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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

The Aura Mission, Science and Validation

The EOS-Aura Mission is designed to answer three basic questions concerning the Earth's atmosphere: 1) Is stratospheric ozone recovering as predicted, 2) what are the processes that control air quality, and 3) how is changes in atmospheric chemistry effecting climate? Aura's four instruments work synergistically and are dedicated to answering these questions. Aura's instruments observe from the ultraviolet to the microwave region and view in the nadir and limb. This capability allows measurements of all the critical source, radical, and reservoir gases in the stratosphere to be observed globally on a daily basis. Aura will also continue the TOMS global ozone trend record. Observations in the troposphere will be conducted with the best spatial resolution and coverage ever achieved from space. Key pollutants, including aerosols, gases, and their precursors are the primary targets for Aura. High vertical resolution measurements will be made in the vicinity of the tropopause to better define the interactions of the UT/LS and particularly determine the amount downward transport of ozone and upward transport.of water vapor where both contribute to climate forcing. Aura will also measure aerosols in the stratosphere and troposphere where they play a role in ozone chemistry, air quality and climate. Aura data will be used by several environmental agencies for their decision support systems. Aura post launch validation program includes an augmented ground based measurement program which include the operational networks which measure atmospheric composition. Validation will be conducted under a range of geophysical conditions and throughout most of Aura s observing range. Balloon campaigns will conducted from a variety of latitudes and numerous aircraft missions are planned to cover an altitude range from the middle troposphere to the lower stratosphere and include in-situ and remote sensors. Long duration Un-inhabited aircraft are also being considered as part of the validation program. Substantial collaboration is planned with other chemistry satellite missions such as Envisat, SciSat, and Odin in order to make efficient use of resources and to provide continuity among these missions.

Hilsenrath, Ernest↗
NASA NTRS1980

Examples of realistic aerosol particles collected in a cascade impactor

In this paper some scanning electron microscope photomicrographs showing examples of a variety of particulate aerosol shapes are presented. Compositions of particles also are presented. These particles represent samples from a number of different sources and locations including: solid propellant rocket motor plumes, active volcano plumes, the lower stratosphere over Sondrestrom, Greenland, and the upper troposphere over northern Texas. The particles were collected from aboard an aircraft with a cascade impactor which classified them according to aerodynamic size into 10 size intervals ranging from submicron to greater than 25 micrometers in diameter. The cascade impactor also served to measure the mass concentration as a function of particle size. The variety of shapes and compositions found among these particles suggest difficulties in obtaining reliable size distribution data from light scattering measurements.

Woods, D. C.↗
NASA NTRS2015

On the Feasibility of Monitoring Carbon Monoxide in the Lower Troposphere from a Constellation of Northern Hemisphere Geostationary Satellites (PART 1)

By the end of the current decade, there are plans to deploy several geostationary Earth orbit (GEO) satellite missions for atmospheric composition over North America, East Asia and Europe with additional missions proposed. Together, these present the possibility of a constellation of geostationary platforms to achieve continuous time-resolved high-density observations over continental domains for mapping pollutant sources and variability at diurnal and local scales. In this paper, we use a novel approach to sample a very high global resolution model (GEOS-5 at 7 km horizontal resolution) to produce a dataset of synthetic carbon monoxide pollution observations representative of those potentially obtainable from a GEO satellite constellation with predicted measurement sensitivities based on current remote sensing capabilities. Part 1 of this study focuses on the production of simulated synthetic measurements for air quality OSSEs (Observing System Simulation Experiments). We simulate carbon monoxide nadir retrievals using a technique that provides realistic measurements with very low computational cost. We discuss the sampling methodology: the projection of footprints and areas of regard for geostationary geometries over each of the North America, East Asia and Europe regions; the regression method to simulate measurement sensitivity; and the measurement error simulation. A detailed analysis of the simulated observation sensitivity is performed, and limitations of the method are discussed. We also describe impacts from clouds, showing that the efficiency of an instrument making atmospheric composition measurements on a geostationary platform is dependent on the dominant weather regime over a given region and the pixel size resolution. These results demonstrate the viability of the "instrument simulator" step for an OSSE to assess the performance of a constellation of geostationary satellites for air quality measurements.

GEOS-5↗
NASA NTRS1999

Sulfate and Pb-210 Simulated in a Global Model Using Assimilated Meteorological Fields

This report presents the results of distributions of tropospheric sulfate, Pb-210 and their precursors from a global 3-D model. This model is driven by assimilated meteorological fields generated by the Goddard Data Assimilation Office. Model results are compared with observations from surface sites and from multiplatform field campaigns of Pacific Exploratory Missions (PEM) and Advanced Composition Explorer (ACE). The model generally captures the seasonal variation of sulfate at the surface sites, and reproduces well the short-term in-situ observations. We will discuss the roles of various processes contributing to the sulfate levels in the troposphere, and the roles of sulfate aerosol in regional and global radiative forcing.

Chin, Mian↗
NASA NTRS1993

Measurements of atmospheric dimethylsulfide, hydrogen sulfide, and carbon disulfide during GTE/CITE 3

Measurements of atmospheric dimethylsulfide (DMS), hydrogen sulfide (H2S), and carbon disulfide (CS2) were made over the North and South Atlantic Ocean as part of the Global Tropospheric Experiment/Chemical Instrumentation Test and Evaluation (GTE/CITE 3) project. DMS and CS2 samples were collected and analyzed using an automated gas chromatography/flame photometric detection system with a sampling frequency of 10 min. H2S samples were collected using silver nitrate impregnated filters and analyzed by fluorescence quenching. The DMS data from both hemispheres have a bimodal distribution. Over the North Atlantic this reflects the difference between marine and continental air masses. Over the South Atlantic it may reflect differences in the sea surface source of DMS, corresponding to different air mass source regions. The median boundary layer H2S and CS2 levels were significantly higher in the northern hemisphere than the southern hemisphere, reflecting the higher frequency of samples influenced by pollutant and/or coastal emissions. Composite vertical profiles of DMS and H2S are similar to each other, are consistent with a sea surface source. Vertical profiles of CS2 have maxima in the free troposphere, implicating a continental source. The low levels of H2S and CS2 found in the southern hemisphere constrain the role of these compounds in global budgets to significantly less than previously estimated.

Cooper, David J.↗
NASA NTRS2004

Jupiter's Atmospheric Temperatures: From Voyager IRIS to Cassini CIRS

Retrievals run on Cassini Composite Infrared Spectrometer data obtained during the distant Jupiter flyby have been used to generate global temperature maps of the planet in the troposphere and stratosphere. Similar retrievals were performed on Voyager 1 IRIS data and have provided the first detailed IRIS map of the stratosphere. In both data sets, high latitude troposphere temperatures are presented for the first time, and the meridional gradients indicate the presence of circumpolar jets. Thermal winds were calculated for each data set and show strong vertical shears in the zonal winds at low latitudes. The temperatures retrieved from the two spacecraft were also compared with yearly ground-based data obtained over the intervening two decades. Tropospheric temperatures reveal gradual changes at low latitudes, with little obvious seasonal or short-term variation (Orton et al. 1994). Stratospheric temperatures show much more complicated behavior over short timescales, consistent with quasi-quadrennial oscillations at low latitudes, as suggested in prior analyses of shorter intervals of ground- based data (Orton et al. 1991, Friedson 1999). A scaling analysis indicates that meridional motions, mechanically forced by wave or eddy convergence, play an important role in modulating the temperatures and winds in the upper troposphere and stratosphere on seasonal and shorter time scales. At latitudes away from the equator, the mechanical forcing can be derived simply from a temporal record of temperature and its vertical derivative. Ground-based observations with improved vertical resolution and/or long-term monitoring from spacecraft are required for this purpose.

Simon-Miller, Amy A.↗
NASA NTRS2001

Environmental Impact Overview

Aircraft emissions are deposited throughout the atmosphere, and at the lower stratosphere and upper troposphere they have greater potential to change ozone abundance and affect climate. There are significant uncertainties arising from the incomplete knowledge of the composition and evolution of the exhaust emissions, particularly regarding reactive trace species, particles, and their gaseous precursors. NASA Glenn Research Center at Lewis Field has considered its role in answering these challenges and has been committed to strengthening its aerosol/particulate research capabilities with initial emphasis on establishing advanced measurement systems and a particulate database. Activities currently supported by the NASA Ultra-Efficient Engine Technology (UEET) Program and accomplishment up to date will be described.

Peddie, Catherine↗
NASA NTRS2017

Assessing the Altitude and Dispersion of Volcanic Plumes Using MISR Multi-angle Imaging from Space: Sixteen Years of Volcanic Activity in the Kamchatka Peninsula, Russia

Volcanic eruptions represent a significant source of atmospheric aerosols and can display local, regional and global effects, impacting earth systems and human populations. In order to assess the relative impacts of these events, accurate plume injection altitude measurements are needed. In this work, volcanic plumes generated from seven Kamchatka Peninsula volcanoes (Shiveluch, Kliuchevskoi, Bezymianny, Tolbachik, Kizimen, Karymsky and Zhupanovsky), were identified using over 16 years of Multi-angle Imaging SpectroRadimeter (MISR) measurements. Eighty-eight volcanic plumes were observed by MISR, capturing 3-25% of reported events at individual volcanoes. Retrievals were most successful where high intensity events persisted over a period of weeks to months. Compared with existing ground and airborne observations, and alternative satellite-based reports compiled by the Global Volcanism Program (GVP), MISR plume height retrievals showed general consistency; the comparison reports appear to be skewed towards the region of highest concentration observed in MISR-constrained vertical plume extent. The report observations display less discrepancy with MISR toward the end of the analysis period, with improvements in the suborbital data likely the result of the deployment of new instrumentation. Conversely, the general consistency of MISR plume heights with conventionally reported observations supports the use of MISR in the ongoing assessment of volcanic activity globally, especially where other types of volcanic plume observations are unavailable. Differences between the northern (Shiveluch, Kliuchevskoi, Bezymianny and Tolbachik) and southern (Kizimen, Karymsky and Zhupanovsky) volcanoes broadly correspond to the Central Kamchatka Depression (CKD) and Eastern Volcanic Front (EVF), respectively, geological sub-regions of Kamchatka distinguished by varying magma composition. For example, by comparison with reanalysis-model simulations of local meteorological conditions, CKD plumes generally were less constrained by mid-tropospheric (< 6 km) layers of vertical stability above the boundary layer, suggesting that these eruptions were more energetic than those in the EVF

Kamchatka↗
NASA NTRSDate not supplied

Observations of the Age of Air from the Northern Hemisphere Midlatitude Surface

Understanding and modeling the interhemispheric transport (IHT) of trace gases and aerosols is important for interpreting past (and projecting future) changes in atmospheric composition. One IHT measure -- the mean age since air was last at the Northern Hemisphere (NH) midlatitude surface – represents a fundamental property of tropospheric transport that can be estimated from measurements of sulfur hexafluoride (SF6). Here we use SF6 measurements obtained from the recent NASA Atmospheric Tomography Mission (ATom) to construct observational estimates of the mean age throughout the troposphere. We compare the ATom based ages, which span all four seasons during the period 2016-2018 over both the Pacific and Atlantic Oceans, with previous in situ-based estimates obtained from the HIAPER Pole‐to‐Pole Observations (HIPPO) project, which are available only for the Pacific. In order to interpret the observed variations in mean age and their relationship with the large-scale flow we use simulations of the Goddard Earth Observing System (GEOS) general circulation model, constrained with meteorological fields derived from the Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2), performed over the entire MERRA-2 period (including ATom). We confirm results from previous studies showing that the model ages are biased old compared to the observational estimates. However, we also show that this model bias is reduced in more recent years, which we interpret in terms of changes in the latitudinal distribution of SF6 emissions over the 2000s.

interhemispheric transport (IHT)↗
NASA NTRS2008

Observations and Modeling of Composition of Upper Troposphere/Lower Stratosphere (UTILS): Isentropic Mixing Events and Morphology of HNO3 as Observed by HIRDLS and Comparison with Results from Global Modeling Initiative

isentropic exchange of air masses between the tropical upper troposphere and mid-latitude lowermost stratosphere (the so-called "middle world") is an important pathway for stratospheric-tropospheric exchange. A seasonal, global view of this process has been difficult to obtain, in part due to the lack of the vertical resolution in satellite observations needed to capture the laminar character of these events. Ozone observations at a resolution of about 1 km from the High Resolution Dynamic Limb Sounder (HIRDLS) on NASA's Aura satellite show instances of these intrusions. Such intrusions should also be observable in HN03 observations; however, the abundances of nitric acid could be additionally controlled by chemical processes or incorporation and removal into ice clouds. We present a systematic examination of the HIRDLS data on O3 and HNO3 to determine the seasonal and spatial characteristics of the distribution of isentropic intrusions. At the same time, we compare the observed distributions with those calculated by the Global Modeling Initiative combined tropospheric-stratospheric model, which has a vertical resolution of about I km. This Chemical Transport Model (CTM) is driven by meteorological fields obtained from the GEOS-4 system of NASA/Goddard Global Modeling and Assimilation Office (GMAO), for the Aura time period, at a vertical resolution of about 1 km. Such comparison brings out the successes and limitations of the model in representing isentropic stratospheric-tropospheric exchange, and the different processes controlling HNO3 in the UTAS.

Rodriquez, J. M.↗
NASA NTRS2006

Preface to Special Section: Validation of Atmospheric Infrared Sounder Observations

The papers described below demonstrate that the AIRS calibrated radiances and retrieved geophysical products generally meet or exceed the prelaunch specifications. The retrieved quantities show little variation in uncertainty as a function of cloud amount. However, AIRS retrieval yield is a rapidly decreasing function of cloud amount; at about 80% cloudiness essentially no infrared radiances are used in the retrieval processes. Also, AIRS performance has not been demonstrated for all conditions and products. Calibrated and forward calculated radiances meet performance specifications for conditions varying from the cold poles to warm tropics. The retrieval system performs well over extrapolar land in the free troposphere (~2-15 km above the surface) and over extrapolar oceans at all tropospheric altitudes. The AIRS retrieval algorithms have not been optimized for polar winter conditions, so no such results are presented in these papers.

temperature↗
NASA NTRSDate not supplied

NASA's High-Resolution GEOS Forecasting and Reanalysis Products: A Unified Tool from Local to Global Scales

NASA's GMAO produces high-resolution global forecasts for weather, aerosols, and air quality. The NASA Global Earth Observing System (GEOS) model has been expanded to provide global near-real-time 5-day forecasts of atmospheric chemical composition at unprecedented horizontal resolution of 0.25 degrees (~25 km), freely available to the public. This composition forecast system (GEOS-CF) combines the operational GEOS weather forecasting model with the state-of-the-science GEOS-Chem chemistry module to provide detailed analysis of a wide range of air pollutants such as ozone, carbon monoxide, nitrogen oxides, and fine particulate matter (PM2.5). GEOS-CF also assimilated satellite observations into the system for improved representation of weather and smoke. The assimilation system is currently being expanded to include chemically reactive trace gases. While the main focus of this new product is on tropospheric air quality information, the GEOS-Chem chemistry model used in this system includes the unified tropospheric stratospheric chemistry mechanism for improved forecasts of total column ozone during anomalous dynamical and chemical events. I will discuss current capabilities of the GEOS Constituent Data Assimilation System (CoDAS) to improve atmospheric composition modeling and possible future directions for GEOS-CF and reanalysis products. In addition, I will show how machine learning techniques can be used to correct for sub-grid-scale variability, which further improves model estimates at a given observation site.

Co-DAS↗
NASA NTRS2015

Fire Influences on Atmospheric Composition, Air Quality, and Climate

Fires impact atmospheric composition through their emissions, which range from long-lived gases to short-lived gases and aerosols. Effects are typically larger in the tropics and boreal regions but can also be substantial in highly populated areas in the northern mid-latitudes. In all regions, fire can impact air quality and health. Similarly, its effect on large-scale atmospheric processes, including regional and global atmospheric chemistry and climate forcing, can be substantial, but this remains largely unexplored. The impacts are primarily realised in the boundary layer and lower free troposphere but can also be noticeable in upper troposphere/lower stratosphere (UT/LS) region, for the most intense fires. In this review, we summarise the recent literature on findings related to fire impact on atmospheric composition, air quality and climate. We explore both observational and modelling approaches and present information on key regions and on the globe as a whole. We also discuss the current and future directions in this area of research, focusing on the major advances in emission estimates, the emerging efforts to include fire as a component in Earth system modelling and the use of modelling to assess health impacts of fire emissions.

Air quality↗
DOE OSTI2025

Tropospheric aerosols over the western North Atlantic Ocean during the winter and summer deployments of ACTIVATE 2020: life cycle, transport, and distribution

The Aerosol Cloud meTeorology Interactions oVer the western ATlantic Experiment (ACTIVATE) is a NASA mission to characterize aerosol–cloud interactions over the western North Atlantic Ocean (WNAO). Such characterization requires understanding of life cycle, composition, transport pathways, and distribution of aerosols over the WNAO. This study uses the GEOS-Chem model to simulate aerosol distributions and properties that are evaluated against aircraft, ground-based, and satellite observations during the winter and summer field deployments in 2020 of ACTIVATE. Transport in the boundary layer (BL) behind cold fronts was a major mechanism for the North American continental outflow of pollution to the WNAO in winter. Turbulent mixing was the main driver for the upward transport of sea salt within and ventilation out of BL in winter. The BL aerosol composition was dominated by sea salt, which increased in the summer, followed by organics and sulfate. Aircraft in situ aerosol measurements provided useful constraints on wet scavenging in GEOS-Chem. The model generally captured observed features such as continental outflow, land–ocean gradient, and mixing of anthropogenic aerosols with sea salt. Model sensitivity experiments with elevated smoke injection heights to the mid-troposphere (versus within BL) better reproduced observations of smoke aerosols from the western US wildfires over the WNAO in the summer. Model analysis suggests strong hygroscopic growth of sea salt particles and their seeding of marine BL clouds over the WNAO (< 35° N). Future modeling efforts should focus on improving parameterizations for aerosol wet scavenging, implementing realistic smoke injection heights, and applying high-resolution models that better resolve vertical transport.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1985

The photochemistry of atmospheres: Earth, the other planets, and comets

Papers on the photochemistry of the early atmosphere, the troposphere, stratosphere, and upper atmosphere are presented. Consideration is given to the effect of chemical constituents on the climate and atmosphere. Topics discussed include the composition of the atmospheres of Venus, Mars, the outer planets and their satellites, and the chemical changes which occur in comets.

Levine, J. S.↗
NASA NTRS2002

Convection and Easterly Wave Structure Observed in the Eastern Pacific Warm-Pool during EPIC-2001

During September-October 2001, the East Pacific Investigation of Climate Processes in the Coupled Ocean-Atmosphere System (EPIC-2001) ITCZ field campaign focused on studies of deep convection in the warm-pool region of the East Pacific. In addition to the TAO mooring array, observational platforms deployed during the field phase included the NOAA ship RN Ronald H. Brown, the NSF ship RN Horizon, and the NOAA P-3 and NCAR C-130 aircraft. This study combines C-band Doppler radar, rawinsonde, and surface heat flux data collected aboard the RN Brown to describe ITCZ convective structure and rainfall statistics in the eastern Pacific as a function of 3-5 day easterly wave phase. Three distinct easterly wave passages occurred during EPIC-2001. Wind and thermodynamic data reveal that the wave trough axes exhibited positively correlated U and V winds and a slight westward phase tilt with height. A relatively strong (weak) northeasterly deep tropospheric shear followed the trough (ridge) axis. Temperature and humidity perturbations exhibited mid-to upper level cooling (warming) and drying (moistening) in the northerly (trough and southerly) phase. At low levels warming (cooling) occurred in the northerly (southerly) phase with little change in the relative humidity, though mixed layer mixing ratios were larger during the northerly phase. When composited, radar, sounding, lightning and surface heat flux observations suggest the following systematic behavior as a function of wave phase: approximately zero to one quarter wavelength ahead of (behind) the wave trough in northerly (southerly) flow, larger (smaller) CAPE, lower (higher) CIN, weaker (stronger) tropospheric shear, higher (lower) conditional mean rain rates, higher (lower) lightning flash densities, and more (less) robust convective vertical structure occurred. Latent and sensible heat fluxes reached a minimum in the northerly phase and then increased through the trough, reaching a peak during the ridge phase (leading the peak in CAPE). From a radar echo coverage perspective, larger areas of light rain and slightly larger (10%) area averaged rain rates occurred in the vicinity of, and just behind, the trough axes in southerly flow. Importantly, the transition in convective structure observed across the trough axis when considered with the relatively small change in area mean rain rates suggests the presence of a transition in the vertical structure of diabatic heating across the easterly waves examined. The inferred transition in heating structure is supported by radar diagnosed divergence profiles that exhibit convective (stratiform) characteristics ahead of (behind) the trough.

Peterson, Walter A.↗
NASA NTRSDate not supplied

Observing and Projecting the Lasting Fate of the Hunga Eruption on Atmospheric Water Vapor and Hydroxyl Radical

On 15th Jan. 2022 the submarine Hunga volcano erupted injecting approximately 0.5 Tg of sulfur dioxide into the stratosphere, but more significantly added 150-170 Tg of water vapor to the stratospheric background (over a 10% perturbation) in a matter of several hours. The sulfur dioxide rapidly converted to sulfate aerosol and along with water vapor, was transported around the Southern Hemisphere sub-tropics into midlatitudes and beyond with some transport into the Northern Hemisphere. With a much longer lifetime than sulfate aerosol, measurable water vapor mass anomalies have persisted with only small losses over more than 2 years since the eruption and are likely to continue above background for the remainder of the decade. Satellite measurements from limb and nadir viewing observing instruments provide the information needed to reasonably initialize the Hunga eruption in the Goddard Earth Observing System (GEOS) model using the “replay” framework coupled to the Global Modeling Initiative (GMI) stratosphere-troposphere chemical mechanism for the recent past and have continued the simulations into the future with the free running chemistry climate model (CCM). Using a number of model ensemble members together with the satellite observations, we quantify how the Hunga eruption is perturbing atmospheric composition and climate and projecting the influences to come as the enhanced water vapor continues in the stratosphere with only very slow removal mechanisms. Modeling suggests that the water rich eruption enhanced stratospheric hydroxyl radiacal (OH) and is supported by the speed of the observed conversion of SO2 into sulfate aerosol. These simulations also suggest a significant reduction in tropospheric OH over the mid-high latitude Southern Hemisphere, which has implications for numerous species that are impacted by this radical. The Hunga eruption provides a useful test of chemistry climate models and an opportunity for observation-based process understanding and in making new connections.

Hunga volcano↗
NASA NTRS2018

Thermal Emission From Saturn's Polar Cyclones

We have used data from the Cassini Composite Infrared Spectrometer to map the temperatures in Saturn's polar cyclones at the highest spatial resolution obtained during the Cassini mission. We find temperature contrasts of 7 K in the upper troposphere within 1.4° of both poles, roughly 50 percent larger than earlier measurements at lower spatial resolution. The polar hot spots weaken with depth, disappearing near 500 mbar. In the stratosphere, the polar hot spot becomes broader, extending 4° from the poles, and weakens with altitude disappearing near 1 mbar. A thermal relaxation model shows that the tropospheric hot spot is consistent with adiabatic heating from subsidence with a vertical velocity of about −0.05 mm/s above 500 mbar. The observed temperature gradients imply that the winds in the polar cyclone decay with increasing altitude over roughly three pressure scale heights above the 200‐mbar level.

Polar↗