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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
NASA NTRS2013

Interpreting SBUV Smoothing Errors: an Example Using the Quasi-biennial Oscillation

The Solar Backscattered Ultraviolet (SBUV) observing system consists of a series of instruments that have been measuring both total ozone and the ozone profile since 1970. SBUV measures the profile in the upper stratosphere with a resolution that is adequate to resolve most of the important features of that region. In the lower stratosphere the limited vertical resolution of the SBUV system means that there are components of the profile variability that SBUV cannot measure. The smoothing error, as defined in the optimal estimation retrieval method, describes the components of the profile variability that the SBUV observing system cannot measure. In this paper we provide a simple visual interpretation of the SBUV smoothing error by comparing SBUV ozone anomalies in the lower tropical stratosphere associated with the quasi-biennial oscillation (QBO) to anomalies obtained from the Aura Microwave Limb Sounder (MLS). We describe a methodology for estimating the SBUV smoothing error for monthly zonal mean (mzm) profiles. We construct covariance matrices that describe the statistics of the inter-annual ozone variability using a 6 yr record of Aura MLS and ozonesonde data. We find that the smoothing error is of the order of 1percent between 10 and 1 hPa, increasing up to 15-20 percent in the troposphere and up to 5 percent in the mesosphere. The smoothing error for total ozone columns is small, mostly less than 0.5 percent. We demonstrate that by merging the partial ozone columns from several layers in the lower stratosphere/troposphere into one thick layer, we can minimize the smoothing error. We recommend using the following layer combinations to reduce the smoothing error to about 1 percent: surface to 25 hPa (16 hPa) outside (inside) of the narrow equatorial zone 20 S-20 N.

ozone profile retrievals↗
NASA NTRS1971

Estimation of total ozone from satellite measurements of backscattered ultraviolet earth radiance.

Total ozone is estimated from Nimbus IV satellite measurements of the attenuation of backscattered radiances at wavelengths between 3100 and 3400 A. A measurement of the backscattered radiance at 3800 A, outside the ozone absorption band, is used to determine an equivalent Lambert albedo for the cloud-ground-haze surface viewed by the instrument. The measured relative attenuation at two wavelengths is compared with such values precomputed for a series of standard ozone profiles and corrected for the equivalent Lambert albedo. Total ozone is obtained by interpolation. Two alternative methods are used to assign an equivalent Lambert albedo at the absorbing wavelengths. Total ozone values estimated by these methods are compared with the Dobson (ground-truth) data by linear regression. The available evidence suggests that the true standard error of the satellite data may be 0.015 atm-cm or less for solar zenith angles smaller than 60 deg.

Mateer, C. L.↗
NASA NTRS1977

Electrochemical concentration cell ozonesonde performance evaluation

A large number of electrochemical concentration cell (EDD) ozonesondes were calibrated relative to ultraviolet photometric absorption (254 nm) to determine their precision and accuracy. The average agreement with UV photometry was found to be good, but with considerable variation from one ECC ozonesonde to another. Applying individual calibrations to vertical ozone profiles reduced the systematic differences between ECC ozonesonde total ozone values and Dobson spectrophotometric determinations of the same quantity, but did not improve random differences.

Torres, A. L.↗
NASA NTRS2008

Improving Air Quality Forecasts with AURA Observations

Past studies have identified model initial and boundary conditions as sources of reducible errors in air-quality simulations. In particular, improving the initial condition improves the accuracy of short-term forecasts as it allows for the impact of local emissions to be realized by the model and improving boundary conditions improves long range transport through the model domain, especially in recirculating anticyclones. During the August 2006 period, we use AURA/OMI ozone measurements along with MODIS and CALIPSO aerosol observations to improve the initial and boundary conditions of ozone and Particulate Matter. Assessment of the model by comparison of the control run and satellite assimilation run to the IONS06 network of ozonesonde observations, which comprise the densest ozone sounding campaign ever conducted in North America, to AURA/TES ozone profile measurements, and to the EPA ground network of ozone and PM measurements will show significant improvement in the CMAQ calculations that use AURA initial and boundary conditions. Further analyses of lightning occurrences from ground and satellite observations and AURA/OMI NO2 column abundances will identify the lightning NOx signal evident in OMI measurements and suggest pathways for incorporating the lightning and NO2 data into the CMAQ simulations.

Newchurch, M. J.↗
NASA NTRSDate not supplied

Developing A Continuous Ozone Record Through the SAGE and Aura Missions With NASA Reanalysis Products

During the last quarter of the 20th century, the Stratospheric Aerosol and Gas Experiment (SAGE) missions were crucial in monitoring the loss and the subsequent recovery of the stratospheric ozone layer. Due to the employed solar occultation and self-calibration method, the SAGE monitors have produced stable data throughout the lifetime of each instrument. However, over ten years passed between the end of the SAGE II and SAGE III/M3M missions in 2005 and the launch of SAGE III/ISS instrument in 2017, leaving a gap in the data that much be bridged in order to assess the trends in the ozone record. Reanalysis products, such as the Modern-Era Retrospective analysis for Research and Applications, version 2 (MERRA-2), are attractive candidates for trend analysis due to the statistically optimized combination of multiple observing systems and the regular temporal and spatial coverage. In this study, we explore using the SAGE records to develop a stable reanalysis data product, suitable for trend analysis, from the start of the SAGE II record in 1984 through the present. Changes in the assimilated observation systems can introduce discontinuities within the MERRA-2 ozone record, such as in 2004 when the MERRA-2 system shifted from assimilating ozone retrievals collected by SBUV instruments to those collected by instruments onboard the Aura satellite. We follow the radiative transfer procedure outlined by Wargan et al. (2018) to address discontinuities in the MERRA-2 ozone dataset at the 2004 transition and during the Aura record. SAGE II ozone profiles are used to address discontinuities in upper stratospheric ozone associated with changes in the MERRA-2 meteorological observing system in 1998 and 1995. Lastly, we will use the resulting bias-corrected MERRA-2 ozone fields to assess the relative performance of the data from different SAGE sensors.

SAGE↗
NASA NTRSDate not supplied

Developing A Continuous Ozone Record Through the SAGE and Aura Missions With NASA Reanalysis Products

During the last quarter of the 20th century, the Stratospheric Aerosol and Gas Experiment (SAGE) missions were crucial in monitoring the loss and subsequent recovery of the stratospheric ozone layer. Due to the employed solar occultation and self-calibration method, the SAGE monitors have produced stable data throughout the lifetime of each instrument. However, over ten years passed between the end of the SAGE II and SAGE III/M3M missions in 2005 and the launch of SAGE III/ISS instrument in 2017, leaving a gap in the data that must be bridged in order to assess trends in the ozone record. The Modern-Era Retrospective analysis for Research and Applications, version 2 (MERRA-2) reanalysis product, with output available starting in 1980, is an attractive candidate for trend analysis due to the statistically optimized combination of multiple observing systems and the regular temporal and spatial coverage. However, changes in the assimilated observation systems can introduce discontinuities within the MERRA-2 ozone record, such as in 2004 when the MERRA-2 system shifted from assimilating ozone retrievals collected by SBUV instruments to those collected by instruments onboard the Aura satellite. In this study, we explore using the SAGE II record as a transfer function to develop a stable reanalysis data product, suitable for trend analysis, from the start of the SAGE II record in 1984 through the present. We follow the procedure outlined by Wargan et al. (2018) to address discontinuities in the MERRA-2 ozone dataset at the 2004 transition and during the Aura record. SAGE II ozone profiles are used to correct discontinuities in upper stratospheric ozone associated with changes in the MERRA-2 meteorological observing system in 1998 and 1995. We will then assess the relative performance of the data from different SAGE sensors using the resulting bias-corrected MERRA-2 ozone fields.

Pamela Wales↗
NASA NTRSDate not supplied

Upping the TEMPO on Air Pollution Observations from Space for Enhanced Science Applications

The Tropospheric Emissions: Monitoring of Pollution (TEMPO) mission was launched into Geostationary Earth Orbit (GEO) to 91°W longitude on April 7, 2023, and had a successful First Light period from July 31 – August 2 where the first hourly daytime scans across the TEMPO Field of Regard (FoR) covering greater North America were performed. First light images of nitrogen dioxide (NO2) were released to the public on August 24. In addition to NO2, TEMPO will provide hourly daytime observations of formaldehyde (HCHO), sulfur dioxide (SO2), ozone (O3), bromine (BrO), water vapor (H2O), and aerosols, at high spatial resolution (~2.0 x 4.75 km2) across the FoR. The hyperspectral ultraviolet-to-visible measurements from the TEMPO imaging grating spectrometer will permit an ozone profile retrieval capable of monitoring the diurnal evolution of ozone in the planetary boundary layer. The non-standard or special scan operations of TEMPO at sub-hourly frequency (e.g., 2-10 minutes) over selected slices of the FoR will further enhance monitoring capabilities during air quality disasters (e.g., wildfires, volcanic eruptions, dust storms, industrial accidents), research studies, and field campaign operations. A large diversity of stakeholders and end-users have been engaged in the TEMPO Early Adopters Program, supported by the NASA Applied Sciences Program, which aims to enhance health and air quality applications and maximize the societal benefit of TEMPO data when operational data becomes publicly available in the spring of 2024. Key outcomes from the Early Adopters Program include the pre-launch use of TEMPO proxy data to prepare the community for operational data, tailoring the data dissemination and visualization tools for the mission based on user needs, and enhancing the TEMPO special operations component of the mission through early adopter studies. This presentation will provide the latest TEMPO mission and Early Adopters Program updates, initiatives from the TEMPO special operations, and early demonstrations of science applications enabled through TEMPO data, while also showcasing the First Light imagery.

Air Quality↗
NASA NTRS2012

Classification of Ascension Island and Natal Ozonesondes Using Self-Organizing Maps

Ozone profiles from balloon-borne ozonesondes are used for development of satellite algorithms and in chemistry-climate model initialization, assimilation and evaluation. An important issue in the application of these profiles is how best to treat variations where varying photochemical and dynamical influences can cause the ozone mixing ratio in the tropospheric segments of the profile to change by of a factor of 2-3 within a day. Clustering techniques are an ideal way to approach the statistical classification of profile data and we apply self-organizing maps to tropical tropospheric SHADOZ data, hypothesizing that the data will sort according to various influences on ozone, namely anthropogenic sources like biomass burning, meteorological conditions, and stratospheric or extra-tropical intrusions. Self-organizing maps, that use a learning algorithm to reveal the most prominent features of a data set according to a specified number of clusters, have been determined for the 1998-2009 SHADOZ profiles over Ascension Island (512 profiles, 7.98 deg. S, 14.42 deg. W) and Natal, Brazil (425 profiles, 5.42degS, 35.38degW). The 2 × 2 self-organizing map, which creates 4 clusters, reveals that deviations from the average ozone in the free troposphere include both increased ozone resulting from seasonal biomass burning in Africa and locally reduced ozone brought about by convective lifting of unpolluted boundary-layer air. Expanding to a 4 × 4 self-organizing map shows how biomass burning influences the yearly cycle of tropospheric ozone at Ascension Island and captures the seasonality of ozone at both Ascension Island and Natal. Comparing Ascension Island and Natal using a 4 × 4 self-organizing map at each site reveals similarities in mid-tropospheric ozone, but shows differences in lower-tropospheric ozone due to Ascension Island being closer to African biomass burning and more affected by descent from the mean Walker circulation, with less convective activity, than Natal.

algorithms↗
NASA NTRS2002

Looking at Ozone From a New Angle: Shuttle Ozone Limb Sounding Experiment-2 (SOLSE-2)

The ozone layer above Earth is our planet's fragile sunscreen, protecting people, vegetation, and wildlife. NASA has been measuring ozone for more than 20 years by looking down, but SOLSE-2 will show that more information is available by looking at ozone from the side, at Earth's limb or atmospheric boundary. When the ozone layer is compromised, increased ultraviolet (UV) levels from the sun cause health problems ranging from severe sunburns to skin cancer and cataracts. A concerted global effort has been made to reduce or eliminate the production of chemicals that deplete ozone, but the ozone layer is not expected to recover for many decades because these chemicals can remain active in the atmosphere for up to 100 years. We know now that ozone monitoring needs to be focused in the lower stratosphere. The discovery of the ozone hole in 1985 demonstrated that very large changes in ozone were occurring in the lower stratosphere near 20 km, instead of the upper stratosphere as first expected, and where current ozone instruments are focused. Measuring ozone from a tangential perspective that is centered at the limb provides ozone profiles concentrated in the lower stratosphere. The first flight of SOLSE proved that this technique achieves the accuracy and coverage of traditional measurements, and surpasses the altitude resolution and depth of retrieval of conventional techniques. Results from the first flight convinced the science community to design the next generation ozone monitoring satellite based on SOLSE. The Ozone Mapping and Profiling Suite (OMPS) is currently being built for the NPOESS satellite. The primary objective of SOLSE-2 is to confirm the promising results of the first flight over a wider range of viewing conditions and spectral wavelengths. Sometimes a really hard problem can be solved when you look at it from a different angle! While scientists conduct research, protect yourself by observing the UV index and spend less unprotected time outdoors.

McPeters, Richard↗
NASA NTRS2004

AROTAL Ozone and Temperature Vertical Profile Measurements from the NASA DC-8 during the SOLVE II Campaign

The AROTAL instrument (Airborne Raman Ozone Temperature and Aerosol Lidar) - a collaboration between scientists at NASA Goddard Space Flight Center, and Langley Research Center - was flown on the NASA DC-8 during the SOLVE II Campaign during January and February, 2003. The flights were flown from the Arena Arctica in Kiruna, Sweden. We report measurements of temperature and ozone profiles showing approximately a 600 ppbv loss in ozone near 17.5 km, over the time frame of the aircraft campaign. Comparisons of ozone profiles from AROTAL are made with the SAGE III instrument.

McGee, Thomas J.↗
NASA NTRS1974

Behavior of atmospheric ozone determined from Nimbus satellite backscatter ultraviolet data

A substantial global data base on the spatial and temporal variations of high level atmospheric ozone distribution and total ozone amount for the time period 1970 through 1973 was obtained by the Backscatter Ultraviolet (BUV) instrument onboard the Nimbus 4 satellite. BUV total ozone data from all available orbits on each day of the period were processed to obtain zonal mean ozone amounts. Northern Hemisphere ozone and Southern Hemisphere ozone values are given, and the interhemispheric relationships identified. Vertical ozone profile information is interpreted to furnish data on seasonal total ozone changes. Selected ozone mixing ratio cross sections were analyzed, and the resulting zonally-symmetric patterns are presented.

Krueger, A. J.↗
NASA NTRS1986

Wavelength dependence of aerosol backscatter coefficients obtained by multiple wavelength Lidar measurements

Aerosols are often classified into several general types according to their origins and composition, such as maritime, continental, and stratospheric aerosols, and these aerosol types generally have different characteristics in chemical and physical properties. The present study aims at demonstrating the potential for distinguishing these aerosol types by the wavelength dependence of their backscatter coefficients obtained from quantitative analyses of multiple wavelength lidar signals. Data from the NASA Airborne Differential Abosrption lidar (DIAL) S ystems, which can measure aerosol backscatter profiles at wavelenghts of 300, 600, and 1064 nm and ozone profiles of backscatter coefficients for these three wavelength were derived from the observations of aerosols of different types. Observations were performed over the Atlantic Ocean, the Southwestern United States, and French Guyana.

Sasano, Y.↗
NASA NTRS1992

Buffering of stratospheric circulation by changing amounts of tropical ozone - A Pinatubo case study

Stratospheric aerosol from Mount Pinatubo heated the tropical lower stratosphere by about 0.3 K/day mainly due to absorption of terrestrial infrared radiation. This heating was dissipated by: (1) an observed increase in stratospheric temperatures, which enhanced the radiation cooling; (2) additional mean upward motion, observed for the aerosol cloud, which led to adiabatic cooling; and (3) reductions in ozone concentrations resulting from enhanced upward motions. Each of these processes operated on a different time scale: maximum temperatures were observed after about 90 days; maximum ozone losses of about -1.5 ppm occurred after 140 days when the enhanced vertical velocities effectively lifted the ozone profile by about 2 km. We believe this shows that ozone plays an important role in buffering vertical motion in the tropical lower stratosphere, and hence the residual Brewer Dobson circulation of the whole stratosphere.

Kinne, S.↗
NASA NTRS2002

Derivation of Tropospheric Column Ozone from the EPTOMS/GOES Co-Located Data Sets using the Cloud Slicing Technique

A recently developed technique called cloud slicing used for deriving upper tropospheric ozone from the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) instrument combined together with temperature-humidity and infrared radiometer (THIR) is no longer applicable to the Earth Probe TOMS (EPTOMS) because EPTOMS does not have an instrument to measure cloud top temperatures. For continuing monitoring of tropospheric ozone between 200-500hPa and testing the feasibility of this technique across spacecrafts, EPTOMS data are co-located in time and space with the Geostationary Operational Environmental Satellite (GOES)-8 infrared data for 2001 and early 2002, covering most of North and South America (45S-45N and 120W-30W). The maximum column amounts for the mid-latitudinal sites of the northern hemisphere are found in the March-May season. For the mid-latitudinal sites of the southern hemisphere, the highest column amounts are found in the September-November season, although overall seasonal variability is smaller than those of the northern hemisphere. The tropical sites show the weakest seasonal variability compared to higher latitudes. The derived results for selected sites are cross validated qualitatively with the seasonality of ozonesonde observations and the results from THIR analyses over the 1979-1984 time period due to the lack of available ozonesonde measurements to study sites for 2001. These comparisons show a reasonably good agreement among THIR, ozonesonde observations, and cloud slicing-derived column ozone. With very limited co-located EPTOMS/GOES data sets, the cloud slicing technique is still viable to derive the upper tropospheric column ozone. Two new variant approaches, High-Low (HL) cloud slicing and ozone profile derivation from cloud slicing are introduced to estimate column ozone amounts using the entire cloud information in the troposphere.

Ahn, C.↗
NASA NTRS2021

Residual Temperature Bias Effects in Stratospheric Species Distributions from LIMS

The Nimbus 7 Limb Infrared Monitor of theStratosphere (LIMS) instrument operated from 25 Octo-ber 1978 through 28 May 1979. Its version 6 (V6) profileswere processed and archived in 2002. We present severaldiagnostic examples of the quality of the V6 stratospheric species distributions based on their level 3 zonal Fourier co-efficient products. In particular, we show that there are smalldifferences in the ascending (A) minus descending (D) or-bital temperature–pressure orT(p) profiles (theirA−Dval-ues) that affect (A−D) species values. SystematicA−Dbi-ases inT(p) can arise from small radiance biases and/or fromviewing anomalies along orbits. There can also be (A−D)differences inT(p) due to not resolving and correcting forall of the atmospheric temperature gradient along LIMS tan-gent view-paths. An error inT(p) affects species retrievalsthrough (1) the Planck blackbody function in forward calcu-lations of limb radiance that are part of the iterative retrievalalgorithm of LIMS, and (2) the registration of the measuredLIMS species radiance profiles in pressure altitude, mainlyfor the lower stratosphere. There are clearA−Ddifferencesfor ozone, H2O, and HNO3but not for NO2. Percentage differences are larger in the lower stratosphere for ozone andH2O because those species are optically thick. We evaluateV6 ozone profile biases in the upper stratosphere with the aid of comparisons against a monthly climatology of UV–ozone soundings from rocketsondes. We also provide resultsof time series analyses of V6 ozone, H2O, and potential vor-ticity for the middle stratosphere to show that their average(A+D) V6 level 3 products provide a clear picture of the evolution of those tracers during Northern Hemisphere win-ter. We recommend that researchers use the average V6 level3 product for their science studies of stratospheric ozone andH2O, while keeping in mind that there are uncorrected non-local thermodynamic equilibrium effects in daytime ozone inthe lower mesosphere and in daytime H2O in the uppermoststratosphere. We also point out that the present-day Soundingof the Atmosphere using Broadband Emission Radiometry(SABER) experiment provides measurements and retrievalsof temperature and ozone that are nearly free of anomalousdiurnal variations and of effects from gradients at low and middle latitudes.

Ellis Remsberg↗
NASA NTRS1991

The use of satellite data to determine the distribution of ozone in the troposphere

Measurements from two independent satellite data sets have been used to derive the climatology of the integrated amount of ozone in the troposphere. These data have led to the finding that large amounts of ozone pollution are generated by anthropogenic activity originating from both the industrialized regions of the Northern Hemisphere and from the southern tropical regions of Africa. To verify the existence of this ozone anomaly at low latitudes, an ozonesonde capability has been established at Ascension Island (8 deg S, 15 deg W) since July 1990. According to the satellite analyses, Ascension Island is located downwind of the primary source region of this ozone pollution, which likely results from the photochemical oxidation of emissions emanating from the widespread burning of savannas and other biomass. These in situ measurements confirm the existence of large amounts of ozone in the lower atmosphere. A summary of these ozonesonde data to date will be presented. In addition, we will present some ozone profile measurements from SAGE II which can be used to provide upper tropospheric ozone measurements directly in the tropical troposphere. A preliminary comparison between the satellite observations and the ozonesonde profiles in the upper troposphere and lower stratosphere will also be presented.

Fishman, Jack↗
NASA NTRS2008

Evaluation of Near-Tropopause Ozone Distributions in the Global Modeling Initiative Combined Stratosphere/Troposphere Model with Ozonesonde Data

The NASA Global Modeling Initiative has developed a combined stratosphere/troposphere chemistry and transport model which fully represents the processes governing atmospheric composition near the tropopause. We evaluate model ozone distributions near the tropopause, using two high vertical resolution monthly mean ozone profile climatologies constructed with ozonesonde data, one by averaging on pressure levels and the other relative to the thermal tropopause. Model ozone is high biased at the SH tropical and NH midlatitude tropopause by approx. 45% in a 4 deg. latitude x 5 deg. longitude model simulation. Increasing the resolution to 2 deg. x 2.5 deg. increases the NH tropopause high bias to approx. 60%, but decreases the tropical tropopause bias to approx. 30%, an effect of a better-resolved residual circulation. The tropopause ozone biases appear not to be due to an overly vigorous residual circulation or excessive stratosphere/troposphere exchange, but are more likely due to insufficient vertical resolution or excessive vertical diffusion near the tropopause. In the upper troposphere and lower stratosphere, model/measurement intercomparisons are strongly affected by the averaging technique. NH and tropical mean model lower stratospheric biases are less than 20%. In the upper troposphere, the 2 deg. x 2.5 deg. simulation exhibits mean high biases of approx. 20% and approx. 35% during April in the tropics and NH midlatitudes, respectively, compared to the pressure averaged climatology. However, relative-to-tropopause averaging produces upper troposphere high biases of approx. 30% and 70% in the tropics and NH midlatitudes. This is because relative-to-tropopause averaging better preserves large cross-tropopause O3 gradients, which are seen in the daily sonde data, but not in daily model profiles. The relative annual cycle of ozone near the tropopause is reproduced very well in the model Northern Hemisphere midlatitudes. In the tropics, the model amplitude of the near tropopause annual cycle is weak. This is likely due to the annual amplitude of mean vertical upwelling near the tropopause, which analysis suggests is approx. 30% weaker than in the real atmosphere.

Considine, David B.↗