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At least 289 records · Page 16

SAGE Aerosol Measurements. Volume 2: 1 January - 31 December 1980

The stratospheric Aerosol and Gas Experiment (SAGE) satellite system, launched on February 18, 1979, provides profiles of aerosol extinction at wavelengths of 1.00 and 0.45 micron, ozone concentration, and nitrogen dioxide concentration. Data taken during sunset events in the form of zonal averages and seasonal averages of the aerosol extinction at 1.00 and 0.45 micron, ratios of the aerosol extinction to the molecular extinction at 1.00 micron, and ratios of the aerosol extinction at 0.45 micron to the aerosol extinction at 1.00 micron are presented. The averages for l980 are shown in tables and in profile and contour plots (as a function of altitude and latitude). In addition, temperature data provided by the National Oceanic and Atmospheric Administration (NOAA) for the time and location of each SAGE measurement are averaged and shown in a similar format.

Mccormick, M. P.↗

Seasonal and diurnal variation of the atmospheric NO2 at Syowa Station, Antarctica

Extensive attention has been directed to nitrogen dioxide (NO2) since its important role in the atmospheric chemistry relating to the stratospheric ozone (e.g., WMO, 1982) has been pointed out. However, the behavior of NO2 in the atmosphere has still not been fully confirmed, although ground-based, balloon and satellite measurements of NO2 have been reported by many scientists. Especially, only a few measurements made at high latitude in the Southern Hemisphere have been reported. The total atmospheric NO2 by ground-based visible absorption spectroscopy at Syowa Station (69 deg S, 39.6 deg E), Antarctica. The observation continued from March 1983, to January 1984. The principles of measurement, instrumentation and the method of data analysis are described in detail.

Shibasaki, K.↗

Using PCDS to study the influence of UV flux variation on the middle atmosphere

The value of the Pilot Climate Data System (PCDS) in examining the influences of short-period solar flux variations on the middle atmosphere was demonstrated. Several Nimbus satellite data sets proposed for the study exist in the PCDS. Planned for retrieval through the PCDS are ozone mixing ratios and cumulative ozone profiles available from the Backscatter Ultraviolet Spectrophotometer on Nimbus-4. Also to be accessed are Nimbus-7 data sets that will provide ozone and nitrogen dioxide mixing ratios, temperature profiles from the Limb Infrared Monitor of the Stratosphere, and ozone mixing ratio profiles from the Solar Backscatter Ultraviolet Spectrophotometer. Bypassing the time-consuming process of reading raw data tapes, the researchers plan to transfer the PCDS processed data to an IBM PC at Iowa State University. The IBM PC will serve as an intermediate vehicle for transferring the data to the NOAA CYBER 840 at Boulder, Colorado, where research will continue on both an eight-layer radiative-photochemical numerical model and on a nonlinear dynamical model. in this research are the FGGE and ERB data sets. These relevant data sets also reside in the PCDS. Problems associated with remote access to the PCDS were discussed in regard to all the PCDS data sets.

Heilman, W.↗

The microwave and far-infrared spectra of the O-(18)H radical

Far-infrared laser magnetic resonance (LMR) spectroscopy was used to calculate the frequencies, wavelengths, and line strengths for transitions of O-(18)H molecules at microwave and far-infrared frequencies. In this experiment, a molecular transition frequency is tuned into coincidence with that of a fixed frequency laser by the application of a variable magnetic field. The O-(18)H radicals, detected in natural abundance (0.20 percent), were produced by the reaction of hydrogen atoms with nitrogen dioxide. These data together with microwave frequencies ascertained by Gottlieb, Redford, and Smith (1974) were used to determine the parameters of an effective Hamiltonian. Rotational levels up to J = 5.5 were involved. Results are indicated schematically and the low-lying energy levels of O-(18)H are shown. It is concluded that the frequencies of transitions between levels studied directly in the LMR experiment are reliable.

Comben, E. R.↗

SAGE aerosol measurements. Volume 3: January 1, 1981 to November 18, 1981

The Stratospheric Aerosol and Gas Experiment (SAGE) satellite system, launched February 18, 1979, obtained profiles of aerosol extinction at 1.00 micron and 0.45 micron ozone concentration, and nitrogen dioxide concentration. Data taken during sunset events are presented in the form of zonal and seasonal averages of aerosol extinction of 1.00 micron and 0.45 micron, ratios of aerosol extinction to molecular extinction at 1.00 micron and ratios of aerosol extinction at 0.45 micron to aerosol extinction at 1.00 micron. Averages for 1981 are shown in tables, and in profile and contour plots (as a function of altitude and latitude). In addition, temperature data provided by NOAA for the time and location of each SAGE measurement are averaged and shown in a similar format. The stratospheric aerosol distribution for 1981 shows effects of volcanically injected material from eruptions of Ulawun, Alaid, and Pagan. Peak values of aerosol extinction at 0.45 micron and 1.00 micron were 2 to 4 times higher than typical peak values observed during near background conditions. Stratospheric aerosol optical depth values at 1.00 microns increased by a factor of about 2 from near background levels in regions of volcanic activity. During the year, these values ranged from between 0.001 and 0.006. The largest were near the location of a recent eruption. The distribution of the ratio of aerosol to molecular extinction at 1.00 microns also showed that maximum values are found in the vicinity of an eruption. These maximums varied in altitude, but remained below a height of about 25 km. No attempt has been made to give detailed explanations or interpretations of these data. The intent is to provide, in a ready-to-use visual format, representative zonal and seasonal averages of aerosol extinction data for the third calendar year of the SAGE data set to facilitate atmospheric and climatic studies.

Mccormick, M. Patrick↗

The Stratospheric Aerosol and Gas Experiment II (SAGE II) design and in-orbit performance

The design and in-orbit performance data are presented for the Stratospheric Aerosol and Gas Experiment II (SAGE II) instrument which was launched by Shuttle on the Earth Radiation Budget Satellite. SAGE II is a sun photometer that measures the extinction of solar radiation caused by the earth's atmosphere in seven spectral channels ranging in center wavelength from 0.385 to 1.02 micrometers. These measurements, which occur twice each orbit during satellite sunrise and sunset, are inverted to yield vertical distributions of stratospheric aerosols, ozone, water vapor, and nitrogen dioxide. The SAGE II instrument consists of a Cassegrain telescope with a two axis gimbal mounting, a grating spectrometer, and a 12 bit data system. The instrument tracks the solar centroid in the azimuth plane and vertically scans the instrument's instantaneous field of view across the sun for tangent altitudes ranging from the earth's horizon to 150 km. SAGE II is a third generation instrument following the highly successful Stratospheric Aerosol Measurement II (SAM II) and SAGE I programs.

Mauldin, L. E., III↗

The effect of temperature on Shuttle glow

The glow on ram surfaces of the Space Shuttle has been reported from a series of photographic observations made during several orbiter missions. These measurements have shown that the spectrum of the glow is a continuum, has a spectral peak at 680 nm, and the brightness decreases with altitude. The spectrum has been tentatively identified as the nitrogen dioxide continuum and follows the interaction of adsorbed nitric oxide with ramming atmospheric oxygen. In this paper the variation of the glow brightness among several different Shuttle flights is reexamined and it is shown that a major contributing factor to glow brightness is probably the temperature of the rammed surface. The derived temperature dependence is also consistent with the Atmospheric Explorer-C satellite 'red' glow intensity data.

Swenson, G. R.↗

Radiative heating and cooling rates in the middle atmosphere

One of the limitations to the accurate calculation of radiative heating and cooling rates in the stratosphere and mesosphere has been the lack of accurate data on the atmospheric temperature and composition. Data from the LIMS experiment on Nimbus-7 has been extended to the South Pole with the aid of other observations. The data have been used as input to codes developed by Ramanathan and Dickinson to calculate the individual components and the net radiative heating rates from 100-0.1 mb. Solar heating due to ozone, nitrogen dioxide, carbon dioxide, water vapor and oxygen is shown to be nearly balanced by cooling in the thermal infrared spectral region due to carbon dioxide, ozone and water vapor. In the lower stratosphere, infrared transfer by ozone leads to heating that is sensitive to the distribution of tropospheric ozone, clouds and water vapor. The heating and cooling rates are adjusted slightly in order to satisfy the global mass balance. The results are in qualitative agreement with earlier calculations, but show additional detail. There is as strong temporal and vertical variation of cooling in the tropics. Radiative relaxation times are as short as 7 days or less at the stratopause.

Gille, John C.↗

NO2 heterodyne frequency measurements with a tunable diode laser, a CO laser transfer oscillator and CO2 laser standards

Heterodyne frequency measurements have been made on selected groups of nitrogen dioxide rovibronic transitions between 1580.8 and 1650.7/cm. The groups are separated by 7 to 10/cm, and the intent is to provide a limited (and interim) calibration table for the region. In addition to a table of measured frequencies in the region, figures of spectra in the vicinity of the measured lines are included to provide a map for identifying the transitions measured.

Zink, L. R.↗

Design and performance of the halogen occultation experiment (HALOE) remote sensor

HALOE is an optical remote sensor that measures extinction of solar radiation caused by the earth's atmosphere in eight channels, ranging in wavelength from 2.5 to 10.1 microns. These measurements, which occur twice each satellite orbit during solar occultation, are inverted to yield vertical distributions of middle atmosphere ozone (O3), water vapor, nitrogen dioxide, nitric oxide, hydrogen fluoride, hydrogen chloride, and methane. A channel located in the 2.7 region is used to infer the tangent point pressure by measuring carbon dioxide absorption. The HALOE instrument consists of a two-axis gimbal system, telescope, spectral discrimination optics and a 12-bit data system. The gimbal system tracks the solar radiometric centroid in the azimuthal plane and tracks the solar limb in the elevation plane, placing the instrument's instantaneous field-of-view 4 arcmin down from the solar top edge. The instrument gathers data for tangent altitudes ranging from 150 km to the earth's horizon. Prior to an orbital sunset and after an orbital sunrise, HALOE automatically performs calibration sequences to enhance data interpretation. The instrument is presently being tested at the NASA Langley Research Center in preparation for launch on the Upper Atmosphere Research Satellite near the end of this decade. This paper describes the instrumenmt design, operation, and functional performance.

Baker, R. L.↗

SAGE II - An overview

The Stratospheric Aerosol and Gas Experiment II (SAGE II) aboard the Earth Radiation Budget Satellite was launched from Shuttle in October 1984. SAGE II is a seven-channel sun-photometer measuring stratospheric aerosols, ozone, water vapor, and nitrogen dioxide during each spacecraft sunrise and sunset. In addition to stratospheric information, mid-tropospheric and higher water vapor, ozone, and aerosol data are being produced in cloud-free regions, and cloud data everywhere else. Aerosol information is being produced at three wavelengths and, together with water vapor data, is providing a global microphysical description of the aerosol.

Mccormick, M. P.↗

Antarctic stratospheric chemistry of chlorine nitrate, hydrogen chloride, and ice - Release of active chlorine

The reaction rate between atmospheric hydrogen chloride (HCl) and chlorine nitrate (ClONO2) is greatly enhanced in the presence of ice particles; HCl dissolves readily into ice, and the collisional reaction probability for ClONO2 on the surface of ice with HCl in the mole fraction range from about 0.003 to 0.010 is in the range from about 0.05 to 0.1 for temperatures near 200 K. Chlorine is released into the gas phase on a time scale of at most a few milliseconds, whereas nitric acid (HNO3), the other product, remains in the condensed phase. This reaction could play an important role in explaining the observed depletion of ozone over Antarctica; it releases photolytically active chlorine from its most abundant reservoir species, and it promotes the formation of HNO3 and thus removes nitrogen dioxide from the gas phase. Hence it establishes the necessary conditions for the efficient catalytic destruction of ozone by halogenated free radicals.

Molina, Mario J.↗

Antarctic ozone depletion chemistry - Reactions of N2O5 with H2O and HCl on ice surfaces

In a study concerning Antarctic ozone depletion, reactions of dinitrogen pentoxide with water and hydrochloric acid were studied on ice surfaces in a Knudsen cell flow reactor. The N2O5 reacted on ice at 185 K to form condensed-phase nitric acid (HNO3). This reaction may provide a sink for odd nitrogen, NO(x), during the polar winter, a requirement in nearly all models of Antarctic ozone depletion. The reaction of N2O5 on HCl-ice surfaces at 185 K produced gaseous nitryl chloride (ClNO2) and condensed-phase HNO3 and proceeded until all of the HCl within the ice was depleted. The ClNO2 which did not react or condense on ice at 185 K, can be readily photolyzed in the Antarctic spring to form atomic chlorine for catalytic ozone destruction cycles. The other photolysis product, gaseous nitrogen dioxide may be important in the partitioning of NO(x) between gaseous and condensed phases in the Antarctic winter.

Tolbert, Margaret A.↗

CANOZE measurements of the Arctic ozone hole

In CANOZE 1 (Canadian Ozone Experiment), a series of 20 ozone profile measurements were made in April, 1986 from Alert at 82.5 N. CANOZE is the Canadian program for study of the Arctic winter ozone layer. In CANOZE 2, ozone profile measurements were made at Saskatoon, Edmonton, Churchill and Resolute during February and March, 1987 with ECC ozonesondes. Ground based measurements of column ozone, nitrogen dioxide and hydrochloric acid were conducted at Saskatoon. Two STRATOPROBE balloon flights were conducted on February 26 and March 19, 1987. Two aerosol flights were conducted by the University of Wyoming. The overall results of this study will be reported and compared with the NOZE findings. The results from CANOZE 3 in 1988, are also discussed. In 1988, as part of CANOZE 3, STRATOPROBE balloon flights were conducted from Saskatchewan on January 27 and February 13. A new lightweight infrared instrument was developed and test flown. A science flight was successfully conducted from Alert (82.5 N) on March 9, 1988 when the vortex was close to Alert; a good measurement of the profile of nitric acid was obtained. Overall, the Arctic spring ozone layer exhibits many of the features of the Antarctic ozone phenomenon, although there is obviously not a hole present every year. The Arctic ozone field in March, 1986 demonstrated many similarities to the Antarctic ozone hole. The TOMS imagery showed a crater structure in the ozone field similar to the Antarctic crater in October. Depleted layers of ozone were found in the profiles around 15 km, very similar to those reported from McMurdo. Enhanced levels of nitric acid were measured in air which had earlier been in the vortex. The TOMS imagery for March 1987 did not show an ozone crater, but will be examined for an ozone crater in February and March, 1988, the target date for the CANOZE 3 project.

Evans, W. F. J.↗

Performance characterization and transient investigation of multipropellant resistojets

The multipropellant resistojet thruster design initially was characterized for performance in a vacuum tank using argon, carbon dioxide, nitrogen, and hydrogen, with gas inlet pressures ranging from 13.7 to 310 kPa (2 to 45 psia) over a heat exchanger temperature range of ambient to 1200 C (2200 F). Specific impulse, the measure of performance, had values ranging from 120 to 600 seconds for argon and hydrogen respectively, with a constant heat exchanger temperature of 1200 C (2200 F). When operated under ambient conditions typical specific impulse values obtained for argon and hydrogen ranged from 55 to 290 seconds, respectively. Performance measured with several mixtures of argon and nitrogen showed no significant deviation from predictions obtained by directly weighting the argon and nitrogen individual performance results. Another aspect of the program investigating transient behavior, showed responses depended heavily on the start-up scenario used. Steady state heater temperatures were achieved in 20 to 75 minutes for argon, and in 10 to 90 minutes for hydrogen. Steady state specific impulses were achieved in 25 to 60, and 20 to 60 minutes respectively.

Braunscheidel, Edward P.↗

Observations of atmospheric water vapor with the SAGE 2 instrument

The Stratospheric Aerosol and Gas Experiment 2 (SAGE 2) is discussed. The SAGE 2 instrument was a multichannel spectrometer that inferred the vertical distribution of water vapor, aerosols, nitrogen dioxide, and ozone by measuring the extinction of solar radiation at spacecraft sunrise/sunset. At altitudes above 20 km, the SAGE 2 and LIMS (Limb Infrared Monitor of the Stratosphere) data are in close agreement. The discrepancies below this altitude may be attributed to differences in the instruments' field of view and time of data acquisition.

Larsen, Jack C.↗

Performance characterization and transient investigation of multipropellant resistojets

The multipropellant resistojet thruster design initially was characterized for performance in a vacuum tank using argon, carbon dioxide, nitrogen, and hydrogen, with gas inlet pressures ranging from 13.7 to 310 kPa (2 to 45 psia) over a heat exchanger temperature range of ambient to 1200 C (2200 F). Specific impulse, the measure of performance, had values ranging from 120 to 600 seconds for argon and hydrogen respectively, with a constant heat exchanger temperature of 1200 C (2200 F). When operated under ambient conditions typical specific impulse values obtained for argon and hydrogen ranged from 55 to 290 seconds, respectively. Performance measured with several mixtures of argon and nitrogen showed no significant deviation from predictions obtained by directly weighting the argon and nitrogen individual performance results. Another aspect of the program investigating transient behavior, showed responses depended heavily on the start-up scenario used. Steady state heater temperatures were achieved in 20 to 75 minutes for argon, and in 10 to 90 minutes for hydrogen. Steady state specific impulses were achieved in 25 to 60, and 20 to 60 minutes, respectively.

Braunscheidel, Edward P.↗

SAGE 3: A visible wavelength limb sounder

A brief description is presented for the SAGE 3 (Stratospheric Aerosol and Gas Experiment 3) instrument that has been selected to fly onboard the National Polar Platform 1 (NPOP 1) for the Earth Observational System (Eos) in 1996. The SAGE 3 instrument will perform earth limb sounding with the solar occultation technique measuring the ultraviolet (UV), the visible, and the near infrared (IR) wavelength solar radiation. The instrument will produce atmospheric data for the vertical distribution of aerosol, ozone, nitrogen dioxide, water vapor, and oxygen. The details of the instrument design, data flow, and processing requirements are discussed.

Chu, W. P.↗