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At least 289 records · Page 16

Influence of Benzene on the Optical Properties of Titan Haze Laboratory Analogs in the Mid-Visible

The Cassini Ion and Neutral Mass Spectrometer (Waite, Jr., et al., 2007) and the Composite Infrared Spectrometer (Coustenis, A., et al., 2007) have detected benzene in the upper atmosphere and stratosphere of Titan. Photochemical reactions involving benzene in Titan's atmosphere may influence polycyclic aromatic hydrocarbon formation, aerosol formation, and the radiative balance of Titan's atmosphere. We measure the effect of benzene on the optical properties of Titan analog particles in the laboratory. Using cavity ring-down aerosol extinction spectroscopy, we determine the real and imaginary refractive index at 532 nm of particles formed by benzene photolysis and Titan analog particles formed with ppm-levels of benzene. These studies are compared to the previous study by Hasenkopf, et a1. (2010) of Titan analog particles formed by methane photolysis.

Yoon, Y. Heidi↗

Comparison between infrared Martian disk spectra and optical properties of terrestrial analogs

Medium spectral resolution (20 kaysers) infrared measurements of the Martian disk made between 2900 and 5600 kaysers from the NASA Lear Airborne Observatory have been successfully compared with predictions derived from a model of the Martian soil and atmosphere. Modeling of the Martian atmosphere permitted the extraction of Martian soil reflectance in the CO2 bands centered at 3657 kaysers. Three Martian soil analogs previously considered acceptable - limonite, montmorillonite, and basalt - were analyzed to determine the optical complex indices of refraction in the same range as the airborne observations, for mathematical modeling. A characteristic surface particle size approximately 1 to 3 microns diameter is indicated. It is concluded that the Martian soil surface near-infrared optical properties are consistent with a soil composition similar to montmorillonite or limonite, mixed with a basalt.

Egan, W. G.↗

Optical properties of irregular interstellar grains

In order to study the interaction of light with interstellar grains, the authors represent an irregular particle by a network of interacting dipoles whose polarizability is determined in a first approach by the Clausius-Mossoti relationship. Typically, 10,000 dipoles are considered. In the case of spherical particles, the results from Mie theory are fully recovered. The main interest of this method is to study with good accuracy the implications of surface roughness and/or inhomogeneities on optical properties in the infrared spectral range, particularly of the silicate emission features.

Perrin, J. M.↗

The Atlantic Meridional Transect: Spatially Extensive Calibration and Validation of Optical Properties and Remotely Sensed Measurements of Ocean Colour

Twice a year, the Royal Research Ship (RRS) James Clark Ross (JCR) steams a meridional transect of the atlantic Ocean between Grimsly (UK) and Stanley (Falkland Islands) with a port call in Montevideo (Uruguay), as part of the annual research activities of the British Antarctic Survey (BAS). In September, the JCR sails from the UK, and the following April it makes the return trip. The ship is operated by the BAS for the Natural Environment Research Council (NERC). The Atlantic Meridional Transect (AMT) Program exploits the passage of the JCR from approximately 50 deg. N to 50 deg. S with a primary objective to investigate physical and biological processes, as well as to measure the mesi-to-basin-scale bio-optical properties of the atlantic Ocean. The calibration and validation of remotely sensed observations of ocean colour is an inherent objective of these studies: first, by relating in situ measurements of water leaving radiance to satellite measurement, and second, by measuring the bio-optically active constituents of the water.

Aiken, James↗

Planning for Validation of Optical Property Degradation Predictions Using On-Orbit Telemetry

NASA’s Gateway Power and Propulsion Element (PPE) will employ high power Xenon Hall thrusters to transit from Earth orbit to a lunar near-rectilinear halo orbit (NRHO). Due to the extended duration of this transit phase and a high thruster duty cycle, there is expected to be significant material erosion caused by the ion plume and subsequent redeposition onto the main spacecraft radiators. While plume modeling and tests of redeposition have attempted to quantify the resulting impact to radiator optical properties, significant uncertainties remain. The flight of PPE presents an opportunity to validate some of the assumptions in this analytical chain, but there will be no specialized hardware that can directly characterize the property changes. However, the planned mission includes periods with significant solar flux to the radiators both early and late in the transit inducing differential heat loads on the vehicle. This presentation will explore options for analyzing possible impacts of various levels of redeposition and whether the severity can be accurately characterized via existing planned telemetry during a nominal mission.

PPE↗

Raman scattering and in-water ocean optical properties

Inelastic (transpectral) scattering may contribute significantly to the in-water light field. Major mechanisms for inelastic scattering include Raman scattering, which is important in clear ocean waters, and fluorescence from a variety of sources, which may be important in more turbid waters. The Raman cross section for liquid water is found to be 8.2 x 10 to the -30th sq cm/sr molecule, which is in agreement with the lower range of published values. Inelastic scattering has important ramifications for several aspects of marine biooptics, including the determination of in-water spectral absorption, the estimation of clear-water ocean optical properties, and possibly various aspects of algal photobiology.

Marshall, Bruce R.↗

The Measurement of Aerosol Optical Properties using Continuous Wave Cavity Ring-Down Techniques

Large uncertainties in the effects that aerosols have on climate require improved in situ measurements of extinction coefficient and single-scattering albedo. This paper describes the use of continuous wave cavity ring-down (CW-CRD) technology to address this problem. The innovations in this instrument are the use of CW-CRD to measure aerosol extinction coefficient, the simultaneous measurement of scattering coefficient, and small size suitable for a wide range of aircraft applications. Our prototype instrument measures extinction and scattering coefficient at 690 nm and extinction coefficient at 1550 nm. The instrument itself is small (60 x 48 x 15 cm) and relatively insensitive to vibrations. The prototype instrument has been tested in our lab and used in the field. While improvements in performance are needed, the prototype has been shown to make accurate and sensitive measurements of extinction and scattering coefficients. Combining these two parameters, one can obtain the single-scattering albedo and absorption coefficient, both important aerosol properties. The use of two wavelengths also allows us to obtain a quantitative idea of the size of the aerosol through the Angstrom exponent. Minimum sensitivity of the prototype instrument is 1.5 x 10(exp -6)/m (1.5 M/m). Validation of the measurement of extinction coefficient has been accomplished by comparing the measurement of calibration spheres with Mie calculations. This instrument and its successors have potential to help reduce uncertainty currently associated with aerosol optical properties and their spatial and temporal variation. Possible applications include studies of visibility, climate forcing by aerosol, and the validation of aerosol retrieval schemes from satellite data.

Strawa, Anthony W.↗

The Measurement of Aerosol Optical Properties Using Continuous Wave Cavity Ring-Down Techniques

Large uncertainties in the effects that aerosols have on climate require improved in-situ measurements of extinction coefficient and single-scattering albedo. This abstract describes the use of continuous wave cavity ring-down (CW-CRD) technology to address this problem. The innovations in this instrument are the use of CW-CRD to measure aerosol extinction coefficient, the simultaneous measurement of scattering coefficient, and small size suitable for a wide range of aircraft applications. Our prototype instrument measures extinction and scattering coefficient at 690 nm and extinction coefficient at 1550 nm. The instrument itself is small (60 x 48 x 15 cm) and relatively insensitive to vibrations. The prototype instrument has been tested in our lab and used in the field. While improvements in performance are needed, the prototype has been shown to make accurate and sensitive measurements of extinction and scattering coefficients. Combining these two parameters, one can obtain the single-scattering albedo and absorption coefficient, both important aerosol properties. The use of two wavelengths also allows us to obtain a quantitative idea of the size of the aerosol through the Angstrom exponent. Minimum sensitivity of the prototype instrument is 1.5 x 10(exp -6)/m (1.5/Mm). Validation of the measurement of extinction coefficient has been accomplished by comparing the measurement of calibration spheres with Mie calculations. This instrument and its successors have potential to help reduce uncertainty currently associated with aerosol optical properties and their spatial and temporal variation. Possible applications include studies of visibility, climate forcing by aerosol, and the validation of aerosol retrieval schemes from satellite data.

Strawa, A. W.↗

Optical properties of the crustal aerosol - Relation to chemical and physical characteristics

Crustal aerosol absorption, expressed as a wavelength dependent imaginary index of refraction, n(im), was measured at both visible and infrared wavelengths. Measurements at visible wavelengths show values of n(im) that range from 0.02 at 300 nm to 0.004 to 700 nm. Infrared measurements show an absorption that is dominated by a silicate absorption with a maximum value of n(im) of about 1 near 10 microns. Comparisons of the present measurements with other reported measurements of well-documented crustal aerosols show a great deal of similarity among the measured values. It is shown that these measured optical properties, and the similarities and differences in the measured values, can be understood in terms of mineralogical characteristics of the aerosol and fractionation processes that occur in the generation and transport of these aerosols.

Patterson, E. M.↗

The formation of compact groups of galaxies. I: Optical properties

The small crossing time of compact groups of galaxies (t(sub cr)H(sub 0) approximately less than 0.02) makes it hard to understand why they are observable at all. Our dissipationless N-body simulations show that within a single rich collapsing group compact groups of galaxies continually form. The mean lifetime of a particular compact configuration if approximately 1 Gyr. On this time scale, members may merge and/or other galaxies in the loose group may join the compact configuration. In other words, compact configurations are continually replaced by new systems. The frequency of this process explains the observability of compact groups. Our model produces compact configurations (compact groups (CG's) with optical properties remarkably similar to Hickson's (1982) compact groups (HCG's): (1) CG's have a frequency distribution of members similar to that of HCG's; (2) CG's are approximately equals 10 times as dense as loose groups; (3) CG's have dynamical properties remarkably similar to those of HCG's; (4) most of the galaxy members of CG's are not merger remnants. The crucial aspect of the model is the relationship between CG's and the surrounding rich loose group. Our model predicts the frequency of occurrence of CG's. A preliminary analysis of 18 rich loose groups is consistent with the model prediction. We suggest further observational tests of the model.

Diaferio, Antonaldo↗

Bio-Optical Properties of the Arabian Sea as Determined by In-Situ and SeaWifs Data

The overall objective of this work was to characterize optical and fluorescence properties in the euphotic zone during two British Ocean Flux Study (BOFS) Arabian Sea cruises. This was later expanded in 1995 to include three U.S. Joint Global Ocean Flux Study (JGOFS) Arabian Sea Cruises. The region was to be divided into one or more "bio-optical provinces", within each of which a single set of regression models was to be developed to relate the vertical distribution of irradiance attenuation and normalized fluorescence (SF and NF) to remote sensing reflectance and diffuse attenuation coefficient [K(490)]. The working hypothesis was that over relatively large spatial and temporal scales, the vertical profiles of bio-optical properties were predictable.

Trees, Charles C.↗

Effect of Ram and Zenith Exposure on the Optical Properties of Polymers in Space

The temperature of spacecraft is influenced by the solar absorptance and thermal emittance of the external spacecraft materials. Optical and thermal properties can degrade over time in the harsh low Earth orbital (LEO) space environment where spacecraft external materials are exposed to various forms of radiation, thermal cycling, and atomic oxygen. Therefore, it is important to test the durability of spacecraft materials in the space environment. One objective of the Polymers and Zenith Polymers Experiments was to determine the effect of LEO space exposure on the optical properties of various spacecraft polymers. These experiments were flown as part of the Materials International Space Station Experiment 7 (MISSE 7) mission on the exterior of the International Space Station (ISS) for 1.5 years. Samples were flown in ram, wake or zenith directions, receiving varying amounts of atomic oxygen and solar radiation exposure. Total and diffuse reflectance and transmittance of flight and corresponding control samples were obtained post-flight using a Cary 5000 UV-Vis-NIR Spectrophotometer. Integrated air mass zero solar absorptance (s) of the flight and control samples were computed from the total transmittance and reflectance, and compared. The optical data are compared with similar polymers exposed to space for four years as part of MISSE 2, and with atomic oxygen erosion data, to help understand the degradation of these polymers in the space environment. Results show that prolonged space exposure increases the solar absorptance of some materials. Knowing which polymers remain stable will benefit future spacecraft design.

Yuanchun Li↗

Synthesis, Crystal Structure, and Optical Properties of the Barium meta -Pertechnetate Ba[TcO 4 ] 2

High-quality single crystals of the colorless title compound Ba[ 99 TcO 4 ] 2 were prepared from radioactive, isotope-pure 99 TcO 2 by oxidation with H 2 O 2 in an aqueous ammonia solution and subsequent cation metathesis using an ion-exchange column. Single-crystal X-ray diffraction revealed Ba[TcO 4 ] 2 to crystallize isotopically to Ba[MnO 4 ] 2 in the orthorhombic space group Fddd with the lattice parameters a = 747.34(5) pm, b = 1244.08(7) pm, and c = 1511.23(9) pm for Z = 8. Its crystal structure features [BaO 12 ] 22- icosahedra surrounded by ten [TcO 4 ] - tetrahedra connected via two edges and eight corners. The optical properties of Ba[TcO 4 ] 2 investigated by UV-vis spectroscopy show the broad O 2- → Tc 7+ ligand-to-metal charge transfer (2p → 4d) process within these discrete [TcO 4 ]- anions at an absorption maximum of around 350 nm.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Comparison of Cloud Microphysical and Optical Properties during TOGA-COARE

The impact of cirrus clouds on climate is an issue of research interest currently. Whether cirrus clouds heat or cool the Earth-atmosphere system depends on the cloud shortwave albedo and infrared reflectance and absorptance. These in turn are determined by the size distribution, phase, and composition of particles in the clouds. The TOGA-COARE campaign presented an excellent opportunity to study cirrus clouds and their influence on climate. In this campaign, a microphysics instrument package was flown aboard the DC-8 aircraft at medium altitudes in cirrus clouds. This package included a 2D Greyscale Cloud Particle Probe, a Forward Scattering Spectrometer Aerosol Probe, and an ice crystal replicator. At the same time the ER-2 equipped with a radiation measurement system flew coordinated flight tracks above the DC-8 at very high altitude. The radiation measurement made were short and long wave fluxes, as well as narrowband fluxes, both upwelling and downwelling. In addition LIDAR data is available. The existence of these data sets allows for a the comparison of radiation measurement with microphysical measurements. For example, the optical depth and effective radius retrieved from the ER-2 radiation measurements can be compared to the microphysical data. Conversely, the optical properties and fluxes produced by the clouds can be calculated from the microphysical measurements and compared to those measured aboard the ER-2. The assumptions required to make these comparisons are discussed. Typical microphysical results show a prevalence of micron-sized particles, in addition to the cloud particles that exceed 100 mm. The large number of small particles or "haze" cause the effective cloud radii to shift to smaller sizes, leading to changes in optical parameters.

Strawa, A. W.↗

Synthesis, vapor growth, polymerization, and characterization of thin films of novel diacetylene derivatives of pyrrole. The use of computer modeling to predict chemical and optical properties of these diacetylenes and poly(diacetylenes)

In the present work two diacetylene derivatives of pyrrole which are predicted by semiempirical AM1 calculations to have very different properties, are synthesized; the polymerizability of these diacetylenes in the solid state is determined, and the results are compared to the computer predictions. Diacetylene 1 is novel in that the monomer is a liquid at room temperature; this may allow for the possibility of polymerization in the liquid state as well as the solid state. Thin poly(diacetylene) films are obtained from compound 1 by growing films of the monomer using vapor deposition and polymerizing with UV light; these films are then characterized. Interestingly, while the poly(diacetylene) from 1 does not possess good nonlinear optical properties, the monomer exhibits very good third-order effects (phase conjugation) in solution. Dilute acetone solutions of the monomer 1 give intensity-dependent refractive indices on the order of 10 exp -6 esu; these are 10 exp 6 times better than for CS2.

Paley, M. S.↗

The Surface Chemical Composition of Lunar Samples and Its Significance for Optical Properties

The surface iron, titanium, calcium, and silicon concentration in numerous lunar soil and rock samples was determined by Auger electron spectroscopy. All soil samples show a large increase in the iron to oxygen ratio compared with samples of pulverized rock or with results of the bulk chemical analysis. A solar wind simulation experiment using 2 keV energy alpha -particles showed that an ion dose corresponding to approximately 30,000 years of solar wind increased the iron concentration on the surface of the pulverized Apollo 14 rock sample 14310 to the concentration measured in the Apollo 14 soil sample 14163, and the albedo of the pulverized rock decreased from 0.36 to 0.07. The low albedo of the lunar soil is related to the iron + titanium concentration on its surface. A solar wind sputter reduction mechanism is discussed as a possible cause for both the surface chemical and optical properties of the soil.

Gold, T.↗

Optical Properties of Nanosatellite Hardware

Over the last decade, a number of very small satellites have been launched into space. These have been called nanosatellites (generally of a weight between 1 and 10 kg) or picosatellites (weight <1 kg). This also includes CubeSats, which are based on 10-cm cube units. With the addition of the Japanese Experiment Module (JEM) Small Satellite Orbital Deployer (J-SSOD) to the International Space Station (ISS), CubeSats are easily cycled through the JEM airlock and deployed into space (fig. 1). The number of CubeSats launched since 2003 was approaching 100 at the time of publication, and the authors expect this trend in research to continue, particularly for high school and college flight experiments. Because these spacecraft are so small, there is usually no allowance for shielding or active heating or cooling of the avionics and other hardware. Parts that are usually ignored in the thermal analysis of larger spacecraft may contribute significantly to the heat load of a tiny satellite. In addition, many small satellites have commercial-off-the-shelf (COTS) components. To reduce costs, many providers of COTS components do not include the optical and physical parameters necessary for accurate thermal analysis. Marshall Space Flight Center participated in the development and analysis of the Space Missile Defense Command-Operational Nanosatellite Effect (SMDC-ONE) and the Edison Demonstration of Smallsat Networks (EDSN) nanosatellites. These optical property measurements are documented here in hopes that they may benefit future nanosatellite and picosatellite programs and aid thermal analysis to ensure project goals are met, with the understanding that material properties may vary by vendor, batch, manufacturing process, and preflight handling. Where possible, complementary data are provided from ground simulations of the space environment and flight experiments, such as the Materials on International Space Station Experiment (MISSE) series. NASA gives no recommendation, endorsement, or preference, either expressed or implied, concerning materials and vendors used. Solar absorptance was calculated from spectral reflectance measurements made from 250 to 2,800 nm with an AZ Technology Laboratory Portable Spectroreflectometer (LPSR) model 300. ASTM E-903 was the test method used under normal laboratory conditions, and ASTM E-490 was the solar spectral irradiance data used to calculate solar absorptance. Most of the samples were flat, but stray light was minimized as much as possible with either a blackbody or black cloth as sample background. The LPSR has repeatability of approximately +/-1%, where solar absorptance is given as range, that is, from actual measurements taken across the sample. Infrared emittance measurements were made with an AZ Technology TEMP 2000A infrared reflectometer. This instrument measures the total hemispheric reflectance averaged over 3-35 micrometer wavelengths. ASTM E-408 was the test method used under normal laboratory conditions. 3 Stray light was minimized as much as possible. The TEMP 2000A has repeatability of approximately +/-0.5%, where infrared emittance is given as a range, that is, from actual measurements taken across the sample.

Finckenor, M. M.↗