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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

C-13 nuclear magnetic resonance in graphite intercalation compounds

The C-13 NMR chemical shifts of graphite intercalation compounds have been calculated. For acceptor types, the shifts come mainly from the paramagnetic (Ramsey) intra-atomic terms. They are related to the gross features of the two-dimensional band structures. The calculated anisotropy is about - 140 ppm and is independent of the finer details such as charge transfer. For donor types, the carbon 2p pi orbitals are spin-polarized because of mixing with metal-conduction electrons, thus there is an additional dipolar contribution which may be correlated with the electronic specific heat. The general agreement with experimental data is satisfactory.

Tsang, T.↗

In vivo nuclear magnetic resonance imaging

During the past year the Woodlands Baylor Magnetic Resonance Imaging (MRI) facility became fully operational. A detailed description of this facility is given. One significant instrument addition this year was the 100 MHz, 40cm bore superconducting imaging spectrometer. This instrument gives researchers the capability to acquire high energy phosphate spectra. This will be used to investigate ATP, phosphocreatinine and inorganic phosphate changes in normal and atrophied muscle before, during and after exercise. An exercise device for use within the bore of the imaging magnet is under design/construction. The results of a study of T sub 1 and T sub 2 changes in atrophied muscle in animals and human subjects are given. The imaging and analysis of the lower leg of 15 research subjects before and after 5 weeks of complete bedrest was completed. A compilation of these results are attached.

Leblanc, A.↗

Nuclear Magnetic Resonance Used to Quantify the Effect of Pyrolysis Conditions on the Oxidative Stability of Silicon Oxycarbide Ceramics

This work was undertaken in support of the Low Cost Ceramic Composite Virtual Company, (LC^3), whose members include Northrop Grumman Corporation, AlliedSignal Inc., and Allison Advanced Development Company. LC^3 is a cost-shared effort funded by the Advanced Research Projects Agency (ARPA) and the LC^3 participants to develop a low-cost fabrication methodology for manufacturing ceramic matrix composite structural components. The program, which is being administered by the U.S. Air Force Wright Laboratory Materials Directorate, is focused on demonstrating a ceramic matrix composite turbine seal for a regional aircraft engine. This part is to be fabricated by resin transfer molding of a siloxane polymer into a fiber preform that will be transformed into a ceramic by pyrolytic conversion.

Source record↗

Ultra-low field nuclear magnetic resonance and magnetic resonance imaging to discriminate and identify materials

Method comprising obtaining an NMR measurement from a sample wherein an ultra-low field NMR system probes the sample and produces the NMR measurement and wherein a sampling temperature, prepolarizing field, and measurement field are known; detecting the NMR measurement by means of inductive coils; analyzing the NMR measurement to obtain at least one measurement feature wherein the measurement feature comprises T1, T2, T1.rho., or the frequency dependence thereof; and, searching for the at least one measurement feature within a database comprising NMR reference data for at least one material to determine if the sample comprises a material of interest.

36 MATERIALS SCIENCE↗

Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations

A continuous-flow (CF) magic angle sample spinning (CF-MAS) NMR rotor and probe are described for investigating reaction dynamics, stable intermediates/transition states, and mechanisms of catalytic reactions in situ. The rotor includes a sample chamber of a flow-through design with a large sample volume that delivers a flow of reactants through a catalyst bed contained within the sample cell allowing in-situ investigations of reactants and products. Flow through the sample chamber improves diffusion of reactants and products through the catalyst. The large volume of the sample chamber enhances sensitivity permitting in situ .sup.13C CF-MAS studies at natural abundance.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Speculation on a Solar Chronometer for Climate

Solar activity has been correlated to climatic fluctuations and has been postulated as a major factor in quasi-periodic global climatic change. However, correlations are not explanations of physical mechanisms and do not couple cause with effect. A mechanism for a chronometer for solar output variability is proposed based on relations between properties of thermonuclear fusion, nuclear magnetic moment, and nuclear magnetic resonance. A fundamental oscillation of a nucleus with a net nuclear magnetic moment (NMM) is the precession of its axis of rotation when subjected to a magnetic field. Nuclear magnetic resonance (NMR) is the preferred frequency of precession for a nucleus of a particular isotope when placed in a magnetic field of specific intensity. The NMM for those isotopes involved in the proton-proton (p-p) chain pathway for solar fusion varies from strong positive to strong negative. Individual fusion events, for hydrogen and helium isotopes which release varying amounts of energy, may be controlled by NMR frequencies. The pulses of energy from fusion events occurring at NMR frequencies in the solar interior may be transformed into pressure or gravity waves that emerge as gravity or acoustic waves at the surface. Dictated by spherical harmonics, certain wavelengths may be reinforced and reenter the solar interior to modulate the fusion process. Qualitative analysis of solar and climatic data support the interaction of the three basic components of the chronometer, magnetic activity, oscillation frequency, and solar energy output.

Perry, Charles A.↗