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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
NASA NTRS2015

Data-Driven Surface Traversability Analysis for Mars 2020 Landing Site Selection

The objective of this paper is three-fold: 1) to describe the engineering challenges in the surface mobility of the Mars 2020 Rover mission that are considered in the landing site selection processs, 2) to introduce new automated traversability analysis capabilities, and 3) to present the preliminary analysis results for top candidate landing sites. The analysis capabilities presented in this paper include automated terrain classification, automated rock detection, digital elevation model (DEM) generation, and multi-ROI (region of interest) route planning. These analysis capabilities enable to fully utilize the vast volume of high-resolution orbiter imagery, quantitatively evaluate surface mobility requirements for each candidate site, and reject subjectivity in the comparison between sites in terms of engineering considerations. The analysis results supported the discussion in the Second Landing Site Workshop held in August 2015, which resulted in selecting eight candidate sites that will be considered in the third workshop.

Ono, Masahiro↗
NASA NTRS2013

Experimental Database with Baseline CFD Solutions: 2-D and Axisymmetric Hypersonic Shock-Wave/Turbulent-Boundary-Layer Interactions

A database compilation of hypersonic shock-wave/turbulent boundary layer experiments is provided. The experiments selected for the database are either 2D or axisymmetric, and include both compression corner and impinging type SWTBL interactions. The strength of the interactions range from attached to incipient separation to fully separated flows. The experiments were chosen based on criterion to ensure quality of the datasets, to be relevant to NASA's missions and to be useful for validation and uncertainty assessment of CFD Navier-Stokes predictive methods, both now and in the future. An emphasis on datasets selected was on surface pressures and surface heating throughout the interaction, but include some wall shear stress distributions and flowfield profiles. Included, for selected cases, are example CFD grids and setup information, along with surface pressure and wall heating results from simulations using current NASA real-gas Navier-Stokes codes by which future CFD investigators can compare and evaluate physics modeling improvements and validation and uncertainty assessments of future CFD code developments. The experimental database is presented tabulated in the Appendices describing each experiment. The database is also provided in computer-readable ASCII files located on a companion DVD.

Database↗
NASA NTRS1984

Chemical Modification of the Surface of High Modulus Carbon Fibers

The deposition of selected monomers on the surface of high modulus carbon fibers was studied. The fundamental principles which provide the basis for the design of a predictable interfacial bond between carbon fibers and polymeric matrices are described.

Source record↗
DOE OSTI2025

Selective Adsorption of Thiol-Containing Molecules on Copper Sulfide Surfaces via Molecule–Surface Disulfide Bridges

Recent results in the fields of nanoenhanced agriculture and expanding interest in prebiotic chemistry have placed increased emphasis on understanding the chemically selective interaction of small molecules with the surfaces of metal sulfides. Here, we present an integrated experimental and computational study of the interaction of thiol-containing molecules with copper sulfide (covellite) surfaces in aqueous media. In situ Fourier-transform infrared (FTIR) measurements and ex situ X-ray photoelectron spectroscopy (XPS) measurements show that molecules bearing free thiol groups, including glutathione and cysteine, bind strongly to CuS (covellite) nanoparticles and to CuS (001) single crystals, while control studies show that similar molecules lacking the free thiol group exhibit much less binding. Additional experiments show that these thiol-containing molecules interact transiently with CuO nanoparticle surfaces but are readily removed by rinsing. The FTIR and XPS experiments demonstrate that adsorption of molecular thiols to CuS surfaces occurs in a chemically selective manner. Further experimental studies and density functional calculations show that the preferred mode of binding is through the surface S atoms, forming a Solid–S–S–Molecule disulfide linkage. While the role of disulfide linkages in controlling structure and function of proteins and other biomolecules is widely known, the formation of surface disulfide linkages as a motif for covalent molecular binding at surfaces has not been established previously.

36 MATERIALS SCIENCE↗
NASA NTRS2009

Calculation of Stress Intensity Factors for Interfacial Cracks in Fiber Metal Laminates

Stress intensity factors for interfacial cracks in Fiber Metal Laminates (FML) are computed by using the displacement ratio method recently developed by Sun and Qian (1997, Int. J. Solids. Struct. 34, 2595-2609). Various FML configurations with single and multiple delaminations subjected to different loading conditions are investigated. The displacement ratio method requires the total energy release rate, bimaterial parameters, and relative crack surface displacements as input. Details of generating the energy release rates, defining bimaterial parameters with anisotropic elasticity, and selecting proper crack surface locations for obtaining relative crack surface displacements are discussed in the paper. Even though the individual energy release rates are nonconvergent, mesh-size-independent stress intensity factors can be obtained. This study also finds that the selection of reference length can affect the magnitudes and the mode mixity angles of the stress intensity factors; thus, it is important to report the reference length used with the calculated stress intensity factors.

Wang, John T.↗
NASA NTRS1997

Surface Plasmon Tunable Color Filter and Projection Display

A novel projection display, based on a new phenomenon of voltage-induced color-selective absorption with surface plasmons, are able to generate bright image on a large screen with high efficiency. In addition, neither color filters or nor phosphors are needed to generate the color.

surface↗
NASA NTRS1996

Surface Plasmon Tunable Color Filter and Projection Display

A novel projection display, based on a new phenomenon of voltage-induced color-selective absorption with surface plasmons, are able to generate bright image on a large screen with high efficiency. In addition, neither color filters nor phosphors are needed to generate the color. With the incident beam of ±7° half cone angle, the color purity of this device can be as good as the CRT displays, and the contrast ratio can reach over 200:1.

projection↗
DOE OSTI2025

Surface structure of water from soft X-ray second harmonic generation

The microscopic structure of water’s surface is crucial to many natural and industrial processes, but studying its hydrogen bond (H-bond) network directly remains challenging due to the required interfacial sensitivity of experimental techniques. By leveraging advances in flat liquid sheet microjets and terawatt-scale attosecond soft X-ray pulses from the LCLS X-ray free electron laser, we employed soft X-ray second harmonic generation (SXSHG) spectroscopy to examine the liquid water/vapor interface. SXSHG combines the elemental selectivity of X-ray spectroscopies with the surface selectivity of SHG and gives access to the electronic structure of interfacial species. Here, we show the SXSHG spectrum differs from bulk water’s X-ray absorption, with its peak shifted several eV, indicating a vastly different electronic environment at the interface as compared to the bulk. First-principles electronic structure calculations show the signal is highly sensitive to H-bond interactions, such as water molecules accepting a single H-bond, which are surface abundant.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Signatures of a spin-active interface and a locally enhanced Zeeman field in a superconductor-chiral material heterostructure

A localized Zeeman field, intensified at heterostructure interfaces, could play a crucial role in a broad area including spintronics and unconventional superconductors. Conventionally, the generation of a local Zeeman field is achieved through magnetic exchange coupling with a magnetic material. However, magnetic elements often introduce defects, which could weaken or destroy superconductivity. Alternatively, the coupling between a superconductor with strong spin-orbit coupling and a nonmagnetic chiral material could serve as a promising approach to generate a spin-active interface. Here, we leverage an interface superconductor, namely, induced superconductivity in noble metal surface states, to probe the spin-active interface. Our results unveil an enhanced interface Zeeman field, which selectively closes the surface superconducting gap while preserving the bulk superconducting pairing. The chiral material, i.e., trigonal tellurium, also induces Andreev bound states (ABS) exhibiting spin polarization. The field dependence of ABS manifests a substantially enhanced interface Landég-factor (g eff ~ 12), thereby corroborating the enhanced interface Zeeman energy.

Science & Technology - Other Topics↗
NASA NTRS1973

Handbook on passive thermal control coatings

A handbook of passive thermal control surfaces data pertaining to the heat transfer requirements of spacecraft is presented. Passive temperature control techniques and the selection of control surfaces are analyzed. The space environmental damage mechanisms in passive thermal control surfaces are examined. Data on the coatings for which technical information is available are presented in tabular form. Emphasis was placed on consulting only those references where the experimental simulation of the space environment appeared to be more appropriate.

Mookherji, T. K.↗
NASA NTRS1993

An experimental study of the effects of bodyside compression on forward swept sidewall compression inlets ingesting a turbulent boundary layer

Forward swept sidewall compression inlets have been tested in the Mach 4 Blowdown Facility at the NASA Langley Research Center to study the effects of bodyside compression surfaces on inlet performance in the presence of an incoming turbulent boundary layer. The measurements include mass flow capture and mean surface pressure distributions obtained during simulated combustion pressure increases downstream of the inlet. The kerosene-lampblack surface tracer technique has been used to obtain patterns of the local wall shear stress direction. Inlet performance is evaluated using starting and unstarting characteristics, mass capture, mean surface pressure distributions and permissible back pressure limits. The results indicate that inlet performance can be improved with selected bodyside compression surfaces placed between the inlet sidewalls.

Rodi, Patrick E.↗
NASA NTRS2014

Strategy for Ranking the Science Value of the Surface of Asteroid 101955 Bennu for Sample Site Selection for Osiris-REx

OSRIS-REx is NASA's New Frontiers 3 sample return mission that will return at least 60 g of pristine surface material from near-Earth asteroid 101955 Bennu in September 2023. The scientific value of the sample increases enormously with the amount of knowledge captured about the geological context from which the sample is collected. The OSIRIS-REx spacecraft is highly maneuverable and capable of investigating the surface of Bennu at scales down to the sub-cm. The OSIRIS-REx instruments will characterize the overall surface geology including spectral properties, microtexture, and geochemistry of the regolith at the sampling site in exquisite detail for up to 505 days after encountering Bennu in August 2018. The mission requires at the very minimum one acceptable location on the asteroid where a touch-and-go (TAG) sample collection maneuver can be successfully per-formed. Sample site selection requires that the follow-ing maps be produced: Safety, Deliverability, Sampleability, and finally Science Value. If areas on the surface are designated as safe, navigation can fly to them, and they have ingestible regolith, then the scientific value of one site over another will guide site selection.

Nakamura-Messenger, K.↗
DOE OSTI2025

Surface-Controlled TiO 2 Nanocrystals with Catalytically Active Single-Site Co Incorporation for the Oxygen Evolution Reaction

The design of advanced electrocatalysts is often hindered by uncertainties in identifying and controlling the active surfaces and catalytic centers within heterogeneous materials. Here we present the synthesis of single-site Co catalysts, substitutionally doped into surface-controlled TiO 2 anatase nanocrystals, aimed at enhancing the oxygen evolution reaction (OER). Grand canonical quantum mechanics calculations reveal that the kinetics of the OER, following an adsorbate evolution mechanism, is markedly influenced by the coordination environment of Co. The simulations suggest significantly higher turnover frequencies when Co is doped into the (001) surface of TiO 2 compared to the (101) surface. Consistent with the computational findings, experimental results show that Co-doped TiO 2 (Co-TiO 2 ) nanoplates with selectively exposed {001} surfaces exhibit enhanced current densities and turnover frequencies compared to Co-TiO 2 nanobipyramids with {101} surfaces. This study highlights the synergy between theoretical calculations and precision synthesis in the development of more effective catalysts.

25 ENERGY STORAGE↗
NASA NTRSDate not supplied

Evaluation of Materials and Surfaces for Lunar Regolith Adherence Characterization (RAC) Payload Samples

As the quest for long term lunar exploration and habitation comes closer to reality, widespread efforts are ongoing to effectively mitigate lunar dust surface contamination and infiltration. This dust is hazardous to humans and tends to adhere tenaciously to all exposed surfaces, causing performance issues and ultimately failure. While several active and passive technologies have been developed to address this challenge, assessing the performance of these technologies in the actual lunar environment is extremely important. The regolith adherence characterization (RAC) experiment payload provides an important opportunity for this evaluation. The RAC payload is designed by Alpha Space for the National Aeronautics and Space Administration (NASA)and scheduled to be flown to the moon in 2023 on the Firefly Aerospace Blue Ghost lander. As there were a limited number of slots available for materials to be chosen for this mission, it was critical to make an informed selection. Two polymers, a carbon fiber reinforced composite and a metal alloy were chosen to be a diverse selection of structural materials from NASA Langley Research Center. Each material was topographically modified using laser ablation patterning. This article briefly describes the selection and testing procedure and some of the results obtained for the passive dust mitigating materials and surfaces selected for this lunar surface experiment.

Lunar Dust↗
NASA NTRS1994

Potential landing sites for Mars Pathfinder

In addition to a better understanding of the geological evolution of Mars, new techniques for processing available data have emerged, new data have been acquired, and the engineering approaches for placing spacecraft on the surface have evolved. Selection of the Mars Pathfinder landing site must take these issues into account, along with mission constraints. An advantage of Mars Pathfinder is the rover for sampling surface materials over a range of tens of meters. However, engineering constraints and the limited scientific payload of this mission require new approaches for landing site selection. One approach is to select sites exhibiting a wide variety of rocks near the lander. An alternative approach is to select sites in which the regional geology consists of a single rock type representing a key datum for the geological study of Mars, and is uniformly distributed within the landing ellipse.

Kuzmin, Ruslan O.↗
NASA NTRS1994

User's guide for the thermal analyst's help desk expert system

A guide for users of the Thermal Analyst's Help Desk is provided. Help Desk is an expert system that runs on a DOS based personal computer and operates within the EXSYS expert system shell. Help Desk is an analysis tool designed to provide users having various degrees of experience with the capability to determine first approximations of thermal capacity for spacecraft and instruments. The five analyses supported in Help Desk are: surface area required for a radiating surface, equilibrium temperature of a surface, enclosure temperature and heat loads for a defined position in orbit, enclosure temperature and heat loads over a complete orbit, and selection of appropriate surface properties. The two geometries supported by Help Desk are a single flat plate and a rectangular box enclosure.

Ormsby, Rachel A.↗
DOE OSTI2026

Towards Spatial Control of Reaction Selectivity on Photocatalysts using Area Selective Atomic Layer Deposition on Model Dual Site Electrocatalyst Platform

Photocatalytic water splitting is a promising route to low-cost H2; however, this approach is currently limited by solar-to-hydrogen (STH) conversion efficiencies in the sub-10% range. Z-scheme water splitting, in which H2 and O2 evolving particles are operated in separate compartments and electronically coupled by a soluble redox mediator, offers improvements in STH efficiency but introduces high rates of undesired side and back reactions. Nanoscopic oxide coatings (e.g., CrOx, and SiOx) have previously been used to selectively block undesired reactants from reaching active sites; however, a coating encapsulating the entire photocatalyst particle limits activity as the particle can no longer facilitate both half reactions. In contrast to photodeposition, which may produce non-uniform overlayers due to the difficulty of controlling local electrochemical reactivity on the surface, area-selective atomic layer deposition (AS-ALD) can be used to deposit conformal ultrathin oxide coatings while preserving access to non-growth areas of a substrate surface. To develop this technique for Z-scheme photocatalysts, we performed AS-ALD of TiO2 on a dual site planar electrocatalyst based on interdigitated arrays of Pt and Au. Self-assembled monolayers of 1-octadecanethiol (ODT) were used to block growth on the Au array, resulting in a patterned surface in which only the Pt sites were encapsulated with TiO2. These electrocatalysts demonstrated localized reaction selectivity for hydrogen evolution reaction (HER) over the TiO2/Pt sites, while the uncoated Au sites retained activity towards Fe(II)/Fe(III) redox (FeRR). Under independent potential control, these microelectrodes showed that selectively deposited TiO2 coatings can suppress the rate of back reactions on neighboring active sites by an order of magnitude compared to uncoated control samples.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗