 3}AlC phase as well as fine and homogeneous microstructure. The wear mechanism changes from abrasive wear to abrasive wear plus adhesive wear with the increased graphene content.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Electrochemically reduced graphene oxide nanosheet coatings as solid lubricants in humid air

Highlights: • A facile, low cost and green approach to fabricate ERGO coatings is reported. • The feasibility of using ERGO coatings as solid lubricants is demonstrated. • ERGO coatings reduce copper’s COF to 1/6 and wear rate to more than 1/260. - Abstract: A facile, low cost and green approach to fabricating graphene nanosheet coatings is reported. It is composed of spraying graphene oxide (GO) suspension to form GO nanosheet coatings followed by a low voltage electrochemical reduction process. The tribological performance of the as-prepared electrochemically reduced graphene oxide (ERGO) nanosheet coatings on copper disk are evaluated by sliding against steel ball in humid air. The friction coefficient of copper is reduced to 1/6 its value, and its specific wear rate is reduced more than two orders of magnitude when copper disk is coated with ERGO nanosheet coatings. These improved tribological performance are attributed to the presence of ERGO nanosheets in the sliding interface of steel vs. copper friction pair. They not only provide easy shearing, reducing the friction coefficient, but also effectively suppress abrasive wear and adhesive wear, decreasing the wear rate of copper disk.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Review of heat transfer enhancement techniques for single phase flows

The thermal energy exchange between a flowing fluid and its confining channel is a ubiquitous process in modern society. To enhance the fluid-to-wall or wall-to-fluid heat transfer, several techniques have been developed to maximize the contact area between the fluid and the inner wall and/or disrupt the flow to enhance circulation or induce turbulence. Deployment of channels having features capable of enhancing heat transfer enables the reduction of heat exchanger size while maintaining performance. Reduction in equipment size is critical due to the ability to minimize the required volume of costly working fluids and to mitigate potential safety concerns associated with total system fluid volume. Here, a comprehensive review of single-phase heat transfer enhancement techniques is presented. The article provides a thorough comparison by analyzing the heat transfer rate, pressure drop, and other operational aspects. Single-phase heat transfer enhancement methods are divided into active and passive techniques. Active methods such as electrohydrodynamic (EHD), magnetohydrodynamics (MHD), or mechanical motion require external power to create enhancement. Passive methods such as dimples, fins, or tape inserts do not require external input and rely only on surface modification. Although active methods are more expensive and difficult to implement compared to passive techniques, it enables active control of heat transfer augmentation. Finally, this review develops and summarizes key learning data for design optimization enabled by additive manufacturing and machine learning algorithms, helping to inform these next-generation heat exchanger design methodologies for a plethora of modern applications such as electrification of vehicles, computing, and classical industries.

42 ENGINEERING↗

Review of heat transfer enhancement techniques in two-phase flows for highly efficient and sustainable cooling

We show that two-phase internal flow is ubiquitous to many systems due to its ability to transfer large amounts of heat effectively. Recent advances motivated by sustainability have pushed towards augmenting the heat transfer between the tube and the two-phase working fluid. Augmenting heat transfer in two-phase flows enables process intensification, and compactness leading to reduced cost and material consumption. This review investigates the effect of heat transfer enhancement techniques on different fluids including R134a, R407C, R22, etc … The techniques are categorized into passive and active and focus on durable enhancement methods which do not include surface structuring or coating. Passive techniques utilize geometrical and surface modifications to induce better mixing. Several passive techniques are analyzed including fins, inserts, and more. In analyzing these techniques, the effect of changing geometric parameters is studied, and the limitations are highlighted. Further, active techniques that enable heat transfer enhancement through applying power are also investigated. Electrohydrodynamic approaches are analyzed and compared to passive techniques. Additionally, the implications of heat exchange enhancement in the context of global energy are discussed. An energy analysis discretized by the use sector is conducted, with an emphasis on predicting the future potential for renewable and sustainable development. Moreover, although active approaches provide the highest heat transfer enhancement, due to implementation difficulties, passive techniques are more frequently adopted. The review ends with discussion of next-generation heat exchangers which will rely more on additive manufacturing due to its flexibility and reduced cost per part as the technology matures.

Nusselt number↗

The extended wedge method: Atomic force microscope friction calibration for improved tolerance to instrument misalignments, tip offset, and blunt probes

One of the major challenges in understanding and controlling friction is the difficulty in bridging the length and time scales of macroscale contacts and those of the single asperity interactions they comprise. While the atomic force microscope (AFM) offers a unique ability to probe tribological surfaces in a wear-free single-asperity contact, instrument calibration challenges have limited the usefulness of this technique for quantitative nanotribological studies. A number of lateral force calibration techniques have been proposed and used, but none has gained universal acceptance due to practical considerations, configuration limitations, or sensitivities to unknowable error sources. This paper describes a simple extension of the classic wedge method of AFM lateral force calibration which: (1) allows simultaneous calibration and measurement on any substrate, thus eliminating prior tip damage and confounding effects of instrument setup adjustments; (2) is insensitive to adhesion, PSD cross-talk, transducer/piezo-tube axis misalignment, and shear-center offset; (3) is applicable to integrated tips and colloidal probes; and (4) is generally applicable to any reciprocating friction coefficient measurement. The method was applied to AFM measurements of polished carbon (99.999% graphite) and single crystal MoS{sub 2} to demonstrate the technique. Carbon and single crystal MoS{sub 2} had friction coefficients of {mu}= 0.20 {+-} 0.04 and {mu}= 0.006 {+-} 0.001, respectively, against an integrated Si probe. Against a glass colloidal sphere, MoS{sub 2} had a friction coefficient of {mu}= 0.005 {+-} 0.001. Generally, the measurement uncertainties ranged from 10%-20% and were driven by the effect of actual frictional variation on the calibration rather than calibration error itself (i.e., due to misalignment, tip-offset, or probe radius).

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Electric force microscopy of semiconductors: Theory of cantilever frequency fluctuations and noncontact friction

An electric force microscope employs a charged atomic force microscope probe in vacuum to measure fluctuating electric forces above the sample surface generated by dynamics of molecules and charge carriers. We present a theoretical description of two observables in electric force microscopy of a semiconductor: the spectral density of cantilever frequency fluctuations (jitter), which are associated with low-frequency dynamics in the sample, and the coefficient of noncontact friction, induced by higher-frequency motions. The treatment is classical-mechanical, based on linear response theory and classical electrodynamics of diffusing charges in a dielectric continuum. Calculations of frequency jitter explain the absence of contributions from carrier dynamics to previous measurements of an organic field effect transistor. Calculations of noncontact friction predict decreasing friction with increasing carrier density through the suppression of carrier density fluctuations by intercarrier Coulomb interactions. The predicted carrier density dependence of the friction coefficient is consistent with measurements of the dopant density dependence of noncontact friction over Si. Our calculations predict that in contrast to the measurement of cantilever frequency jitter, a noncontact friction measurement over an organic semiconductor could show appreciable contributions from charge carriers.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Impact of laser power density on tribological properties of Pulsed Laser Deposited DLC films

Fabrication of wear resistant and low friction carbon films on the engineered substrates is considered as a challenging task for expanding the applications of diamond-like carbon (DLC) films. In this paper, pulsed laser deposition (PLD) technique is used to deposit DLC films on two different types of technologically important class of substrates such as silicon and AISI 304 stainless steel. Laser power density is one of the important parameter used to tailor the fraction of sp{sup 2} bonded amorphous carbon (a-C) and tetrahedral amorphous carbon (ta-C) made by sp{sup 3} domain in the DLC film. The I(D)/I(G) ratio decreases with the increasing laser power density which is associated with decrease in fraction of a-C/ta-C ratio. The fraction of these chemical components is quantitatively analyzed by EELS which is well supported to the data obtained from the Raman spectroscopy. Tribological properties of the DLC are associated with chemical structure of the film. However, the super low value of friction coefficient 0.003 is obtained when the film is predominantly constituted by a-C and sp{sup 2} fraction which is embedded within the clusters of ta-C. Such a particular film with super low friction coefficient is measured while it was deposited on steel at low laser power density of 2 GW/cm{sup 2}. The super low friction mechanism is explained by low sliding resistance of a-C/sp{sup 2} and ta-C clusters. Combination of excellent physical and mechanical properties of wear resistance and super low friction coefficient of DLC films is desirable for engineering applications. Moreover, the high friction coefficient of DLC films deposited at 9GW/cm{sup 2} is related to widening of the intergrain distance caused by transformation from sp{sup 2} to sp{sup 3} hybridized structure.

36 MATERIALS SCIENCE↗

Growth mechanism and composition of ultrasmooth a-C:H:Si films grown from energetic ions for superlubricity

Growth mechanism and ion energy dependence of composition of ultrasmooth a-C:H:Si films grown from ionization of tetramethylsilane (TMS) and toluene mixture at a fixed gas ratio have been investigated by varying the applied bias voltage. The dynamic scaling theory is employed to evaluate the roughness evolution of a-C:H:Si films, and to extract roughness and growth exponents of α ∼ 0.51 and β ∼ 0, respectively. The atomically smooth surface of a-C:H:Si films with Ra ∼ 0.1 nm is thermally activated by the energetic ion-impact induced subsurface “polishing” process for ion dominated deposition. The ion energy (bias voltage) plays a paramount role in determining the hydrogen incorporation, bonding structure and final stoichiometry of a-C:H:Si films. The hydrogen content in the films measured by ERDA gradually decreases from 36.7 to 17.3 at. % with increasing the bias voltage from 0.25 to 3.5 kV, while the carbon content in the films increases correspondingly from 52.5 to 70.1 at. %. The Si content is kept almost constant at ∼9–10 at. %. Depending on the ion-surface interactions, the bonding structure of a-C:H:Si films grown in different ion energy regions evolves from chain-developed polymer-like to cross-linked diamond-like to sp{sup 2}-bonded a–C as revealed by XPS, Raman, and FTIR analysis. Such a structural evolution is reflected in their measured nanomechanical properties such as hardness, modulus, and compressive stress. An enhanced viscoplastic behavior (i.e., viscoplastic exponent of ∼0.06) is observed for polymeric a-C:H:Si films. A hydrogen content threshold (H > 20 at. %) exists for the as-grown a-C:H:Si films to exhibit superlow friction in dry N{sub 2} atmosphere. An extremely low friction coefficient of ∼0.001 can be obtained for polymer-like a-C:H:Si film. These near-frictionless a-C:H:Si films are strongly promising for applications in industrial lubricating systems.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Electron microscopic evidence for a tribologically induced phase transformation as the origin of wear in diamond

Tribological testing of a coarse-grained diamond layer, deposited by plasma-enhanced chemical vapor deposition, was performed on a ring-on-ring tribometer with a diamond counterpart. The origin of the wear of diamond and of the low friction coefficient of 0.15 was studied by analyzing the microstructure of worn and unworn regions by transmission and scanning electron microscopy. In the worn regions, the formation of an amorphous carbon layer with a thickness below 100 nm is observed. Electron energy loss spectroscopy of the C-K ionization edge reveals the transition from sp{sup 3}-hybridized C-atoms in crystalline diamond to a high fraction of sp{sup 2}-hybridized C-atoms in the tribo-induced amorphous C-layer within a transition region of less than 5 nm thickness. The mechanically induced phase transformation from diamond to the amorphous phase is found to be highly anisotropic which is clearly seen at a grain boundary, where the thickness of the amorphous layer above the two differently oriented grains abruptly changes.

36 MATERIALS SCIENCE↗

Impact of higher-order flows in the moment equations on Pfirsch-Schlüter friction coefficients

The impact of the higher-order flows in the moment approach on an estimate of the friction coefficients is numerically examined. The higher-order flows are described by the lower-order hydrodynamic flows using the collisional plasma assumption. Their effects have not been consistently taken into account thus far in the widely used neoclassical transport codes based on the moment equations in terms of the Pfirsch-Schlüter flux. Due to numerically solving the friction-flow matrix without using the small-mass ratio expansion, it is clearly revealed that incorporating the higher-order flow effects is of importance especially for plasmas including multiple hydrogenic ions and other lighter species with similar masses.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Energy relaxation of a dissipative quantum oscillator

The dissipative harmonic oscillator is studied as a model for vibrational relaxation in a liquid environment. Continuum limit expressions are derived for the time-dependent average energy, average width of the population, and the vibrational population itself. The effect of the magnitude of the solute-solvent interaction, expressed in terms of a friction coefficient, solvent temperature, and initial energy of the oscillator on the relaxation has been studied. These results shed light on the recent femtosecond stimulated Raman scattering probe of the 1570 cm{sup −1} −C=C− stretching mode of trans-Stilbene in the first (S{sub 1}) excited electronic state. When the oscillator is initially cold with respect to the bath temperature, its average energy and width increase in time. When it is initially hot, the average energy and width decrease with time in qualitative agreement with the experimental observations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effect of radiation and magnetohydrodynamic free convection boundary layer flow on a solid sphere with Newtonian heating in a micropolar fluid

In this paper, the effect of radiation on magnetohydrodynamic free convection boundary layer flow on a solid sphere with Newtonian heating in a micropolar fluid, in which the heat transfer from the surface is proportional to the local surface temperature, is considered. The transformed boundary layer equations in the form of nonlinear partial differential equations are solved numerically using an implicit finite difference scheme known as the Keller-box method. Numerical solutions are obtained for the local wall temperature and the local skin friction coefficient, as well as the velocity, angular velocity and temperature profiles. The features of the flow and heat transfer characteristics for various values of the Prandtl number Pr, micropolar parameter K, magnetic parameter M, radiation parameter N{sub R}, the conjugate parameter γ and the coordinate running along the surface of the sphere, x are analyzed and discussed.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Nanoscale wear and kinetic friction between atomically smooth surfaces sliding at high speeds

The kinetic friction and wear at high sliding speeds is investigated using the head-disk interface of hard disk drives, wherein the head and the disk are less than 10 nm apart and move at sliding speeds of 5–10 m/s relative to each other. While the spacing between the sliding surfaces is of the same order of magnitude as various AFM based fundamental studies on friction, the sliding speed is nearly six orders of magnitude larger, allowing a unique set-up for a systematic study of nanoscale wear at high sliding speeds. In a hard disk drive, the physical contact between the head and the disk leads to friction, wear, and degradation of the head overcoat material (typically diamond like carbon). In this work, strain gauge based friction measurements are performed; the friction coefficient as well as the adhering shear strength at the head-disk interface is extracted; and an experimental set-up for studying friction between high speed sliding surfaces is exemplified.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Optimizing the equal channel angular pressing process (ECAP) operation parameters to produce bulk nanostructure materials

In this work we were interested in doing simulation using finite elements analysis (FEA) to study the equal channel angular pressing process (ECAP), which is currently one of the most popular methods of severe plastic deformation Processes (SPD). for fabricating Ultra-Fine Grained (UFG) materials, because it allows very high strains to be imposed leading to extreme work hardening and microstructural refinement. The main object of this study is to establish the influence of main parameters which effect ECAP process which are magnitude of the die angle and the friction coefficient. The angle studied between (90-135°) degree, and magnitude of the friction coefficient μ between (0.12-0.6), and number of pass. The samples were made from aluminum alloy at room temperature with (15X 15) mm cross section and 150 mm length. The simulation result shows that normal elastic strain, shears elastic strain, and max. shear elastic strain increased, when changing the angle from 90° to 100°. and decrease between the angle 110° to 135°. Also the total deformation increased when we change die angle from 90° to 135°. By studding the friction effect on the die and sample we noted that increasing the friction coefficient from 0.12 to 0.6, normal elastic strain, and shear elastic strain increased and increasing the friction coefficient from 0.1 to 0.6 decrease the normal and shear stress.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Tribological properties of CrN coatings deposited by nitro-chromizing treatment on AISI D2 steel

In this work, the wear test of uncoated and chromium nitride coated AISI D2 cold work tool steel against alumina ball realized at 0.1 m/s sliding speeds and under the loads of 2.5N, 5N and 10N. Steel samples were nitrided at 575°C for 8 h in the first step of the coating process, and then chromium nitride coating was performed thermo-reactive deposition technique (TRD) in a powder mixture consisting of ferro-chromium, ammonium chloride and alumina at 1000°C for 2 h. Nitro-chromized samples were characterized by X-Ray diffraction analysis (XRD), scanning electron microscopy (SEM), micro-hardness and ball on disk wear tests. The coating layer formed on the AISI D2 steel was compact and homogeneous. X-ray studies showed that the phase formed in the coated layer is Cr{sub 2}N. The depth of the layer was 8.15 µm. The average hardness of the layer was 2160±15 HV{sub 0.025}. For uncoated and chromium nitride materials, wear rate increased with increasing load. The results of friction coefficient and wear rate of the tested materials showed that the CrN coating presents the lowest results.

36 MATERIALS SCIENCE↗

The mechanical properties measurement of multiwall carbon nanotube reinforced nanocrystalline aluminum matrix composite

Nanocrystalline aluminum matrix composite containing carbon nanotubes were fabricated using physical mixing method followed by cold pressing. The microstructure of the composite has been investigated using X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy techniques. These studies revealed that the carbon nanotubes were homogeneously dispersed throughout the metal matrix. The consolidated samples were pressureless sintered in inert atmosphere to further actuate a strong interface between carbon nanotubes and aluminum matrix. The nanoindentation tests carried out on considered samples showed that with the addition of 0.5 wt% carbon nanotubes, the hardness and elastic modulus of the aluminum matrix increased by 21.2 % and 2 % repectively. The scratch tests revealed a decrease in the friction coefficient of the carbon nanotubes reinforced composite due to the presence of lubricating interfacial layer. The prepared composites were promising entities to be used in the field of sporting goods, construction materials and automobile industries.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Slip length crossover on a graphene surface

Using equilibrium and non-equilibrium molecular dynamics simulations, we study the flow of argon fluid above the critical temperature in a planar nanochannel delimited by graphene walls. We observe that, as a function of pressure, the slip length first decreases due to the decreasing mean free path of gas molecules, reaches the minimum value when the pressure is close to the critical pressure, and then increases with further increase in pressure. We demonstrate that the slip length increase at high pressures is due to the fact that the viscosity of fluid increases much faster with pressure than the friction coefficient between the fluid and the graphene. This behavior is clearly exhibited in the case of graphene due to a very smooth potential landscape originating from a very high atomic density of graphene planes. By contrast, on surfaces with lower atomic density, such as an (100) Au surface, the slip length for high fluid pressures is essentially zero, regardless of the nature of interaction between fluid and the solid wall.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗