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At least 289 records · Page 16

Results from the Gas Chromatograph Mass Spectrometer (GCMS) Experiment on the Cassini-Huygens Probe

The Gas Chromatograph Mass Spectrometer was one of six instruments on the Cassini-Huygens Probe mission to Titan. The GCMS measured in situ the chemical composition of the atmosphere during the probe descent and served as the detector for the pyrolization products for the Aerosol Collector Pyrolyser (ACP) experiment to determine the composition of the aerosol particles. The GCMS collected data from an altitude of 146 km to ground impact. The Probe and the GCMS survived impact and collected data for 1 hour and 9 minutes on the surface. Mass spectra were collected during descent and on the ground over a range of mlz from 2 to 141. The major constituents of the lower atmosphere were confirmed to be N2 and CH4. The methane mole fraction was uniform in the stratosphere. It increased below the tropopause, at about 32 km altitude, monotonically toward the surface, reaching a plateau at about 8 km at a level near saturation. After surface impact a steep increase of the methane signal was observed, suggesting evaporation of surface condensed methane due to heating by the GCMS sample inlet heater. The measured mole fraction of Ar-40 is 4.3x10(exp -5) and of Ar-36 is 2.8x10(exp -7). The other primordial noble gases were below 10(exp -8) mole fraction. The isotope ratios of C-12/C-13 determined from methane measurements are 82.3 and of N-14/N-15 determined from molecular nitrogen are 183. The D/H isotope ratio determined from the H2 and HD measurements is 2.3x10(exp -4). Carbon dioxide, ethane, acetylene and cyanogen were detected evaporating from the surface in addition to methane. The GCMS employed a quadrupole mass filter with a secondary electron multiplier detection system and a gas sampling system providing continuous direct atmospheric composition measurements and batch sampling through three gas chromatographic (GC) columns, a chemical scrubber and a hydrocarbon enrichment cell. The GCMS gas inlet was heated to prevent condensation, and to evaporate volatiles from the surface after impact.

Niemann, Hasso↗

The Neutral Mass Spectrometer on the Lunar Atmosphere and Dust Environment Explorer Mission

The Neutral Mass Spectrometer (NMS) of the Lunar Atmosphere and Dust Environment Explorer (LADEE) Mission is designed to measure the composition and variability of the tenuous lunar atmosphere. The NMS complements two other instruments on the LADEE spacecraft designed to secure spectroscopic measurements of lunar composition and in situ measurement of lunar dust over the course of a 100-day mission in order to sample multiple lunation periods. The NMS utilizes a dual ion source designed to measure both surface reactive and inert species and a quadrupole analyzer. The NMS is expected to secure time resolved measurements of helium and argon and determine abundance or upper limits for many other species either sputtered or thermally evolved from the lunar surface.

Moon↗

Mass spectrometer calibration standard

Inert perfluorinated alkane and alkyl ethers mixture is used to calibrate mass spectrometer. Noncontaminating, commercially-available liquid provides series of reproducible reference peaks over broad mass spectrum that ranges over mass numbers from 1 to 200.

Ross, D. S.↗

A remote operation quadrupole mass spectrometer using a custom radio-frequency link approach

A commercial quadrupole mass spectrometer (residual gas analyzer, RGA) system has been modified to operate at large separations of its electronics console and sensing head. The methods implemented have made practical applications, as well as operation, of such a system possible for the first time. This advance was stimulated by a need for placing sensors at remote (45 or 60 m) chamber locations for space simulation testing of orbital flight spacecraft. Emphasis is placed on instrument functional requirements and describing the hardware changes and adjustment techniques necessary to assure operation at the extended cable lengths.

Tashbar, P. W.↗

The measurement of chemically reactive atmospheric constituents by mass spectrometers carried on high-speed spacecraft

The quasi-open-source mass spectrometer carried on the Atmospheric Explorer-C satellite has a mode of operation which utilizes the velocity of the vehicle to distinguish between incoming ambient particles and ambient particles which have struck instrument surfaces and become accommodated. Utilization of this mode has made possible the simultaneous measurement of atomic and molecular ambient oxygen without the ambiguity which usually arises due to surface reactions in the instrument. The method appears promising as a means for analyzing planetary atmospheres or the gas surrounding comets.

Nier, A. O.↗

Theory of the fly-through mode for neutral mass spectrometers

The Atmosphere Explorer satellites carry a quasi-open source neutral mass spectrometer which has the capability to operate in a nonstagnating or 'fly-through' mode. Technical information on the operating characteristics of fly-through along with considerable scientific data have been acquired in this mode. When the vehicle is spun, the fly-through signal contains information on the kinetic temperature as well as the neutral density. Both quantities can be extracted from the data once the theory of operation is formulated in terms of the ambient gas velocity distribution and the angular response of the instrument.

Kayser, D. C.↗

A Segmented Time-of-Flight Mass Spectrometer

The present paper describes the design of a time-of-flight mass spectrometer (TOFMS) in which the single flight tube of a conventional TOFMS has been replaced by several cylindrical electrostatic lenses in tandem. By a judicious choice of voltages on these lenses, an improved TOFMS has been realized which has a superior mass and energy resolution, shorter flight lengths, excellent signal-to-noise ratio and less stringent requirements on the bias voltages.

Srivastava, S. K.↗

Lunar orbital mass spectrometer experiment.

One of the Orbital Science experiments on Apollo 15 was a mass spectrometer designed to measure the composition and distribution of the lunar atmosphere. It operated for nearly 90 hours, producing spectra of an unexpectedly complex nature, indicating that many complex gas molecules exist in the vicinity of the spacecraft. The most plausible explanation is that there was continual vaporization of frozen or liquid drops of water, fuel, or other matter that had been ejected from the spacecraft with small relative velocity so that these particles remained in nearby orbits. The search for naturally occurring gases in these spectra involves a statistical analysis of the data which has not been completed to date. A theoretical prediction regarding the possibilities of detecting lunar volcanism from orbit is included.

Hoffman, J. H.↗

A technique for mass spectrometer measurements of atomic and molecular oxygen in the lower thermosphere

A neutral mass spectrometer with a quasi-open ion source was flown on each of the Atmosphere Explorer (AE) C, D, and E satellites. The three instruments provided an opportunity to study the effects of different source insert materials on the source surface chemistry. It was found that, after a period of conditioning in space, the recombination coefficient of atomic oxygen on gold appears to be substantially lower than it is on Nichrome V. The lower recombination coefficient on gold allows the spectrometer to directly measure a significant fraction of the incident atomic oxygen, making it possible to distinguish between ambient O and O2. Equations are developed to calculate the atomic and molecular oxygen densities. Preliminary measurements of molecular oxygen densities obtained by this technique agree well with measurements taken in the fly-through mode of operation.

Kayser, D. C.↗

Neutral composition measurements by the Pioneer Venus Neutral Mass Spectrometer during orbiter re-entry

Measurements by the Pioneer Venus Orbiter Neutral Mass Spectrometer (ONMS) instrument during Orbiter re-entry have been made from 18-24 hours local solar time, above 170 km, of He, and from midnight to 4.5 hours below 200 km of He, N, O, CO, N2, and CO2. Preliminary results indicate that in the post-midnight sector He is the dominant species above 170 km, O the dominant species from 140-170 km and CO2 the dominant species below 140 km. Estimated scale height temperatures for He, O, and CO2 of about 105-120 K are similar to those observed in 1978-1980 at higher solar activity. The densities at 1 am local solar time and at 150 km are within 35% of those measured earlier. The He bulge is also similar to that observed in 1978-1980 confirming that thermosphere superrotation is still present. Comparison with the results of a Venus Thermosphere General Circulation Model suggests the nightside is not sensitive to changes in solar activity due to the isolation of the day and night thermospheres. apparently, the relatively small changes in the dayside thermosphere with solar activity have little impact on the nightside thermosphere.

Kasprzak, W. T.↗