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At least 289 records · Page 16

In Situ Geochemical Analysis and Age Dating of Rocks Using Laser Ablation-Miniature Mass Spectrometer

A miniaturized instrument for performing chemical and isotopic analysis of rocks has been developed. The rock sample is ablated by a laser and the neutral species produced are analyzed using the JPL-invented miniature mass spectrometer. The direct sampling of neutral ablated material and the simultaneous measurement of all the elemental and isotopic species are the novelties of this method. In this laser ablation-miniature mass spectrometer (LA-MMS) method, the ablated neutral atoms are led into the electron impact ionization source of the MMS, where they are ionized by a 70-eV electron beam. This results in a secondary ion pulse typically 10-100 microsecond wide, compared to the original 5-10-nanosecond laser pulse duration. Ions of different masses are then spatially dispersed along the focal plane of the magnetic sector of the miniature mass spectrometer and measured in parallel by a modified CCD (charge-coupled device) array detector capable of detecting ions directly. Compared to conventional scanning techniques, simultaneous measurement of the ion pulse along the focal plane effectively offers a 100% duty cycle over a wide mass range. LAMMS offers a more quantitative assessment of elemental composition than techniques that detect laser-ionized species produced directly in the ablation process because the latter can be strongly influenced by matrix effects that vary with the structure and geometry of the surface, the laser beam, and the ionization energies of the elements. The measurement of high-precision isotopic ratios and elemental composition of different rock minerals by LAMMS method has been demonstrated. The LA-MMS can be applied for the absolute age determination of rocks. There is no such instrument available presently in a miniaturized version that can be used for NASA space missions. Work is in progress in the laboratory for geochronology of rocks using LA-MMS that is based on K-Ar radiogenic dating technique.

Sinha, Mahadeva P.↗

Towards an Imaging Mid-Infrared Heterodyne Spectrometer

We are developing a concept for a compact, low-mass, low-power, mid-infrared (MIR; 5- 12 microns) imaging heterodyne spectrometer that incorporates fiber optic coupling, Quantum Cascade Laser (QCL) local oscillator, photomixer array, and Radio Frequency Software Defined Readout (RFSDR) for spectral analysis. Planetary Decadal Surveys have highlighted the need for miniaturized, robust, low-mass, and minimal power remote sensing technologies for flight missions. The drive for miniaturization of remote sensing spectroscopy and radiometry techniques has been a continuing process. The advent of MIR fibers, and MEMS techniques for producing waveguides has proven to be an important recent advancement for miniaturization of infrared spectrometers. In conjunction with well-established photonics techniques, the miniaturization of spectrometers is transitioning from classic free space optical systems to waveguide/fiber-based structures for light transport and producing interference effects. By their very nature, these new devices are compact and lightweight. Mercury-Cadmium-Telluride (MCT) and Quantum Well Infrared Photodiodes (QWIP) arrays for heterodyne applications are also being developed. Bulky electronics is another barrier that precluded the extension of heterodyne systems into imaging applications, and our RFSDR will address this aspect.

Hewagama, T.↗

Rest-wavelength Fiducials for the ITER Core Imaging X-ray Spectrometer

Absolute wavelength references are needed to derive the plasma velocities from the Doppler shift of a given line emitted by a moving plasma. We show that such reference standards exist for the strongest x-ray line in neonlike W64+, which has become the line of choice for the ITER (Latin the way) core imaging x-ray spectrometer. Close-by standards are the Hf L3 line and the Ir L2 line, which bracket the W64+ line by 30 eV; other standards are given by the Ir L1 and L2 lines and the Hf L1 and L2 lines, which bracket the W64+ line by 40 and 160 eV, respectively. The reference standards can be produced by an x-ray tube built into the ITER spectrometer. We present spectra of the reference lines obtained with an x-ray microcalorimeter and compare them to spectra of the W64+ line obtained both with an x-ray microcalorimeter and a crystal spectrometer

Rest-wavelength↗

Adaptive Tunable Laser Spectrometer for Space Applications

An architecture and process for the rapid prototyping and subsequent development of an adaptive tunable laser absorption spectrometer (TLS) are described. Our digital hardware/firmware/software platform is both reconfigurable at design time as well as autonomously adaptive in real-time for both post-integration and post-launch situations. The design expands the range of viable target environments and enhances tunable laser spectrometer performance in extreme and even unpredictable environments. Through rapid prototyping with a commercial RTOS/FPGA platform, we have implemented a fully operational tunable laser spectrometer (using a highly sensitive second harmonic technique). With this prototype, we have demonstrated autonomous real-time adaptivity in the lab with simulated extreme environments.

Flesch, Gregory↗

Inficon Transpector MPH Mass Spectrometer Random Vibration Test Report

The purpose of this test report is to summarize results from the vibration testing of the INFICON Transpector MPH100M model Mass Spectrometer. It also identifies requirements satisfied, and procedures used in the test. As a payload of Resource Prospector, it is necessary to determine the survivability of the mass spectrometer to proto-qualification level random vibration. Changes in sensitivity of the mass spectrometer can be interpreted as a change in alignment of the instrument. The results of this test will be used to determine any necessary design changes as the team moves forward with flight design.

Transpector↗

Key Elements of a Low Voltage, Ultracompact Plasma Spectrometer

Taking advantage of technological developments in wafer-scale processing over the past two decades, such as deep etching, 3-D chip stacking, and double-sided lithography, we have designed and fabricated the key elements of an ultracompact 1.5cm (exp 3)plasma spectrometer that requires only low-voltage power supplies, has no microchannel plates, and has a high aperture area to instrument volume ratio. The initial design of the instrument targets the measurement of charged particles in the 3-20keV range with a highly directional field of view and a 100 duty cycle; i.e., the entire energy range Is continuously measured. In addition to reducing mass, size, and voltage requirements, the new design will affect the manufacturing process of plasma spectrometers, enabling large quantities of identical instruments to be manufactured at low individual unit cost. Such a plasma spectrometer is ideal for heliophysics plasma investigations, particularly for small satellite and multispacecraft missions. Two key elements of the instrument have been fabricated: the collimator and the energy analyzer. An initial collimator transparency of 20 with 3deg x 3deg angular resolution was achieved. The targeted 40 collimator transparency appears readily achievable. The targeted energy analyzer scaling factor of 1875 was achieved; i.e.20 keV electrons were selected for only a 10.7V bias voltage in the energy analyzer.

Scime, E. E.↗

Miniature X-Ray Solar Spectrometer: A Science-Oriented, University 3U CubeSat

The miniature x-ray solar spectrometer is a three-unit CubeSat developed at the Laboratory for Atmospheric and Space Physics at the University of Colorado, Boulder. Over 40 students contributed to the project with professional mentorship and technical contributions from professors in the Aerospace Engineering Sciences Department at University of Colorado, Boulder and from Laboratory for Atmospheric and Space Physics scientists and engineers. The scientific objective of the miniature x-ray solar spectrometer is to study processes in the dynamic sun, from quiet sun to solar flares, and to further understand how these changes in the sun influence the Earth's atmosphere by providing unique spectral measurements of solar soft x-rays. The enabling technology providing the advanced solar soft x-ray spectral measurements is the Amptek X123, a commercial off-the-shelf silicon drift detector. The Amptek X123 has a low mass (approx. 324 g after modification), modest power consumption (approx. 2.50 W), and small volume (6.86 x 9.91 x 2.54 cm), making it ideal for a CubeSat. This paper provides an overview of the miniature x-ray solar spectrometer mission: the science objectives, project history, subsystems, and lessons learned, which can be useful for the small-satellite community.

Mason, James P.↗

Dual Ion Spectrometers and Their Calibration for the Fast Plasma Investigation on NASA's Magnetospheric Multiscale Mission

The scientific target of NASA's Magnetospheric Multiscale (MMS) mission is to study the fundamentally important phenomenon of magnetic reconnection. Theoretical models of this process predict a small size, on the order of hundred kilometers, for the ion diffusion region where ions are demagnetized at the dayside magnetopause. This region may typically sweep over the spacecraft at relatively high speeds of 50 km/s, requiring the fast plasma investigation (FPI) instrument suite to have an extremely high time resolution for measurements of the 3D particle distribution functions. As part of the FPI on MMS, the 16 dual ion spectrometers (DIS) will provide fast (150 ms) 3D ion velocity distributions, from 10 to 30,000 eV/q, by combining the measurements from four dual spectrometers on each of four MMS spacecraft. For any multispacecraft mission, the response uniformity among the spectrometer set assumes an enhanced importance. Due to these demanding instrument requirements and the effort of calibrating more than 32 sensors (16 × 2) within a tight schedule, a highly systematic and precise calibration was required for measurement repeatability. To illustrate how this challenge was met, a brief overview of the FPI DIS was presented with a detailed discussion of the calibration method of approach and implementation. Finally, a discussion of DIS performance results, their unit-to-unit variation, and the lessons learned from this calibration effort are presented.

Coffey, V. N.↗

Composite Infrared Spectrometer (CIRS) on Cassini

The Cassini spacecraft orbiting Saturn carries the composite infrared spectrometer (CIRS) designed to study thermal emission from Saturn and its rings and moons. CIRS, a Fourier transform spectrometer, is an indispensable part of the payload providing unique measurements and important synergies with the other instruments. It takes full advantage of Cassini's 13-year-long mission and surpasses the capabilities of previous spectrometers on Voyager 1 and 2. The instrument, consisting of two interferometers sharing a telescope and a scan mechanism, covers over a factor of 100 in wavelength in the mid and far infrared. It is used to study temperature, composition, structure, and dynamics of the atmospheres of Jupiter, Saturn, and Titan, the rings of Saturn, and surfaces of the icy moons. CIRS has returned a large volume of scientific results, the culmination of over 30 years of instrument development, operation, data calibration, and analysis. As Cassini and CIRS reach the end of their mission in 2017, we expect that archived spectra will be used by scientists for many years to come.

Jennings, Donald E.↗

Numerical Investigation of Ion Transport in the MOMA Ion Mass Spectrometer

The Mars Organic Molecule Analyzer (MOMA) is a miniature ion trap mass spectrometer designed for the upcoming ExoMars Rover mission. The spectrometer uses laser desorption to ionize a Martian soil sample within an instrument internal clean zone maintained at ambient Martian pressure. A high-speed aperture valve transiently opens to allow ionized constituents, along with the ambient gas, to enter a vacuum cavity containing a linear ion trap mass spectrometer. The ambient clean zone and the vacuum cavity are connected via a few centimeter long aperture valve ion guide tube. In this paper, we present results from a recently completed numerical investigation of ion transport from the ion source across the ion guide. Specifically, we focus on collisional coupling between ions and the neutral molecules flowing into the vacuum cavity. The simulation domain contains the ambient region, and we consider the variation in ion conductance with ambient pressure. We also analyze the impact of a fixed potential bias applied to the aperture valve. Simulations are performed with a two-dimensional axisymmetric PIC / DSMC code Starfish. Numerical results are compared to experimental data.

Breida, Lubos↗

In-Flight Calibration of Hitomi Soft X-Ray Spectrometer. (1) Background

The X-Ray Spectrometer (XRS) instrument of Suzaku provided the first measurement of the non-X-ray background (NXB) of an X-ray calorimeter spectrometer, but the data set was limited. The Soft X-ray Spectrometer (SXS) instrument of Hitomi was able to provide a more detailed picture of X-ray calorimeter background, with more than 360 ks of data while pointed at the Earth, and a comparable amount of blank-sky data. These data are important not only for analyzing SXS science data, but also for categorizing the contributions to the NXB in X-ray calorimeters as a class. In this paper, we present the contributions to the SXS NXB, the types and effectiveness of the screening, the interaction of the screening with the broad-band redistribution, and the residual background spectrum as a function of magnetic cut-off rigidity. The orbit-averaged SXS NXB in the range 0.3-12 keV was 4 × 10(exp −2) counts s(exp −1) -sq cm. This very low background in combination with groundbreaking spectral resolution gave SXS unprecedented sensitivity to weak spectral lines.

Kilbourne, Caroline A.↗

Anomalous Uses of Mass Spectrometers at NASA

At the Harsh Environment Mass Spectrometer workshop we focus on bringing the Mass spectrometer to the sample because it's not practical to bring the samples back to the laboratories. However there are many NASA mass spectrometer applications where we bring the samples to the instrument. This presentation will discuss some of those applications that are ripe for innovative instrument development.

Loftin, Kathleen B.↗

Analytical Techniques for Retrieval of Atmospheric Composition with the Quadrupole Mass Spectrometer of the Sample Analysis at Mars Instrument Suite on Mars Science Laboratory

The Sample Analysis at Mars (SAM) instrument suite is the largest scientific payload on the Mars Science Laboratory (MSL) Curiosity rover, which landed in Mars׳ Gale Crater in August 2012. As a miniature geochemical laboratory, SAM is well-equipped to address multiple aspects of MSL׳s primary science goal, characterizing the potential past or present habitability of Gale Crater. Atmospheric measurements support this goal through compositional investigations relevant to martian climate evolution. SAM instruments include a quadrupole mass spectrometer, a tunable laser spectrometer, and a gas chromatograph that are used to analyze martian atmospheric gases as well as volatiles released by pyrolysis of solid surface materials (Mahaffy et al., 2012). This report presents analytical methods for retrieving the chemical and isotopic composition of Mars׳ atmosphere from measurements obtained with SAM׳s quadrupole mass spectrometer. It provides empirical calibration constants for computing volume mixing ratios of the most abundant atmospheric species and analytical functions to correct for instrument artifacts and to characterize measurement uncertainties. Finally, we discuss differences in volume mixing ratios of the martian atmosphere as determined by SAM (Mahaffy et al., 2013) and Viking (Owen et al., 1977, Oyama and Berdahl, 1977) from an analytical perspective. Although the focus of this paper is atmospheric observations, much of the material concerning corrections for instrumental effects also applies to reduction of data acquired with SAM from analysis of solid samples.

quadropole mass spectometer↗

Second-Generation Micro-Spec: A Compact Spectrometer for Far-Infrared and Submillimeter Space Missions

Micro-Spec is a direct-detection spectrometer which integrates all the components of a diffraction-grating spectrometer onto a ≈ 10-sq.cm chip through the use of superconducting microstrip transmission lines on a single- crystal silicon substrate. The second generation of Micro-Spec is being designed to operate with a spectral re- solution of at least 512 in the far-infrared and submillimeter (420–540 GHz, 714–555 μm) wavelength range, a band of interest for NASA's experiment for cryogenic large-aperture intensity mapping called EXCLAIM. EXCLAIM will be a balloon-borne telescope that is being designed to map the emission of redshifted carbon monoxide and singly-ionized carbon lines over a redshift range 0 < z < 3.5 and it will be the first demonstration of the Micro-Spec technology in a space-like environment. This work reviews the status of the Micro-Spec design for the EXCLAIM telescope, with emphasis on the spectrometer's two-dimensional diffractive region, through which light of different wavelengths is focused on kinetic inductance detectors along the instrument focal plane. An optimization process is used to generate a geometrical configuration of the diffractive region that satisfies l range and performance. An initial optical design optimized for n terms of geometric layout, spectral purity and efficiency.

Cataldo, Giuseppe↗

Uncertainties for Pre- and Post-Launch Radiometric Calibration of Imaging Spectrometers for Multi-Sensor Applications

An important aspect to using imaging spectrometer data is the radiometric characterization and calibration of the sensors and validation of their data products and doing so with error budgets with known traceability. The radiometric accuracy of a given sensor is important for demonstrating the expected quality of data from the sensor. Known traceability allows data from multiple sensors to be directly comparable as will become more important in the near future with the expected launches of multiple imaging spectrometers from multiple countries, agencies, and commercial entities. The current work describes the state of pre- and post-launch radiometric absolute and relative uncertainties and their role in harmonising on-orbit data. Examples of prelaunch uncertainties based on the calibration of EnMAP and the calibration planned for the CLARREO Pathfinder Mission are presented highlighting recent work in the area of detector-based approaches using tunable laser sources. Post-launch calibration approaches for Pathfinder, EnMAP, CHIME, and DESIS including traditional vicarious calibration methods and the challenges of working with commercial data are presented. The vicarious calibration discussion relies on the example of the recently-available RadCalNet data to describe typical methods and challenges that will be faced when harmonising data between imaging spectrometers as well as with multispectral sensors.

Thome, K.↗

The Marshall Grazing Incidence X-ray Spectrometer (MaGIXS) Solar Sounding Rocket Campaign – Calibration and Performance

The Marshall Grazing Incidence X-ray Spectrometer (MaGIXS) is a sounding rocket experiment that is designed to observe, for the first time, soft X-ray spectra of high-temperature, low-emission plasma of coronal structures spatially resolved along a narrow slit.MaGIXS observation involves a set of high temperature spectral lines in soft X-rays from 0.5 - 2.0 keV from an active region core,which will extend the DEM coverage from 3MK to 10MK constraining the slope of the DEM fall-off. The novel instrument designincludes a Wolter-I type telescope and a 3-optic grazing-incidence spectrometer. The spectrometer consists of a finite conjugatemirror pair and a blazed planar, varied line spaced grating, which disperses the rays on to a CCD and provides a high spatial andspectral resolution. Component level instrument testing, integration of the instrument and end-to-end X-ray calibration are carriedout using the X-ray and Cryogenic Facility (XRCF) at NASA Marshall Space Flight Center. MaGIXS is scheduled for launch in2021. We will present the results of X-ray calibration tests for MaGIXS and discuss the expected inflight performance throughdifferent solar observation scenarios.

P. S. Athiray↗

4-Pixel Heterodyne Receiver at 1.9 THz using a CMOS Spectrometer

We present results from a 4x1-pixel 1.9 THz heterodyne array for the astrophysically important [CII] spectral line. A 4-pixel multiplier chain at 1.9 THz, with a compact spacing of 5 mm, is used as an LO. Receiver performance is verified by y-factor measurements with measured sensitivities of 900 K. Finally, using a coherent source near the target frequency of 1.9 THz, we down convert to baseband and measure spectra with both an IBOB and a new CMOS-based spectrometer. The CMOS spectrometer provides several advantages over more traditional spectrometers because of its compact size and low power consumption. This receiver prototype is easily scalable to other frequencies and larger focal plane arrays. Furthermore, because of its compact configuration, it can be easily packaged for orbital or sub-orbital missions.

Mehdi, Imran↗