Search NASA⌕ Search

SEARCH · Search NASA

Results for “Induced polarization”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Giant optical nonlinearity of Fermi polarons in atomically thin semiconductors

In this study, realizing strong nonlinear optical responses is a long-standing goal of both fundamental and technological importance. Recently, substantial efforts have been focused on exploring excitons in solids to achieve nonlinearities even down to few-photon levels. However, a crucial tradeoff arises as strong light–matter interactions require large oscillator strength and short radiative lifetime of excitons, which limits their nonlinearity. Here we experimentally demonstrate strong nonlinear optical responses with large oscillator strength by exploiting the coupling between excitons and carriers in an atomically thin semiconductor. By controlling the electric field and electrostatic doping of trilayer WSe 2 , we observe the hybridization between intralayer and interlayer excitons and the formation of Fermi polarons. Substantial optical nonlinearity is observed under continuous-wave and pulsed laser excitation, where the Fermi polaron resonance blueshifts by as much as ~10 meV. Intriguingly, we observe a remarkable asymmetry in the optical nonlinearity between electron and hole doping, which is tunable by the applied electric field. We attribute these features to the optically induced valley polarization due to the interactions between excitons and free charges. Our results establish atomically thin heterostructures as a highly versatile platform for engineering nonlinear optical response with applications to classical and quantum optoelectronics.

2d materials↗
DOE OSTI2021

First principles study of nearly strain-free Ni/WSe 2 and Ni/MoS 2 interfaces

Metal/transition metal dichalcogenide interfaces are the subject of active research, in part because they provide various possibilities for interplay of electronic and magnetic properties with potential device applications. Here, we present results of our first principles calculations of nearly strain-free Ni/WSe 2 and Ni/MoS 2 interfaces in thin-film geometry. It is shown that while both the WSe 2 and MoS 2 layers adjacent to Ni undergo metallic transition, the layers farther from the interface remain semiconducting. In addition, a moderate value of spin-polarization is induced on interfacial WSe 2 and MoS 2 layers. At the same time, the electronic and magnetic properties of Ni are nearly unaffected by the presence of WSe 2 and MoS 2 , except a small reduction of magnetic moment at the interfacial Ni atoms. Furthermore, these results can be used as a reference for experimental efforts on epitaxial metal/transition metal dichalcogenide heterostructures, with potential application in modern magnetic storage devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Generation of E × B flow shear by finite orbit width effects from heat sources in tokamaks

Here we present a possible mechanism for the generation of strong E × B flow shear relevant to internal transport barrier formation in tokamak plasmas. From gyrokinetic calculations, we show that strong E × B flow shear can be generated by finite orbit width (FOW) effects associated with a non-uniform heat source and is sufficient to lead to transport barrier formation in the core region with a moderate power level. Two FOW effects inducing neoclassical polarization are shown to be responsible for this: (1) the radial drift of particle orbit center due to the variation of the heat source within orbit width and (2) the non-uniformly evolved orbit width by the non-uniform heating.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Octahedral rotations in Ruddlesden-Popper layered oxides under pressure from first principles

The combination of reduced dimensionality and tunable structural distortions in layered perovskite oxides makes these materials ideal platforms for designing novel properties and functionalities. One example is hybrid improper ferroelectricity in n = 2 Ruddlesden-Popper oxides, where the combination of a layered crystal structure and rotations of the metal-oxide octahedra break symmetry and induce a polarization. Precisely controlling the octahedral rotation distortions, for example by the application of hydrostatic pressure, provides a pathway to tune and optimize the properties of these materials. Here we combine group theoretic methods, density functional theory calculations, and Landau theory analysis to investigate how octahedral rotations respond to pressure in the hybrid improper ferroelectrics Sr 3 Zr 2 O 7 , Ca 3 Ti 2 O 7 , and Sr 3 Sn 2 O 7 . We find that factors that are known to control the pressure response of ABO 3 perovskites—the formal charge of the A- and B-site cations, tolerance factor, and B-site chemistry—also impact the pressure response of these layered perovskites. We also show that coupling between the octahedral rotation and strain order parameters plays a key role in determining the overall pressure response. Despite some similarities, we find that these layered perovskites display a distinct pressure response compared to their ABO 3 perovskite analogs. By identifying trends and underlying mechanisms that control octahedral rotations in Ruddlesden-Popper oxides under pressure, this work lays the foundation for tailoring the structure and properties of these materials.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Searching for axionlike time-dependent cosmic birefringence with data from SPT-3G

Ultralight axionlike particles (ALPs) are compelling dark matter candidates because of their potential to resolve small-scale discrepancies between Λ CDM predictions and cosmological observations. Axion-photon coupling induces a polarization rotation in linearly polarized photons traveling through an ALP field; thus, as the local ALP dark matter field oscillates in time, distant static polarized sources will appear to oscillate with a frequency proportional to the ALP mass. We use observations of the cosmic microwave background from SPT-3G, the current receiver on the South Pole Telescope, to set upper limits on the value of the axion-photon coupling constant g φ γ over the approximate mass range 10 - 22 – 10 - 19 eV , corresponding to oscillation periods from 12 hours to 100 days. For periods between 1 and 100 days ( 4.7 × 10 - 22 eV ≤ m φ ≤ 4.7 × 10 - 20 eV ), where the limit is approximately constant, we set a median 95% C.L. upper limit on the amplitude of on-sky polarization rotation of 0.071 deg. Assuming that dark matter comprises a single ALP species with a local dark matter density of 0.3 GeV / cm 3 , this corresponds to g φ γ < 1.18 × 10 - 12 GeV - 1 × ( m φ 1.0 × 10 - 21 eV ) . These new limits represent an improvement over the previous strongest limits set using the same effect by a factor of ~ 3.8 .

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2023

Optically Active Spin Defects in Few-Layer Thick Hexagonal Boron Nitride

Optically active spin defects in hexagonal boron nitride (hBN) are promising quantum systems for the design of two-dimensional quantum sensing units offering optimal proximity to the sample being probed. In this Letter, we first demonstrate that the electron spin resonance frequencies of boron vacancy centers ($V$$^{–}_{B}$) can be detected optically in the limit of few-atomic-layer thick hBN flakes despite the nanoscale proximity of the crystal surface that often leads to a degradation of the stability of solid-state spin defects. We then analyze the variations of the electronic spin properties of $V$$^{–}_{B}$ centers with the hBN thickness with a focus on (i) the zero-field splitting parameters, (ii) the optically induced spin polarization rate and (iii) the longitudinal spin relaxation time. Furthermore, this Letter provides important insights into the properties of $V$$^{–}_{B}$ centers embedded in ultrathin hBN flakes, which are valuable for future developments of foil-based quantum sensing technologies.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

Heteroanionic Ruddlesden-Popper ferroelectrics from anion order and octahedral tilts

We describe a strategy to design ferroelectric heteroanionic materials based on the coupling of anion order and octahedral tilts in n = 1 Ruddlesden-Popper structures, which allows noncentrosymmetric and polar compounds to arise from centrosymmetric anion-ordered structures. Here we investigate the relative phase stabilities of the polymorphs of Sr 2 ScO 3 F and Ca 2 ScO 3 F derived from this coupling using electronic structure calculations. We find that large degrees of octahedral tilting can stabilize different anion orders derived from assembly of [ScO 5 F] 8– octahedra. To further understand the link between octahedral tilting and anion order, we quantitatively separate the contributions of electrostatics and covalent interactions to the stability of tilts. We find that the tilts are driven primarily by covalent interactions and that local out-of-plane polar displacements, induced from the anion order, further stabilize the octahedral tilts through the pseudo-Jahn-Teller effect.

36 MATERIALS SCIENCE↗
DOE OSTI2023

High phase resolution: Probing interactions in complex interfaces with sum frequency generation

An often-quoted statement attributed to Wolfgang Pauli is that God made the bulk, but the surface was invented by the devil. Although humorous, the statement really reflects frustration in developing a detailed picture of a surface. In the last several decades, that frustration has begun to abate with numerous techniques providing clues to interactions and reactions at surfaces. Often these techniques require considerable prior knowledge. Complex mixtures on irregular or soft surfaces—complex interfaces—thus represent the last frontier. Two optical techniques: sum frequency generation (SFG) and second harmonic generation (SHG) are beginning to lift the veil on complex interfaces. Of these techniques, SFG with one excitation in the infrared has the potential to provide exquisite molecular- and moiety-specific vibrational data. This Perspective is intended both to aid newcomers in gaining traction in this field and to demonstrate the impact of high-phase resolution. It starts with a basic description of light-induced surface polarization that is at the heart of SFG. The sum frequency is generated when the input fields are sufficiently intense that the interaction is nonlinear. This nonlinearity represents a challenge for disentangling data to reveal the molecular-level picture. Three, high-phase-resolution methods that reveal interactions at the surface are described.

Biophysics↗
DOE OSTI2021

Electrical and Seismic Response of Saline Permafrost Soil during Freeze - Thaw Transition: Supporting Data

These data were collected during a repeat freeze-thaw cycle on a saline permafrost portion of a core to understand mechanical and geophysical property changes over time. The core used for the experiment was collected from the NGEE-Arctic Site 0 transect site located in the Barrow Environmental Observatory (BEO) in Barrow, Alaska. This region features polygonal ground, and the core was collected in the center of a flat centered polygon. The saline permafrost portion of the core was at the bottom 260-280 cm below ground surface. Data files (*.csv) include: Electrical signal change during freeze-thaw-refreeze cycle at 1 Hz; Spectral data - Complex resistivity data during Freeze-thaw of the saline permafrost core; Seismic data; and CT cross sections (*.jpg) of the core sample from approximately the same location: (A, D) before the test (thawed), (B, E) after the test (frozen), and (C, F) after deep freeze (frozen).The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1975

Effects of spanwise blowing on the pressure field and vortex-lift characteristics of a 44 deg swept trapezoidal wing

Wind-tunnel data were obtained at a free-stream Mach number of 0.26 for a range of model angle of attack, jet thrust coefficient, and jet location. Results of this study show that the sectional effects to spanwise blowing are strongly dependent on angle of attack, jet thrust coefficient, and span location; the largest effects occur at the highest angles of attack and thrust coefficients and on the inboard portion of the wing. Full vortex lift was achieved at the inboard span station with a small blowing rate, but successively higher blowing rates were necessary to achieve full vortex lift at increased span distances. It is shown that spanwise blowing increases lift throughout the angle-of-attack range, delays wing stall to higher angles of attack, and improves the induced-drag polars. The leading-edge suction analogy can be used to estimate the section and total lifts resulting from spanwise blowing.

Campbell, J. F.↗
NASA NTRS1983

The influence of gravity wave breaking on the general circulation of the middle atmosphere

The zonal mean solstice circulation of the global middle atmosphere is simulated using a semi-spectral numerical model. Radiative heating and cooling is computed by the algorithm of Wehrbein and Leovy. Mechanical dissipation is represented by the gravity wave breaking parameterization of Lindzen. An inertial adjustment parameterization is used to prevent the development of inertially unstable meridional shears near the equator. It is shown that gravity wave drag and diffusion in the mesosphere can account for the observed large departure from radiative equilibrium in both summer and winter. Experiments incorporating a forced stationary wavenumber 1 disturbance indicate that planetary wave EP flux convergences, although they may modify the mean flow profile significantly, cannot provide the major source of mechanical dissipation in the winter mesosphere. A simulated sudden warming is accompanied by an equally strong mesospheric cooling. This cooling is caused primarily by the relaxation of the polar mesosphere toward radiative equilibrium when the easterly mean winds in the polar stratosphere induced by the sudden warming reduce the transmission of gravity waves into the mesosphere.

Holton, J. R.↗
NASA NTRS1985

Electric Field Containerless Processing Technology

The objective of this task is to develop the science and technology base required to design and construct a high temperature electric field positioning module that could be used by materials scientists to conduct containerless science experiments in a low gravity environment. Containerless science modules that employ electric fields to position and manipulate samples offer several advantages over acoustic or electromagnetic systems. The electric field system will operate not only at atmospheric pressures but also in a vacuum, in contrast to the acoustic modules which can only operate in atmosphere where the acoustic forces are sufficient. The electric field technique puts minimum energy into the sample, whereas the electromagnetic system can deposit energy into the sample through eddy current heat as well as physical mixing in the sample. Two types of electric field modules have been constructed and tested to date. One employs a charged sample and uses electrostatic forces to position and control the sample. The second type of module induces electrical polarization of the sample and electric field gradients to position and control the sample.

Elleman, D. D.↗
NASA NTRS1991

Optical design of the Moderate Resolution Imaging Spectrometer - Tilt (MODIS-T) for the Earth Observing System (Eos)

The Moderate Resolution Imaging Spectrometer (MODIS) is an Earth viewing sensor that is planned as a facility instrument for the Earth Observing System (Eos) scheduled to begin functioning in the late 1990's. The MODIS is composed of two mutually supporting sensors one of which is MODIS-T, where 'T' signifies a tiltable along-track field of view. MODIS-T is a 32 channel imaging spectrometer with a required 10 nm to 15 nm spectral resolution (FWHM) in the 400 nm to 880 nm spectral range with less than 2.3 percent instrument induced linear polarization. The instrument provides at nadir a 33 km by 1500 km swath with a 1.1 km spatial resolution and an along-track pointing capability of +/- 50 deg about nadir. The heart of the optical design consists of a f/3 grating-type reflecting Schmidt camera.

Maymon, Peter W.↗
NASA NTRS1995

Electrochromatographic separation of proteins

We have developed a modified electrochromatography system which minimizes Joule heating at electric field strengths up to 125 V/cm. A non-linear equilibrium model is described which incorporates electrophoretic mobility, hydrodynamic flow velocity, and an electrically induced concentration polarization at the surface of the stationary phase. This model is able to provide useful estimates of protein retention time and velocity in a column packed with Sephadex gel and subjected to an electric field. A correlation of electrophoretic mobility of peptide and proteins with respect to their charge, molecular mass, and asymmetry enables the selection of solute target molecules for electrochromatographic separations. Good separation of protein mixtures have been obtained.

NASA Discipline Life Support Systems↗
NASA NTRS2018

WFIRST Coronagraph Flight Performance Modeling

As it has for the past few years, numerical modeling is being used to predict the on-orbit, high-contrast imaging performance of the WFIRST coronagraph, which was recently defined to be solely a technology demonstrator. A consequence has been a realignment of modeling priorities and revised applications of modeling uncertainty factors and margins, which apply to multiple factors such as pointing and wavefront jitter, thermally-induced deformations, polarization, and aberration sensitivities. At the same time, the models have increased in fidelity as additional parameters have been added, such as time-dependent pupil shear and mid-spatial-frequency deformations of the primary and secondary mirrors, detector effects, and reaction-wheel-speed-dependent pointing and wavefront jitter.

Trauger, John↗
NASA NTRSDate not supplied

Observing Ice Phase Clouds and Precipitation with Millimeter- and Submillimeter-wave Radiometry during the IMPACTS field campaign: Algorithm Development for the Emerging Class of Microwave Radiometers

Millimeter- and submillimeter-wave (mmWave, submm) radiometers provide significant information content on atmospheric water in liquid, ice, and vapor phases. Recent sensors, such as the Global Precipitation Measurement (GPM) or the Temporal Experiment for Storms and Tropical Systems Technology – Demonstration (TEMPEST-D), use mmWave bands to improve estimation of ice-phase precipitation, and future missions, such as the Atmosphere Observing System (AOS), will extend to submm to provide additional information on thinner ice clouds, linking clouds and precipitation and therefore elucidating the links between weather, climate, and the water cycle. To support the expanded use of mmWave/submm radiometry and exploit the available information content on condensed water mass, we demonstrate ice and liquid water path retrievals for NASA Goddard Space Flight Center's airborne radiometers the Conical Scanning Millimeter-wave Imaging Radiometer (CoSMIR) and the Configurable Scanning Submillimeter-wave Instrument/Radiometer (CoSSIR, formerly the Compact Scanning Submillimeter Imaging Radiometer). The analysis is based on data collected during the Investigation of Microphysics and Precipitation for Atlantic Coast-Threatening Storms (IMPACTS) field campaign. A simulation study compares and contrasts retrievals for CoSMIR and CoSSIR, with CoSSIR demonstrating higher skill in ice retrievals, particularly for thin clouds, and the CoSMIR frequencies performing better for liquid. Additionally, we look at dual-polarized radiances observed by CoSMIR during the first two IMPACTS deployments to understand the polarization signatures induced by oriented hydrometeors. Results will be presented in the context of upcoming missions and sensors including AOS and the Ice Cloud Imager (ICI). We will describe the objectives for the expected first flight of the newly upgraded CoSSIR during the final IMPACTS deployment, and we will share novel science investigations we plan to undertake with CoSSIR's new capabilities. Popular Summary: Ice in clouds and falling snow is an important component of weather, climate, and water resources. To better use a new class of sensors that provide information on atmospheric ice, we developed an approach to measure ice clouds and falling snow using airborne data taken during the Investigation of Microphysics and Precipitation for Atlantic Coast-Threatening Storms (IMPACTS), a field campaign to study winter storms. We look at the results for two similar instruments to understand how those differences affect these measurements of clouds and snow, and we further investigate the information the sensors can provide on properties of the clouds and snow.

Ian S Adams↗
NASA NTRSDate not supplied

Observing Ice Phase Clouds and Precipitation with Millimeter- and Submillimeter-wave Radiometry during the IMPACTS field campaign: Algorithm Development for the Emerging Class of Microwave Radiometers

Millimeter- and submillimeter-wave (mmWave, submm) radiometers provide significant information content on atmospheric water in liquid, ice, and vapor phases. Recent sensors, such as the Global Precipitation Measurement (GPM) or the Temporal Experiment for Storms and Tropical Systems Technology – Demonstration (TEMPEST-D), use mmWave bands to improve estimation of ice-phase precipitation, and future missions, such as the Atmosphere Observing System (AOS), will extend to submm to provide additional information on thinner ice clouds, linking clouds and precipitation and therefore elucidating the links between weather, climate, and the water cycle. To support the expanded use of mmWave/submm radiometry and exploit the available information content on condensed water mass, we demonstrate ice and liquid water path retrievals for NASA Goddard Space Flight Center's airborne radiometers the Conical Scanning Millimeter-wave Imaging Radiometer (CoSMIR) and the Configurable Scanning Submillimeter-wave Instrument/Radiometer (CoSSIR, formerly the Compact Scanning Submillimeter Imaging Radiometer). The analysis is based on data collected during the Investigation of Microphysics and Precipitation for Atlantic Coast-Threatening Storms (IMPACTS) field campaign. A simulation study compares and contrasts retrievals for CoSMIR and CoSSIR, with CoSSIR demonstrating higher skill in ice retrievals, particularly for thin clouds, and the CoSMIR frequencies performing better for liquid. Additionally, we look at dual-polarized radiances observed by CoSMIR during the first two IMPACTS deployments to understand the polarization signatures induced by oriented hydrometeors. Results will be presented in the context of upcoming missions and sensors including AOS and the Ice Cloud Imager (ICI). We will describe the objectives for the expected first flight of the newly upgraded CoSSIR during the final IMPACTS deployment, and we will share novel science investigations we plan to undertake with CoSSIR's new capabilities. Popular Summary: Ice in clouds and falling snow is an important component of weather, climate, and water resources. To better use a new class of sensors that provide information on atmospheric ice, we developed an approach to measure ice clouds and falling snow using airborne data taken during the Investigation of Microphysics and Precipitation for Atlantic Coast-Threatening Storms (IMPACTS), a field campaign to study winter storms. We look at the results for two similar instruments to understand how those differences affect these measurements of clouds and snow, and we further investigate the information the sensors can provide on properties of the clouds and snow.

Ian S Adams↗
NASA NTRSDate not supplied

Self-Aligned Focusing Schlieren at the 0.3-M Transonic Cryogenic Tunnel and the National Transonic Facility

The implementation of a self-aligned focusing schlieren (SAFS) system at two cryogenic wind tunnels at NASA Langley Research Center is discussed. Risk-reduction testing of the SAFS system was first performed at the 0.3-M Transonic Cryogenic Tunnel to evaluate the system’s operation in a small-scale characteristic cryogenic facility. Testing was conducted with three models: a three-quarter span 25.4-mm-diameter cylinder, a semi-span 65A006 tapered unswept airfoil, and a full-span SC(3)-0712 airfoil. Testing with the cylinder and semi-span airfoil revealed a highly dynamic shock environment, whereas the shock on the full-span airfoil was stationary, solidifying the usage of this model for a pre-/post-shock particle tracking velocimetry measurement. Temperature-induced polarization-altering window stresses were encountered during low-temperature testing, and were mitigated using a “non-ideal” quartz/quartz Rochon prism that had largely been neglected since the SAFS system’s first introduction in favor of the more favorable “ideal” glass/quartz Rochon prism. The size of the SAFS system was then decreased in order to fit inside an environmentally-controlled camera can enclosure at the National Transonic Facility (NTF) for testing of a sting-mounted aircraft model. The SAFS system was demonstrated to be effective at filtering out the large density gradient flow in the 0.3-M plenum, and the thick, high density turbulent boundary layers on the wind tunnel walls at the NTF. Results of the testing campaigns and improvements to future systems are discussed.

Joshua M. Weisberger↗