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NASA NTRS2000

Demonstration of Plasma Arc Environmental Technology Applications for the Demilitrization of DOD Stockpiles

Since 1989 the US Army Construction Engineering Research Laboratories (USACERL) have been active participants in the research and development towards establishing Plasma Arc Technology (PAT) as an efficient, economical, and safe hazardous waste immobilization tool. A plasma torch capable of generating high temperatures makes this technology a viable and powerful tool for the thermal destruction of various military industrial waste streams into an innocuous ceramic material no longer requiring hazardous waste landfill disposal. The emerging plasma environmental thermal treatment process has been used to safely and efficiently meet the waste disposal needs for various demilitarized components disposal needs, such as: (1) pyrotechnic smoke assemblies, (2) thermal batteries, (3) proximity fuses, (4) cartridge actuated devices (CADs), and (5) propellant actuated devices (PADs). MSE Technology Applications, Inc., (MSE) has proposed and fabricated a Mobile Plasma Treatment System to be a technology demonstrator for pilotscale mobile plasma waste processing. The system is capable of providing small-scale waste remediation services, and conducting waste stream applicability demonstrations. The Mobile Plasma Treatment System's innovative concept provides the flexibility to treat waste streams at numerous sites and sites with only a limited quantity of waste, yet too hazardous to transport to a regional fixed facility. The system was designed to be operated as skid mounted modules; consisting of a furnace module, controls module, offgas module, and ancillary systems module. All system components have been integrated to be operated from a single control station with both semi-continuous feeding and batch slag-pouring capability.

Smith, Ed↗

NASA NTRS2000

Demonstration of Plasma Arc Environmental Technology Applications for the Demilitarization of DOD Stockpiles

Since 1989 the U.S. Army Construction Engineering Research Laboratories (USACERL) have been active participants in the research and development toward establishing Plasma Arc Technology (PAT) as an efficient, economical, and safe hazardous waste immobilization tool. A plasma torch capable of generating high temperatures makes this technology a viable and powerful tool for the thermal destruction of various military industrial waste streams into an innocuous ceramic material no longer requiring hazardous waste landfill (Class 1) disposal. The emerging pl asma environmental thermal treatment process, has been used to safely and efficiently meet the waste disposal needs for various demilitarized components disposal needs, such as: pyrotechnic smoke assemblies, thermal batteries, proximity fuses, cartridge actuated devices (CAD's), and propellant actuated devices (PAD's). MSE Technology Applications, Inc., (MSE) has proposed and fabricated a Mobile Plasma Treatment System to be a technology demonstrator for pilot-scale mobile plasma waste processing. The system is capable of providing small-scale waste remediation services, and conducting waste stream applicability demonstrations. The Mobile Plasma Treatment System's innovative concept provides the flexibility to treat waste streams at numerous sites and sites with only a limited quantity of waste, yet too hazardous to transport to a regional fixed facility. The system was designed to be operated as skid mounted modules; consisting of a furnace module, controls module, offgas module, and ancillary systems module. All system components have been integrated to be operated from a single control station with both semi-continuous feeding and batch slag-pouring capability.

Smith, Ed↗

NASA NTRS2001

Vacuum Plasma Spray Forming of Tungsten Lorentz Force Accelerator Components

The Vacuum Plasma Spray (VPS) Laboratory at NASA's Marshall Space Flight Center has developed and demonstrated a fabrication technique using the VPS process to form anode sections for a Lorentz force accelerator from tungsten. Lorentz force accelerators are an attractive form of electric propulsion that provides continuous, high-efficiency propulsion at useful power levels for such applications as orbit transfers or deep space missions. The VPS process is used to deposit refractory metals such as tungsten onto a graphite mandrel of the desired shape. Because tungsten is reactive at high temperatures, it is thermally sprayed in an inert environment where the plasma gun melts and accelerates the metal powder onto the mandrel. A three-axis robot inside the chamber controls the motion of the plasma spray torch. A graphite mandrel acts as a male mold, forming the required contour and dimensions of the inside surface of the anode. This paper describes the processing techniques, design considerations, and process development associated with the VPS forming of the Lorentz force accelerator.

Zimmerman, Frank R.↗

NASA NTRS2001

Infrared Signature Masking by Air Plasma Radiation

This report summarizes the results obtained during a research program on the infrared radiation of air plasmas conducted in the High Temperature Gasdynamics Laboratory at Stanford University under the direction of Professor Charles H. Kruger, with Dr. Christophe O. Laux as Associate Investigator. The goal of this research was to investigate the masking of infrared signatures by the air plasma formed behind the bow shock of high velocity missiles. To this end, spectral measurements and modeling were made of the radiation emitted between 2.4 and 5.5 micrometers by an atmospheric pressure air plasma in chemical and thermal equilibrium at a temperature of approximately 3000 K. The objective was to examine the spectral emission of air species including nitric oxide, atomic oxygen and nitrogen lines, molecular and atomic continua, as well as secondary species such as water vapor or carbon dioxide. The cold air stream injected in the plasma torch contained approximately 330 parts per million of CO2, which is the natural CO2 concentration in atmospheric air at room temperatures, and a small amount of water vapor with an estimated mole fraction of 3.8x10(exp -4).

Kruger, Charles H.↗

NASA NTRS2001

Vapor Grown Carbon Fiber/Phenolic Matrix Composites for Rocket Nozzles and Heat Shields

The ablation and mechanical and thermal properties of vapor grown carbon fiber (VGCF)/phenolic resin composites were evaluated to determine the potential of using this material in solid rocket motor nozzles. Composite specimens with varying VGCF loading (30%-50% wt) including one sample with ex-rayon carbon fiber plies were prepared and exposed to a plasma torch for 20 s with a heat flux of 16.5 MW/sq m at approximately 1650 C. Low erosion rates and little char formation were observed, confirming that these materials were promising for rocket motor nozzle materials. When fiber loadings increased, mechanical properties and ablative properties improved. The VGCF composites had low thermal conductivities (approximately 0.56 W/m-C) indicating they were good insulating materials. If a 65% fiber loading in VGCF composite can be achieved, then ablative properties are projected to be comparable to or better than the composite material currently used on the Space Shuttle Reusable Solid Rocket Motor (RSRM).

Patton, R. D.↗

NASA NTRS1994

A Study of High Altitude Hypersonic Flow-Field Radiation

This paper presents the results of the works carried out jointly at Stanford University and Ames Research Center under a grant from the Ballistic Missile Defense Organization (BMDO) (formerly the Strategic Defense Initiative Organization) to explain and understand the results of the two flight experiments, Bow Shock Ultra-Violet 1 and Bow Shock Ultra-Violet 2, carried out by the Organization. A portion of the material contained in this paper has been reported elsewhere in open literature. However, this paper provides (1) the details of scientific contents not available in those literature, (2) the links among those and the logical order of the efforts involved, and (3) some materials not contained in any open literature. The first author is responsible for execution of the work; the second author directed the work of the first author. In the two flight experiments mentioned above, the spectra of radiation in the ultraviolet wavelength range incident on the stagnation point of a blunt body were measured at the flight speeds of 3.8 and 5.2 km/sec over a wide range of altitudes. The results were compared first with the calculations made using the original version of the NEQAIR/STRAP codes written earlier by the second author. At low altitudes, the calculations agreed with the measurement. However, at high altitudes, the calculations underestimated the intensity of the radiation by several orders of magnitudes. A shock tube experiment was carried out at CALSPAN and a plasma-torch experiment was carried out at Stanford University to produce experimental data to help explain the discrepancy. In addition, the shock tube experiment at Ames Research Center carried out independently of the BMDO was also found to be relevant to this question. In this paper, several theoretical models are developed and calculations using the models were carried out to explain the results not only of the flight experiments but also of the CALSPAN, Stanford, and Ames experiments. The are: (1) the diffusion model for the rotational mode to explain the slowness of rotational excitation, (2) assignment of different vibrational temperatures and different relaxation rates for different molecules, and (3) the modification of the NEQAIR code to accommodate the new experimental data. This paper shows that the discrepancy between the flight data and calculation is smaller with the present model, but is still substantial.

Moreau, Stephane↗

NASA NTRS2001

Laser Ignition Technology for Bi-Propellant Rocket Engine Applications

The fiber optically coupled laser ignition approach summarized is under consideration for use in igniting bi-propellant rocket thrust chambers. This laser ignition approach is based on a novel dual pulse format capable of effectively increasing laser generated plasma life times up to 1000 % over conventional laser ignition methods. In the dual-pulse format tinder consideration here an initial laser pulse is used to generate a small plasma kernel. A second laser pulse that effectively irradiates the plasma kernel follows this pulse. Energy transfer into the kernel is much more efficient because of its absorption characteristics thereby allowing the kernel to develop into a much more effective ignition source for subsequent combustion processes. In this research effort both single and dual-pulse formats were evaluated in a small testbed rocket thrust chamber. The rocket chamber was designed to evaluate several bipropellant combinations. Optical access to the chamber was provided through small sapphire windows. Test results from gaseous oxygen (GOx) and RP-1 propellants are presented here. Several variables were evaluated during the test program, including spark location, pulse timing, and relative pulse energy. These variables were evaluated in an effort to identify the conditions in which laser ignition of bi-propellants is feasible. Preliminary results and analysis indicate that this laser ignition approach may provide superior ignition performance relative to squib and torch igniters, while simultaneously eliminating some of the logistical issues associated with these systems. Further research focused on enhancing the system robustness, multiplexing, and window durability/cleaning and fiber optic enhancements is in progress.

Thomas, Matthew E.↗

NASA NTRS2002

Hybrid Propulsion Testing at Marshall Space Flight Center

Hybrid propulsion testing involving eleven and twenty-four inch motors performed at the Marshall Space Flight Center (MSFC) from the early 1990's to the present are discussed. Topics covered include: Solid Propulsion Investigation Program, Joint NASA Industry Research and Development (JIRAD) program, Large Subscale Solid Rocket Combustion Simulator (LSSRCS), Hybrid Propulsion Demonstration Program (HPDP), Hybrid Propulsion for Launch Vehicle Booster (HPTLV), Peroxide Hybrid Upper Stage (PHUS) and Solid Fuel Torch (SFT).

Prince, Andrew S.↗

NASA NTRS1993

Welding Sensor System

A system originally designed for welding components of the huge Space Shuttle external tank led to a laser-based automated welder for industrial use. A laser sensor tracks the seam where two pieces of metal are to be joined, measures gaps, misfits and automatically corrects welding of torch distance and height. A small industrial computer translates the sensor's information to the weld head and records and displays weld data for control purposes and analysis. The system was modified for commercial use by Marshall Space Flight Center (MSFC), Martin Marietta and Applied Research, Inc., which produces the commercial system. Applications are in industrial welding processes that require repetitive operations and a high degree of reliability.

Source record↗

NASA NTRS1987

Jewelry Design

A jeweler's torch generates temperatures of 1,400 - 1,800 degrees. Asbestos blocks were used as soldering bases but they were disintegrating at high temperatures. Space Shuttle tiles, manufactured by Lockheed Missiles & Space Co., offered a base with temperature resistance far beyond his requirements.

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NASA NTRS2002

Thermal Stir Welding: A New Solid State Welding Process

Thermal stir welding is a new welding process developed at NASA's Marshall Space Flight Center in Huntsville, AL. Thermal stir welding is similar to friction stir welding in that it joins similar or dissimilar materials without melting the parent material. However, unlike friction stir welding, the heating, stirring and forging elements of the process are all independent of each other and are separately controlled. Furthermore, the heating element of the process can be either a solid-state process (such as a thermal blanket, induction type process, etc), or, a fusion process (YG laser, plasma torch, etc.) The separation of the heating, stirring, forging elements of the process allows more degrees of freedom for greater process control. This paper introduces the mechanics of the thermal stir welding process. In addition, weld mechanical property data is presented for selected alloys as well as metallurgical analysis.

Ding, R. Jeffrey↗

NASA NTRS1982

Automatic Welding System

Robotic welding has been of interest to industrial firms because it offers higher productivity at lower cost than manual welding. There are some systems with automated arc guidance available, but they have disadvantages, such as limitations on types of materials or types of seams that can be welded; susceptibility to stray electrical signals; restricted field of view; or tendency to contaminate the weld seam. Wanting to overcome these disadvantages, Marshall Space Flight Center, aided by Hayes International Corporation, developed system that uses closed-circuit TV signals for automatic guidance of the welding torch. NASA granted license to Combined Technologies, Inc. for commercial application of the technology. They developed a refined and improved arc guidance system. CTI in turn, licensed the Merrick Corporation, also of Nashville, for marketing and manufacturing of the new system, called the CT2 Optical Trucker. CT2 is a non-contracting system that offers adaptability to broader range of welding jobs and provides greater reliability in high speed operation. It is extremely accurate and can travel at high speed of up to 150 inches per minute.

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NASA NTRS1976

Explosive Entrances

Explosive Technology, Inc. manufactured explosives first used by NASA to separate stages of the Gemini launch vehicle. When firemen need to get into a burning building or chop a hole to provide ventilation, axes can be devastatingly slow. Controlled explosives developed to separate manned upper stages of space rockets in case of mishap have been adapted to cutting emergency exits and demolishing unsafe buildings and bridges. Detonation cuts through thick steel girders or other materials more cleanly than torches or saws. This device can also cut emergency holes in airplanes and trains so surviving passengers can escape.

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NASA NTRS1976

Portable Home Welder

Pyronetics, Inc. manufactured a small, do-it-yourself welding torch which weighs only 7 pounds, gives a 5,000 degree Farenheit flame, and costs only $40.00. This resulted from information provided by a NASA Industrial Application Center at the University of Southern California. The center provided information on chlorate candles, unique in that they generate oxygen while burning. A retrospective search uncovered information on composition, hazards, applications, manufacturers, and shipping regulations.

Source record↗

NASA NTRS2003

Thermal Stir Welding: A New Solid State Welding Process

Ding, R. Jeffrey↗

NASA NTRS2003

Evaluation and Characterization Study of Dual Pulse Laser-Induced Spark (DPLIS) for Rocket Engine Ignition System Application

This paper addresses the progress of technology development of a laser ignition system at NASA Marshall Space Flight Center (MSFC). Laser ignition has been used at MSFC in recent test series to successfully ignite RP1/GOX propellants in a subscale rocket chamber, and other past studies by NASA GRC have demonstrated the use of laser ignition for rocket engines. Despite the progress made in the study of this ignition method, the logistics of depositing laser sparks inside a rocket chamber have prohibited its use. However, recent advances in laser designs, the use of fiber optics, and studies of multi-pulse laser formats3 have renewed the interest of rocket designers in this state-of the-art technology which offers the potential elimination of torch igniter systems and their associated mechanical parts, as well as toxic hypergolic ignition systems. In support of this interest to develop an alternative ignition system that meets the risk-reduction demands of Next Generation Launch Technology (NGLT), characterization studies of a dual pulse laser format for laser-induced spark ignition are underway at MSFC. Results obtained at MSFC indicate that a dual pulse format can produce plasmas that absorb the laser energy as efficiently as a single pulse format, yet provide a longer plasma lifetime. In an experiments with lean H2/air propellants, the dual pulse laser format, containing the same total energy of a single laser pulse, produced a spark that was superior in its ability to provide sustained ignition of fuel-lean H2/air propellants. The results from these experiments are being used to optimize a dual pulse laser format for future subscale rocket chamber tests. Besides the ignition enhancement, the dual pulse technique provides a practical way to distribute and deliver laser light to the combustion chamber, an important consideration given the limitation of peak power that can be delivered through optical fibers. With this knowledge, scientists and engineers at Los Alamos National Laboratory and CFD Research Corporation have designed and fabricated a miniaturized, first-generation optical prototype of a laser ignition system that could be the basis for a laser ignition system for rocket applications. This prototype will be tested at MSFC in future subscale rocket ignition tests.

Osborne, Robin↗

NASA NTRS2004

Flame Retardant Epoxy Resins

As part of a program to develop fire resistant exterior composite structures for future subsonic commercial aircraft, flame retardant epoxy resins are under investigation. Epoxies and their curing agents (aromatic diamines) containing phosphorus were synthesized and used to prepare epoxy formulations. Phosphorus was incorporated within the backbone of the epoxy resin and not used as an additive. The resulting cured epoxies were characterized by thermogravimetric analysis, propane torch test, elemental analysis and microscale combustion calorimetry. Several formulations showed excellent flame retardation with phosphorous contents as low as 1.5% by weight. The fracture toughness of plaques of several cured formulations was determined on single-edge notched bend specimens. The chemistry and properties of these new epoxy formulations are discussed.

Thompson, C. M.↗

NASA NTRS2004

Vacuum Plasma Spray Forming of Tungsten Lorentz Force Accelerator Components

The Vacuum Plasma Spray (VPS) Laboratory at NASA's Marshall Space Flight Center, working with the Jet Propulsion Laboratory, has developed and demonstrated a fabrication technique using the VPS process to form anode and cathode sections for a Lorentz force accelerator made from tungsten. Lorentz force accelerators are an attractive form of electric propulsion that provides continuous, high-efficiency propulsion at useful power levels for such applications as orbit transfers or deep space missions. The VPS process is used to deposit refractory metals such as tungsten onto a graphite mandrel of the desired shape. Because tungsten is reactive at high temperatures, it is thermally sprayed in an inert environment where the plasma gun melts and deposits the molten metal powder onto a mandrel. A three-axis robot inside the chamber controls the motion of the plasma spray torch. A graphite mandrel acts as a male mold, forming the required contour and dimensions for the inside surface of the anode or cathode of the accelerator. This paper describes the processing techniques, design considerations, and process development associated with the VPS forming of Lorentz force accelerator components.

Zimmerman, Frank R.↗