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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
NASA NTRS2018

Design, Implementation, and Performance of the Astro-H Soft X-Ray Spectrometer Aperture Assembly and Blocking Filters

The calorimeter array of the JAXA Astro-H (renamed Hitomi) soft x-ray spectrometer (SXS) was designed to provide unprecedented spectral resolution of spatially extended cosmic x-ray sources and of all cosmic x-ray sources in the Fe-K band around 6 keV. The properties that made the SXS array a powerful x-ray spectrometer also made it sensitive to photons from the entire electromagnetic band as well as particles. If characterized as a bolometer, it would have had a noise equivalent power of <4 × 10(exp −18) W/((Hz)(exp 0.5)). Thus, it was imperative to shield the detector from thermal radiation from the instrument and optical and UV photons from the sky. In addition, it was necessary to shield the coldest stages of the instrument from the thermal radiation emanating from the warmer stages. These needs were addressed by a series of five thin-film radiation-blocking filters, anchored to the nested temperature stages, that blocked long-wavelength radiation while minimizing x-ray attenuation. The aperture assembly was a system of barriers, baffles, filter carriers, and filter mounts that supported the filters and inhibited their potential contamination. The three outer filters also had been equipped with thermometers and heaters for decontamination. We present the requirements, design, implementation, and performance of the SXS aperture assembly and blocking filters.

Kilbourne, Caroline A.↗
DOE OSTI2019

Highly active thermally stable nanoporous gold catalyst

In one embodiment, a method includes depositing oxide nanoparticles on a nanoporous gold support to form an active structure and functionalizing the deposited oxide nanoparticles. In another embodiment, a system includes a nanoporous gold structure comprising a plurality of ligaments, and a plurality of oxide particles deposited on the nanoporous gold structure; the oxide particles are characterized by a crystalline phase.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Experiment and simulation of high-speed gas jet penetration into a semicircular fluidized bed

This work marks the third in a series of experiments that were in a semi-circular, gas-fluidized bed with side jets. In this work, the particles are (nominally) 1 mm ceramic beads. The bed is operated just at and slightly above and below the minimum fluidization velocity and additional fluidization is provided by two high-speed gas located on the sides of the bed near the flat, front face of the unit. Two primary measurements are taken: high-speed video recording of the front of the bed and bed pressure drop from a tap in the back of the bed. Particle Image Velocimetry (PIV) is used to determine particle motion, characterized as a mean Froude number, from the high-speed video. A CFD-DEM model of the bed is presented using the recently released MFIX-Exa code. Four model subvariants are considered using two methods of representing the jets and two drag models, both of which are calibrated to exactly match the experimentally measured minimum fluidization velocity. Although it is more difficult to determine the jet penetration depths in a straightforward manner as in the previous works using Froude number contours, the CFD-DEM results compare quite well to the PIV measurements, particularly for submodel flow Syam. Unfortunately, the good agreement of the solids-phase is overshadowed by significant disagreement in the gas-phase data. Specifically, the predicted time averaged standard deviation of the pressure drop is found to be over an order of magnitude larger than measured. Due to the low value of the measurements, just 1% of the mean bed pressure drop, it seems possible that the data is in error. On the other hand, the model may not be accurately capturing pressure attenuation through an under-fluidized region in the back of the bed. Without the possibility additional experiments to test the validity of the data, this work is simply being reported “as is” without being able to indicate which, either the simulation or the experiment, is more correct.<br>

Fullmer, William D.↗
DOE OSTI2023

Initial results from electron microscopy from AGR 5/6/7 Capsule 1 fuel and

Initial results from electron microscopy from AGR 5/6/7 Capsule 1 fuel and applications of other microanalysis techniques to irradiated TRISO fuel. Includes detail on characterization of particles from AGR 5/6/7 Capsule 1, which include background and motivation, x-ray computed tomography on four particles from compact 1-7-9, SEM/EDS of particles from compacts 1-7-9 and 1-7-4, and Summary. Local thermal conductivity measurement on AGR-2 particles also discussed.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2023

Highly active thermally stable nanoporous gold catalyst

In one embodiment, a product includes a nanoporous gold structure comprising a plurality of ligaments, and a plurality of oxide particles deposited on the nanoporous gold structure; the oxide particles are characterized by a crystalline phase.

Biener, Juergen↗
NASA NTRS1986

Laser microprobe characterization of C species in Interplanetary Dust Particles (IDP)

Preliminary results of a study whose aim is the characterization of carbon (C) species in microvolumes of materials by means of laser ionization mass spectrometry (LIMS) are presented. The LIMS instrument employs a pulsed UV laser to produce nearly instantaneous vaporization and ionization of materials, followed by acceleration and time-of-flight analysis of the ions produced. LIMS provides a survey technique with nearly simultaneous acquisition of mass spectra covering the entire elemental range. The main limitation of the LIMS technique at present is its limited ability to perform quantitative analysis, due in part to insufficient knowledge of the mechanism of laser-solid interaction. However, considerable effort is now being directed at making LIMS a more quantitative technique. A variety of different C samples, both natural and man made were analyzed to establish the ability of LIMS to differentiate among the various C phases. The results of preliminary analyses performed on meteoritical and interplanetary dust samples are also presented. The C standards selected for the LIMS characterization range from essentially amorphous soot to diamond, which exhibits the highest degree of ordering.

Dibrozolo, F. R.↗
DOE OSTI2018

Synthesis, Spectroscopy, and Magnetic Characterizations of PVP-Assisted Nanoscale Particle

Inverse spinel ferrite of nonmagnetic metal-doped ferro-ferric oxide was synthesized by co-precipitation technique, and its characterizations have been performed by XRD, FTIR, TEM, EDX, VSM, and EPR. XRD figures show the prepared samples in their cubic phase and that their crystallite faces vary from 5.57 to 18.47 nm. FTIR spectra of the as-synthesized samples were performed in the range of 400 and 4000 cm{sup −1} and annealed at 600 {sup ∘}C. The TEM revealed that the syllable construction of the nanoscale particles was agglomerated in their crystalline sample. From VSM study, the sample obtained has a doublet pattern, and ferromagnetic performance was observed from the samples. From EPR spectra, the line shape and the g values obtained for the samples conformed to superparamagnetic resonance due to Mg{sup + 2} ions with a stoichiometric composition. These typical magnetic hypnotic specifications are used for various sensing applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

INBOUND APPOINTEE PUBLICATION Importance of Substrate-Particle Repulsion for Protein-Templated Assembly of Metal Nanoparticles

We study the protein-directed assembly of colloidal gold nanoparticles on de novo designed protein nanofiber templates. Using sequential assembly on glass substrates, we attach of positively-charged gold nanoparticles to protein nanofibers engineered to have a high density of negatively-charged surface residues. Using a combination of electron and optical microscopy, we measure the density of particle attachment and characterize binding specificity. By varying nanoparticle size and pH of the solution, we explore the importance of charge-dependent particle-fiber and particle-substrate interactions. We find an inverse correlation between particle size and attachment density to the protein nanofibers, attributed to the balance between size-dependent electrostatic particle-fiber attraction and particle-substrate repulsion. We show pH-dependent particle attachment density and binding specificity in relation to the protonation fraction of each assembly layer. Finally, we employ hyperspectral scattering microscopy to draw conclusions about particle density and interparticle spacings of optically-observable particle assemblies.

Guye, Kathryn N.↗
DOE OSTI2025

Tomographic assessment of peening for metallurgical bonding in cold spray

It is widely asserted that peening densifies cold spray coatings and improves particle–particle and particle–substrate bonding, yet systematic studies analyzing the evolution of bonding due to peening particle strikes are scarce. We explore peening at the level of individual particle impacts, by creating two-particle Cu-on-Cu stacks using laser-induced particle impact testing. Exploring impact velocities that range from the onset of bonding at the “critical velocity”, V cr , to its peak near 1.4⋅V cr , we perform full 3D tomography of the particle stacks to characterize the bonding state at the particle-substrate interface. Direct labeling of non-bonded patches and the total particle-substrate interface permits quantification and comparison of bonding in single impacts with bonding after subsequent impacts to reveal the origins of the peening effect. The data reveal a surprising finding: although a second impact directly atop the first particle increases the area of the particle-substrate interface (~40% area increase), there is no improvement in metallurgical bonding. Analysis of these data suggest that not only area expansion (and associated oxide rarefication), but also stress-induced extrusion of metal at that interface needs to occur to achieve metal-on-metal contact to see an enhancement in bonding. Furthermore, our analysis suggests that the subsequent impacting particle needs to have ~70% more kinetic energy to produce additional bonding; this implies that particle and velocity distributions within a spray may be helpful, and that peening may rely on unaligned impacts.

Bonding↗
DOE OSTI2025

AERO-MAP: a data compilation and modeling approach to understand spatial variability in fine- and coarse-mode aerosol composition

Abstract. Aerosol particles are an important part of the Earth climate system, and their concentrations are spatially and temporally heterogeneous, as well as being variable in size and composition. Particles can interact with incoming solar radiation and outgoing longwave radiation, change cloud properties, affect photochemistry, impact surface air quality, change the albedo of snow and ice, and modulate carbon dioxide uptake by the land and ocean. High particulate matter concentrations at the surface represent an important public health hazard. There are substantial data sets describing aerosol particles in the literature or in public health databases, but they have not been compiled for easy use by the climate and air quality modeling community. Here, we present a new compilation of PM2.5 and PM10 surface observations, including measurements of aerosol composition, focusing on the spatial variability across different observational stations. Climate modelers are constantly looking for multiple independent lines of evidence to verify their models, and in situ surface concentration measurements, taken at the level of human settlement, present a valuable source of information about aerosols and their human impacts complementarily to the column averages or integrals often retrieved from satellites. We demonstrate a method for comparing the data sets to outputs from global climate models that are the basis for projections of future climate and large-scale aerosol transport patterns that influence local air quality. Annual trends and seasonal cycles are discussed briefly and are included in the compilation. Overall, most of the planet or even the land fraction does not have sufficient observations of surface concentrations – and, especially, particle composition – to characterize and understand the current distribution of particles. Climate models without ammonium nitrate aerosols omit ∼ 10 % of the globally averaged surface concentration of aerosol particles in both PM2.5 and PM10 size fractions, with up to 50 % of the surface concentrations not being included in some regions. In these regions, climate model aerosol forcing projections are likely to be incorrect as they do not include important trends in short-lived climate forcers.

Mahowald, Natalie M. (ORCID:000000022873997X)↗
DOE OSTI2025

Gain characterization of LGAD sensors with beta particles and 28-MeV protons

Low Gain Avalanche Diodes, also known as LGADs, are widely considered for fast-timing applications in high energy physics, nuclear physics, space science, medical imaging, and precision measurements of rare processes. Such devices are silicon-based and feature an intrinsic gain due to a p + -doped layer that allows the production of a controlled avalanche of carriers, with multiplication on the order of 10–100. This technology can provide time resolution on the order of 20–30 ps, and variants of this technology can provide precision tracking too. The characterization of LGAD performance has so far primarily been focused on the interaction of minimum ionizing particles for high energy and nuclear physics applications. This article expands the study of LGAD performance to highly-ionizing particles, such as 28-MeV protons, which are relevant for several future scientific applications, e.g. in biology and medical physics, among others. These studies were performed with a beam of 28-MeV protons from a tandem Van de Graaff accelerator at Brookhaven National Laboratory and beta particles from a ^90Sr source; these were used to characterize the response and the gain of an LGAD as a function of bias voltage and collected charge. Here, the experimental results are also compared to TCAD simulations.

47 OTHER INSTRUMENTATION↗
DOE OSTI2020

Classical gravitational scattering at $\mathcal{O}(G^3)$ from Feynman diagrams

We perform a Feynman diagram calculation of the two-loop scattering amplitude for gravitationally interacting massive particles in the classical limit. Conveniently, we are able to sidestep the most taxing diagrams by exploiting the test-particle limit in which the system is fully characterized by a particle propagating in a Schwarzschild spacetime. We assume a general choice of graviton field basis and gauge fixing that contains as a subset the well-known deDonder gauge and its various cousins. As a highly nontrivial consistency check, all gauge parameters evaporate from the final answer. Moreover, our result exactly matches that of Bern et al., here verified up to sixth post-Newtonian order while also reproducing the same unique velocity resummation at third post-Minkowksian order.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2023

Symmetry and scaling in one-dimensional compressible two-phase flow

Investigations of shock compression of heterogeneous materials often focus on the shock front width and overall profile. The number of experiments required to fully characterize the dynamic response of a material often belie the structure–property relationships governing these aspects of a shock wave. Recent observations measured a pronounced shock-front width on the order of 10 s of ns in particulate composites. We focus on particulate composites with disparate densities and investigate whether the mechanical interactions between the phases are adequate to describe this emergent behavior. The analysis proceeds with a general Mie–Grüneisen equation of state for the matrix material, a general drag force law with general power-law scaling for the particle-matrix coupling of the phases, and a volume fraction-dependent viscosity. Lie group analysis is applied to one-dimensional hydrodynamic flow equations for the self-consistent interaction of particles embedded in a matrix material. The particle phase is characterized by a particle size and volume fraction. The Lie group analysis results in self-similar solutions reflecting the symmetries of the flow. The symmetries lead to well-defined scaling laws, which may be used to characterize the propagation of shock waves in particle composites. An example of the derived scaling laws for shock attenuation and rise time is shown for experimental data on shock-driven tungsten-loaded polymers. A key result of the Lie analysis is that there is a relationship between the exponents characterizing the form of the drag force and the exponent characterizing the shock velocity and its attenuation in a particulate composite. Comparison to recent experiments results in a single exponent that corresponds to a conventional drag force.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2001

Studies of Fundamental Particle Dynamics in Microgravity

This work summarizes theoretical and experimental concepts used to design the flight experiment mission for SHIVA - Spaceflight Holography Investigation in a Virtual Apparatus. SHIVA is a NASA project that exploits a unique, holography-based, diagnostics tool to understand the behavior of small particles subjected to transient accelerations. The flight experiments are designed for testing model equations, measuring g, g-jitter, and other microgravity phenomena. Data collection will also include experiments lying outside of the realm of existing theory. The regime under scrutiny is the low Reynolds number, Stokes regime or creeping flow, which covers particles and bubbles moving at very low velocity. The equations describing this important regime have been under development and investigation for over 100 years and yet a complete analytical solution of the general equation had remained elusive yielding only approximations and numerical solutions. In the course of the ongoing NASA NRA, the first analytical solution of the general equation was produced by members of the investigator team using the mathematics of fractional derivatives. This opened the way to an even more insightful and important investigation of the phenomena in microgravity. Recent results include interacting particles, particle-wall interactions, bubbles, and Reynolds numbers larger than unity. The Space Station provides an ideal environment for SHIVA. Limited ground experiments have already confirmed some aspects of the theory. In general the space environment is required for the overall experiment, especially for cases containing very heavy particles, very light particles, bubbles, collections of particles and for characterization of the space environment and its effect on particle experiments. Lightweight particles and bubbles typically rise too fast in a gravitational field and heavy particles sink too fast. In a microgravity environment, heavy and light particles can be studied side-by-side for long periods of time.

Rangel, Roger↗
NASA NTRS2016

Accurately Characterizing the Importance of Wave-Particle Interactions in Radiation Belt Dynamics: The Pitfalls of Statistical Wave Representations

Wave-particle interactions play a crucial role in energetic particle dynamics in the Earths radiation belts. However, the relative importance of different wave modes in these dynamics is poorly understood. Typically, this is assessed during geomagnetic storms using statistically averaged empirical wave models as a function of geomagnetic activity in advanced radiation belt simulations. However, statistical averages poorly characterize extreme events such as geomagnetic storms in that storm-time ultralow frequency wave power is typically larger than that derived over a solar cycle and Kp is a poor proxy for storm-time wave power.

Murphy, Kyle R.↗
NASA NTRS1994

Latex samples for RAMSES electrophoresis experiment on IML 2

The objectives of these reported studies were to provide ground based support services for the flight experiment team for the RAMSES experiment to be flown aboard IML-2. The specific areas of support included consultation on the performance of particle based electrophoresis studies, development of methods for the preparation of suitable samples for the flight hardware, the screening of particles to obtain suitable candidates for the flight experiment, and the electrophoretic characterization of sample particle preparations. The first phases of these studies were performed under this contract, while the follow on work was performed under grant number NAG8 1081, 'Preparation and Characterization of Latex Samples for RAMSES Experiment on IML 2.' During this first phase of the experiment the following benchmarks were achieved: Methods were tested for the concentration and resuspension of latex samples in the greater than 0.4 micron diameter range to provide moderately high solids content samples free of particle aggregation which interferred with the normal functioning of the RAMSES hardware. Various candidate latex preparations were screened and two candidate types of latex were identified for use in the flight experiments, carboxylate modified latex (CML) and acrylic acid-acrylamide modified latex (AAM). These latexes have relatively hydrophilic surfaces, are not prone to aggregate, and display sufficiently low electrophoretic mobilities in the flight buffer so that they can be used to make mixtures to test the resolving power of the flight hardware.

Seaman, Geoffrey V. F.↗
DOE OSTI2020

Design and Characterization of a Phonon-Mediated Cryogenic Particle Detector with an eV-Scale Threshold and 100 keV-Scale Dynamic Range

We present the design and characterization of a cryogenic phonon-sensitive Si detector exploiting the Neganov-Trofimov-Luke effect to detect single-charge excitations. This device achieved 2.65(2) eV phonon energy resolution when operated without a voltage bias across the crystal and a corresponding charge resolution of 0.03 electron-hole pairs at 100 V bias. With a continuous-readout data acquisition system and an offline optimum-filter trigger, we obtain a 9.2 eV threshold with a trigger rate of the order of 20 Hz. The detector's energy scale is calibrated up to 120 keV using an energy estimator based on the pulse area. The high performance of this device allows its application to different fields where excellent energy resolution, low threshold, and large dynamic range are required, including dark matter searches, precision measurements of coherent neutrino-nucleus scattering, and ionization yield measurements.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

Design and characterization of a phonon-mediated cryogenic particle detector with an eV-scale threshold and 100 keV-scale dynamic range

We present the design and characterization of a cryogenic phonon-sensitive Si detector exploiting the Neganov-Tromov-Luke effect to detect single-charge excitations. This device achieved 2.65(2) eV phonon energy resolution when operated without a voltage bias across the crystal and a corresponding charge resolution of 0.03 electron-hole pairs at 100 V bias. With a continuous-readout data acquisition system and an oine optimum-filter trigger, we obtain a 9.2 eV threshold with a trigger rate of the order of 20 Hz. The detector's energy scale is calibrated up to 120 keV using an energy estimator based on the pulse area. The high performance of this device allows its application to different fields where excellent energy resolution, low threshold, and large dynamic range are required, including dark matter searches, precision measurements of coherent neutrino-nucleus scattering, and ionization yield measurements.

Ren, R↗