Mass-spectrometry
Mass spectrometric analyses of meteoritic and lunar samples containing lead and thallium
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Mass spectrometric analyses of meteoritic and lunar samples containing lead and thallium
Valeraldehyde o-nitrophenylhydrazone mass spectrum with low intensity peak due to combined hydroxyl and water loss from molecular ion
Synthesized amino esters and ketones with varying distance between functionalities, examining mass spectral fragmentation
Mass spectral properties of alkoxycyclohexanol trimethylsilyl ethers and alkoxycyclohexyl trimethylsilanes, using deuterium labeling
Real time high resolution mass spectroscopy using digital computer techniques for data acquisition, processing and presentation
Modulated molecular beam mass and phase spectroscopy applications in hot oxygen radiative attachment, crossed beam chemical kinetics and neutrals clustering in free jets
Surface state energy positions determination in high-energy gap semiconductors by photovoltage spectral distribution
Prebiotic organic matter in solar system, investigating contamination free amino acid catalytic synthesis from deuterated reactants
Apollo 12 lunar surface samples analysis for organic compounds by mass spectroscopy and pyrolysis-gas chromatography
During the Gemini 5 mission, 26 spectrographic observations on various cloud types were obtained using the oxygen A band (7600 A). An example of the types of spectrum and photograph involved represents a cloud in the intertropical convergence zone. Densitometer traces of the spectra of three types of clouds (high, medium, and low) are shown. It was apparent qualitatively that radiation transmission in the oxygen band for a high cloud was much greater than that for a low cloud. The results proved the feasibility of cloud altitude measurements from a spacecraft by this method.
Infrared radiance measurements from geological materials were studied. These involved laboratory and field spectroscopic measurements, both on the ground and airborne. A proven, feasible system is presented for airborne use over terrains with minimal vegetation. It has been shown that the spectral emittance concepts can be utilized in emittance ratio imagery which depicts the silicate composition of the terrain.
The construction of the Stanford Spectral Digital Data Acquisition System is described. The objective of the system is to record both the spectral distribution of incoming radiation from the rock samples measured by the spectroradiometer (Exotech Model 10-34 Circular Variable Filter Infrared Spectroradiometer) together with other weather information. This system is designed for both laboratory and field measurement programs. The multichannel inputs (8 channels) of the system are as follows: Ch 1 the Spectro-radiometer, Ch 2 the radiometer (PRT-5), and Ch 3 to Ch 8 for the weather information. The system records data from channel 1 and channel 2 alternately for 48 times, before a fast sweep across the six weather channels, to form a single scan in the scan counter. The operation is illustrated in a block diagram, and the theory of operation is described. The outputs are written on a 7-track magnetic tape with IBM compatible form. The format of the tape and the playback computer programs are included. The micro-pac digital modules and a CIPHER model 70 tape recorder (Cipher Data Products) are used. One of the major characteristics of this system is that it is externally clocked by the spectroradiometer instead of taking data at intervals of various wavelengths by using internal-clocking.
Concentrations of primordial radioelements and of cosmogenic radionuclides in crystalline rocks, breccias, and soils from the Ocean of Storms were determined. Concentrations of K, Th, U, Al-26, and Na-22 were determined for seven clastic or brecciated rocks, three sieved samples of fines, and one composite sample of sawdust from the cutting of a fragmental rock, all from samples obtained on the Apollo 14 mission. The K, Th, and U concentrations and cogmogenic radionuclide abundances in rocks and soils from Apollo 15 are also discussed.
The use of interactive graphics is presented as an attractive method for performing multi-parameter data analysis of proton recoil distributions to determine neutron spectra. Interactive graphics allows the user to view results on-line as the program is running and to maintain maximum control over the path along which the calculation will proceed. Other advantages include less time to obtain results and freedom from handling paper tapes and IBM cards.
Basic nitrogenous compounds isolated from extracts of Green River Formation oil shale were analyzed. The major homologous constituents found were the compositional types - namely, quinolines, tetrahydrequinolines with minor amounts of pyridines and indoles series and traces of more aromatized nitrogen compounds. These results are correlated with nitrogen compounds isolated from Green River Formation retort oil and are a survey of the unaltered nitrogen compounds indigeneous to the shale.
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Methods for infrared radiance measurements from geological materials were studied for airborne use over terrains with minimal vegetation. The tasks of the investigation were: (1) calculation of emittance ratios, (2) comparison of IR spectral emittance data with K-band scatterometer data over Pisgah Crater, and (3) standard infrared spectral file. Published papers reporting the research are included.
Experimental tests were made to determine whether analysis of volatile metabolic products, formed in situ, is a viable procedure for an extraterrestrial life detection system. Laboratory experiments, carried out under anaerobic conditions with addition of carbon source, extended to include a variety of soils and additional substrates. In situ experiments were conducted without amendment using a vacuum sampling system.