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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

Robotic Measurement of Holdup Deposit Volume in Gaseous Diffusion Piping to Quantify U-235 Content - 18375

During D and D of old gaseous diffusion uranium enrichment facilities, radiometric assay of U-235 holdup in pipes is a costly, time consuming, and labor-intensive process. Subject to human interpretation using approximate modeling, radiometric assay introduces significant challenges. Taking advantage of routine demolition activities in which D and D cuts pipes open, robotic in-pipe assay is explored. The novel method introduced here generates models of the internal pipe and deposit surface geometries that are used to derive volumetric quantities. The pipe surface is sensed using a non-contact inductive proximity sensor and the deposit surface is sensed using an optical laser triangulation sensor. These sensors are mounted on a spinning disk and driven down the pipe to construct a helical point cloud of discrete measurements. Surfaces are fit to each of the two point clouds to create a watertight volume that represents the holdup. This provides the location and volume per foot of pipe that is used to compare against criticality incredible (CI) thresholds during evaluation. The robotic system collects data autonomously, deploying and returning to the same pipe opening from which it is launched. This provides redundant measurements of the pipe and deposit surfaces as well as odometry used in localization. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Development and Validation of SAM Multi-dimensional Flow Model for Thermal Mixing and Stratification Modeling

Thermal mixing and stratification in large pools or enclosures are very important phenomena that are critical to nuclear reactor safety. Because of the wide ranges of time and length scales associated with such phenomena, accurate modeling and simulation of thermal mixing and stratification remain as the key unresolved, challenging problems for reactor transient analyses. In traditional system analysis codes, simplified zero-dimensional (0-D) models are widely used for their high numerical efficiency, but they generally suffer from very limited prediction accuracies or range of applicability. Like traditional system analysis codes, the current version of the SAM code has implemented such simplified 0-D and one-dimensional mixing models. On the other hand, high-resolution Computational Fluid Dynamics (CFD) tools are often used to model complex thermal mixing and stratification phenomena. They are, however, generally numerically expensive, and they require large amounts of computational resources. It is therefore desirable to implement advanced and efficient thermal mixing and stratification modeling capabilities embedded in a system analysis code. This approach will improve the accuracy of reactor safety analyses when thermal mixing and stratification are involved, and also avoid using the large computational resources needed for high-resolution CFD analysis. Currently, with the support of the U.S. DOE Office of Nuclear Energy’s Nuclear Energy Advanced Modeling and Simulation program, an effort has been launched to develop and implement a multi-dimensional flow model in the system analysis code SAM, and demonstrate its applications to model thermal mixing and stratification phenomena in large enclosures. The main outcomes of this research and development activity are summarized in this report, which presents an attempt to include a built-in advanced multi-dimensional flow model in a system analysis code with the focus on overcoming the simulation challenges of thermal mixing and stratification phenomena. In this report, we start with the introduction of existing SAM code capabilities to simulate thermal mixing and stratification phenomena, which is followed by a short summary of the multi-dimensional model implemented in the SAM code, including both the physical model and the Finite Element Method code implementation. In this study, two options were implemented in the SAM code to model turbulent flows: a relatively simple built-in turbulence model and an interface to accept externally computed turbulent viscosities (e.g., from a high- resolution CFD simulation). Code validation studies on this newly added capability were then carried out to compare SAM simulation results with experimental data from the SUPERCAVNA facility, which was designed to study the complex flow recirculation and thermal stratification phenomena relevant to sodium fast reactor designs. In this study, one transient and two steady-state test cases were used for code validation. Different approaches have been used to model the complex turbulence flow fields in the SUPERCAVNA facility. A highly simplified zero-equation turbulence model was first used, but it was determined that it is too simple to capture the complex turbulence flow fields in these test cases. Subsequently, the code validation continued with the use of turbulent viscosity data from high-resolution STAR-CCM+ CFD simulations to improve the accuracy of the results. Using this approach, the SAM simulation results showed very good agreement with both the SUPERCAVNA experimental data and STAR-CCM+ simulation results. In this report, we demonstrate the development, implementation, and successful validation of a multi-dimensional flow model in the SAM code, which aims to improve the simulation accuracy for complex thermal mixing and stratification phenomena. Lessons have also been learned, including that in cases where the flow fields are not well predicted by the zero-equation model, the iinput of turbulent viscosities from an external source can enhance the overall predictive capabilities needed to accurately capture complex thermal-hydraulic phenomena. Therefore, future research will be needed to further improve the code’s capabilities, such as by developing a more efficient and robust approach to capture the turbulence effects in the SAM code.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Information Carried by Electromagnetic Radiation Launched from Accelerated Polarization Currents

We show experimentally that a continuous, linear, dielectric antenna in which a superluminal polarization-current distribution accelerates can be used to transmit a broadband signal that is reproduced in a comprehensible form at a chosen target distance and angle. The requirement for this exact correspondence between broadcast and received signals is that each moving point in the polarization-current distribution approaches the target at the speed of light at all times during its transit along the antenna. This results in a one-to-one correspondence between the time at which each point on the moving polarization current enters the antenna and the time at which all of the radiation emitted by this particular point during its transit through the antenna arrives simultaneously at the target. This has the effect of reproducing the desired time dependence of the original broadcast signal. For other observer-detector positions, the time dependence of the signal is scrambled, due to the nontrivial relationship between emission (retarded) time and reception time. This technique represents a contrast to conventional radio transmission methods; in most examples of the latter, signals are broadcast with little or no directivity, selectivity of reception being achieved through the use of narrow frequency bands. In place of this, the current paper uses a spread of frequencies to transmit information to a particular location; the signal is weaker and has a scrambled time dependence elsewhere. Here, we point out the possible relevance of this mechanism to 5G neighborhood networks and pulsar astronomy.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Discovery of gamma- and X-ray pulsations from the young and energetic PSR J1357$-$6429 with Fermi and XMM-Newton

Context. Since the launch of the Fermi satellite, the number of known gamma-ray pulsars has increased tenfold. Most gamma-ray detected pulsars are young and energetic, and many are associated with TeV sources. PSR J1357-6429 is a high spin-down power pulsar (È = 3.1 × 1036 erg s -1 ), discovered during the Parkes multibeam survey of the Galactic plane, with significant timing noise typical of very young pulsars. In the very-high-energy domain (E > 100 GeV), H.E.S.S. has reported the detection of the extended source HESS J1356-645 (intrinsic Gaussian width of 12') whose centroid lies 7' from PSR J1357-6429. Aims. We search for gamma- and X-ray pulsations from this pulsar, characterize the neutron star emission and explore the environment of PSR J1357-6429. Methods. Using a rotational ephemeris obtained with 74 observations made with the Parkes telescope at 1.4 GHz, we phase-fold more than two years of gamma-ray data acquired by the Large Area Telescope on-board Fermi as well as those collected with XMM-Newton, and perform gamma-ray spectral modeling. Results. Significant gamma- and X-ray pulsations are detected from PSR J1357-6429. The light curve in both bands shows one broad peak. Gamma-ray spectral analysis of the pulsed emission suggests that it is well described by a simple power-law of index 1.5 ± 0.3 stat ± 0.3 syst with an exponential cut-off at 0.8 ± 0.3 stat ± 0.3 syst GeV and an integral photon flux above 100 MeV of (6.5 ± 1.6 stat ± 2.3 syst ) × 10 -8 cm -2 s -1 . The X-ray spectra obtained from the new data provide results consistent with previous work. Upper limits on the gamma-ray emission from its potential pulsar wind nebula (PWN) are also reported. Conclusions. Assuming a distance of 2.4 kpc, the Fermi LAT energy flux yields a gamma-ray luminosity for PSR J1357-6429 of L γ = (2.13 ± 0.25 stat ± 0.83 syst ) × 1034 erg s -1 , consistent with an relationship. The Fermi non-detection of the pulsar wind nebula associated with HESS J1356-645 provides new constraints on the electron population responsible for the extended TeV emission.

79 ASTRONOMY AND ASTROPHYSICS↗

Strategies for Working Remotely: Responding to Pandemic-Driven Change.

In response to the COVID-19 pandemic, the Exascale Computing Project’s (ECP) Interoperable Design of Extreme-scale Application Software (IDEAS) productivity team launched the panel series Strategies for Working Remotely to facilitate informal, cross-organizational dialog in the absence of face-to-face meetings. In a time of pandemic, organizations increasingly need to reach across perceived boundaries to learn from each other, so that we can move beyond stand-alone silos to more connected multidisciplinary and multiorganizational configurations. The present paper argues that the unplanned transition to remote work, overuse of electronic communication, and need to unlearn habits associated with an overreliance on face-to-face, created unique opportunities to learn from the situation and accelerate cross-institutional cooperation and collaboration through online community dialog facilitated by informal panel discussions. Recommendations for facilitating online panel discussions to foster cross-organizational dialog are provided by applying the Simulation Experience Design Method.

Raybourn, Elaine M.↗

Innovating Distributed Embedded Energy Prize (InDEEP): A Lessons Learned Report

The U.S. Department of Energy's Water Power Technologies Office (WPTO) launched the Innovating Distributed Embedded Energy Prize (InDEEP) in March 2023 to accelerate innovation in Distributed Embedded Energy Conversion Technologies (DEEC-Tec) for ocean wave energy. Administered by the National Laboratory of the Rockies (NLR) with technical support from Sandia National Laboratories (SNL), InDEEP focused on the development of small, distributed, and embeddable energy converters (DEECs) and their integration into scalable DEEC-Tec metamaterials for marine renewable energy applications. Spanning three phases over two years, InDEEP awarded approximately $2.3 million to teams from academia, industry, and startups. Phase I emphasized conceptual design. Phase II moved into the prototyping of individual DEECs. Phase III required integration into functional DEEC-Tec metamaterial prototypes. Across 60 submissions, teams explored a wide range of energy conversion mechanisms - including piezoelectric, variable-capacitance, ionic, and inductive methods. Note, the prize did not include the design nor demonstration of ocean wave energy conversion systems. Rather, the prize only required participants to design and demonstrate individual DEECs and corresponding DEEC-Tec metamaterials. This prize utilized a mix of novel and proven techniques to attract participants from outside marine energy, including an engagement leaderboard, robust recruitment, technical expert mentorship, and a suite of technical trainings. Key insights from the competition emphasized that DEEC-Tec metamaterials must be intentionally designed to produce beneficial emergent behaviors - advantages that go beyond simply combining multiple DEEC units. Top-performing teams showed that thoughtful design of system architecture, coordinated deformation, and systems adaptabilities could unlock meaningful performance gains both at the DEEC system level and DEEC-Tec metamaterial system level. A critical realization was that many DEEC-Tec metamaterials could benefit from being designed to accept lower-frequency energy inputs and shift those into higher-frequencies per each DEEC making up the respective DEEC-Tec metamaterial. Other important takeaways included the need for rigorous and quantitative performance testing, effective integration of power conditioning electronics, and the pivotal role of material science in enabling innovative, adaptive DEEC-Tec-based energy conversion designs. InDEEP also helped establish a growing DEEC-Tec community of practitioners, attracting participants from beyond traditional marine energy sectors. Through a strong support infrastructure, InDEEP fostered early-stage innovation and laid a foundation for future DEEC-Tec-based ocean wave energy conversion solutions - positioning DEEC-Tec as a promising pathway toward scalable, resilient ocean wave energy conversion. Through focused R&D of individual DEECs and their integration into DEEC-Tec metamaterials, alongside a growing, multidisciplinary community catalyzed by InDEEP, there is a strong opportunity to drive a disruptive shift in ocean wave energy conversion design and development. This convergence of novel architectures, emergent behaviors, and collaborative innovation positions DEEC-Tec as a transformative approach, moving the field from rigid, centralized energy conversion-based designs to resilient, modular systems highly adaptable for real-world ocean wave energy conversion applications.

16 TIDAL AND WAVE POWER↗

NUMERICAL SIMULATION OF THE SVS 13 MICROJET AND BOW SHOCK BUBBLE

Numerical simulations of the SVS 13 microjet and bow shock bubble are performed using the WENO method that reproduces the main features and dynamics of data from the Keck Telescope/OSIRIS velocity-resolved integral field spectrograph: an expanding, cooler bow shock bubble, with the bubble center moving at approximately 50 km s{sup −1} with a radial expansion velocity of 11 km s{sup −1}, surrounding the fast, hotter jet, which is propagating at 156 km s{sup −1}. Contact and bow shock waves are visible in the simulations both from the initial short jet pulse that creates the nearly spherical bow shock bubble and from the fast microjet, while a terminal Mach disk shock is visible near the tip of the continuous microjet, which reduces the velocity of the jet gas down to the flow velocity of the contact discontinuity at the leading edge of the jet. At 21.1 years after the launch of the initial bubble pulse, the jet has caught up with and penetrated almost all the way across the bow shock bubble of the slower initial pulse. At times later than about 22 years, the jet has penetrated through the bubble and thereafter begins to subsume its spherical form. Emission maps from the simulations of the jet—traced by the emission of the shock-excited 1.644 μ m [Fe ii] line—and the bow shock bubble—traced in the lower excitation 2.122 μ m H{sub 2} 1–0 S(1) line—projected onto the plane of the sky are presented, and are in good agreement with the Keck observations.

79 ASTRONOMY AND ASTROPHYSICS↗

Surrogate Post-Detonation Urban Debris (SPUD): Standard Reference Materials 4600 and 4601

If a terrorist nuclear explosion were to occur in the United States, high-quality (accurate and precise) legally defensible nuclear forensics measurements will be required to assure the certainty and confidence needed, for conclusions drawn from these data will be coupled with law enforcement and intelligence information for the purposes of attribution and retribution. Standard Reference Materials (SRMs)/Certified Reference Materials (CRMs) establish the traceability, accuracy, and precision of nuclear forensic measurements and provide the ability to benchmark measurement methods essential to meeting the requirements of legal scrutiny. Currently there is a critical shortage of key SRMs/CRMs required for accurate and precise measurements that are fundamental to nuclear measurements supporting pre- and post-detonation nuclear forensics. Supplies either do not exist, are not good enough, are in short supply, and/or are very expensive. The radionuclide measurement techniques and data quality objectives for pre- and post-detonation nuclear forensics are quite different than the applications for which the current suite of available SRMs/CRMs was developed. Specifically, 1) modern mass spectrometry methods have largely replaced traditional activity-based measurement methods for quantifying small quantities of long-lived radionuclides and most trace radionuclide SRMs/CRMs are certified for activity and are thus not adequate for current applications, 2) modern instrumental methods are capable of higher precision than historic measurement techniques, and in some cases exceed the precision of the available SRMs/CRMs, and 3) the quality assurance requirements for pre- and post-detonation nuclear forensics are such that the existing cadre of SRMs/CRMs does not adequately support the needs for method validation. There are numerous governmental stakeholders both within the US (DOE, DoD) and internationally (IAEA, JRC-ITU) whose missions are either directly involved with nuclear forensics measurements or rely on the forensic data obtained to make the exacting policy decisions (DOJ (FBI), DHS, CIA, DIA, DoD) associated with disrupting the production of illicit nuclear materials, interdicted nuclear materials or a nuclear/radiological detonation event. Starting in 2008 the DHS NTNFC, in collaboration with NBL and NIST, took on the production of suitable SRMs/CRMs for the pre-detonation nuclear forensics community. Two CRMs have been released since the start of this effort and two more are slated for completion in 2016. More recently, NIST, as a part of its mission as the US National Metrology Institute (NMI) to deliver standards (providing traceability) and foster homeland security, has launched the first certification campaign of a measurement traceable post nuclear detonation SRM. NIST, in cooperation with partner labs (AFIT (DoD), FBI (DOJ), and NPL) and with support from the FBI, has developed two Surrogate Post-Detonation Urban Debris (SPUD) Standard Reference Materials (SRMs) - SRM 4600 and 4601. These SRMs have been developed to simulate the expected debris mixture from the detonation of an Improvised Nuclear Device (IND) in an urban environment, which is capable of producing fresh fission as well as activation products. The elemental composition of the vitrified debris materials is a composite of minerals and metals characteristic of the concrete and steel, the building materials that would be exposed to a nuclear detonation and whose resulting activation products would be found in rubble samples collected for forensics evidence and attribution. Additionally, because post-detonation samples would also contain short-lived fission products, the debris materials have been doped with Uranium (U). To create the nuclear fission products, samples of the SPUD materials can be placed in a well-characterized nuclear reactor and exposed to a set neutron flux and energy, causing the encased U atoms to split and yield short-lived fission products. Because a known amount of U is added to the SPUD materials it is feasible to determine the concentration of the resulting fission products. The subsequent irradiated SPUD glass would be chemically similar to samples that would be generated in an actual detonation, and thus can serve as a standardized reference material for nuclear forensic post detonation measurements. (authors)

61 RADIATION PROTECTION AND DOSIMETRY↗

Physical and Thermomechanical Properties of Yttrium Hydride from Large Scale Bulk Metal Hydriding Furnace

Given the superior thermal stability and highly attainable hydrogen density, yttrium hydride is an excellent high-temperature moderator material in advanced thermal neutron spectrum reactors that require small core volumes. Yttrium hydride has been selected as the moderator material for the Transformational Challenge Reactor, which was launched at Oak Ridge National Laboratory (ORNL) in 2019. However, fabrication of large-scale crack-free yttrium hydride is challenging and very limited efforts have been committed to the characterization of bulk yttrium hydride in response to the need to establish a complete database of the thermomechanical properties of YHx. In this report, the challenges associated with fabricating large-scale crack-free yttrium hydride are discussed herein. In response to those challenges, a hydriding system was designed and constructed at ORNL and was used to successfully fabricate crack-free yttrium hydride in complex geometries at large scales. This was accomplished by precisely controlling the hydrogen’s partial pressure and the retort temperature, which was informed by the well-established thermodynamic properties of the binary H-Y system. Hydrogen content in as-fabricated hydride was determined by the weight change method and vacuum hot extraction technique, complemented by the X-ray diffraction (XRD). In addition, significant efforts are being dedicated to establishing a complete database of the thermomechanical properties of as-fabricated yttrium hydride. In FY2020, we investigated the thermophysical properties of yttrium hydrides as a function of temperature (room temperature to 700°C) and hydrogen concentration (H/Y ratio ranges from 1.52 to 1.93). The results indicate that at the temperatures below 300 °C, the hydrogen content did not have a significant influence on the thermal expansion, while the specific heat capacity, the thermal diffusivity, and the calculated thermal conductivity were slightly higher for the higher H/Y ratio. Between 300°C and 700 °C, a reversible second-order endothermic transition in all measured thermal properties was observed. It was also found that the onset temperatures of the observed transition varied, with the composition having inverse dependence on the hydrogen content. An attempt was made to explain the behavior of the thermophysical properties at higher temperatures by considering the order– disorder transition as a result of hydrogen redistribution. In addition, nanoindentation was employed to determine the elastic modulus and hardness and to capture the crystal orientation dependence of these parameters. Vickers hardness was also reported. The final section of the report introduces ongoing neutron irradiation campaign of yttrium hydride.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Turnover rates on complex heterogeneous catalysts

Since the beginning of the new millennium, there has been very rapid growth in the synthesis and characterization of new and complex nanomaterials, stimulated in part by the launch of the US National Nanotechnology Initiative in 2000. Nanostructured solid catalysts used in the large-scale production of fuels and chemicals are one of the most successful implementations of nanotechnology related to chemistry, although many of the major advancements in the field occurred before the emphasis on nanoscale structures was popularized. Discovery of new materials and manipulation of existing materials with atomic precision have become more common recently, with catalysis often claimed as a beneficiary of the research. Although catalysis in the presence of these materials is usually demonstrated by observing the chemical transformation of reactants into products, the nature of the active site and therefore a quantitative evaluation of a site-specific reaction rate remains elusive because of the complexity of the material. In this Perspective, the evaluation of reaction rates on complex materials will be discussed in light of recent progress in the use of transient kinetic methods.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Experimental results from the VENUS-F critical reference state for the GUINEVERE accelerator driven system project

The GUINEVERE (Generation of Uninterrupted Intense Neutron pulses at the lead Venus Reactor) project was launched in 2006 within the framework of FP6 EUROTRANS in order to validate online reactivity monitoring and subcriticality level determination in accelerator driven systems (ADS). Therefore, the VENUS reactor at SCK.CEN in Mol, Belgium, was modified towards a fast core (VENUS-F) and coupled to the GENEPI-3C accelerator built by CNRS. The accelerator can operate in both continuous and pulsed mode. The VENUS-F core is loaded with enriched Uranium and reflected with solid lead. A well-chosen critical reference state is indispensable for the validation of the online subcriticality monitoring methodology. Moreover, a benchmarking tool is required for nuclear data research and code validation. In this paper, the design and the importance of the critical reference state for the GUINEVERE project are motivated. The results of the first experimental phase on the critical core are presented. The control rods worth is determined by the positive period method and the application of the Modified Source Multiplication (MSM) method allows the determination of the worth of the safety rods. The results are implemented in the VENUS-F core certificate for full exploitation of the critical core. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Planck 2015 results: I. Overview of products and scientific results

The European Space Agency’s Planck satellite, which is dedicated to studying the early Universe and its subsequent evolution, was launched on 14 May 2009. It scanned the microwave and submillimetre sky continuously between 12 August 2009 and 23 October 2013. In February 2015, ESA and the Planck Collaboration released the second set of cosmology products based ondata from the entire Planck mission, including both temperature and polarization, along with a set of scientific and technical papers and a web-based explanatory supplement. This study gives an overview of the main characteristics of the data and the data products in the release, as well as the associated cosmological and astrophysical science results and papers. The data products include maps of the cosmic microwave background (CMB), the thermal Sunyaev-Zeldovich effect, diffuse foregrounds in temperature and polarization, catalogues of compact Galactic and extragalactic sources (including separate catalogues of Sunyaev-Zeldovich clusters and Galactic cold clumps), and extensive simulations of signals and noise used in assessing uncertainties and the performance of the analysis methods. The likelihood code used to assess cosmological models against the Planck data is described, along with a CMB lensing likelihood. Finally, scientific results include cosmological parameters derived from CMB power spectra, gravitational lensing, and cluster counts, as well as constraints on inflation, non-Gaussianity, primordial magnetic fields, dark energy, and modified gravity, and new results on low-frequency Galactic foregrounds.

79 ASTRONOMY AND ASTROPHYSICS↗

Accelerating Clean Energy Commercialization. A Strategic Partnership Approach

Technology development in the clean energy and broader clean tech space has proven to be challenging. Long-standing methods for advancing clean energy technologies from science to commercialization are best known for relatively slow, linear progression through research and development, demonstration, and deployment (RDD&D); and characterized by well-known valleys of death for financing. Investment returns expected by traditional venture capital investors have been difficult to achieve, particularly for hardware-centric innovations, and companies that are subject to project finance risks. Commercialization support from incubators and accelerators has helped address these challenges by offering more support services to start-ups; however, more effort is needed to fulfill the desired clean energy future. The emergence of new strategic investors and partners in recent years has opened up innovative opportunities for clean tech entrepreneurs, and novel commercialization models are emerging that involve new alliances among clean energy companies, RDD&D, support systems, and strategic customers. For instance, Wells Fargo and Company (WFC) and the National Renewable Energy Laboratory (NREL) have launched a new technology incubator that supports faster commercialization through a focus on technology development. The incubator combines strategic financing, technology and technical assistance, strategic customer site validation, and ongoing financial support.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

RidgeAlloy: A high pressure die casting alloy that captures the approaching wave of automotive body sheet scrap

Oak Ridge National Laboratory (ORNL) has recently launched an effort to economically expand the North American aluminum supply chain by designing and developing a new family of Al-Mg-Si-Fe-Mn structural die cast aluminum alloys that can be made from up to 100% mixed 5xxx and 6xxx series automotive post-consumer sheet scrap and do not require heat treatment. The goal is to develop an alloy capable of capturing the approaching scrap wave of aluminum sheet intensive vehicles (in the 2030’s) into integrated structural high pressure die castings, rather than down-cycling these high-grade sheet alloys into non-structural castings. ORNL discovered a significant gap in the commercial thermodynamic databases that were unable to predict the trends of a key primary intermetallic phase as a function of composition. Experiments were performed to correct this gap and to create a unique, corrected quaternary database for Al-Mg-Si-Fe. High throughput computational methods, including solidification simulations, were used to identify a composition volume capable of avoiding this embrittling primary intermetallic phase, even at higher Fe + Si contents. Laboratory scale castings validated the thermodynamic and solidification predictions and resulted in lab-cast alloys with little primary intermetallic, and which met or exceeded structural casting properties requirements for yield strength and ductility. An accelerated demonstration of an HPDC automotive part was conducted in collaboration with two U.S. small businesses. Ingots made from 100% recycled 5xxx and 6xxx series scrap (plus Fe) were used to die cast one variant of this new family of Al-Mg-Si-Fe-Mn alloys (with high Si + Fe content) into a mid-sized HPDC structural-type automotive component. The HPDC alloy demonstration part showed good properties (especially ductility) and good castability for a complex component.

Plotkowski, Alex [ORNL] (ORCID:0000000154718681)↗

Mobile phone collection, reuse and recycling in the UK

Highlights: > We characterized the key features of the voluntary UK mobile phone takeback network via a survey. > We identified 3 flows: information; product (handsets and accessories); and incentives. > There has been a significant rise in the number of UK takeback schemes since 1997. > Most returned handsets are low quality; little data exists on quantities of mobile phones collected. > Takeback schemes increasingly divert EoL mobile phones from landfill and enable reuse/recycling. - Abstract: Mobile phones are the most ubiquitous electronic product on the globe. They have relatively short lifecycles and because of their (perceived) in-built obsolescence, discarded mobile phones represent a significant and growing problem with respect to waste electrical and electronic equipment (WEEE). An emerging and increasingly important issue for industry is the shortage of key metals, especially the types of metals found in mobile phones, and hence the primary aim of this timely study was to assess and evaluate the voluntary mobile phone takeback network in the UK. The study has characterised the information, product and incentives flows in the voluntary UK mobile phone takeback network and reviewed the merits and demerits of the incentives offered. A survey of the activities of the voluntary mobile phone takeback schemes was undertaken in 2008 to: identify and evaluate the takeback schemes operating in the UK; determine the target groups from whom handsets are collected; and assess the collection, promotion and advertising methods used by the schemes. In addition, the survey sought to identify and critically evaluate the incentives offered by the takeback schemes, evaluate their ease and convenience of use; and determine the types, qualities and quantities of mobile phones they collect. The study has established that the UK voluntary mobile phone takeback network can be characterised as three distinctive flows: information flow; product flow (handsets and related accessories); and incentives flow. Over 100 voluntary schemes offering online takeback of mobile phone handsets were identified. The schemes are operated by manufacturers, retailers, mobile phone network service operators, charities and by mobile phone reuse, recycling and refurbishing companies. The latter two scheme categories offer the highest level of convenience and ease of use to their customers. Approximately 83% of the schemes are either for-profit/commercial-oriented and/or operate to raise funds for charities. The voluntary schemes use various methods to collect mobile phones from consumers, including postal services, courier and in-store. The majority of schemes utilise and finance pre-paid postage to collect handsets. Incentives offered by the takeback schemes include monetary payments, donation to charity and entry into prize draws. Consumers from whom handsets and related equipment are collected include individuals, businesses, schools, colleges, universities, charities and clubs with some schemes specialising on collecting handsets from one target group. The majority (84.3%) of voluntary schemes did not provide information on their websites about the quantities of mobile phones they collect. The operations of UK takeback schemes are decentralised in nature. Comparisons are made between the UK's decentralised collection system versus Australia's centralised network for collection of mobile phones. The significant principal conclusions from the study are: there has been a significant rise in the number of takeback schemes operating in the UK since the initial scheme was launched in 1997; the majority of returned handsets seem to be of low quality; and there is very little available information on the quantities of mobile phones collected by the various schemes. Irrespective of their financial motives, UK takeback schemes increasingly play an important role in sustainable waste management by diverting EoL mobile phones from landfills and encouraging reuse and recycling. Recommendations for future actions to improve the management of end-of-life mobile phone handsets and related accessories are made.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Sample environment effects on synchrotron-measured temperature profiles in an approximant of optical floating zone crystal growth

Even though the growth of crystals using optical floating zone furnaces has had an immense scientific impact, the implementation of this method remains more of an art than a science due to the difficulty of obtaining quantitative information about the sample thermal profile during crystal growth. Building on recent work demonstrating that in situ synchrotron studies can be used to map sample rod temperatures during heating, investigations were carried out to better understand how the sample environment affects the sample temperature profile. Through a combination of experimental studies and modeling efforts, it is shown that the environment in the furnace can strongly influence the sample temperature at the lamp focus, the steepness of the vertical temperature gradient, and the timescale required for sample heating and cooling - effects which can combine to produce a strong history-dependence to sample temperature profiles. It is demonstrated that the furnace effects can be effectively captured in thermal models, allowing both the steady-state and time-dependent behavior of the sample to be accurately reproduced with predictive models, and providing a launching point for improved furnace designs that can more readily deliver desired thermal profiles.

36 MATERIALS SCIENCE↗

VLBI FOR GRAVITY PROBE B. V. PROPER MOTION AND PARALLAX OF THE GUIDE STAR, IM PEGASI

We present the principal astrometric results of the very long baseline interferometry (VLBI) program undertaken in support of the Gravity Probe B (GP-B) relativity mission. VLBI observations of the GP-B guide star, the RS CVn binary IM Pegasi (HR 8703), yielded positions at 35 epochs between 1997 and 2005. We discuss the statistical assumptions behind these results and our methods for estimating the systematic errors. We find the proper motion of IM Peg in an extragalactic reference frame closely related to the International Celestial Reference Frame 2 (ICRF2) to be -20.83 {+-} 0.03 {+-} 0.09 mas yr{sup -1} in right ascension and -27.27 {+-} 0.03 {+-} 0.09 mas yr{sup -1} in declination. For each component, the first uncertainty is the statistical standard error and the second is the total standard error (SE) including plausible systematic errors. We also obtain a parallax of 10.37 {+-} 0.07 mas (distance: 96.4 {+-} 0.7 pc), for which there is no evidence of any significant contribution of systematic error. Our parameter estimates for the {approx}25 day period orbital motion of the stellar radio emission have SEs corresponding to {approx}0.10 mas on the sky in each coordinate. The total SE of our estimate of IM Peg's proper motion is {approx}30% smaller than the accuracy goal set by the GP-B project before launch: 0.14 mas yr{sup -1} for each coordinate of IM Peg's proper motion. Our results ensure that the uncertainty in IM Peg's proper motion makes only a very small contribution to the uncertainty of the GP-B relativity tests.

79 ASTRONOMY AND ASTROPHYSICS↗

The Detection of Mesoscale Convective Systems by the GPM Ku-Band Spaceborne Radar

The Global Precipitation Measurement (GPM) core observatory satellite launched in 2014 features more extended latitudinal coverage (65 degree S-65 degree N) than its predecessor Tropical Rainfall Measuring Mission (TRMM, 35 degree S-35 degree N). The Ku-band radar onboard of the GPM is known to be capable of characterizing the 3D structure of deep convection globally. In this study, GPM’s capability for detecting mesoscale convective systems (MCSs) is evaluated. Extreme convective echoes seen by GPM are compared against an MCS database based on tracking convective entities over the contiguous US. The tracking is based on geostationary satellite and ground-based Next Generation Radar (NEXRAD) network data obtained during the 2014-2016 warm seasons. Results show that more than 70% of the GPM-detected Deep-Wide Convective Core (DWC) and Wide Convective Core (WCC) objects are part of NEXRAD identified MCSs, indicating that GPM-classified DWCs and WCCs correlate well with typical MCSs containing large convective features. By applying this method to the rest of the world, a global view of MCS distribution is obtained. This work reveals GPM’s potential in MCS detection at the global scale, particularly over remote regions without dense observation network.

3D reflectivity structure↗