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At least 289 records · Page 16

Chemistry of Star-Forming Cores

Chemical effects arising from the exchange of molecules between dust and gas in dense clumps are described. Selective desorption of CO and N2 from grains in cool cores can account for the presence of ammonia in several cores in the NGC 2024 cloud. Evaporation of ices containing methanol and ethanol can lead to detectable abundances of (C2H5)(sub 2)O and CH3OC2H5. Results are presented for the hot core chemistries of sulphur and phosphorus which are initiated by evaporated hydrogen sulphide and phosphine. The implications of these studies for understanding the nature of molecular mantles, the evolution of molecular complexity in the gas phase, and the presence of small-scale abundance gradients in star-forming regions, are briefly discussed.

Charnley, S. B.↗

Low Temperature Formation of Carbonaceous Grains from Hydrocarbons and PAHs with the COSmIC Facility

Complex carbon molecules and ions are ubiquitous in space and form the building blocks of the carbonaceous components of cosmic dust grains, ultimately contributing to the formation of planets. We report experimental investigations of the low temperature chemical pathways leading to the formation of cosmic grain analogs from gas phase molecular precursors to better understand the evolution of cosmic carbon. The study of the formation of dust is essential to understand and to quantify the budget of extraterrestrial organic molecules. Although dust plays an important role in the evolution of interstellar chemistry and in the formation of organic molecules, little is known on the formation and destruction processes of carbonaceous dust. The experiments were performed using the Cosmic Simulation Chamber (COSmIC) to generate and characterize solid grains formed from gas phase precursors under controlled conditions representative of astrophysical environments [1]. Using COSmIC, it is possible to investigate the evolution of cosmic carbon from the formation of neutral and ionized hydrocarbons and PAHs in the gas phase [2], to solid carbon grains [3, 4, 5]. This is achieved by using a pulsed slit discharge nozzle to produce an adiabatic jet expansion and cool down Ar-hydrocarbon and PAH gas mixtures to astrophysically relevant temperature before inducing chemistry by generating a plasma discharge in the stream of the expansion. This plasma induced chemistry results in the formation of complex molecules and solid particles, analogs of cosmic grains in situ in the plasma expansion (i.e., without wall effects) that are carried by the accelerated gas in the expansion, and collected on substrates placed a few centimeters downstream of the electrodes. The results of a preliminary solid phase ex-situ analysis of cosmic grain analogs produced from a series of gas mixtures including hydrocarbons such as CH4 and C2H2 [3] and PAHs [4, 5] found in circumstellar ejecta of late C stars will be discussed. SEM imaging was used to provide insight on the impact of the precursors on the morphology and growth structure of the grains produced [3]. Laser desorption mass spectrometry was used to identify the molecules making up the main structures within the condensed grains [4] while X-ray irradiation and X-ray photoemission spectroscopy were used to investigate the impact the impact of stellar X-rays on cosmic dust.

Carbonaceous Grains↗

Liquid Piston with Spray Cooling Near-Isothermal Compressor

The goal of this project was to prototype and characterize the performance of a liquid-piston spray-cooled gas compressor. The working principle of the compressor enables optimized high-efficiency operation over a very wide range of operating conditions, unlike conventional compressors that are optimized for a narrow range of operating conditions. The compressor technology is suitable for many applications, such as gas pipeline transport, gas storage, and commercial and residential heat pumps. Both physical testing and computational fluid dynamics (CFD) modeling of the processes using the Oak Ridge National Laboratory high-performance computing center were completed. The experimental and CFD studies focused on a near-isothermal liquid-piston compressor (LPC) that uses propylene glycol to compress CO 2 . The first prototype demonstrated isothermal operation during several sequentially executed cycles of CO 2 compression and raised the temperature of the compressed CO 2 by only 2 K, compared with approximately 6 K when the gas was compressed non-isothermally. Isothermal operation was demonstrated at CO 2 flow rates of up to 2 L/min. The second prototype was designed with two compression chambers to allow continuous flow of high-pressure CO 2 . However, the design of the valve train to direct flow between the compression chambers was not sufficient to allow demonstration of CO 2 compression. Numerical simulations of the LPC in which the compression chamber was filled with propylene glycol injected from the bottom inlet were performed using large eddy simulation (LES) with the wall-adapting local eddy-viscosity subgrid-scale model coupled with the multiphase volume of fluid (VOF) model to simulate the transient interface between gas and liquid and to capture the heat and mass transfers within the compression chamber. In this effort, the effects of boundary conditions applied to the LES-VOF calculations (i.e., no wall, an adiabatic wall, and a wall with a heat flux subscribed) on the overall pressure and temperature of the CO 2 gas as well as the transient evolution of flow and heat transfer within the compression chamber were investigated and are discussed in this report. The LES calculation with no wall showed no dynamical flow patterns, and the volume-averaged temperature of CO 2 increased from 305 to 392.7 K, whereas LES calculations with a constant wall temperature or a wall heat flux had similar increases of CO 2 temperatures. The results of the LES simulation using a wall heat flux showed different stages in the compression process and revealed dynamical formation and interaction of CO 2 gas layers and circulation flow patterns within the chamber that contributed to the overall heat transfer between the solid wall, gas, and liquid surface in the compressor. Though an industrial partnership for commercializing the compressor was not secured, the technology was attractive for an industrial partner to use in two research proposals in response to US Department of Energy funding opportunity announcements.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

The Return of Astromaterials to Earth Over the Next Decade

We are entering a new and golden age of sample return missions. In the coming decade we will harvest samples from Comet P/Wild II and interstellar dust courtesy of the STARDUST Mission (Brownlee et al., 1997), an asteroid (probably 4660 Nereus or 1989ML) by the ISAS MUSES-C Mission (ISAS, 1997), and solar wind by the Genesis Mission. A sample return from Mars is also envisioned as early as 2008, and possibly one from the two moons of Mars. It is, however, sobering to realize that MUSES-C aims to return 3-10 g of sample, STARDUST will provide micrograms of comet and interstellar dust, and Genesis will harvest only few micrograms of atoms. The diminutive size of the returning samples may be a source of concern for petrologists used only to looking at hefty lunar rocks and meteorites. How much sample is really needed to achieve prime science objectives, while maintaining a cost effective mission? The range of geological processes that we will want to address with these samples is staggering, encompassing not merely the entire history of the Solar system, but the history of the elements themselves. The interstellar processes include element formation, production and interactions with radiation, formation of organics, grain condensation and evolution, and interactions with magnetic fields. In the pre-accretionary (nebular) environment we wish to understand grain condensation, evaporation and recondensation, shock, radiation processing, solar energetic particle implantation, gas composition, the magnetic environment, and the evolution of organics. Finally, for solid bodies we wish to examine accretion history, shock, brecciation, impact gardening, metamorphism, aqueous alteration, weathering, exposure history, volcanism, fumarolic activity, differentiation, the magnetic environment, atmosphere evolution, and the evolution of organics. Since 1981, NASA has supported asteroid and comet science by collecting dust grains from these bodies in the stratosphere, and making them available for analysis in laboratories worldwide (Warren and Zolensky, 1994). Over the succeeding 17 years, many new techniques have been developed for these painstaking analyses, by at least 24 different laboratories across the globe. Despite the fact that the particle supply has always exceeded the demand, the painstaking efforts required for most of the nano-scale analyses have resulted in only 1520 grains having been analyzed, with a total mass of only 0.52 micrograms. Thus we really require less sample for analysis than one might imagine.

Zolensky, Michael E.↗

Evolution of planetesimal velocities

A self-consistent set of equations for the velocity evolution of a general planetesimal population is presented. The equations are given in a form convenient for calculations of the early stages of planetary accumulation when it is necessary to model the planetesimal swarm by methods of gas dynamics, rather than follow the orbital evolution of individual bodies. Steady state velocities of a simple planetesimal population consisting of two different sizes of bodies are calculated. Dynamical friction is found to be an important mechanism for transferring kinetic energy from the larger planetesimals to the smaller ones. When the small planetesimals are relatively abundant, gas drag and inelastic collisions among the smaller bodies are of comparable importance for dissipating energy from the population.

Stewart, Glen R.↗

The Fast Evolution of SN 2010bh Associated with XRF 100316D

The first observational evidence of a connection between supernovae (SNe) and gamma-ray bursts (GRBs) was found about a decade ago. Since then, only half a dozen spectroscopically confirmed associations have been discovered and XRF 1003160 associated with the type-Ic SN 20lObh is among the latest. Aims. We constrain the progenitor radius, the host-galaxy extinction, and the physical parameters of the explosion of XRF l00316D/SN 20lObh at z 0.059. We study the SN brightness and colours in the context of GRB-SNe. Methods. We began observations with the Gamma-Ray burst Optical and Near-infrared Detector (GROND) 12 hours after the GRB trigger and continued until 80 days after the burst. GROND provided excellent photometric data in six filter bands covering a wavelength range from approximately 350 to 1800 nm, significantly expanding the pre-existing data set for this event. Combining GROND and Swift data, the early broad-band spectral energy distribution (SED) is modelled with a blackbody and afterglow component attenuated by dust and gas absorption. The temperature and radius evolution of the thermal component are analysed and combined with earlier measurements available from the literature. Templates of SN 1998bw are fitted to the SN itself to directly compare the lightcurve properties. Finally, a two-component parametrized model is fitted to the quasi-bolometric light curve. which delivers physical parameters of the explosion. Results. The best-fit models to the broad-band SEDs imply moderate reddening along the line of sight through the host galaxy (A(sub v.host = 1.2 +/- 0.1 mag). Furthermore, the parameters of the blackbody component reveal a cooling envelope at an apparent initial radius of 7 x 10(exp 11) cm, which is compatible with a dense wind surrounding a Wolf-Rayet star. A multicolor comparison shows that SN 2010bh is 60 - 70% as bright as SN 1998bw. Reaching maximum brightness at 8 - 9 days after the burst in the blue bands, SN 20lObh proves to be the most rapidly evolving GRB-SNe to date. Modelling of the quasi-bolometric light curve yields M(sub Ni) = 0.21 +/- 0.03 solar M and M(sub ej) = 2.6 +/- 0.2 solar M, typical of values within the GRB-SN population. The kinetic energy is E(sub k) = (2.4 +/- 0.7) x 10(exp 52) erg, which is making this SN the second most energetic GRB-SN after SN 1998bw. Conclusions. This supernova has one of the earliest peaks ever recorded and thereafter fades more rapidly than other GRB-SNe, hypernovae, or typical type-Ic SNe. This could be explained by a thin envelope expanding at very high velocities, which is therefore unable to retain the gamma-rays that would prolong the duration of the SN event.

Olivares E., F.↗

Noble gases as tracers of the origin and evolution of the Martian atmosphere and the degassing history of the planet

Noble gas analysis of Martian samples can provide answers to a number of crucial questions. Some of the most obvious benefits will be in Martian chronology, using techniques that have been applied to lunar samples. However, these are by no means the only relevant noble gas studies possible. Since Mars has a substantial atmosphere, noble gases can be used to study the origin and evolution of that atmosphere, including the degassing history of the planet. This type of study can provide constraints on: (1) the total noble gas inventory of the planet, (2) the number of noble gas reservoirs existing, and (3) the exchange of gases between these reservoirs. How to achieve these goals are examined.

Swindle, T. D.↗

Effects of Gravity on Bubble Formation at a Plate Orifice

A model of the dynamic regime of gas injection through a submerged plate orifice into an ideally wetting liquid is developed in the circumstance when successively detached bubbles may be regarded as independent objects. Two major factors favor bubble detachment: the buoyancy force and a force due to the momentum inflow into the bubble with injected gas. In normal and moderately reduced gravity, the first factor dominates. At relatively low flow rates, a growing bubble is modeled as a spherical segment touching the orifice perimeter during the whole period of its evolution till detachment. If the flow rate exceeds a critical value, another stage of bubble evolution occurs in which an almost spherical gas envelope is connected with the orifice by a nearly cylindrical gaseous stem that lengthens as the bubble rises above the plate. The bubble continues to grow until the gas supply through the stem is completely cut off, after which back flow of gas into the stem from the bubble becomes possible. In microgravity, the second factor prevails, and the latter stage is always present irrespective of the flow rate. However, the gas envelope rises and the stem lengthens very slowly. This difference in the underlying physical mechanisms provides for key properties of bubble growth and detachment being drastically different in appreciable and sufficiently reduced gravity. The frequency of bubble formation slightly decreases with and the detachment volume is almost proportional to the gas flow rate in the first case, in accordance with familiar relations. In the second case, the first variable is proportional to the flow rate whereas the second one is independent of it. Effects of other parameters, such as the orifice radius, gas and liquid densities, and surface tension are discussed.

Webbon, Bruce W.↗

The Interaction of Hot and Cold Gas in the Disk and Halo of Galaxies

Most of the thermal energy in the Galaxy and perhaps most of the baryons in the Universe are found in hot (log T approximately 5.5 - 7) gas. Hot gas is detected in the local interstellar medium, in supernova remnants (SNR), the Galactic halo, galaxy clusters and the intergalactic medium (IGM). In our own Galaxy, hot gas exists in large superbubbles up to several hundred pc in diameter that locally dominate the interstellar medium (ISM) and determine its thermal and dynamic evolution. While X-ray observations using ROSAT, Chandra and XMM have allowed us to make dramatic progress in mapping out the morphology of the hot gas and in understanding some of its spectral characteristics, there remain fundamental questions that are unanswered. Chief among these questions is the way that hot gas interacts with cooler phase gas and the effects these interactions have on hot gas energetics. The theoretical investigations we proposed in this grant aim to explore these interactions and to develop observational diagnostics that will allow us to gain much improved information on the evolution of hot gas in the disk and halo of galaxies. The first of the series of investigations that we proposed was a thorough exploration of turbulent mixing layers and cloud evaporation. We proposed to employ a multi-dimensional hydrodynamical code that includes non-equilibrium ionization (NEI), radiative cooling and thermal conduction. These models are to be applied to high velocity clouds in our galactic halo that are seen to have O VI by FUSE (Sembach et ai. 2000) and other clouds for which sufficient constraining observations exist.

Slavin, Jonathan↗

Stellar evolution in N-body simulations of disk galaxies. I

The Kalnajs (1972, 1976) Omega models of global mass and velocity distributions are employed in the present two-dimensional N-body simulation, which allows for a spectrum of particle masses, stellar explosions, explosion remnant interactions with an interstellar medium, and the creation of new stars from the gas. Two sequences of runs using the Omega values of 0.8 and 0.9 examine the separate and combined effects of particle mass distribution, the gravitational influence of an interstellar gas distribution on the N-body particles, and stellar evolution, allowing for stellar explosions and star formation from the gas. It is found that both Omega values' nonequilibrium results dramatically change when evolution is allowed to occur. These results call for more realistic coupled N-body and evolution simulations in order to improve the understanding of disk galaxy evolution.

Comins, N. F.↗

Advances in planetary geology

Three dissertations are provided covering (1) the stochastic evolution of asteroidal regoliths and the origin of brecciated and gas-rich meteorites; (2) ridge systems on Mars; and (3) the morphology and evolution of Ganymede and Callisto.

Woronow, A.↗

Deep Learning for Subsurface Flow: A Comparative Study of U‐Net, Fourier Neural Operators, and Transformers in Underground Hydrogen Storage

Subsurface flow research is essential for the sustainable management of natural resources and the environment. Deep learning (DL) has significantly advanced this field by developing efficient and accurate surrogate models to replace computationally expensive physics‐based simulations. These surrogate models are commonly used to predict the spatiotemporal evolution of state variables, such as gas saturation and reservoir pressure, in heterogeneous geological formations. Despite the various DL models applied to this task, there is a lack of studies systematically comparing their performance. This absence of comparative analysis leads to somewhat arbitrary DL model selection in subsurface flow research, resulting in suboptimal performance and potentially inaccurate predictions. To bridge this gap, we conduct a systematic comparison study of three popular DL architectures—U‐Net, Fourier Neural Operators (FNO), and Segmentation Transformer (SETR)—in surrogate modeling of underground hydrogen storage (UHS). We focus on UHS due to its promise of enhancing clean energy resilience and its cyclic operational conditions that represent common scenarios in various subsurface applications. We evaluate the models based on accuracy, training cost, and inference speed. The comparison shows that U‐Net achieves the highest accuracy, followed by SETR and FNO. Despite its lower accuracy, FNO has the highest inference speed. SETR offers competitive accuracy with the least training memory usage, demonstrating the potential of transformers in learning subsurface flow. Our results provide guidance for selecting DL models for surrogate modeling in a wide range of subsurface flow problems.

42 ENGINEERING↗

Evolution and persistence of SiO emission in nanosecond laser ablation plumes

Analyzing laser-produced plasmas in a controlled oxygen-containing environment provides insight into the formation and evolution of molecular species through gas-phase oxidation. This study explores the role of ambient pressure and oxygen availability in forming SiO molecular species in laser ablation plumes. The self-emission emanating during the reactive ablation of Si targets was characterized by optical emission spectroscopy and optical time-of-flight techniques. Our results showed that the SiO species formation was greatly influenced by both the ambient pressure and oxygen availability. The intensity and the persistence of SiO emission bands are lower at higher oxygen concentrations, indicating they are depopulated by the formation of more complex silicon oxides. The oxygen partial pressure effects on plume chemistry showed that SiO formation is favored even with a minimal oxygen concentration in the environment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Lithium–Divertor Interactions and Helium/Hydrogen Trapping in Lithiated Metals (Final Technical Report)

The goal of this project was to develop a fundamental understanding of helium and hydrogen behavior in lithium, both in bulk and at interfaces with tungsten, in order to inform the design of lithium based plasma facing components for fusion devices. Over the course of the award, the project produced the first comprehensive, peer reviewed dataset describing helium energetics, migration behaviors, and defect interactions in lithium. The research demonstrated that helium behaves in ways not previously observed in any other body centered cubic (BCC) metal: its interstitial configurations are more stable than substitutional ones, and its migration barriers are extraordinarily low, in some cases more than an order of magnitude below those in tungsten or iron. These discoveries reveal that helium in lithium diffuses so rapidly that its transport may be dominated by translational motion rather than the vibrationally activated mechanisms that underpin conventional solid state diffusion. This work lays a scientific foundation for understanding gas retention, bubble formation, and wall evolution in lithium based fusion environments and provides new computational tools, most notably a newly developed Li–He interatomic potential, for advancing future modeling efforts.

36 MATERIALS SCIENCE↗

The SAGA Survey. V. Modeling Satellite Systems around Milky Way–Mass Galaxies with Updated UniverseMachine

Abstract Environment plays a critical role in shaping the assembly of low-mass galaxies. Here, we use the U niverse M achine (UM) galaxy–halo connection framework and Data Release 3 of the Satellites Around Galactic Analogs (SAGA) Survey to place dwarf galaxy star formation and quenching into a cosmological context. UM is a data-driven forward model that flexibly parameterizes galaxy star formation rates (SFRs) using only halo mass and assembly history. We add a new quenching model to UM, tailored for galaxies with m ⋆ ≲ 10 9 M ⊙ , and constrain the model down to m ⋆ ≳ 10 7 M ⊙ using new SAGA observations of 101 satellite systems around Milky Way (MW)–mass hosts and a sample of isolated field galaxies in a similar mass range from the Sloan Digital Sky Survey. The new best-fit model, “UM-SAGA,” reproduces the satellite stellar mass functions, average SFRs, and quenched fractions in SAGA satellites while keeping isolated dwarfs mostly star-forming. The enhanced quenching in satellites relative to isolated field galaxies leads the model to maximally rely on halo assembly to explain the observed environmental quenching. Extrapolating the model down to m ⋆ ∼ 10 6.5 M ⊙ yields a quenched fraction of ≳30% for isolated field galaxies and ≳80% for satellites of MW-mass hosts at this stellar mass. Spectroscopic surveys can soon test this specific prediction to reveal the relative importance of internal feedback, cessation of mass and gas accretion, satellite-specific gas processes, and reionization for the evolution of faint low-mass galaxies.

Wang, Yunchong (ORCID:000000018913626X)↗

Thermal instability.

Stability of dilute gas in mechanical and thermal equilibrium with application to nongravitational condensation phenomena in astronomy, particularly solar corona

GAS DYNAMICS↗

The helium content of the galaxy.

Problem of large solar and stellar helium content examined in regard to nucleosynthesis theory that initial composition of galaxy was hydrogen

HELIUM↗

Remote measurement of pollution from aircraft

This paper discusses the problem of the remote measurement of tropospheric air pollution from aircraft platforms. Following a discussion of the energy sources available for passive remote sensing and the location of the absorption bands of the gases, it describes the spectral resolution that would be required and the relative merits of the shorter and longer infrared wavelengths. It then traces the evolution of one instrument concept (the gas filter correlation radiometer) to its present state, and describes flight results that show the technique to be capable of measuring carbon monoxide over water. A new instrument is described that will allow the measurements to be extended to areas over land.

Reichle, H. G., Jr.↗