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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

Advanced Compatibility Characterization Of AF-M315E With Spacecraft Propulsion System Materials Project

All spacecraft require propulsion systems for thrust and maneuvering. Propulsion systems can be chemical, nuclear, electrical, cold gas or combinations thereof. Chemical propulsion has proven to be the most reliable technology since the deployment of launch vehicles. Performance, storability, and handling are three important aspects of liquid chemical propulsion. Bipropellant systems require a fuel and an oxidizer for propulsion, but monopropellants only require a fuel and a catalyst for propulsion and are therefore simpler and lighter. Hydrazine is the state of the art propellant for monopropellant systems, but has drawbacks because it is highly hazardous to human health, which requires extensive care in handling, complex ground ops due to safety and environmental considerations, and lengthy turnaround times for reusable spacecraft. All users of hydrazine monopropellant must contend with these issues and their associated costs. The development of a new monopropellant, intended to replace hydrazine, has been in progress for years. This project will apply advanced techniques to characterize the engineering properties of materials used in AF-M315E propulsion systems after propellant exposure. AF-M315E monopropellant has been selected HQ's Green Propellant Infusion Mission (GPIM) to replace toxic hydrazine for improved performance and reduce safety and health issues that will shorten reusable spacecraft turn-around time. In addition, this project will fundamentally strengthen JSC's core competency to evaluate, use and infuse liquid propellant systems.

McClure, Mark B.↗
NASA NTRSDate not supplied

Hydrogen Peroxide-Water-Ethanol-Monopropellant Blend for CubeSat Propulsion

Monopropellant propulsion that provides high performance and low hazards compared to state-of-art hydrazine are being investigated under NASA, DOD and commercially sponsored green propellant research and development programs. This NASAeffort looks at phosphate stabilized 50% hydrogen peroxide/water –ethanol blends to evaluate their stability and combustion behavior in submillimeter diameter microtube combustion apparatus for cubesat propulsion applications. Exploratory 7-day stabilitytests find no pressure rise in a sealed test tube environment at room temperature indicating at least short term stability of the mixture. Temperature rise during combustion testing in resistively heated nickel microtube apparatus shows that micro-combustion is achieved in the tube. Propellant density is approximately 1.2 g/cm3compared to 1.0 g/cm3for hydrazine. Theoretical specific impulse of the stoichiometric blend is 219 s at a chamber pressure of 20 psia and an area ratio of 30:1. Density-specific impulseof this blendis263 swhile hydrazine is only about 215-220 sin small reaction control system thrusters. This provides about 20-22% more density-specific impulse for the cubesat compared to hydrazine. The theoreticalcombustion temperature is2168°F, whichis thermally compatible with stainless steel materials of constructionand the nickel catalystused in the tests. Combustion test results are given for stoichiometric, as well as fuel-leanand fuel-richpropellant formulations. Thesetests focus on thermally and catalytically supported combustionin the microtube, whichrequires a microtube preheat temperature of about 900°F and sufficient residence time to achieve combustion that is stable and anchored in the tubewithout blowing through the tube unreacted. Thrust class is expected to be in the 10 mN range based on flow rate and estimated specific impulse.Power requirements are generally below 25 Wto heat the tube. Steady state combustion testing is typically conducted for 3 minutes and shows littledegradation of the hardware over multiple test cyclesindicating thatthere is little catalyst degradation over time and littlecatalyst deactivation due tothe phosphate stabilizer inthe hydrogen peroxide.

Monopropellant↗
NASA NTRSDate not supplied

Hydrogen Peroxide-Water-Ethanol Monopropellant Blend for CubeSat Propulsion

Monopropellant propulsion that provides high performance and low hazards compared to state-of-art hydrazine are being investigated under NASA, DOD and commercially sponsored green propellant research and development programs. This NASA effort looks at phosphate stabilized 50% hydrogen peroxide/water –ethanol blends to evaluate their stability and combustion behavior in submillimeter diameter microtube combustion apparatus for cubesat propulsion applications. Exploratory 7-day stability tests find no pressure rise in a sealed test tube environment at room temperature indicating at least short term stability of the mixture. Temperature rise during combustion testing in resistively heated nickel microtube apparatus shows that micro-combustion is achieved in the tube. Propellant density is approximately 1.2 g/cu.cm compared to 1.0 g/cu.cm for hydrazine. Theoretical specific impulse of the stoichiometric blend is 219 s at a chamber pressure of 20 psia and an area ratio of 30:1. Density-specific impulse of this blend is 263 s while hydrazine is only about 215-220 s in small reaction control system thrusters. This provides about 20-22% more density-specific impulse for the cube sat compared to hydrazine. The the oretical combustion temperature is 2168°F, which is thermally compatible with stainless steel materials of construction and the nickel catalyst used in the tests. Combustion test results are given for stoichiometric, as well as fuel-lean and fuel-rich propellant formulations. These tests focus on thermally and catalytically supported combustion in the microtube, which requires a microtube preheat temperature of about 900°F and sufficient residence time to achieve combustion that is stable and anchored in the tube without blowing through the tube unreacted. Thrust class is expected to be in the 10 m N range based on flow rate and estimated specific impulse. Power requirements are generally below 25 W to heat the tube. Steady state combustion testing is typically conducted for 3 minutes and shows little degradation of the hardware over multiple test cycles indicating that there is little catalyst degradation over time and little catalyst deactivation due to the phosphate stabilizer in the hydrogen peroxide.

Monopropellant↗
NASA NTRS2019

Final Dawn Reaction Control System (RCS) propulsion system in-flight characterization

The Dawn spacecraft concluded eleven years of operations on 31-Oct-2018, upon depletion of its hydrazine supply in Ceres orbit during the second extended mission. Dawn’s Reaction Control System performed admirably during this lengthy campaign, including years of unanticipated and novel operation given Reaction Wheel Assembly failures during flight. New and modified modes of thruster operations were implemented during the mission. Pressure transducer drift was negligible, consumable limits were generally not exceeded (except for minor violations in Reaction Control System thruster cycles), and thruster performance was nominal throughout this long interplanetary journey. Tank models of hydrazine remaining mass were consistent with depletion within uncertainties, although thruster consumption-based models ended up being conservative by 15%. Unexpectedly, apparent nitrogen permeation through the hydrazine tank elastomer diaphragm allowed hydrazine in the lines below the tank to be pressurized and subsequently utilized during the final days of the mission.

Mizukami, Masashi↗
NASA NTRS2019

Final Dawn Reaction Control System (RCS) propulsion system in-flight characterization

The Dawn spacecraft concluded eleven years of operations on 31-Oct-2018, upon depletion of its hydrazine supply in Ceres orbit during the second extended mission. Dawn’s Reaction Control System performed admirably during this lengthy campaign, including years of unanticipated and novel operation given Reaction Wheel Assembly failures during flight. New and modified modes of thruster operations were implemented during the mission. Pressure transducer drift was negligible, consumable limits were generally not exceeded (except for minor violations in Reaction Control System thruster cycles), and thruster performance was nominal throughout this long interplanetary journey. Tank models of hydrazine remaining mass were consistent with depletion within uncertainties, although thruster consumption-based models ended up being conservative by 15%. Unexpectedly, apparent nitrogen permeation through the hydrazine tank elastomer diaphragm allowed hydrazine in the lines below the tank to be pressurized and subsequently utilized during the final days of the mission.

Mizukami, Masashi↗
NASA NTRSDate not supplied

Development of ASCENT Propellant Thrusters and Propulsion Systems

Since the 1960s, hydrazine technology has dominated the market of propulsion technology by providing reliable performance on a wide variety of spacecraft. Efforts to replace hydrazine with a higher-performance and safer alternative have engaged numerous emerging technologies in the industry to mature. ASCENT propellant, also known as AF-M315E, is an example of one such green propellant. Initially developed to provide a safer handling environment than hydrazine, ASCENT offers higher overall performance than a hydrazine equivalent by creating more heat during ignition. The next generation of propulsion technology, based on ASCENT propellant, produces a higher impulse and energy density, expanding the realm of applicable missions from LEO to GEO and beyond. Building on a strong background in small satellite technology and expertise in thermal and oxidation resistant materials, Plasma Processes began several thruster programs for variety of small satellite applications using ASCENT-based technology. Plasma Processes’ background expertise in thermal and oxidation resistant materials provides the necessary foundation to create ASCENT-based technology hardware.

Green Propellant↗
NASA NTRS1972

Nozzle exhaust plume backscatter experiment using the JPL Molsink facility

Qualitative tests were made by injecting water through a rocket nozzle wall, and the droplet trajectories were observed photographically. These tests were conducted for nozzles in which boundary layer flow is significant. The tests indicated that both gases and particulate matter will be found in the region outside of the plume boundaries, and can be calculated using current analytical techniques. A test program is being conducted to measure the distribution of exhaust gases from small nozzles using an electron beam/photomultiplier system and a matrix of quartz crystal microbalances. Calibration tests, using simulated hydrazine exhaust product gas mixtures, were also conducted. The test program and results of the pumping calibration tests with hydrazine (simulated hydrazine exhaust products) are reported.

Simon, W.↗
NASA NTRS1972

Material Compatibility with Space Storable Propellants. Design Guidebook

An important consideration in the design of spacecraft for interplanetary missions is the compatibility of storage materials with the propellants. Serious problems can arise because many propellants are either extremely reactive or subject to catalytic decomposition, making the selection of proper materials of construction for propellant containment and control a critical requirement for the long-life applications. To aid in selecting materials and designing and evaluating various propulsion subsystems, available information on the compatibility of spacecraft materials with propellants of interest was compiled from literature searches and personal contacts. The compatibility of both metals and nonmetals with hydrazine, monomethyl hydrazine, nitrated hydrazine, and diborance fuels and nitrogen tetroxide, fluorine, oxygen difluoride, and Flox oxidizers was surveyed. These fuels and oxidizers encompass the wide variety of problems encountered in propellant storage. As such, they present worst case situations of the propellant affecting the material and the material affecting the propellant. This includes material attack, propellant decomposition, and the formation of clogging materials.

Uney, P. E.↗
NASA NTRS1972

Surface tensions of propellants

An apparatus is described for determining the surface tension of propellants by measuring the maximum bubble pressure using two capillaries of different bores. The innovation is the use of a pressure transducer coupled to a bridge supply and a strip chart recorder for registering the development of the pressure difference as the bubble is formed and released. This enables the measurements to be made under controlled atmospheres and to be remotely operated. Preliminary experiments were done on propellant-grade hydrazine and monomethylhydrazine, and on purified hydrazine, at temperatures between 275.4 and 353.2 K. Straight-line expressions and logarithmic expressions reproduce equally well the variation of surface tension with temperature. Contaminated hydrazine, pre-exposed to coupons of 6Al-4V titanium alloy for long periods, gives slightly higher values of surface tension.

Razouk, R.↗
NASA NTRS1972

Survey of auxiliary-propulsion systems for communications satellites.

In order to provide insight for the selection of attitude- and stationkeeping propulsion systems for future communications satellites, current auxiliary-propulsion systems are surveyed. Thruster systems specifically considered are stored gas, vaporizing ammonia/electrothermal, catalytic monopropellant hydrazine, electrothermal monopropellant hydrazine, plenum monopropellant hydrazine, ion, colloid, and pulsed plasma. Each of the thruster types is discussed in three sections: (1) description of thruster system and how it functions, (2) space flight experience, and (3) survey of state-of-the-art thrusters. In addition, a qualitative tabulation of thruster characteristics is included.

Holcomb, L. B.↗
NASA NTRS1973

Operation of small rocket engines in the JPL high-vacuum molecular space simulator (Molsink)

The feasibility of operating small rocket engines in the Molsink facility was demonstrated. A 0.44-N (0.1-lbf) hydrazine engine and a 0.18-N (0.04-lbf) thruster using cold gas from a hydrazine plenum system were operated for both flight duty cycles and off-nominal conditions. The exhaust gases from these thrusters contain NH3, N2, and H2. The chamber was also calibrated for larger bipropellant engines using nitrogen tetroxide/monomethyl hydrazine (NTO/MMH). The exhaust products of these engines contain CO2, CO, H2, H2O, and H2. A mixture of cold gases simulating the engine exhaust was injected through a nozzle under conditions simulating thrust levels up to 26.7-N (6 lbf). Pulsing and continuous operations were investigated. The chamber background pressure traces were compared with the traces obtained for the same thrusters operated with pure nitrogen at approximately equivalent thrust. Satisfactory recuperation times were encountered in all the pulsing modes. Test times greater than 20s were obtained in steady state operation before the vacuum chamber back pressure climbed to prohibitive values.

Chirivella, J. E.↗
NASA NTRS1977

The distribution of ammonia and its photochemical products on Jupiter

Altitude profiles of ammonia and its photochemical products are generated in the light of measurements of the Jovian temperature structure, eddy transport coefficient, improved chemical scheme, and rate constants. Realistic limits are placed on the concentration of hydrazine which may participate in the recycling of ammonia on Jupiter. The maximum hydrazine-ice production rate is calculated to be about 1.3 mg/sq m per Jovian day. The distribution of nitrogen gas is presented with and without supersaturation of hydrazine. The nitrogen mixing ratio near the ammonia cloud top is estimated to be in the range between 10 to the -9th and 10 to the -11th power. An appreciable latitudinal variation in the ammonia concentration is expected.

Atreya, S. K.↗
NASA NTRS1979

Data reduction and performance determination

Definitions, algorithms, and procedures for the reduction of monopropellant thruster measurements to performance parameters are provided. A brief discussion of acquisition and recording systems is also included. Emphasis is placed upon monopropellant hydrazine engines, and some parameters relate specifically to the catalytic decomposition of hydrazine (e.g., percent ammonia dissociation). Performance of other types of monopropellant thrusters may, however, be determined by using procedures similar to those discussed. Two appendixes are included: (1) theoretical performance of monopropellant hydrazine; and (2) calculation of rotational performance.

Source record↗
NASA NTRS1980

Development of a nitrogen generation system

An eight-stage nitrogen generation module was developed. The design integrated a hydrazine catalytic dissociator, three ammonia dissociation stages and four palladium/silver hydrogen separator stages. Alternating ammonia dissociation and hydrogen separation stages are used to remove hydrogen and ammonia formed in the dissociation of hydrazine which results in negligible ammonia and hydrogen concentrations in the product nitrogen stream. An engineering breadboard nitrogen supply subsystem was also developed. It was developed as an integratable subsystem for a central spacecraft air revitalization system. The subsystem consists of the hydrazine storage and feed mechanism, the nitrogen generation module, the peripheral mechanical and electrical components required to control and monitor subsystem performance, and the instrumentation required to interface with other subsystems of an air revitalization system. The breadboard nitrogen supply subsystem was integrated and tested with a one-person capacity experimental air revitalization system. The integration, checkout and testing was successfully accomplished.

Heppner, D. B.↗
NASA NTRS1984

Room-temperature luminescence from kaolin induced by organic amines

Several new, room-temperature luminescent phenomena, resulting from the interaction of kaolin and various amino compounds, have been observed. The emission of light from kaolin pastes (treated with quinoline, pyridine, hydrazine, monoethanolamine, n-butylamine, and piperidine) was shown to decay monotonically over a period of hours to days. More light was released by a given amino compound after it was dried and purified. Hydrazine, in addition to the monotonically decaying photon release, produces delayed pulses of light with peak emission wavelength of 365 nm which last between several hours and several days. These photon bursts are acutely sensitive to the initial dryness of the hydrazine, both in the number of bursts and the integrated photon output. The amount of light and the capacity of the kaolin to produce the delayed burst appeared to be strongly dependent on preliminary heating and on gamma-irradiation, analogous to the dehydration-induced light pulse previously reported from the Ames Research Center. A small, delayed burst of photons occurred when piperidine and n-butylamine were removed by evaporation into an H2SO4 reservoir.

Coyne, L. M.↗
NASA NTRS1989

Ozone/Ultraviolet-Photo-Oxidation Reactor

Experimental chemical-processing system destroys waste hydrazine in water by use of ozone in ultraviolet-photo-oxidation reactor. New process reduces concentrations of hydrazines and intermediate decomposition products in effluent liquid and gas to below limit of detectability. Liquid sprayed in reaction chamber past ultraviolet lamps, against flow of oxygen and ozone. Hydrazines and intermediate decomposition products oxidized to harmless substances. Effectiveness and speed of process depends on maintenance of circulating liquid at correct pH, determines lower limit of oxidation by ozone.

Swartz, Ari Ben↗