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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

MOD: An Organic Detector for the Future Exploration of Mars

The Mars Organic Detector (MOD) is designed to assess whether organic compounds, possibly associated with life, are present in Martian rock and soil samples. MOD has a detection limit that is at least two orders of magnitude more sensitive than the Viking GCMS. MOD is focused on detecting amino acids, amines and PAH (polycyclic aromatic hydrocarbons). Amino acids play an essential role in biochemistry on Earth and PAH are widespread throughout the universe and can provide an indication of the delivery of meteoritic organic material to Mars. The advantage of MOD is the absence of wet chemistry and its simple and robust design. The sample will be extracted from the mineral matrix (0.1 - 1 g of rock-powder) using sublimation and analyzed with a fluorescence detector. The isolation method is based on the fact that amino acids and PAH are volatile at temperatures greater than 150C. The fluorescence detection scheme is based on UV excitation with LED's, optical filters, PrN diode photon detector and a sample calibration reservoir. Fluorescamine is used as a fluorescing reagent for amino acids and amines, while PAH are naturally fluorescent. There is no sample preparation required and the turnaround time for a single analysis is on the order of minutes.

Kminek, G.↗
NASA NTRS1999

Engineering of Novel Biocolloid Suspensions

Colloidal suspensions are materials with a variety of uses from cleaners and lubricants to food, cosmetics, and coatings. In addition, they can be used as a tool for testing the fundamental tenets of statistical physics. Colloidal suspensions can be synthesized from a wide variety of materials, and in the form of monodisperse particles, which can self-assemble into highly ordered colloidal crystal structures. As such they can also be used as templates for the construction of highly ordered materials. Materials design of colloids has, to date, relied on entropic self-assembly, where crystals form as result of lower free energy due to a transition to order. Here, our goal is to develop a completely new method for materials fabrication using colloidal precursors, in which the self-assembly of the ordered colloidal structures is driven by a highly controllable, attractive interaction. This will greatly increase the range of potential structures that can be fabricated with colloidal particles. In this work, we demonstrate that colloidal suspensions can be crosslinked through highly specific biological crosslinking reactions. In particular, the molecules we use are protein-carbohydrate interactions derived from the immune system. This different driving force for self-assembly will yield different and novel suspensions structures. Because the biological interactions are heterotypic (A binding to B), this chemical system can be used to make binary alloys in which the two colloid subpopulations vary in some property - size, density, volume fraction, magnetic susceptibility, etc. An additional feature of these molecules which is unique - even within the realm of biological recognition - is that the molecules bind reversibly on reasonable time-scales, which will enable the suspension to sample different configurations, and allow us to manipulate and measure the size of the suspension dynamically. Because of the wide variety of structures that can be made from these novel colloids, and because the suspension structure can be altered dynamically, we believe this biocolloid system will yield a novel set of materials with many technological applications, including sensors (both biological and non-biological), optical filters and separation media.

Hammer, D. A.↗
NASA NTRS2000

Flame Shapes of Nonbuoyant Laminar Jet Diffusion Flames

The shapes (flame-sheet and luminous-flame boundaries) of steady nonbuoyant round hydrocarbon-fueled laminar-jet diffusion flames in still and coflowing air were studied both experimentally and theoretically. Flame-sheet shapes were measured from photographs using a CH optical filter to distinguish flame-sheet boundaries in the presence of blue C02 and OH emissions and yellow continuum radiation from soot. Present experimental conditions included acetylene-, methane-, propane-, and ethylene-fueled flames having initial reactant temperatures of 300 K, ambient pressures of 4-50 kPa, jet exit Reynolds number of 3-54, initial air/fuel velocity ratios of 0-9 and luminous flame lengths of 5-55 mm; earlier measurements for propylene- and 1,3-butadiene-fueled flames for similar conditions were considered as well. Nonbuoyant flames in still air were observed at micro-gravity conditions; essentially nonbuoyant flames in coflowing air were observed at small pressures to control effects of buoyancy. Predictions of luminous flame boundaries from soot luminosity were limited to laminar smoke-point conditions, whereas predictions of flame-sheet boundaries ranged from soot-free to smoke-point conditions. Flame-shape predictions were based on simplified analyses using the boundary layer approximations along with empirical parameters to distinguish flame-sheet and luminous-flame (at the laminar smoke point) boundaries. The comparison between measurements and predictions was remarkably good and showed that both flame-sheet and luminous-flame lengths are primarily controlled by fuel flow rates with lengths in coflowing air approaching 2/3 lengths in still air as coflowing air velocities are increased. Finally, luminous flame lengths at laminar smoke-point conditions were roughly twice as long as flame-sheet lengths at comparable conditions due to the presence of luminous soot particles in the fuel-lean region of the flames.

Xu, F.↗
NASA NTRS2001

Flame Shapes of Nonbuoyant Laminar Jet Diffusion Flames

The shapes (flame-sheet and luminous-flame boundaries) of steady nonbuoyant round hydrocarbon-fueled laminar-jet diffusion flames in still and coflowing air were studied both experimentally and theoretically. Flame-sheet shapes were measured from photographs using a CH optical filter to distinguish flame-sheet boundaries in the presence of blue CO2 and OH emissions and yellow continuum radiation from soot. Present experimental conditions included acetylene-, methane-, propane-, and ethylene-fueled flames having initial reactant temperatures of 300 K, ambient pressures of 4-50 kPa, jet exit Reynolds number of 3-54, initial air/fuel velocity ratios of 0-9 and luminous flame lengths of 5-55 mm; earlier measurements for propylene- and 1,3-butadiene-fueled flames for similar conditions were considered as well. Nonbuoyant flames in still air were observed at micro-gravity conditions; essentially nonbuoyant flames in coflowing air were observed at small pressures to control effects of buoyancy. Predictions of luminous flame boundaries from soot luminosity were limited to laminar smokepoint conditions, whereas predictions of flame-sheet boundaries ranged from soot-free to smokepoint conditions. Flame-shape predictions were based on simplified analyses using the boundary layer approximations along with empirical parameters to distinguish flame-sheet and luminous flame (at the laminar smoke point) boundaries. The comparison between measurements and predictions was remarkably good and showed that both flame-sheet and luminous-flame lengths are primarily controlled by fuel flow rates with lengths in coflowing air approaching 2/3 lengths in still air as coflowing air velocities are increased. Finally, luminous flame lengths at laminar smoke-point conditions were roughly twice as long as flame-sheet lengths at comparable conditions due to the presence of luminous soot particles in the fuel-lean region of the flames.

Xu, F.↗
NASA NTRS2002

Flame and Soot Boundaries of Laminar Jet Diffusion Flames

The shapes (flame-sheet and luminous-flame boundaries) or steady weakly buoyant round hydrocarbon-fueled laminar-jet diffusion flames in still and coflowing air were studied both experimentally and theoretically. Flame-sheet shapes were measured from photographs using a CH optical filter to distinguish flame-sheet boundaries in the presence of blue CO2 and OH emissions and yellow continuum radiation from soot. Present experimental conditions included acetylene-, methane-, propane-, and ethylene-fueled flames having initial reactant temperatures of 300 K. ambient pressures of 4-50 kPa, jet-exit Reynolds numbers of 3-54, initial air/fuel velocity ratios of 0-9, and luminous flame lengths of 5-55 mm; earlier measurements for propylene- and 1,3-butadiene-fueled flames for similar conditions were considered as well. Nonbuoyant flames in still air were observed at microgravity conditions; essentially nonbuoyant flames in coflowing air were observed at small pressures to control effects of buoyancy. Predictions of luminous flame boundaries from soot luminosity were limited to laminar smoke-point conditions, whereas predictions of flame-sheet boundaries ranged from soot-free to smoke-point conditions. Flame-shape predictions were based on simplified analyses using the boundary-layer approximations along with empirical parameters to distinguish flame-sheet and luminous-flame (at the laminar smoke point) boundaries. The comparison between measurements and predictions was remarkably good and showed that both flame-sheet and luminous-flame lengths are primarily controlled by fuel flow rates with lengths in coflowing air approaching 2/3 of the lengths in still air as coflowing air velocities are increased. Finally, luminous flame lengths at laminar smoke-point conditions were roughly twice as long as flame-sheet lengths at comparable conditions because of the presence of luminous soot particles in the fuel-lean region of the flames.

Xu, F.↗
NASA NTRS2004

Performance Evaluation of Fiber Bragg Gratings at Elevated Temperatures

The development of integrated fiber optic sensors for smart propulsion systems demands that the sensors be able to perform in extreme environments. In order to use fiber optic sensors effectively in an extreme environment one must have a thorough understanding of the sensor s limits and how it responds under various environmental conditions. The sensor evaluation currently involves examining the performance of fiber Bragg gratings at elevated temperatures. Fiber Bragg gratings (FBG) are periodic variations of the refractive index of an optical fiber. These periodic variations allow the FBG to act as an embedded optical filter passing the majority of light propagating through a fiber while reflecting back a narrow band of the incident light. The peak reflected wavelength of the FBG is known as the Bragg wavelength. Since the period and width of the refractive index variation in the fiber determines the wavelengths that are transmitted and reflected by the grating, any force acting on the fiber that alters the physical structure of the grating will change what wavelengths are transmitted and what wavelengths are reflected by the grating. Both thermal and mechanical forces acting on the grating will alter its physical characteristics allowing the FBG sensor to detect both temperature variations and physical stresses, strain, placed upon it. This ability to sense multiple physical forces makes the FBG a versatile sensor. This paper reports on test results of the performance of FBGs at elevated temperatures. The gratings looked at thus far have been either embedded in polymer matrix materials or freestanding with the primary focus of this paper being on the freestanding FBGs. Throughout the evaluation process, various parameters of the FBGs performance were monitored and recorded. These parameters include the peak Bragg wavelength, the power of the Bragg wavelength, and total power returned by the FBG. Several test samples were subjected to identical test conditions to allow for statistical analysis of the data. Test procedures, calibrations, and referencing techniques are presented in the paper along with directions for future research.

Juergens, Jeffrey↗
NASA NTRS2004

Thin-Filament Pyrometry Developed for Measuring Temperatures in Flames

Many valuable advances in combustion science have come from observations of microgravity flames. This research is contributing to the improved efficiency and reduced emissions of practical combustors and is benefiting terrestrial and spacecraft fire safety. Unfortunately, difficulties associated with microgravity have prevented many types of measurements in microgravity flames. In particular, temperature measurements in flames are extremely important but have been limited in microgravity. A novel method of measuring temperatures in microgravity flames is being developed in-house at the National Center for Microgravity Research and the NASA Glenn Research Center and is described here. Called thin-filament pyrometry, it involves using a camera to determine the local gas temperature from the intensity of inserted fibers glowing in a flame. It is demonstrated here to provide accurate measurements of gas temperatures in a flame simultaneously at many locations. The experiment is shown. The flame is a laminar gas jet diffusion flame fueled by methane (CH4) flowing from a 14-mm round burner at a pressure of 1 atm. A coflowing stream of air is used to prevent flame flicker. Nine glowing fibers are visible. These fibers are made of silicon carbide (SiC) and have a diameter of 15 m (for comparison, the average human hair is 75 m in diameter). Because the fibers are so thin, they do little to disturb the flame and their temperature remains close to that of the local gas. The flame and glowing filaments were imaged with a digital black-and-white video camera. This camera has an imaging area of 1000 by 1000 pixels and a wide dynamic range of 12 bits. The resolution of the camera and optics was 0.1 mm. Optical filters were placed in front of the camera to limit incoming light to 750, 850, 950, and 1050 nm. Temperatures were measured in the same flame in the absence of fibers using 50-m Btype thermocouples. These thermocouples provide very accurate temperatures, but they generally are not useful in microgravity tests because they measure temperature at only one location at a time. Thermocouple measurements at a height of 11 mm above the burner were used to calibrate the thin-filament pyrometry system at all four wavelengths. This calibration was used to perform thin-filament pyrometry at other heights above the burner. One such profile is shown in this graph; this is for a height of 21 mm. The agreement between the pyrometry measurements and thermocouple results at this height is excellent in the range of 1000 to 2000 K, with an estimated uncertainty of 50 K and an estimated upper limit of 2500 K. Neither the thermocouple nor the thin-filament pyrometry temperatures have been corrected for radiation, but the correction is expected to be nearly the same for both methods. We anticipate that thin-filament pyrometry similar to that developed here will become an important diagnostic for studies of microgravity flames owing to its accuracy and its ability to simultaneously measure finely spaced temperatures.

Sunderland, Peter B.↗
NASA NTRS2005

Various Analyses of Structures and Systems Pertaining to Optical Communications

The Optical Communications Group intends to experiment with a 2 by 2 meter Fresnel lens to determine its likelihood as an alternative to focusing mirrors for optical communications. The lens was delivered in four sections. A support structure was required for the lens in order to hold the four sections in a single flat plane with an adjustable degree angle. In order to use the 200-in. Hale telescope for optical communications purposes, an optical filter membrane must used to pass the communications wavelength while blocking sunlight wavelengths. This filter must withstand wind gusts of up to 50 miles per hour. Stress analysis predicts that the membrane will survive with a safety factor greater than two. The methods used were verified by pressure testing the material. Mechanical and thermodynamic analyses were performed on a simple Golay cell in order to optimize its dimensions for best performance. Flexures are examined as an inexpensive alternative to traditional methods for kinematically constraining a 1.5-meter spherical mirror.

Petersen, Collin W.↗
NASA NTRS1995

Doppler Observations of the Impact of Comet SL9 Fragment A

An attempt to detect Doppler effects on Jupiter during the impact of fragment A of the Shoemaker-Levy 9 comet is discussed. A short description is given of the technique used to observe the impact. Observations are presented, and a theoretical analysis and inter- pretation are given. The instrumentation used is an advanced and more sensitive version of the Magneto-Optical Filter & a 40 cm telescope.

Shoemaker-Levy 9 Jupiter comet fragment A doppler ↗
NASA NTRS2005

Chromospheric observations in the helium 1083NM line : a new instrument

Photometric, spectroscopic and polarimetric observations in the Helium 1083 nm line provide important diagnostic information on the structure and dynamics of the chromosphere. We describe an imaging instrument designed to probe the chromosphere in the Helium 1083nm line, based on a Helium magneto-optical filter. The instrument has two narrow passbands ((almost equal to) 0.006 nm) in the wings of each line of the Helium 1083nm triplet, high throughput and stability, making it ideal for making high cadence observations in support of studies of chromospheric dynamics and wave propagation. We describe the characteristics of the instrument and present preliminary observations and discuss future plans.

solar atmosphere↗
NASA NTRS2002

Doppler phase shifting using dual, switched phase shifting devices

A system of inducing a phase shift using moving reflector elements. The moving reflectors can be moving mirrors or an acousto-optical filter. The moving reflectors oscillate i.e. the move first in a first direction and then in a second direction. Two different reflectors are used so that the light can be switched between the reflectors. During a first portion of the cycle the light is coupled to the first modulator which moves the reflector in the first direction. The second modulator is out of phase with the first modulator, and the light is switched to that second modulator during a second portion of the cycle. The second modulator is also moving in the first direction when the light is applied thereto. In this way, the light obtains a constant direction Doppler shift.

Gutierrez, Roman C.↗
NASA NTRS2008

A Compact, Modular Superconducting Bolometer Array Package

We have designed a detector package to house a superconducting bolometer array, SQUID multiplexers, bias and integration circuitry, optical filtering, electrical connectors, and thermal/mechanical interfaces. This package has been used successfully in the GISMO 2mm camera, a 128-pixel camera operating at a base temperature of 270mK. Operation at lower temperatures is allowed by providing direct heat sinking to the SQUIDS and bias resistors, which generate the bulk of the dissipation in the package. Standard electrical connectors provide reliable contact while enabling quick installation and removal of the package. Careful design has gone into the compensation for differing thermal expansions, the need for heat sinking of the bolometer array, and the placement of magnetic shielding in critical areas. In this presentation, we detail the design and performance of this detector package and describe its scalability to 1280- pixel arrays in the near future.

Benford, Dominic J.↗
NASA NTRS2008

The On-Orbit Performance of the CALIOP Lidar on CALIPSO

CALIPSO is a joint NASA - CNES satellite currently in its third year of operation in low earth orbit. The satellite is making optical measurements of the Earth s atmosphere to help quantify the impact of aerosols and clouds on the Earth s radiation budget. To do this, it carries three instruments: CALIOP, a two-wavelength polarization-sensitive elastic backscatter lidar; the IIR a three band thermal imaging radiometer; and the WFC a visible single-band imager. CALIOP utilizes a Nd:YAG laser which incorporates a harmonic crystal to provide laser light at both 1064 nm and 532 nm. This beam is expanded and transmitted into the atmosphere at near nadir. The laser light scattered from clouds and aerosols back to the satellite, along with any solar background light, is collected by a one meter diameter beryllium telescope. The captured light is separated into its two wavelengths and optically filtered. The 1064 nm component is detected with an avalanche photodiode, while the 532 nm component is further resolved into two linear polarization components which are then detected by matching photomultiplier tubes. This presentation will describe the lidar and give examples of its on-orbit performance.

Winker, David↗
NASA NTRS2009

Ultra-high Temperature Emittance Measurements for Space and Missile Applications

Advanced modeling and design efforts for many aerospace components require high temperature emittance data. Applications requiring emittance data include propulsion systems, radiators, aeroshells, heatshields/thermal protection systems, and leading edge surfaces. The objective of this work is to provide emittance data at ultra-high temperatures. MSFC has a new instrument for the measurement of emittance at ultra-high temperatures, the Ultra-High Temperature Emissometer System (Ultra-HITEMS). AZ Technology Inc. developed the instrument, designed to provide emittance measurements over the temperature range 700-3500K. The Ultra-HITEMS instrument measures the emittance of samples, heated by lasers, in vacuum, using a blackbody source and a Fourier Transform Spectrometer. Detectors in a Nicolet 6700 FT-IR spectrometer measure emittance over the spectral range of 0.4-25 microns. Emitted energy from the specimen and output from a Mikron M390S blackbody source at the same temperature with matched collection geometry are measured. Integrating emittance over the spectral range yields the total emittance. The ratio provides a direct measure of total hemispherical emittance. Samples are heated using lasers. Optical pyrometry provides temperature data. Optical filters prevent interference from the heating lasers. Data for Inconel 718 show excellent agreement with results from literature and ASTM 835. Measurements taken from levitated spherical specimens provide total hemispherical emittance data; measurements taken from flat specimens mounted in the chamber provide near-normal emittance data. Data from selected characterization studies will be presented. The Ultra-HITEMS technique could advance space and missile technologies by advancing the knowledge base and the technology readiness level for ultra-high temperature materials.

Rogers, Jan↗
NASA NTRS2007

Imaging Spectrometer on a Chip

A proposed visible-light imaging spectrometer on a chip would be based on the concept of a heterostructure comprising multiple layers of silicon-based photodetectors interspersed with long-wavelength-pass optical filters. In a typical application, this heterostructure would be replicated in each pixel of an image-detecting integrated circuit of the active-pixel-sensor type (see figure). The design of the heterostructure would exploit the fact that within the visible portion of the spectrum, the characteristic depth of penetration of photons increases with wavelength. Proceeding from the front toward the back, each successive long-wavelength-pass filter would have a longer cutoff wavelength, and each successive photodetector would be made thicker to enable it to absorb a greater proportion of incident longer-wavelength photons. Incident light would pass through the first photodetector and encounter the first filter, which would reflect light having wavelengths shorter than its cutoff wavelength and pass light of longer wavelengths. A large portion of the incident and reflected shorter-wavelength light would be absorbed in the first photodetector. The light that had passed through the first photodetector/filter pair of layers would pass through the second photodetector and encounter the second filter, which would reflect light having wavelengths shorter than its cutoff wavelength while passing light of longer wavelengths. Thus, most of the light reflected by the second filter would lie in the wavelength band between the cutoff wavelengths of the first and second filters. Thus, further, most of the light absorbed in the second photodetector would lie in this wavelength band. In a similar manner, each successive photodetector would detect, predominantly, light in a successively longer wavelength band bounded by the shorter cutoff wavelength of the preceding filter and the longer cutoff wavelength of the following filter.

Wang, Yu↗
NASA NTRS2010

AlGaN Ultraviolet Detectors for Dual-Band UV Detection

This innovation comprises technology that has the ability to measure at least two ultraviolet (UV) bands using one detector without relying on any external optical filters. This allows users to build a miniature UVA and UVB monitor, as well as to develop compact, multicolor imaging technologies for flame temperature sensing, air-quality control, and terrestrial/counter-camouflage/biosensing applications.

Miko, Laddawan↗
NASA NTRS2004

Ambient-Light-Canceling Camera Using Subtraction of Frames

The ambient-light-canceling camera (ALCC) is a proposed near-infrared electronic camera that would utilize a combination of (1) synchronized illumination during alternate frame periods and (2) subtraction of readouts from consecutive frames to obtain images without a background component of ambient light. The ALCC is intended especially for use in tracking the motion of an eye by the pupil center corneal reflection (PCCR) method. Eye tracking by the PCCR method has shown potential for application in human-computer interaction for people with and without disabilities, and for noninvasive monitoring, detection, and even diagnosis of physiological and neurological deficiencies. In the PCCR method, an eye is illuminated by near-infrared light from a lightemitting diode (LED). Some of the infrared light is reflected from the surface of the cornea. Some of the infrared light enters the eye through the pupil and is reflected from back of the eye out through the pupil a phenomenon commonly observed as the red-eye effect in flash photography. An electronic camera is oriented to image the user's eye. The output of the camera is digitized and processed by algorithms that locate the two reflections. Then from the locations of the centers of the two reflections, the direction of gaze is computed. As described thus far, the PCCR method is susceptible to errors caused by reflections of ambient light. Although a near-infrared band-pass optical filter can be used to discriminate against ambient light, some sources of ambient light have enough in-band power to compete with the LED signal. The mode of operation of the ALCC would complement or supplant spectral filtering by providing more nearly complete cancellation of the effect of ambient light. In the operation of the ALCC, a near-infrared LED would be pulsed on during one camera frame period and off during the next frame period. Thus, the scene would be illuminated by both the LED (signal) light and the ambient (background) light during one frame period, and would be illuminated with only ambient (background) light during the next frame period. The camera output would be digitized and sent to a computer, wherein the pixel values of the background-only frame would be subtracted from the pixel values of the signal-plus-background frame to obtain signal-only pixel values (see figure). To prevent artifacts of motion from entering the images, it would be necessary to acquire image data at a rate greater than the standard video rate of 30 frames per second. For this purpose, the ALCC would exploit a novel control technique developed at NASA s Jet Propulsion Laboratory for advanced charge-coupled-device (CCD) cameras. This technique provides for readout from a subwindow [region of interest (ROI)] within the image frame. Because the desired reflections from the eye would typically occupy a small fraction of the area within the image frame, the ROI capability would make it possible to acquire and subtract pixel values at rates of several hundred frames per second considerably greater than the standard video rate and sufficient to both (1) suppress motion artifacts and (2) track the motion of the eye between consecutive subtractive frame pairs.

Morookian, John Michael↗
NASA NTRS2004

Photodiode-Based, Passive Ultraviolet Dosimeters

Simple, passive instruments have been developed for measuring the exposure of material specimens to vacuum ultraviolet (VUV) radiation from the Sun. Each instrument contains a silicon photodiode and a coulometer. The photocharge generated in the photodiode is stored in the coulometer. The accumulated electric charge measured by use of the coulometer is assumed to be proportional to the cumulative dose of VUV radiation expressed in such convenient units as equivalent Sun hours (ESH) [defined as the number of hours of exposure to sunlight at normal incidence]. Intended originally for use aboard spacecraft, these instruments could also be adapted to such terrestrial uses as monitoring the curing of ultraviolet-curable epoxies. Each instrument includes a photodiode and a coulometer assembly mounted on an interface plate (see figure). The photodiode assembly includes an aluminum housing that holds the photodiode, a poly(tetrafluoroehylene) cosine receptor, and a narrow-band optical filter. The cosine receptor ensures that the angular response of the instrument approximates the ideal angular response (proportional to the cosine of the angle of incidence). The filter is chosen to pass the ultraviolet wavelength of interest in a specific experiment. The photodiode is electrically connected to the coulometer. The factor of proportionality between the charge stored in the coulometer and ultraviolet dosage (in units of ESH) is established, prior to use, in calibration experiments that involve the use of lamps and current sources traceable to the National Institute of Standards and Technology.

Vaughn, Jason A.↗