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The research concerned with the interpretation of lunar data developed during the Apollo Program is reported. The areas of research include: X-ray emission spectra and molecular orbitals of lunar materials, magnetic properties of lunar rock, lunar features, thermal history and evolution of the moon, and the internal constitution and evolution of the moon.
Papers on lunar and planetary science are presented, including petrogenesis and chemistry of lunar samples, geology and petrogenesis of the Apollo 15 landing site, lunar geology and applications, cratering records and cratering effects, differentiated meteorites, chondritic meteorites and asteroids, extraterrestrial grains, Venus, Mars, and icy satellites. The importance of lunar granite and KREEP in very high potassium basalt petrogenesis, indentifying parent plutonic rocks from lunar breccia and soil fragments, glasses in ancient and young Apollo 16 regolith breccias, the formation of the Imbrium basin, the chemistry and petrology of the Apennine Front, lunar mare ridges, studies of Rima Mozart, electromagnetic energy applications in lunar resource mining and construction, detecting a periodic signal in the terrestrial cratering record, and a search for water on the moon, are among the topics discussed. Other topics include the bidirectional reflectance properties of Fe-Ni meteorites, the nature and origin of C-rich ordinary chondrites and chondritic clasts, the dehydration kinetics of shocked serpentine, characteristics of Greenland Fe/Ni cosmic grains, electron microscopy of a hydrated interplanetary dust particle, trapping Ne, Ar, Kr, and Xe in Si2O3 smokes, gossans on Mars, and a model of the porous structure of icy satellites.
NASA is contemplating sending humans to Mars and to the moon for further exploration. Volcanic ashes from Arizona and Hawaii with mineral properties similar to those of lunar and Martian soils, respectively, are used to simulate lunar and Martian environments for instrument testing. Martian soil is highly oxidative; this property is not found in Earth's volcanic ashes. NASA is concerned about the health risk from potential exposure of workers in the test facilities. Fine lunar soil simulant (LSS), Martian soil simulant (MSS), titanium dioxide, or quartz in saline was intratracheally instilled into groups of 4 mice (C57BL/6J) at 0.1 mg/mouse (low dose, LD) or 1 mg/mouse (high dose, HD). Separate groups of mice were exposed to ozone (0.5 ppm for 3 h) prior to MSS instillation. Lungs were harvested for histopathological examination 7 or 90 days after the single dust treatment. The lungs of the LSS-LD groups showed no evidence of inflammation, edema, or fibrosis; clumps of particles and an increased number of macrophages were visible after 7 days but not 90 days. In the LSS-HD-7d group, the lungs showed mild to moderate alveolitis, and perivascular and peribronchiolar inflammation. The LSS-HD-90d group showed signs of mild chronic pulmonary inflammation, septal thickening, and some fibrosis. Foci of particle-laden macrophages (PLMs) were still visible. Lung lesions in the MSS-LD-7d group were similar to those observed in the LSS-HD-7d group. The MSS-LD-90d group had PLMs and scattered foci of mild fibrosis in the lungs. The MSS-HD-7d group showed large foci of PLMs, intra-alveolar debris, mild-to-moderate focal alveolitis, and perivascular and peribronchiolar inflammation. The MSS-HD-90d group showed focal chronic mild-to-moderate alveolitis and fibrosis. The findings in the O(3)-MSS-HD-90d group included widespread intra-alveolar debris, focal moderate alveolitis, and fibrosis. Lung lesions in the MSS groups were more severe with the ozone pretreatment. The effects of O(3) and MSS coexposure appeared to be more than additive. Results for the TiO(2) and quartz controls were consistent with the known pulmonary toxicity of these compounds. The overall severity of lung injury was TiO(2) < LSS < MSS < O(3) + MSS < quartz. Except for TiO(2), the increased duration of dust presence in the lung from 7 to 90 days transformed the acute inflammatory response to a chronic inflammatory lesion. This study showed that LSS and MSS are more hazardous in the lungs than nuisance dusts.
During the Apollo missions, many undesirable situations were encountered that must be mitigated prior to returning humans to the moon. Lunar dust (that part of the lunar regolith less than 20 m in diameter) was found to produce several problems with astronaut s suits and helmets, mechanical seals and equipment, and could have conceivably produced harmful physiological effects for the astronauts. For instance, the abrasive nature of the dust was found to cause malfunctions of various joints and seals of the spacecraft and suits. Additionally, though efforts were made to exclude lunar dust from the cabin of the lunar module, a significant amount of material nonetheless found its way inside. With the loss of gravity correlated with ascent of the lunar module from the lunar surface to rendezvous with the command module, much of the major portions of the contaminating soil and dust began to float, irritating the astronaut s eyes and being inhaled into their lungs. Our goal has been to understand some of the properties of lunar dust that could lead to possible hazards for humans. Due to the lack of an atmosphere, there is nothing to protect the lunar soil from ultraviolet radiation, solar wind, and meteorite impacts. These processes could all serve to activate the soil, or produce reactive surface species. In order to understand the possible toxic effects of the reactive dust, it is necessary to reactivate the dust, as samples returned during the Apollo missions were exposed to the atmosphere of the Earth. We have used grinding and UV exposure to mimic some of the processes occurring on the Moon. The level of activation has been monitored using two methods: fluorescence spectroscopy and electron paramagnetic resonance spectroscopy (EPR). These techniques allow the monitoring of hydroxyl radical production in solution. We have found that grinding of lunar dust produces 2-3 times the concentration of hydroxyl radicals as lunar simulant and 10 times that of quartz. Exposure of the lunar dust to UV radiation under vacuum was also found to lead to hydroxyl radical production. After grinding, we have also monitored loss of reactivity of the dusts by exposing them to conditions of known humidity and temperature. From these tests, it was found that the reactivity half-life of lunar simulant is approximately 3 hours, while that of quartz is approximately 2 hours. Placing lunar dust in solution could lead to effects on mechanical and physiological systems, as well as other biological systems. For instance, while it is known that lunar dust is highly abrasive and caused a variety of problems with suits and equipment during Apollo, it is unknown as to how these properties might be affected in the presence of water or other liquids. It is possible that the dust may release minerals (e.g., metallic nanophase Fe) into solution that could speed corrosion or rust. Also, as lunar dust produces hydroxyl radicals (and possibly other reactive oxygen species) in solution, these radicals could also lead to the breakdown of suit or habitat materials. In the body (i.e., in lung solution), the effects could be two-fold. First, if the lunar dust dissolves, it may release an excess of elements (such as zero-valence metallic Fe) that are necessary for bodily functions but only in certain concentration ranges. For lunar dust, the presence of nanophase iron being released into the body is a concern. Secondly, the hydroxyl radicals or other reactive oxygen species produced by the dust in solution could conceivably interact with cells, leading to various problems. We have studied the dissolution of both ground and unground lunar simulant in buffer solutions of different pH. The concentration of a number of species was determined using mass spectrometry. These studies showed that lowering the pH of the solution causes a dramatic increase in the amount of each element released into solution and that grinding also produces higher concentrations. Finally, we have perfmed initial tests aimed at understanding the effects of lunar simulant on cellular systems. Alveolar epithelial cells were cultured and exposed to different concentrations of dust suspended in cell culture media. After predetermined amounts of time, the media was removed and the concentrations of important inflammatory cytokines (IL6, IL8, and TNF-alpha ) were measured. The results of these tests are being used to develop the correct protocols for tests to be performed using lunar dust samples.
Volatiles and refractories represent the two end-members in the volatility range of species in any surface-bounded exosphere. Volatiles include elements that do not interact strongly with the surface, such as neon (detected on the Moon) and helium (detected both on the Moon and at Mercury), but also argon, a noble gas (detected on the Moon) that surprisingly adsorbs at the cold lunar nighttime surface. Refractories include species such as calcium, magnesium, iron, and aluminum, all of which have very strong bonds with the lunar surface and thus need energetic processes to be ejected into the exosphere. Here we focus on the properties of species that have been detected in the exospheres of inner Solar System bodies, specifically the Moon and Mercury, and how they provide important information to understand source and loss processes of these exospheres, as well as their dependence on variations in external drivers.
The remanent magnetic fields measured to date on the moon are 38 plus or minus 3 gamma at Apollo 12 in Oceanus Procellarum; 103 plus or minus 5 and 43 plus or minus 6 gamma at two Apollo 14 sites separated by 1.1 km in Fra Mauro; and 6 plus or minus 4 gamma at the Apollo 15 Hadley-Apennines site. Measurements show that the 38-gamma remanent field at Apollo 12 is compressed to 54 gamma by a solar wind pressure increase of 7 x 10 to the minus 8th dyne/sq cm. The change in magnetic pressure is proportional to the change in plasma pressure, and the field is compressed primarily in the z (northerly) component. The electrical conductivity of the lunar interior has been determined from magnetic step transient measurements made on the lunar dark side. A range of monotonic conductivity profiles is calculated that provides a fit to the normalized data curve within error limits. Deeper than 90 km into the moon, the conductivity rises from 0.0003 mhos/m to 0.01 mhos/m at 1000 km depth. These conductivities, when converted to temperatures for an assumed lunar material of peridotite, suggest the existence of a thin outer layer (perhaps 90 km thick) in which the temperature rises sharply to 850 to 1050 K, then increases gradually to 1200 to 1500 K at a depth of about 1000 km.
Review of the physical nature of all of the known satellites except the moon. Following a summary of the basic data regarding the size, mass, and density of satellite systems and a description of models that have been proposed for the composition and structure of these systems, a detailed analysis is made of the satellites of Mars, the Galilean satellites, Titan, the other satellites of Saturn, the rings of Saturn, and the remaining objects, with emphasis on studies of their surfaces by imaging, photometry, spectrophotometry, polarimetry, and radiometry.
With NASA’s goal of returning humans to the Moon, it has become increasingly important to understand the impact of lunar regolith on spacecraft systems. The ability to measure the level of dust coverage on a surface is essential. Developing an accurate technique to determine percent area coverage is challenging due to the unique and complex layering of the dust particles on the surface, creating fairy castle structures that form complex towers, bridges, and buttresses using the smallest of dust particles as building blocks. For this study, these structures have been simulated using a unique dust distributor device and imaged with a scanning electron microscope. The results show the dusted surface’s complex topology, thus demonstrating the difficulty with determining the percent area of dust coverage. Implications for dust buildup on spacecraft, even at the microscopic level, can include degraded heat transfer and altered optical properties, making continuation of this research critical to support future human exploration of the Moon.
With NASA’s goal of returning humans to the Moon, it has become increasingly important to understand the impact of lunar regolith on spacecraft systems. The ability to measure the level of dust coverage on a surface is essential. Developing an accurate technique to determine percent area coverage is challenging due to the unique and complex layering of the dust particles on the surface, creating fairy castle structures that form complex towers, bridges, and buttresses using the smallest of dust particles as building blocks. For this study, these structures have been simulated using a unique dust distributor device and imaged with a scanning electron microscope. The results show the dusted surface’s complex topology, thus demonstrating the difficulty with determining the percent area of dust coverage. Implications for dust buildup on spacecraft, even at the microscopic level, can include degraded heat transfer and altered optical properties, making continuation of this research critical to support future human exploration of the Moon.
The new space exploratory vision announced by President Bush on January 14, 2004, initiated new activities at the National Science and Space Administration (NASA) for human space missions to further explore our solar system. NASA is undertaking Lunar exploration to support sustained human and robotic exploration of Mars and beyond. A series of robotic missions to the Moon by 2008 to prepare for human exploration as early as 2015 but no later than 2020 are anticipated. In a similar way, missions to the Moon and Mars are being planned in Europe, Japan and Russia. These space missions will require international participation to solve problems in a number of important technological areas where research is needed, including biomedical risk mitigation as well as life support and habitability on the surface of Mars. Mitigation of dust hazards is one of the most important problems to be resolved for both Lunar and Mars missions. Both Lunar and Martian regolith are unique materials and completely different from the terrestrial soils that we are exposed to on earth. The total absence of water and an atmosphere on the moon and the formation of soil and fine dust by micrometeorite impacts over billions of years resulted in a layer of soil with unique properties. The soil is primarily basaltic in composition with a high glass concentration. The depth of the soil layer varies from a few meters in the mare areas (dark areas on the Lunar near side) to tens of meters in the highland areas (the lighter mountainous areas) and the particle size distribution of this dust layer varies widely with a major mass fraction less than 10 micrometer in diameter. The hard soil from the moon which has been extensively studied by several researchers showed clearly unique properties of Lunar soil. Apollo astronauts became aware of the potentially serious threat to crew health and mission hardware that can be caused by the lunar dust. As reported by McKay and Carrier the mass fraction of the lunar dust with particle diameter smaller than 20p.m probably represents up to 30% of the total mass of regolith. Apollo astronaut Dr. Harrison Schmidt reported that these fine dust particles were clinging to the Extra Vehicular Activity (EVA) suits and to the visors and were limiting the activity on the surface of the moon. The dust particles that were transported with the EVA suits into the lunar module floated throughout the cabin. Crews inhaled the dust particles and noted that they smelled like gun smoke, caused a chocking sensation in the throat and eye irritation. In addition,, some of the mechanical systems were not functioning well because of the dust deposition. It appeared that the dust particles are highly charged electrostatically and Dr. Schmidt noted that future successful Lunar missions will require appropriate dust mitigation technology for protecting astronauts from inhaling toxic particles and mission's life supporting equipment from contamination with the dust particles.
A study of images of the polar regions shows that small craters near the poles of the Moon are distinguished by the following features: 1. they have a smoother shape - see Fig (a); 2. patterned ground (“wrinkled skin”) is often observed in and around the crater - see Figs (a,b,c); 3. outside the craters landslides and cracks are noticeable - see Fig (d); 4. layers or scarps are often visible on the inner slope - see Fig (e). These features (scarps and patterned ground) are typical for Martian craters in the permafrost zone (see Fig f), as well as for similar zones on Earth. It is hypothesized that these features of lunar craters are associated with the presence of permafrost in the polar regions of the Moon. In 2023, the VIPER rover will investigate the distribution of ice (volatile) deposits in the region of the Moon's South Pole. VIPER navigation cameras represent a unique opportunity for the geomorphological analysis of the lunar surface and the study of physical properties of regolith due to multiple key factors: - A large number of high-quality digital images with a good resolution of the South Pole of the Moon, which is a key region for the landing of manned expeditions. - A low position of the Sun, which generates long shadows, creates favorable conditions for object recognition algorithms. - A presence of a rover track in the images enables VIPER wheels to be used as tools for the study of the regolith and the development of a geotechnical model of regolith in the South Pole region. Rover navigation cameras will allow investigation of the distribution and shape of small craters and other structures along the path of the rover and test the hypothesis about geomorphological signatures of permafrost in the lunar polar areas. If a relationship between characteristics of lunar craters and the distribution of permafrost is confirmed, this will open a possibility to remotely determine the deposits of lunar ice from satellite imagery.
The return to the Moon has ignited the need to characterize the lunar regolith using fast, reliable in-situ methods. Characterizing the physical properties of the rocks and soils can be very difficult because of the many complex parameters that influence the measurements. In particular, soil electrical property measurements are influenced by temperature, mineral type, grain size, porosity, and soil conductivity. Determining the dielectric constant of lunar materials may be very important in providing quick characterization of surface deposits, especially for the Moon. A close examination of the lunar regolith samples collected by the Apollo astronauts indicates that the rocks and soils on the Moon are dominated by silicates and oxides. In this presentation, we will show that determining the dielectric constant measurements can provide a simple, quick detection method for minerals that contain titanium, iron, and water. Their presence is manifest by an unusually large imaginary permittivity.
The moon is covered to a depth of several meters with fine material. Heat transfer calculations depend, therefore, for the most part on the properties of the fines. The results are presented of thermal conductivity measurements on fines samples returned by the Apollo 15 mission from the Hadley-Apennine region of the moon. Data are presented as a function of both density and temperature with typical lunar values being used for these parameters.
Development of versatile engineering materials from locally available materials in space is an important step toward the establishment of outposts on the Moon and Mars. Development of the technologies for manufacture of structural and construction materials on the Moon, utilizing local lunar soil (regolith), without the use of water, is an important element for habitats and explorations in space. It is also vital that the mechanical behavior such as strength and tensile, flexural properties, fracture toughness, ductility, and deformation characteristics are defined toward establishment of the ranges of engineering applications of the materials developed. The objectives include two areas: (1) thermal 'liquefaction' of lunar simulant (at about 1100 C) with different additives (fibers, powders, etc.), and (2) development and use of a new triaxial test device in which lunar simulants are first compacted under cycles of loading, and then tested with different vacuums and initial confining or in situ stress. Details of the development of intermediate ceramic composites (ICC) and testing for their flexural and compression characteristics were described in various reports and papers. The subject of behavior of compacted simulant under vacuum was described in previous progress reports and publications; since the presently available device allows vacuum levels up to only 10(exp -4) torr, it is recommended that a vacuum pump that can allow higher levels of vacuum be utilized for further investigation.
Development of versatile engineering materials from locally available materials in space is an important step toward establishment of outposts such as on the moon and Mars. Here development of the technologies for manufacture of structural and construction materials on the moon, utilizing local lunar soil (regolith), without the use of water, is an important element for habitats and explorations in space. It is also vital that the mechanical behavior such as strength and flexural properties, fracture toughness, ductility, and deformation characteristics are defined toward establishment of the ranges of engineering applications of the materials developed. The objectives include two areas: (1) thermal liquefaction of lunar simulant (at about 1100 C) with different additives (fibers, powders, etc.); and (2) development and use of a traxial test device in which lunar simulants are first compacted under cycles of loading, and then tested with different vacuums and initial confining or insitu stress. The second area was described in previous progress reports and publications; since the presently available device allows vacuum levels up to only 10(exp -4) torr, it is recommended that a vacuum pump that can allow higher levels of vacuum is acquired.
Elastic and plastic properties of Fe-light element alloys and compounds are needed to determine the compositions and dynamics of planetary cores. Elastic strength and plastic deformation mechanisms and their relationship to electronic properties of ε-Fe 7 N 3 and γ’-Fe 4 N mixture were investigated by x-ray diffraction and x-ray emission spectroscopy in the diamond anvil cell from 1 bar up to 60 GPa. X-ray diffraction shows that ε-Fe 7 N 3 reaches a pressure of 15–20 GPa before undergoing bulk plasticity at a differential stress of 4.4–10.4 GPa. ε-Fe 7 N 3 is stronger than γ’-Fe 4 N and hcp-Fe which achieve a flow stress of 1.5–3.6 GPa at 10–15 GPa and 2–3 GPa at ~20 GPa, respectively. X-ray emission spectroscopy shows that a decrease in electronic spin moment begins before and completes after plastic flow onset for each nitride, suggesting that pressure-driven changes in electronic arrangement do not trigger a plastic response although they may modify the strength and plastic behavior of Fe-N compounds. Plastic deformation in ε-Fe 7 N 3 and hcp-Fe results in a preferred orientation of (0001) normal to maximum compression, while γ’-Fe 4 N develops a maximum in the (110). Furthermore, these observations may be combined with measurements of elasticity to model seismic properties of cores of small planetary bodies such as Mars, Mercury, and the Moon.
The mechanism by which atmospheric moisture affects the conductivity and dielectric constant of rock specimens was studied in time and frequency domains. It is suggested that adsorbed water molecules alter the surface conductivity in a manner similar to that observed in semiconductors and insulators. Powdered basalts show a low-frequency dispersion produced by the atmospheric moisture remaining in the pore system of the sample in a high vacuum; this effect is attributed to isolated adsorption centers. Simulated lunar permafrost at 100 K and a vacuum of 10 to the -8th power torr together with data on lunar samples contaminated with atmospheric moisture and the dielectric properties of ice at various temperatures indicate that, if permafrost exists in the moon it should present a relaxation peak at approximately 300 Hz; for temperatures up to 263 K it may go up to 20 KHz. It is concluded that in order to have electrical steady state conditions in rock samples it is necessary to have volume charge accumulations at interfaces within the sample and at the electrode sample interface. A method for measuring heterogeneous dielectrics with non-negligible ohmic and dielectric conductivities is proposed and experimentally verified.
High-temperature creep in orthoenstatite under conditions of controlled oxygen fugacity was studied. It was found that creep was conttrolled by the extremely thin layer of SiO2 which wetted the grain boundaries. Slight reduction of the (Mg, Fe)SiO3 enstatite during hot pressing produced microscopic particles of Fe and the thin film of intergranular SiO2. This result highlights another complication in determining the flow properties of iron bearing silicates which constitute the bulk of terrestrial planets and moons. The Phenomenon may be important in the ductile formation of any extraterrestrial body which is formed in a reducing environment. The rheology of dirty ice was studied. This involves micromechanical modeling of hardening phenomena due to contamination by a cosmic distribution of silicate particles. The larger particles are modeled by suspension theory. In order to handle the distribution of particles sizes, the hardening is readed as a critical phenomenon, and real space renormalization group techniques are used. Smaller particles interact directly with the dislocations. The particulate hardening effect was studied in metals. The magnitude of such hardening in ice and the defect chemistry of ice are studied to assess the effects of chemical contamination by methane, ammonia, or other likely contaminants.