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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Quantum Critical Point in the Itinerant Ferromagnet Ni 1– x Rh x

In this paper, we report a chemical substitution-induced ferromagnetic quantum critical point in polycrystalline Ni 1– x Rh x alloys. Through magnetization and muon spin relaxation measurements, we show that the ferromagnetic ordering temperature is suppressed continuously to zero at $x_{\text{crit}}$ = 0.375 while the magnetic volume fraction remains 100% up to $x_{\text{crit}}$, pointing to a second order transition. Non-Fermi liquid behavior is observed close to $x_{\text{crit}}$, where the electronic specific heat Cel/T diverges logarithmically, while immediately above $x_{\text{crit}}$ the volume thermal expansion coefficient $\textit{αV/T}$ and the Grüneisen ratio $Γ = α_V/C_{\text{el}}$ both diverge logarithmically in the low temperature limit, further indication of a ferromagnetic quantum critical point in Ni 1– x Rh x .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

TEA Modeling to Quantify Economic Implications for Biorefinery Processing of Isolated Anatomical Fractions of Corn Stover

The Feedstock-Conversion Interface Consortium (FCIC; https://www.energy.gov/sites/prod/files/2020/01/f70/beto-fcic-overview-web.pdf), a collaboration of nine national laboratory partners, seeks to understand impacts of feedstock attributes on biorefinery performance. It is hypothesized that different individual anatomical fractions of corn stover vary in composition and recalcitrance, such that processing each fraction on its own through dedicated campaigns may enable better biorefinery economics overall relative to processing the whole stover material. This presentation focuses on techno-economic analysis (TEA) modeling to quantify the yield and cost ramifications for processing isolated anatomical fractions of corn stover through a low-temperature conversion biorefinery, reflecting a biochemical processing pathway consisting of biomass deconstruction through pretreatment and enzymatic hydrolysis, sugar fermentation and upgrading to hydrocarbon fuels, and lignin upgrading to value-added coproducts. Commercial-scale process simulation and economic evaluation leveraged experimental and analytical data from FCIC researchers for conversion of whole corn stover plus three individual anatomical fractions (cobs, husks, and stalks) across key steps of the conversion process. Our assessment found encouraging potential for biorefinery economic gains that may be achieved through this approach. TEA results indicated fuel yields varying from 29-44 gallons gasoline equivalent (GGE)/dry ton for the individual anatomical fractions compared to whole stover at 34 GGE/ton, equating to minimum fuel selling prices (MFSPs) between $6.37-$10.18/GGE for the fractions versus $8.76/GGE for whole stover (when lignin is burned), or $9.15-$15.19/GGE for the fractions versus $13.11/GGE for whole stover (when lignin is upgraded to coproducts, based on current experimental performance levels). Cobs and husks demonstrated the ability to achieve the highest fuel yields and lowest MFSPs, outperforming whole stover, while stalks led to the opposite result, as a composite reflection of compositional differences and process convertibility. Notably, even when taking the weighted average of the results reflecting each anatomical fraction weighted by its corresponding makeup of corn stover, this feasibility TEA screening supports feedstock cost allowances on the order of roughly $22-$29/ton as may reflect accommodating additional biomass fractionation equipment during feedstock pre-processing upstream of the conversion biorefinery gate to separate corn stover into such constituent fractions. Or viewed differently, the weighted average MFSP for the fractions was found to be $0.31-$0.32/GGE lower than the MFSP for the whole stover basis across either lignin scenario, when maintaining a fixed biomass feedstock cost. These findings highlight favorable implications for biorefinery economics as may be achieved by moving to a staged campaign approach for processing different corn stover fractions sequentially. Further opportunities exist for future work to fill in data gaps for remaining anatomical constituents (e.g. leaves) that were not included in the initial experimental studies, though are expected to maintain similar trends.

biochemical processing pathway↗
DOE OSTI2022

Advancing Chemical Separations: Unraveling the Structure and Dynamics of Phase Splitting in Liquid–Liquid Extraction

Liquid-liquid extraction (LLE), the go-to process for a variety of chemical separations, is limited by spontaneous organic phase splitting upon sufficient solute loading, called third phase formation. In this study we explore the applicability of critical phenomena theory to gain insight into this deleterious phase behavior with the goal of improving separations efficiency and minimizing waste. Here, a series of samples representative of rare earth purification were constructed to include each of one light and one heavy lanthanide (cerium and lutetium) paired with one of two common malonamide extractants (DMDOHEMA and DMDBTDMA). The resulting postextraction organic phases are chemically complex and often form rich hierarchical structures whose statics and dynamics near the critical point were probed herein with small-angle X-ray scattering and high-speed X-ray photon correlation spectroscopy. Despite their different extraction behaviors, all samples show remarkably similar critical behavior with exponents well described by classical critical point theory consistent with the 3D Ising model, where the critical behavior is characterized by fluctuations with a single diverging length scale. This unexpected result indicates a significant reduction in relevant chemical parameters at the critical point, indicating that the underlying behavior of phase transitions in LLE rely on far fewer variables than are generally assumed. The obtained scalar order parameter is attributed to the extractant fraction of the extractant/diluent mixture, revealing that other solution components and their respective concentrations simply shift the critical temperature but do not affect the nature of the critical fluctuations. These findings point to an opportunity to drastically simplify studies of liquid-liquid phase separation and phase diagram development in general while providing insights into LLE process improvement.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Effects of primordial black holes on IGM history

Currently the asteroid mass window (mass ∼ 10$^{17}$- 10$^{21}$ grams) remains unconstrained for Primordial Black Holes (PBHs) to make up all of the dark matter content of the universe. Given these PBHs have very small masses, their Hawking temperature can be up to hundreds of keV. This study investigates the potential impacts of PBH Hawking radiation on the intergalactic medium from z ∼ 800-25, namely studying the ionization history, kinetic gas temperature, and ultimately the 21 cm signature. We find that for masses on the low edge of the asteroid mass window, there are up two orders of magnitude increases in the ionization fraction and kinetic gas temperature by redshift 25, and the 21 cm spin temperature can differ from non-PBH cosmology by factors of a few. This analysis results in maximum differential brightness temperatures of +17 mK for our lightest PBH masses of 2.12 × 10$^{16}$g. We also show maximal 53 mK discrepancies in differential brightness temperatures between our PBH and non-PBH cosmologies for our lightest PBH mass, while our heaviest PBH mass of 1.65 × 10$^{17}$g shows only 0.5 mK variations. We find the Hawking-radiated electrons and positrons are instrumental in driving these IGM modifications. This study shows the necessity for a rigorous treatment of Hawking radiation in PBH cosmological observables from the dark ages through cosmic dawn.

dark matter theory↗
DOE OSTI2023

Interplay of structure and magnetism in LuFe 4 ⁢Ge 2 tuned by hydrostatic pressure

Lu⁢Fe 4 ⁢Ge 2 crystallizes in the Zr⁢Fe 4 ⁢Si 2 -type structure, hosting chains of Fe tetrahedra giving rise to geometric frustration and low dimensionality. The compound orders antiferromagnetically at around 36 K accompanied by a simultaneous structural transition from a tetragonal phase to an orthorhombic phase. The hydrostatic pressure dependence of the magnetic and structural transitions is investigated using electrical transport, AC magnetic susceptibility, AC calorimetry, M⁢össbauer, muon-spin relaxation (μ⁢SR), and x-ray-diffraction measurements. External pressure suppresses the first-order transition to the antiferromagnetic phase (AFM1) around 1.8 GPa. The structural transition is largely unaffected by pressure and remains between 30 to 35 K for pressures up to 2 GPa. A second antiferromagnetic phase (AFM2) is observed at higher pressures. The transition from the paramagnetic to the AFM2 phase is of second-order nature and appears to be connected to the structural transition. The magnetic volume fraction obtained from μ⁢SR and M⁢össbauer measurements reveal that the entire sample undergoes magnetic ordering in both magnetic phases. In addition, similar low-temperature muon-precession frequencies in AFM1 and AFM2 phases point at similar ordered moments and magnetic structures in both phases. Our results further indicate enhanced magnetic fluctuations in the pressure-induced AFM2 phase. The experimental observations together with density functional theory calculations suggest that the magnetic- and structural-order parameters in Lu⁢Fe 4 ⁢Ge 2 are linked by magnetic frustration, causing the simultaneous magnetostructural transition.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

Quantum materials for nanosensing and fault-tolerant quantum computing

New concepts of symmetry related to topological order emerged from the discovery of the fractional quantum Hall effect and high-temperature superconductivity in strongly correlated electron systems. This led to the study of quantum materials-- materials exhibiting emergent quantum phenomena with no classical analogues. While these materials have engendered exciting basic materials science and physics, realizing novel devices is a key challenge in the field. The goal of this proposal is to harness the unique properties of topological materials for quantum computing and quantum sensing applications. In this project, we investigated a variety of topological superconducting platforms and identified three technologies that can benefit from their quantum properties: quantum memory, single-photon detection, and non reciprocal electronics. The platforms developed in this work will be broadly useful to National Security and Basic Science.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Salt Transport in Crosslinked Hydrogel Membranes Containing Zwitterionic Sulfobetaine Methacrylate and Hydrophobic Phenyl Acrylate

Produced water is a by-product of industrial operations, such as hydraulic fracturing for increased oil recovery, that causes environmental issues since it includes different metal ions (e.g., Li+, K+, Ni2+, Mg2+, etc.) that need to be extracted or collected before disposal. To remove these substances using either selective transport behavior or absorption-swing processes employing membrane-bound ligands, membrane separation procedures are promising unit operations. This study investigates the transport of a series of salts in crosslinked polymer membranes synthesized using a hydrophobic monomer (phenyl acrylate, PA), a zwitterionic hydrophilic monomer (sulfobetaine methacrylate, SBMA), and a crosslinker (methylenebisacrylamide, MBAA). Membranes are characterized according to their thermomechanical properties, where an increased SBMA content leads to decreased water uptake due to structural differences within the films and to more ionic interactions between the ammonium and sulfonate moieties, resulting in a decreased water volume fraction, and Young’s modulus increases with increasing MBAA or PA content. Permeabilities, solubilities, and diffusivities of membranes to LiCl, NaCl, KCl, CaCl2, MgCl2, and NiCl2 are determined by diffusion cell experiments, sorption-desorption experiments, and the solution-diffusion relationship, respectively. Permeability to these metal ions generally decreases with an increasing SBMA content or MBAA content due to the corresponding decreasing water volume fraction, and the permeabilities are in the order of K+ > Na+ > Li+ > Ni2+ > Ca2+ > Mg2+ presumably due to the differences in the hydration diameter.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1978

Turbulence in planetary occultations. II - Effects on atmospheric profiles derived from Doppler measurements. III - Effects on atmospheric profiles derived from intensity measurements

The nature and magnitude of turbulence-induced errors in atmospheric profiles derived from Doppler measurements made during radio occultations are investigated. It is found that turbulence in planetary atmospheres induces both fluctuating and systematic errors in derived profiles, but the errors of both types are very small. Consideration of the occultation of Mariner 10 by Venus and of the Pioneer occultations by Jupiter shows that the rms fractional errors in the atmospheric profiles derived from these observations were less than 0.01 in both temperature and pressure, while the fractional systematic errors were typically of the order of 1 millionth. The extent to which atmospheric profiles derived from radio and optical intensity measurements are affected by turbulence is also examined. The results indicate that turbulence in planetary atmospheres has only a marginal effect on derived profiles in the weak-scattering limit and that the turbulence-induced errors in this case are always much larger than the corresponding errors in profiles derived from radio Doppler measurements.

Haugstad, B. S.↗
NASA NTRS1981

Preacceleration in collapsing magnetic neutral sheets and anomalous abundances of solar flare particles

Levine's (1974) concept of a collapsing magnetic neutral sheet which can accelerate ambient protons to several times the mean thermal speed, provided that the collapse time scale is shorter than the proton Coulomb loss time, is applied to heavier elements in an investigation of the composition of the particles which can be accelerated by such a sheet. Tables of ionization equilibrium are combined with the thermal structure of a constant pressure loop in order to calculate phi sub x (the fraction of an element x which is accelerated) of 18 heavy elements, from carbon to nickel which satisfy a maximum-ionization criterion. Normalizing phi sub x to oxygen, it is found that relative to the composition of the ambient materials, C and N can be depleted by factors of up to 2-10, while other heavy elements, along with hydrogen, are enhanced. The numerical results obtained are qualitatively similar to anomalous abundances reported among solar flare particles.

Mullan, D. J.↗
NASA NTRS1983

Enstatite chondrites - Trace element clues to their origin

Three EH and three EL chondrites have been subjected to RNAA analysis for 20 trace elements, and interelement correlations were examined in order to assess the effects of nebular fractionation and metamorphism. The refractory siderophiles Ir, Os, and Re correlate with the normal siderophiles Ni, Pd, Au, Sb, and Ge, in ELs but not in EHs. The two element groups presumably condensed on separate phases at first, but concentrated in metal during metabolism. Volatiles are consistently more depleted in ELs than EHs. Strong correlations are found for In-Tl, Tl-Bi, and Zn-Cd-In, which are equally consistent with predicted condensation curves for the solar nebula and with volatilization curves for artificially heated Abee. The three factors accounting for 93 percent of variance reflect volatile, siderophile, and chalcophile behavior.

Hertogen, J.↗
NASA NTRS1992

Variable frequency pulsed phase-locked loop method for measuring material nonlinearity

The design of a pressure vessel with an isothermal volume to measure changes in the natural velocities of material continuously over a wide temperature range is reported. Highly sensitive pulsed phase-locked loop technology is used to measure the natural velocity of fatigued aluminum 2024-T4 as a function of pressure at different temperatures. Second derivative variations with respect to pressure and temperature are found to exhibit order-of-magnitude changes at a gauge pressure near 950 kPa at room temperature. This indicates a significant change in certain combinations of second-order and higher-order elastic constants at relatively low pressures. Fractional frequency change as a function of applied pressure for aluminum 2024-T4 with fatigue damage is illustrated.

Yost, William T.↗
NASA NTRS1993

Radiative temperature measurements at Kupaianaha lava lake, Kilauea Volcano, Hawaii

The radiative temperature of the surface of Kupaianaha lava lake is computed using field spectroradiometer data. Observations were made during periods of active overturning. The lake surface exhibits three stages of activity. Magma fountaining and overturning events characterize stage 1, which exhibits the hottest crustal temperatures and the largest fractional hot areas. Rifting events between plates of crust mark stage 2; crustal temperatures in this stage are between 100 C and 340 C, and fractional hot areas are at least an order of magnitude smaller than those in stage 1. Stage 3 is characterized by quiescent periods when the lake is covered by a thick crust. This stage dominates the activity of the lake more than 90 percent of the time. The results of this study are relevant for satellite and airborne measurement of the thermal characteristics of active volcanoes, and indicate that the thermal output of a lava lake varies on a time scale of seconds to minutes.

Flynn, Luke P.↗
NASA NTRS1994

The End of Comet Shoemaker-Levy 9

The pieces of the former Comet Shoemaker-Levy 9 struck Jupiter during the week of July 16-22 1994. We divide the general impact phenomena into four phases: (1) Atmospheric entry should have been accompanied by an entry flash, probably only detectable by the Galileo spacecraft. (2) Aerodynamic forces cause the impactor to explode. We show that the apparent altitude of the explosions is consistent with the analytical model proposed by Zahnle and Chyba et al, with numerical models calculated by Mac Low and Zahnle and Yabe et al., and with dynamically-based estimates of fragment masses Suggested by Scotti and Melosh and Asphaug and Benz. (3) The explosion produces a fireball that propagates most quickly up the wake, as predicted by Takata et al. and Crawford et al. The fireball's luminosity fades over a timescale of 30-60 seconds. (4) Each explosion produced a plume that reached thousands of kilometers above the cloud-tops. The plumes appear to have been dusty and SO illuminated when they reached sunlight. The plumes rose and fell over a period of ten or twenty minutes, governed by the simple laws of ballistics. When plume material (dust) fell back on the atmosphere it was reheated and glowed brightly in the thermal infrared for a period of order ten to twenty minutes; a large fraction of the impact energy was spent thus. Geometry introduces additional factors that complicate interpretation of the observed light curves.

Zahnle, K. J.↗
NASA NTRS2007

Uncertainty Analysis of Historical Hurricane Data

An analysis of variance (ANOVA) study was conducted for historical hurricane data dating back to 1851 that was obtained from the U. S. Department of Commerce National Oceanic and Atmospheric Administration (NOAA). The data set was chosen because it is a large, publicly available collection of information, exhibiting great variability which has made the forecasting of future states, from current and previous states, difficult. The availability of substantial, high-fidelity validation data, however, made for an excellent uncertainty assessment study. Several factors (independent variables) were identified from the data set, which could potentially influence the track and intensity of the storms. The values of these factors, along with the values of responses of interest (dependent variables) were extracted from the data base, and provided to a commercial software package for processing via the ANOVA technique. The primary goal of the study was to document the ANOVA modeling uncertainty and predictive errors in making predictions about hurricane location and intensity 24 to 120 hours beyond known conditions, as reported by the data set. A secondary goal was to expose the ANOVA technique to a broader community within NASA. The independent factors considered to have an influence on the hurricane track included the current and starting longitudes and latitudes (measured in degrees), and current and starting maximum sustained wind speeds (measured in knots), and the storm starting date, its current duration from its first appearance, and the current year fraction of each reading, all measured in years. The year fraction and starting date were included in order to attempt to account for long duration cyclic behaviors, such as seasonal weather patterns, and years in which the sea or atmosphere were unusually warm or cold. The effect of short duration weather patterns and ocean conditions could not be examined with the current data set. The responses analyzed were the storm latitude, longitude and intensity, as recorded in the data set, 24 or 120 hours beyond the current state. Several ANOVA modeling schemes were examined. Two forms of validation were used: 1) comparison with official hurricane prediction performance metrics and 2) cases studies conducted on hurricanes from the 2005 season, which were not included within the model construction and ANOVA assessment. In general, the ANOVA technique did not perform as well as the established official prediction performance metrics published by NOAA; still, the technique did remarkably well in this demonstration with a difficult data set and could probably be made to perform better with more knowledge of hurricane development and dynamics applied to the problem. The technique provides a repeatable prediction process that eliminates the need for judgment in the forecast.

Green, Lawrence L.↗
DOE OSTI2025

Contrasting c -axis and in-plane uniaxial stress effects on superconductivity and stripe order in La 1.885 Ba 0.115 CuO 4

The cuprate superconductor La 2−x Ba x CuO 4 (LBCO) near x = 0.125 is a striking example of intertwined electronic orders, where 3D superconductivity is anomalously suppressed, allowing spin and charge stripe order to develop. Understanding this interplay remains a key challenge in cuprates, highlighting the necessity of external tuning for deeper insight. While in-plane uniaxial stress enhances superconductivity and suppresses stripe order, the effects of c -axis compression remains largely unexplored. Here, we use muon spin rotation ( μ SR) and AC susceptibility with an in situ piezoelectric stress device to investigate the spin-stripe order and superconductivity in LBCO-0.115 under c-axis compression. The measurements reveal a gradual suppression of the superconducting transition temperature ( T c ) with increasing c -axis stress, in stark contrast to the strong enhancement observed under in-plane stress. We further show that while in-plane stress rapidly reduces both the magnetic volume fraction ( V m ) and the spin-stripe ordering temperature ( T so ), c-axis compression has no effect, with V m and T so exhibiting an almost unchanged behavior up to the highest applied stress of 0.21 GPa. These findings demonstrate a strong anisotropy in stress response.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

Measurements of the branching fractions of ${\Xi }_{c}^{+}\to {\Sigma }^{+}{K}_{S}^{0}$, ${\Xi }_{c}^{+}\to {\Xi }^{0}{\pi }^{+}$, and ${\Xi }_{c}^{+}\to {\Xi }^{0}{K}+$ at Belle and Belle II

Using 983.0 fb −1 and 427.9 fb −1 data samples collected with the Belle and Belle II detectors at the KEKB and SuperKEKB asymmetric energy e + e − colliders, respectively, we present studies of the Cabibbo-favored ${\Xi }_{c}^{+}$ decays ${\Xi }_{c}^{+}\to {\Sigma }^{+}{K}_{S}^{0}$ and ${\Xi }_{c}^{+}\to {\Xi }^{0}{\pi }^{+}$, and the singly Cabibbo-suppressed decay ${\Xi }_{c}^{+}\to {\Xi }^{0}{K}^{+}$. The ratios of branching fractions of ${\Xi }_{c}^{+}\to {\Sigma }^{+}{K}_{S}^{0}$ and ${\Xi }_{c}^{+}\to {\Xi }^{0}{K}^{+}$ relative to that of ${\Xi }_{c}^{+}\to {\Xi }^{-}{\pi }^{+}{\pi }^{+}$ are measured for the first time, while the ratio $\mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{0}{\pi }^{+})/\mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{-}{\pi }^{+}{\pi }^{+})$ is also determined and improved by an order of magnitude in precision. The measured branching fraction ratios are $\begin{array}{c}\frac{\mathcal{B}\left({\Xi }_{c}^{+}\to {\Sigma }^{+}{K}_{S}^{0}\right)}{\mathcal{B}\left({\Xi }_{c}^{+}\to {\Xi }^{-}{\pi }^{+}{\pi }^{+}\right)}=0.067\pm 0.007\pm 0.003,\\ \frac{\mathcal{B}\left({\Xi }_{c}^{+}\to {\Xi }^{0}{\pi }^{+}\right)}{\mathcal{B}\left({\Xi }_{c}^{+}\to {\Xi }^{-}{\pi }^{+}{\pi }^{+}\right)}=0.251\pm 0.005\pm 0.010,\\ \frac{\mathcal{B}\left({\Xi }_{c}^{+}\to {\Xi }^{0}{K}^{+}\right)}{\mathcal{B}\left({\Xi }_{c}^{+}\to {\Xi }^{-}{\pi }^{+}{\pi }^{+}\right)}=0.017\pm 0.003\pm 0.001.\end{array}$ Additionally, the ratio $\mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{0}{K}^{+})/\mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{0}{\pi }^{+})$ is measured to be 0.068 ± 0.010 ± 0.004. Here, the first and second uncertainties are statistical and systematic, respectively. Multiplying the ratios by the branching fraction of the normalization mode, $\mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{-}{\pi }^{+}{\pi }^{+})=(2.9\pm 1.3)%$, we obtain the following absolute branching fractions $\begin{array}{c}\mathcal{B}({\Xi }_{c}^{+}\to {\Sigma }^{+}{K}_{S}^{0})=(0.194\pm 0.021\pm 0.009\pm 0.087)\text{%},\\ \mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{0}{\pi }^{+})=(0.728\pm 0.014\pm 0.027\pm 0.326)\text{%},\\ \mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{0}{K}^{+})=(0.049\pm 0.007\pm 0.003\pm 0.022)\text{%},\end{array}$ where the third uncertainties are from $\mathcal{B}({\Xi }_{c}^{+}\to {\Xi }^{-}{\pi }^{+}{\pi }^{+})$.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS2010

An Assessment of Cumulative Axial and Torsional Fatigue in a Cobalt-Base Superalloy

Cumulative fatigue under axial and torsional loading conditions can include both load-order (higMow and low/high) as well as load-type sequence (axial/torsional and torsional/axial) effects. Previously reported experimental studies on a cobalt-base superalloy, Haynes 188 at 538 C, addressed these effects. These studies characterized the cumulative axial and torsional fatigue behavior under high amplitude followed by low amplitude (Kalluri, S. and Bonacuse, P. J., "Cumulative Axial and Torsional Fatigue: An Investigation of Load-Type Sequance Effects," in Multiaxial Fatigue and Deformation: Testing and Prediction, ASTM STP 1387, S. Kalluri, and P. J. Bonacuse, Eds., American Society for Testing and Materials, West Conshohocken, PA, 2000, pp. 281-301) and low amplitude followed by high amplitude (Bonacuse, P. and Kalluri, S. "Sequenced Axial and Torsional Cumulative Fatigue: Low Amplitude Followed by High Amplitude Loading," Biaxial/Multiaxial Fatigue and Fracture, ESIS Publication 31, A. Carpinteri, M. De Freitas, and A. Spagnoli, Eds., Elsevier, New York, 2003, pp. 165-182) conditions. In both studies, experiments with the following four load-type sequences were performed: (a) axial/axial, (b) torsional/torsional, (c) axial/torsional, and (d) torsional/axial. In this paper, the cumulative axial and torsional fatigue data generated in the two previous studies are combined to generate a comprehensive cumulative fatigue database on both the load-order and load-type sequence effects. This comprehensive database is used to examine applicability of the Palmgren-langer-Miner linear damage rule and a nonlinear damage curve approach for Haynes 188 subjected to the load-order and load-type sequencing described above. Summations of life fractions from the experiments are compared to the predictions from both the linear and nonlinear cumulative fatigue damage approaches. The significance of load-order versus load-type sequence effects for axial and torsional loading conditions is discussed. Possible reasons for the observed differences between the computed and observed summations of cycle fractions are rationalized in terms of the observed ever lutions of cyclic axial and shear stress ranges in the cumulative fatigue tests.

Kalluri, Sreeramesh↗
DOE OSTI2021

Visualizing broken symmetry and topological defects in a quantum Hall ferromagnet

The interaction between electrons in graphene under high magnetic fields drives the formation of a rich set of quantum Hall ferromagnetic (QHFM) phases with broken spin or valley symmetry. Visualizing atomic-scale electronic wave functions with scanning tunneling spectroscopy (STS), we resolved microscopic signatures of valley ordering in QHFM phases and spectral features of fractional quantum Hall phases of graphene. At charge neutrality, we observed a field-tuned continuous quantum phase transition from a valley-polarized state to an intervalley coherent state, with a Kekulé distortion of its electronic density. Mapping the valley texture extracted from STS measurements of the Kekulé phase, we could visualize valley skyrmion excitations localized near charged defects. Our techniques can be applied to examine valley-ordered phases and their topological excitations in a wide range of materials.

valley symmetry↗