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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

Pseudo–Jahn–Teller Distortion in a One-Dimensional π-Conjugated Polymer

Structural distortions in low-dimensional π-conjugated systems profoundly influence their electronic properties, but the control of such behavior in laterally extended systems remains challenging. Here, in this study, we demonstrate that a one-dimensional conjugated polymer─ poly -(difluorenoheptalene-ethynylene) (PDFHE)─undergoes a pronounced out-of-plane backbone distortion, equivalent to a spontaneous symmetry breaking (SSB) of its mirror symmetry. We synthesized PDFHE on noble metal surfaces and characterized its structure and electronic states using low-temperature scanning tunneling microscopy (STM). Rather than adopting a planar, high-symmetry conformation, PDFHE relaxes into nonplanar isomers stabilized by a pseudo–Jahn–Teller (PJT) distortion having mirror-odd out-of-plane character. The distortion lowers the total energy and increases the band gap, providing a concise rationale for the observed symmetry breaking. Density functional theory calculations corroborate these findings, providing a microscopic explanation for the SSB. Our results show that even in mechanically robust extended π-systems, subtle electron–lattice coupling can spontaneously drive significant structural rearrangements, even in mechanically robust extended π-systems.

conformation↗

Frieze charge-stripes in a correlated kagome superconductor

In kagome metals, geometric frustration, electronic correlations and band topology combine to produce a wide range of intriguing phenomena. Among them, CsCr$_3$Sb$_5$ offers an opportunity to investigate unconventional superconductivity in a strongly correlated kagome system, with indications of frustrated magnetism and quantum criticality. Here, we demonstrate a cascade of density-wave transitions with distinct symmetries in bulk single crystals of CsCr$_3$Sb$_5$. Using spectroscopic imaging scanning tunneling microscopy, we uncover a unidirectional density wave that breaks all mirror symmetries -- resembling a chiral density wave -- but that also retains a mirror glide symmetry. We refer to this as a frieze charge stripe order phase, as its symmetry properties correspond to one of the fundamental frieze symmetry groups. A combination of high-resolution imaging, Fourier analysis and theoretical simulations reveal the key role of sublattice degrees of freedom in stabilizing this phase, characterized by internal chiral textures of opposite handedness. These findings suggest that superconductivity in CsCr$_3$Sb$_5$ emerges from this distinct density wave state and provide fresh insight into realizing electronic phases governed by frieze symmetry groups in quantum materials.

Cheng, Siyu [Boston College, Chestnut Hill, MA (Un↗

High intensity solar irradiation testing of UV optics

The Orbiting Solar Observatory-I (OSO-8 in orbit) incorporates two high resolution solar pointing spectrometers operating from 1000 A to 4000 A. Energy from the sun enters a Cassegrainian telescope and is focused on a slit while the solar disk is scanned to one arc-second resolution. The stability of the secondary mirrors reflectance was of concern since they would be exposed to intense focused solar energy up to 27 suns. A test program was initiated to simulate this energy input on sample UV mirrors of the MgF2 and LiF types and to evaluate their performance after irradiation. Tests were conducted to simulate the solar spectrum at high intensities (25 suns) and at a single wavelength near Lyman-alpha, but with twenty times the solar intensity at Lyman-alpha. Post-test measurements after every exposure were made at wavelengths from 1025 A to 1849 A. After 75 simulated 'orbits', reflectance changes due to temperature effects were noted to be less than 10%. Reductions in reflectance under high intensity solar radiation were generally greater than 10%. Polymerization of surface contaminations on the LiF mirrors reduced reflectances at short wavelengths by 40%.

Greyerbiehl, J. M.↗

Orbital atomic oxygen effects on thermal control and optical materials - STS-8 results

The effects of exposing 23 specimens of optical and thermal control materials to space at 120 km altitude for over 40 hrs during the STS-8 mission are discussed. Ten samples of paint targeted for the Space Telescope (ST) and the Tethered Satellite were exposed, and included polyurethane, oxide, silicone, and glossy black and white samples which were scanned for alterations in the optical properties after being retrieved. Nine mirror-type materials were also investigated, along with silver specimens typical of solar cell interconnects. The oxygen flow at the orbital altitude was 3.5 x 10 to the 20th atoms/cu cm. The exposures caused no degradation of the magnesium fluoride mirror coatings, while the Kapton coating for the ST solar cell panels showed evidence of losing thickness. The Ag solar cell contacts will require coatings to extend their lifetimes. Overcoatings were also proven necessary for inhibiting degradation of painted surfaces.

Whitaker, A. F.↗

Electro-optical Tuning of Fabry-Perot Interferometers

Compact unit operates much faster than conventional piezoelectric scanners. High voltage creates electric field in Pockels cell, changing refractive properties. Cell changes optical path length between mirrors without mechanically moving anything in gap. High voltage varied rapidly to scan interferometer. Voltage applied longitudinally or transversely, depending on type of Pockels cell. New electro-optic scanner scans given range in one-millionth time of piezoelectric scanner - tens to hundreds of nanoseconds per interferometer order. Also reducing size of interferometer.

Schwemmer, G. K.↗

A Near-Infrared Mapping Spectrometer for investigation of Jupiter and its satellites

The Near-Infrared-Mapping Spectrometer (NIMS) is one of the science instruments in the Galileo mission, which will explore Jupiter and its satellites in the mid-1990's. The NIMS experiment will map geological units on the surfaces of the Jovian satellites and characterize their mineral content; and, for the atmosphere of Jupiter, investigate cloud properties and the spatial and temporal variability of molecular abundances. The optics are gold-coated reflective and consist of a telescope and a grating spectrometer. The balance of the instrument includes a 17-detector (silicon and indium antimonide) focal plane array, a tuning fork chopper, microprocessor-controlled electronics, and a passive radiative cooler. A wobbling secondary mirror in the telescope provides 20 pixels in one dimension of spatial scanning in a pushbroom mode with 0.5 mr x 0.5 mr instantaneous field of view. The spectral range is 0.7-5.2 microns; resolution is 0.025 micron. NIMS is the first infrared experiment to combine both spatial and spectral mapping capability in one instrument.

Aptaker, Irving M.↗

Long path monitoring of tropospheric O3, NO2, H2CO and SO2

Concentrations of tropospheric O3, NO2, H2CO, and SO2 have been measured on the Campus of the 'Universite Libre de Bruxelles' on a routine basis since October 1990. The long path system consists of a source lamp, a first 30 cm f/8 Cassegrain type telescope which collimates the light onto a slightly parabolic mirror placed on the roof of a building situated 394 m away from the laboratory. The light is sent back into a second 30 cm Cassegrain telescope. This telescope has been modified so that the output beam is a 5 cm diameter parallel beam. This beam is then focused onto the entrance aperture of the BRUKER IFS120HR fourier transform spectrometer. The two telescopes are mounted on alignment devices and the external mirror is equipped with a driving system operated from the laboratory. The choice of the light source (either a 1000 W high pressure 'ozone free' xenon lamp or a 250 W tungsten filament) and of the detector (either a solar blind UV-diode or a silicon diode) depended on the spectral region studied. These regions lie respectively from 26,000 cm(exp -1) to 30,000 cm(exp -1) (260-380 nm) and from 14,000 cm(exp -1) to 30,000 cm(exp -1) (330-700 nm). The spectra have been recorded at the resolution of 16 cm(exp -1) and with a dispersion of 7.7 cm(exp -1). They have been measured during the forward and the backward movements of the mobile mirror, in double sided mode; each spectrum is an average of 2000 scans. The time required to record a spectrum is about 45 minutes. The shape of the raw spectra in the two investigated regions are represented.

Vandaele, A. C.↗

Tilting A Small Reflector For Vernier Pointing Of A Large Antenna

Simple vernier pointing technique devised to facilitate scanning beam pointing of large paraboloidal reflector so line of sight of antenna sweeps out narrow cone about fixed axis (conical scan, also known as "conscan" in art). Scan effected by one of relatively small beam-waveguide reflectors or mirrors that couple signals between antenna and distant transmitting and/or receiving electronic circuits. Easier to tilt small mirror than to tilt massive antenna structure.

Veruttipong, Watt↗

Development and Operations of the Astrophysics Data System

SAO TASKS ACCOMPLISHED: Abstract Service: (1) Continued regular updates of abstracts in the databases, both at SAO and at all mirror sites; (2) Established a new naming convention of QB books in preparation for adding physics books from Hollis or Library of Congress; (3) Modified handling of object tag so as not to interfere with XHTML definition; (4) Worked on moving 'what's new' announcements to a majordomo email list so as not to interfere with divisional mail handling; (5) Implemented and tested new first author feature following suggestions from users at the AAS meeting; (6) Added SSRv entries back to volume 1 in preparation for scanning of the journal; (7) Assisted in the re-configuration of the ADS mirror site at the CDS and sent a new set of tapes containing article data to allow re-creation of the ADS article data lost during the move; (8) Created scripts to automatically download Astrobiology.

Murray, Stephen S.↗

High-Resolution, Wide-Field-of-View Scanning Telescope

A proposed telescope would afford high resolution over a narrow field of view (<0.10 ) while scanning over a total field of view nominally 16 wide without need to slew the entire massive telescope structure. The telescope design enables resolution of a 1-m-wide object in a 50- km-wide area of the surface of the Earth as part of a 200-km-wide area field of view monitored from an orbit at an altitude of 700 km. The conceptual design of this telescope could also be adapted to other applications both terrestrial and extraterrestrial in which there are requirements for telescopes that afford both wide- and narrow-field capabilities. In the proposed telescope, the scanning would be effected according to a principle similar to that of the Arecibo radio telescope, in which the primary mirror is stationary with respect to the ground and a receiver is moved across the focal surface of the primary mirror. The proposed telescope would comprise (1) a large spherical primary mirror that would afford high resolution over a narrow field of view and (2) a small displaceable optical relay segment that would be pivoted about the center of an aperture stop to effect the required scanning (see figure). Taken together, both comprise a scanning narrow-angle telescope that does not require slewing the telescope structure. In normal operation, the massive telescope structure would stare at a fixed location on the ground. The inner moveable relay optic would be pivoted to scan the narrower field of view over the wider one, making it possible to retain a fixed telescope orientation, while obtaining high-resolution images over multiple target areas during an interval of 3 to 4 minutes in the intended orbit. The pivoting relay segment of the narrow-angle telescope would include refractive and reflective optical elements, including two aspherical mirrors, to counteract the spherical aberration of the primary mirror. Overall, the combination of the primary mirror and the smaller relay optic would provide narrow-angle, diffraction-limited high resolution at a wavelength of 500 nm.

Sepulveda, Cesar↗

Production and Performance of the InFOCmicronS 20-40 keV Graded Multilayer Mirror

The International Focusing Optics Collaboration for micron Crab Sensitivity (InFOC micronS) balloon-borne hard x-ray incorporates graded multilayer technology to obtain significant effective area at energies previously inaccessible to x-ray optics. The telescope mirror consists of 2040 segmented thin aluminum foils coated with replicated Pt/C multilayers. A sample of these foils was scanned using a pencil-beam reflectometer to determine, multilayer quality. The results of the reflectometer measurements demonstrate our capability to produce large quantity of foils while maintaining high-quality multilayers with a mean Nevot-Croce interface roughness of 0.5nm. We characterize the performance of the complete InFOC micronS telescope with a pencil beam raster scan to determine the effective area and encircled energy function of the telescope. The effective area of the complete telescope is 78, 42 and 22 square centimeters at 20 30 and 40 keV. respectively. The measured encircled energy fraction of the mirror has a half-power diameter of 2.0 plus or minus 0.5 arcmin (90% confidence). The mirror successfully obtained an image of the accreting black hole Cygnus X-1 during a balloon flight in July, 2001. The successful completion and flight test of this telescope demonstrates that graded-multilayer telescopes can be manufactured with high reliability for future x-ray telescope missions such as Constellation-X.

Berendse, F.↗

Integrated optics in an electrically scanned imaging Fourier transform spectrometer

An efficient, lightweight and stable, Fourier transform spectrometer was developed. The mechanical slide mechanism needed to create a path difference was eliminated by the use of retro-reflecting mirrors in a monolithic interferometer assembly in which the mirrors are not at 90 degrees to the propagation vector of the radiation, but rather at a small angle. The resulting plane wave fronts create a double-sided inteferogram of the source irradiance distribution which is detected by a charge-coupled device image sensor array. The position of each CCD pixel in the array is an indication of the path difference between the two retro-reflecting mirrors in the monolithic optical structure. The Fourier transform of the signals generated by the image sensor provide the spectral irradiance distribution of the source. For imaging, the interferometer assembly scans the source of irradiation by moving the entire instrument, such as would occur if it was fixedly mounted to a moving platform, i.e., a spacecraft. During scanning, the entrace slot to the monolithic optical structure sends different pixels to corresponding interferograms detected by adjacent columns of pixels of the image sensor.

Breckinridge, James B.↗

Characterizations of the mirror attenuator mosaic - Solar diffuser plate

The mirror attenuator mosaic (MAM), a solar diffuser plate, was used for the flight calibration of the broadband shortwave (0.2-5-microns) and total (0.2 to greater than 200-microns) Earth Radiation Budget Experiment scanning thermistor bolometer radiometers. The MAM solar-reflecting surface consisted of a tightly packed array of vacuum-deposited aluminum, concave spherical mirrors, while its solar-absorbing surface consisted of black chrome. The effective reflectance of the MAM was constant to within +/- 2 percent after almost 2 years in orbit, a marked improvement over earlier solar diffusers.

Lee, Robert B., III↗

The University of Durham Mark 3 very high energy gamma ray telescope

A new very high energy gamma-ray telescope employing the atmospheric Cerenkov light technique and currently nearing completion is described. The telescope is designed to have capability as both a wide angle instrument (4 degree field of view) for sky survey work and as a narrow field of view instrument (1.35 degrees) for conventional drift-scanning and tracking modes of operation. The telescope consists of two 10 sq. m. mirrors operated in fast coincidence with multiple phototube assemblies at the prime focus of each mirror. The design philosophy of the instrument is discussed and comparisons of its performance with our previous telescopes are made.

Chadwick, P. M.↗

The ALEXIS data processing package: An IDL based system

The Array of Low Energy X-ray Imaging Sensors (ALEXIS) experiment consists of a mini-satellite containing six wide angle EUV/ultrasoft x-ray telescopes. Its purpose is to map out the sky in three narrow (approximately 5 percent) bandpasses around 66, 71, and 93 eV. The 66 and 71 eV bandpasses are centered on intense Fe emission lines which are characteristic of million degree plasmas such as the one thought to produce the soft x-ray background. The 93 eV bandpass is not near any strong emission lines and is more sensitive to continuum sources. The mission will be launched on the Pegasus Air Launched Vehicle in the second half of 1992 into a 400-nautical-mile, high inclination orbit and will be controlled entirely from a small ground station located at Los Alamos. The project is a collaborative effort between Los Alamos National Laboratory, Sandia National Laboratory, and the University of California-Berkeley Space Sciences Laboratory. The six telescopes are arranged in three pairs. As the satellite spins twice a minute they scan the entire anti-solar hemisphere. Each f/1 telescope consists of a spherical, multilayer-coated mirror with a curved, microchannel plate detector located at the prime focus. The multilayer coatings determine the bandpasses of the telescopes. The field of view of each telescope is 30 degrees with a spatial resolution of 0.5 degree, limited by spherical aberration. The data processing requirements for ALEXIS are large. Each event is one of the six telescopes is telemetered to the ground with its time of arrival and position on the detector. This information must be folded with the aspect solution for the satellite to reconstruct the direction on the sky from which the photon came. Because of the way the six telescopes scan the sky, the effective exposure calculation is also very computationally intensive. ALEXIS may generate up to 100 megabytes of raw data per day, which are converted into a gigabyte per day of processed data. While the processing job for ALEXIS is sizable, the programming staff is small. To maximize programming efficiency, and to make the best use of tools available in the public domain, we chose IDL as our software development platform. IDL was used from the start of instrument development through flight. We use IDL as a top-level executive for the processing tasks (replacing Unix shell scripts), as a device independent graphics engine, as a database manager, and as a final data manipulator. IDL routines spawn special purpose C programs to perform detailed telemetry deconvolution and other specialized functions. We discuss the use of IDL and C within the processing and archiving strategy for the ALEXIS data anlaysis system as implemented on a SPARCstation platform. We also show results from our End-to-End software simulation capability as processed by our analysis codes.

Bloch, J. J.↗

Elevation scanning laser/multi-sensor hazard detection system controller and mirror/mast speed control components

The electro-mechanical and electronic systems involved with pointing a laser beam from a roving vehicle along a desired vector are described. A rotating 8 sided mirror, driven by a phase-locked dc motor servo system, and monitored by a precision optical shaft encoder is used. This upper assembly is then rotated about an orthogonal axis to allow scanning into all 360 deg around the vehicle. This axis is also driven by a phase locked dc motor servo-system, and monitored with an optical shaft encoder. The electronics are realized in standard TTL integrated circuits with UV-erasable proms used to store desired coordinates of laser fire. Related topics such as the interface to the existing test vehicle are discussed.

Craig, J.↗

The Lyman alpha coronagraph

The rocket-borne Lyman alpha coronagraph (RLAC) is to be used in the absence of a natural solar eclipse to determine coronal temperatures from measurements of the line width of Lyman-alpha and to determine neutral hydrogen densities of coronal material from the absolute intensity. The coronagraph consists of a 75-cm Fastie-Ebert scanning spectrometer with an AMR 641 photoelectric detection system, an off-axis parabolic primary mirror, and an occulting system. A special optical arrangement achieves rejection of radiation from the solar disk.

Kohl, J. L.↗

Determination of the NOAA-20 VIIRS TEB RVS from Emissive Radiation Measurements During the Pitch Maneuver

The Visible Infrared Imaging Radiometer Suite (VIIRS) is a key sensor carried on the newly launched (November 18, 2017) Joint Polar Satellite System-1 (JPSS-1), now transitioned to NOAA-20, and the Suomi National Polar-orbiting Partnership (SNPP) satellite. The two VIIRS sensors are nearly identical in design. Its on-board calibration components include a solar diffuser (SD) and a solar diffuser stability monitor (SDSM) for the reflective solar bands (RSB), a V-groove blackbody for the thermal emissive bands (TEB), and a space view (SV) port for background subtraction. These on-board calibrators are located at fixed scan angles. The VIIRS response versus scan angle (RVS) was characterized prelaunch in lab ambient conditions and is currently used to calibrate the on-orbit response for all scan angles relative to the calibrator's scan angle. A spacecraft level pitch maneuver was scheduled during the initial intensive Cal/Val testing for both the NOAA-20 and SNPP. The pitch maneuver provided a rare opportunity for VIIRS to make observations of deep space over the entire scan angle range, which can be used to characterize the TEB RVS. This study provides our analysis of the NOAA-20 pitch maneuver data and assessment of the derived TEB RVS. A comparison between the RVS determined by the pitch maneuver observations and prelaunch lab measurements is conducted for each band, detector, and mirror side of the half angle mirror.

VIIRS↗