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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1969

Models of Earth's Atmosphere (120 to 1000 Km)

Atmospheric conditions encountered by a spacecraft in orbit about the Earth are important factors in space vehicle design, mission planning, and mission operations. Density is the primary atmospheric property that affects the spacecraft's orbital altitude, lifetime, and motion in the altitude range of 120 to 1000 kilometers. Near the lower limit of this range where density is greatest, a spacecraft will generally remain in orbit for a very short time; near the upper limit, the density effect on orbital lifetime is almost negligible. Density directly affects the torques which result from aerodynamic interaction between the space vehicle and the atmosphere; such torques must be considered in design of spacecraft attitude control systems. Density scale height is required in heating calculations for space vehicles re-entering the Earth's upper atmosphere. Density as well as chemical composition and temperature are needed in calculating a spacecraft's drag coefficient. Chemical composition and temperature also are required in the design of experiment sensors to be flown in this altitude range. Because of variability of atmospheric conditions with spatial location and solar condition, invariant models of the Earth's atmosphere (120 to 1000 kilometers) would not be useful for most engineering applications. Therefore, this monograph presents a computerized version of Jacchia's prediction method to provide models of the Earth's atmosphere which vary with solar condition and location. The resulting atmospheric models, which are predicted for particular times and locations, provide atmospheric density, chemical composition, temperature, molecular mass, and density scale height between 120 and 1000 kilometers altitude. In addition to the computerized method, a quick-look prediction method is given that may be used to obtain an estimate of atmospheric density for any time and spatial location without the use of a computer. A sample problem illustrates this method. Both methods provide models of mean density and models having reasonable upper extremes for density. The analytical approaches in both methods are considered to be the best available, but they could be refined considerably by additional data and study. Information contained in this monograph applies to altitudes between 120 and 1000 kilometers; other design criteria monographs in this series will provide atmospheric information below this altitude region.

Weidner, D. K.↗
NASA NTRS2017

Using Advanced Mass Spectrometry Techniques to Fully Characterize Atmospheric Organic Carbon: Current Capabilities and Remaining Gaps

Organic compounds in the atmosphere vary widely in their molecular composition and chemical properties, so no single instrument can reasonably measure the entire range of ambient compounds. Over the past decade, a new generation of in-situ, field-deployable mass spectrometers has dramatically improved our ability to detect, identify, and quantify these organic compounds, but no systematic approach has been developed to assess the extent to which currently available tools capture the entire space of chemical identity and properties that is expected in the atmosphere. Reduced-parameter frameworks that have been developed to describe atmospheric mixtures are exploited here to characterize the range of chemical properties accessed by a suite of instruments. Multiple chemical spaces (e.g. oxidation state of carbon vs. volatility, and oxygen number vs. carbon number) were populated with ions measured by several mass spectrometers, with gas- and particle-phase α-pinene oxidation products serving as the test mixture of organic compounds. Few gaps are observed in the coverage of the parameter spaces by the instruments employed in this work, though the full extent to which comprehensive measurement was achieved is difficult to assess due to uncertainty in the composition of the mixture. Overlaps between individual ions and regions in parameter space were identified, both between gas- and particle-phase measurements, and within each phase. These overlaps were conservatively found to account for little (<10%) of the measured mass. However, challenges in identifying overlaps and in accurately converting molecular formulas into chemical properties (such as volatility or reactivity) highlight a continued need to incorporate structural information into atmospheric measurements.

G. Isaacman-VanWertz↗
NASA NTRS2006

Titan's Atmospheric Composition from Observations by the Cassini Infrared Spectrometer

The Composite Infrared Spectrometer (CIRS) aboard the Cassini spacecraft has been making observations during the fly-bys of Titan since the Saturn-Orbit-Insertion in July 2004. The observations provide infrared them1 emission spectra of Titan s atmosphere in three spectral channels covering the 10/cm to 1400/cm spectral region, with variable spectral resolutions of 0.53/cm and 2.8/cm. The uniquely observed spectra exhibit rotational and vibrational-rotational spectral lines of the molecular constituents of Titan s atmosphere that may be analyzed to retrieve information about the composition, thermal structure, and physical and dynamical processes in the remotely sensed atmosphere. We present an analysis of Titan's infrared spectra observed during July 2004 (TO), December 2004 (Tb) and February 2005 (T3), for retrieval of the stratospheric thermal structure, distribution of the hydrocarbons, nitriles, and oxygen bearing constituents, such as C2H2, C2H4, C2H6, C3H8, HCN, HC3N, CO, and CO2 . Preliminary results on the distribution and opacity of haze in Titan s atmosphere are discussed.

Abbas, M. M.↗
NASA NTRS1972

Thermospheric temperature measurement technique.

A method for measurement of temperature in the earth's lower thermosphere from a high-velocity probes is described. An undisturbed atmospheric sample is admitted to the instrument by means of a free molecular flow inlet system of skimmers which avoids surface collisions of the molecules prior to detection. Measurement of the time-of-flight distribution of an initially well-localized group of nitrogen metastable molecular states produced in an open, crossed electron-molecular beam source, yields information on the atmospheric temperature. It is shown that for high vehicle velocities, the time-of-flight distribution of the metastable flux is a sensitive indicator of atmospheric temperature. The temperature measurement precision should be greater than 94% at the 99% confidence level over the range of altitudes from 120-170 km. These precision and altitude range estimates are based on the statistical consideration of the counting rates achieved with a multichannel analyzer using realistic values for system parameters.

Hueser, J. E.↗
NASA NTRS1985

A preliminary spectroscopic assessment of the Spacelab 1/Shuttle optical environment

Attention is given to the Space Lab/Space Shuttle-borne Imaging Spectrometric Observatory's 1150-8000 A spectral data, which was gathered while this instrument package was looking tangentially away from the earth and into the velocity vector. The spectrum is noted to contain the expected atmospheric features, together with bright molecular bands between 6400 and 8000 A. These bands appear to be part of the N2 First Positive system. If most of the emission is due to this system, two excitation mechanisms are implied: direct collisional excitation of the local Shuttle atmosphere by the terrestrial atmosphere, or alternatively a surface interaction which generates metastable N2(A); this subsequently radiates via inverse first positive N2 transitions, followed by first positive transitions.

Torr, M. R.↗
NASA NTRS1992

Analysis of stellar occultation data for planetary atmospheres. I - Model fitting, with application to Pluto

Consideration is given to an analytic model for a stellar-occultation light curve developed for a small, spherically symmetric planetary atmosphere that includes thermal and molecular weight gradients in a region that overlies an extinction layer. The model incorporates two equivalent sets of parameters. One set specifies the occultation light curve in terms of signal levels, times, and time intervals. The other set specifies physical parameters of the planetary atmosphere. Equations are given for the transforming between the sets of parameters, including their errors and correlation coefficients. Detailed numerical calculations are presented for a benchmark case. The results obtained are consistent with the isothermal prediction of the 'methane-thermostat' model of Pluto's atmosphere.

Elliot, J. L.↗
NASA NTRS1987

Atmospheric odd oxygen production due to the photodissociation of ordinary and isotopic molecular oxygen

Line-by-line calculations are performed to determine the contributions of the Schumann-Runge bands of ordinary and isotopic oxygen to the photodissociation of these molecules at different altitudes. The contributions to the dissociation rates of the satellite lines and of the first and higher vibrational states of the initial molecular states are found to be insignificant. At 70 km, (O-16)(O-18) is found to produce 10 times as much odd oxygen as would be produced if the isotope did not have selective absorption, and 6 percent of the odd oxygen produced is due to this isotope. It is noted that the excess odd oxygen produced is not enough to explain the excess quantity of ozone observed in the atmosphere, which cannot be accounted for in photochemical models. Comparison with previous results is made.

Omidvar, K.↗
NASA NTRS1976

Structure of the neutral upper atmosphere of Mars - Results from Viking 1 and Viking 2

Neutral mass spectrometers carried on the aeroshells of Viking 1 and Viking 2 indicate that carbon dioxide is the major constituent of the Martian atmosphere over the height range 120 to 200 kilometers. The atmosphere contains detectable concentrations of nitrogen, argon, carbon monoxide, molecular oxygen, atomic oxygen, and nitric oxide. The upper atmosphere exhibits a complex and variable thermal structure and is well mixed to heights in excess of 120 kilometers.

Nier, A. O.↗
NASA NTRS1980

Atmospheric corrections to passive microwave observations of the ocean

Microwave observations of the ocean surface are contaminated to a greater or lesser degree by the overlying atmosphere. The principal components of the atmosphere contributing to this contamination are molecular oxygen, water vapor, and water droplets. By means of measurements at several well-chosen frequencies, these atmospheric parameters may be removed from ocean observations and themselves retrieved as a by-product. This is the basic concept of the Scanning Multifrequency Radiometer (SMMR). These corrections may be made by quasi-linear means to useful accuracies, even in the presence of moderate rain.

Wilheit, T.↗
NASA NTRS2001

Meteoric Ions in Planetary Ionospheres

Solar system debris, in the form of meteoroids, impacts every planet. The flux, relative composition and speed of the debris at each planet depends on the planet's size and location in the solar system. Ablation in the atmosphere evaporates the meteoric material and leaves behind metal atoms. During the ablation process metallic ions are formed by impact ionization. For small inner solar system planets, including Earth, this source of ionization is typically small compared to either photoionization or charge exchange with ambient molecular ions. For Earth, the atmosphere above the main deposition region absorbs the spectral lines capable of ionizing the major metallic atoms (Fe and Mg) so that charge exchange with ambient ions is the dominant source. Within the carbon dioxide atmosphere of Mars (and possibly Venus), photoionization is important in determining the ion density. For a heavy planet like Jupiter, far from the sun, impact ionization of ablated neutral atoms by impacts with molecules becomes a prominent source of ionization due to the gravitational acceleration to high incident speeds. We will describe the processes and location and extent of metal ion layers for Mars, Earth and Jupiter, concentrating on flagging the uncertainties in the models at the present time. This is an important problem, because low altitude ionosphere layers for the planets, particularly at night, probably consist predominantly of metallic ions. Comparisons with Earth will be used to illustrate the differing processes in the three planetary atmospheres.

Pesnell, W. D.↗
NASA NTRS1993

Eddy mixing coefficient upper limit derived from the photochemical balance of O2

This work is based on the study of the photochemical balance of molecular oxygen in the martian atmosphere by using a one-dimensional model of photochemical reactions involving species derived from CO2 and H2O. The model is basically similar to one used previously for the study of the regulation of CO on a global scale, but the chemical rates are taken from another source. In the present scheme, the regulation of molecular oxygen is studied over timescales of the order of its photochemical lifetime (approximately equals 30 yr), which is much shorter than typical escape timescales. Thus, the escape fluxes are fixed to the values given by 3 and 4. We examine the calculated equilibrium abundances of O2 for given thermal, eddy diffusion coefficients and H2O profiles. The thermal profile is taken from in the lower atmosphere. At higher levels, in order to include the diurnal and seasonal thermal profile variability, we have also used the IRTM data. In order to study the influence of both temperature and pressure profiles on the O2 mixing ratio, we have made several tests corresponding to different martian seasons. The results show that the influence of pressure and temperature is quantitatively weak compared to the one of K and of the water vapor density (H2O). Thus, in the following we have fixed the pressure at the surface to a value of 7 mbar and we have used unique standard thermal profile corresponding to a profile roughly averaged over the year, the season, and the day: T equal 205 K at 0 km altitude, 175 K at 25 km, and 145 K at 50 km.

Rosenqvist, J.↗
NASA NTRS1979

H2 emission in the solar atmosphere

New identifications of emission lines of molecular hydrogen in the EUV spectrum of sunspots are reported. The spectra were obtained during the first and second flights of the Naval Research Laboratory's High Resolution Telescope and Spectrograph (HRTS). While most of the lines originate in the Lyman bands, fluorescence from the Werner bands has been found for the first time in the solar atmosphere. H2 fluorescent emission has also been identified in the spectra of a solar flare observed with NRL's normal incidence spectrograph on Skylab. Column densities for H2 are derived from intensities of lines in the sunspot spectra.

Bartoe, J.-D. F.↗
NASA NTRS2015

Evolution of the Far-Infrared Cloud at Titan's South Pole

A condensate cloud on Titan identified by its 220 cm−1 far-infrared signature continues to undergo seasonal changes at both the north and south poles. In the north, the cloud, which extends from 55 N to the pole, has been gradually decreasing in emission intensity since the beginning of the Cassini mission with a half-life of 3.8 years. The cloud in the south did not appear until 2012 but its intensity has increased rapidly, doubling every year. The shape of the cloud at the south pole is very different from that in the north. Mapping in 2013 December showed that the condensate emission was confined to a ring with a maximum at 80 S. The ring was centered 4deg from Titanʼs pole. The pattern of emission from stratospheric trace gases like nitriles and complex hydrocarbons (mapped in 2014 January) was also offset by 4deg, but had a central peak at the pole and a secondary maximum in a ring at about 70 S with a minimum at 80 S. The shape of the gas emission distribution can be explained by abundances that are high at the atmospheric pole and diminish toward the equator, combined with correspondingly increasing temperatures. We discuss possible causes for the condensate ring. The present rapid build up of the condensate cloud at the south pole is likely to transition to a gradual decline from 2015 to 2016. Key words: molecular processes - planets and satellites: atmospheres - planets and satellites: composition - planets and satellites: individual (Titan) - radiation mechanisms: thermal

Cassini↗
NASA NTRS2016

Isotopic Ratios of Carbon and Oxygen in Titan's CO Using Alma

We report interferometric observations of carbon monoxide (CO) and its isotopologues in Titan's atmosphere using the Atacama Large Millimeter/submillimeter Array (ALMA). The following transitions were detected: CO (J = 1-0, 2-1, 3-2, 6-5), C-13 O (J = 2-1, 3-2, 6-5), C-18 O (J = 2-1, 3-2), and C-17 O (J = 3-2). Molecular abundances and the vertical atmospheric temperature profile were derived by modeling the observed emission line profiles using NEMESIS, a line-by-line radiative transfer code. We present the first spectroscopic detection of O-17 in the outer solar system with C-17 O detected at greater than 8 sigma confidence. The abundance of CO was determined to be 49.6 +/- 1.8 ppm, assumed to be constant with altitude, with isotopic ratios C-12/C-13 = 89.9 +/- 3.4, O-16/O-18 = 486 +/- 22, and O-16/O-17 = 2917 +/- 359. The measurements of C-12/C-13 and O-16/O-18 ratios are the most precise values obtained in Titan's atmospheric CO to date. Our results are in good agreement with previous studies and suggest no significant deviations from standard terrestrial isotopic ratios.

Serigano, Joseph↗
NASA NTRS1972

Interpretation of the Minkowski bands in Grw + 70 deg 8247.

Demonstration on the basis of the spectral structure of circular polarization in Grw + 70 deg 8247, that the absorption bands are at least in part molecular in origin. The spectrum of molecular helium has strong bands coincident with several of the Minkowski bands and, in particular, at high temperature shows a strong band head at about 4125 A. Helium molecules could be formed in sufficient density to give the absorption features in the star if it has a pure helium atmosphere. The Zeeman effect in molecular helium can explain in general the observed spectral features in the polarization and also may be responsible for the continuum polarization.

Angel, J. R. P.↗
NASA NTRS1982

The Mars reference atmosphere

A nominal atmospheric model of Mars is presented, with detailed consideration being given to the various sources of variability in the Martian atmosphere. A basic model for the midlatitude summer is outlined for the northern and southern hemispheres. Attention is given to meteorological variability due to winds, diurnal and seasonal pressure variations, temperature changes, and the effects of dust opacity, particularly on temperature stratification. Viking lander IR thermal mapper data are examined in terms of diurnal and latitudinal temperature variations, and cloud and haze formation and locations are discussed. Mass spectrometry of the atmosphere is used to describe the molecular abundances, and water vapor measurements are reviewed. Finally, radio occultation, UV airglow, and mass spectrometry of the Martian upper atmosphere are investigated, along with the temperature structure of the upper atmosphere.

Kliore, A.↗
NASA NTRS1990

Triton, Pluto and Charon

On the eve of the Voyager encounter with Neptune and Triton, the knowledge of the surface and atmosphere of the satellite has made some progress. Methane, and perhaps molecular nitrogen, appears to dominate the surface and atmospheric chemistry. Sketchy evidence suggests changes in the disposition and state of the volatile materials on this body in the past few years, perhaps in response to the extreme seasons. Pluto and its satellite Charon are at last revealed in some detail, chiefly resulting from observations of the mutual transits and occultations of 1985-1990. A stellar occultation by Pluto in 1988 has given the first detailed information on the planet's atmosphere. The density of the Pluto-Charon system indicates a bulk composition consisting of silicates and water ice, suggesting formation directly from the solar nebula.

Cruikshank, D. P.↗