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At least 289 records · Page 16

Using X-ray radiography to study oxygen flow in a proton exchange membrane electrolyzer operating under balanced pressure conditions

Of the various water electrolyzer technologies, the proton exchange membrane electrolyzer (PEMWE) is one of the best solutions for producing clean hydrogen without releasing CO 2 . In order to allow for widespread use of clean hydrogen, it is necessary to decrease its cost, which is intrinsically related to system operation. Current PEMWE plants operate in differential mode, directly pressurizing hydrogen and benefiting from thermodynamic compression, which increases overall system efficiency. However, high differential pressure above 30 bar can cause membrane stress, resulting in membrane creeping and failure. Pressurizing the water and operating at balanced pressure allows hydrogen to be produced at higher pressures while preserving the integrity of the membrane and porous layers. Nevertheless, the impact of pressurizing water on PEMWE performance must be better understood to maximize performance under balanced pressure conditions. Here, this study examined the impact of water pressure on two-phase flow. A high-pressure electrolyzer setup was developed to perform operando X-ray radiography and examine oxygen transport with high temporal resolution. The imaging segmentation process, developed to capture bubble properties in the channel, was applied to a specific experiment. The results clearly showed that as pressure increased up to 30 bars, the initial bubbly flow transitioned to slug flow, which led to channel saturation with oxygen. This work demonstrates that two-phase flow in an electrolyzer can be studied using X-ray radiography, which has the advantages of fast measurements and the ability to probe dense materials, such as those required for pressurized electrolyzers.

Balanced high pressure operation↗

Reduced gravity boiling and condensing experiments simulated with the COBRA/TRAC computer code

A series of reduced-gravity two-phase flow experiments has been conducted with a boiler/condenser apparatus in the NASA KC-135 aircraft in order to obtain basic thermal-hydraulic data applicable to analytical design tools. Several test points from the KC-135 tests were selected for simulation by means of the COBRA/TRAC two-fluid, three-field thermal-hydraulic computer code; the points were chosen for a 25-90 percent void-fraction range. The possible causes for the lack of agreement noted between simulations and experiments are explored, with attention to the physical characteristics of two-phase flow in one-G and near-zero-G conditions.

Cuta, Judith M.↗

Pressure distribution in a converging-diverging nozzle during two-phase choked flow of subcooled nitrogen

Choked flow rates and axial pressure distributions were measured for subcooled nitrogen in a converging-diverging nozzle with a constant area section in the throat region. Stagnation pressures ranged from slightly above saturation to twice the thermodynamic critical pressure. Stagnation temperatures ranged from 0.75 to 1.03 times the thermodynamic critical temperature. The choking plane appears to be at the divergence end of the constant area throat section. At high stagnation pressures the fluid appears to stay liquid well into the constant area throat region; however, at near saturation stagnation pressures it appears that vaporization occurs at or before the entrance to the constant area throat region. The throat-to-stagnation pressure ratio data exhibits an anomalous flat region. This anomaly appears to be fundamentally related to the two-phase process and not merely to the present specific nozzle geometry. The fluid appears to be metastably all liquid below the saturation pressure. The data are compared to various flow models. No model adequately describes the whole range of the experiment.

Simoneau, R. J.↗

Gas and drop behavior in reacting and non-reacting air-blast atomizer sprays

A detailed study of the two-phase flow produced by a gas-turbine air-blast atomizer is performed with the goal of identifying the interaction between the two phases for both nonreacting and reacting conditions. A two-component phase Doppler interferometry is utilized to characterize three flowfields produced by the atomizer: (1) the single-phase flow, (2) the two-phase nonreacting spray, and (3) the two-phase reacting spray. Measurements of the mean and fluctuating axial and azimuthal velocities for each phase are obtained. In addition, the droplet size distribution, volume flux, and concentration are measured. The results reveal the strong influence of the dispersed phase on the gas, and the influence of reaction on both the gas and the droplet field. The presence of the spray significantly alters the inlet condition of the atomizer. With this alteration quantified, it is possible to deduce that the inertia associated with the dispersed phase damps the fluctuating velocities of the gas. Reaction reduces the volume flux of the droplets, broadens the local volume distribution of the droplets in the region of the reaction zone, increases the axial velocities and radial spread of the gas, and increases the anisotropy in the region of the reaction zone.

Mcdonell, Vincent G.↗

Pressure distribution in a converging-diverging nozzle during two-phase choked flow of subcooled nitrogen

Choked flow rates and axial pressure distributions were measured for subcooled nitrogen in a converging-diverging nozzle with a constant area section in the throat region. Stagnation pressures ranged from slightly above saturation to twice the thermodynamic critical pressure. Stagnation temperatures ranged from 0.75 to 1.03 times the thermodynamic critical temperature. The choking plane is at the divergence end of the constant area throat section. At high stagnation pressures the fluid stays liquid well into the constant area throat region; at near saturation stagnation pressures it appears that vaporization occurs at or before the entrance to the constant area throat region. The throat-to-stagnation pressure ratio data exhibits an anomalous flat region, and this anomaly is related to the two-phase process. The fluid is metastably all liquid below the saturation pressure.

Simoneau, R. J.↗

Hydrodynamics of Packed Bed Reactor in Low Gravity

Packed bed reactors are well known for their vast and diverse applications in the chemical industry; from gas absorption, to stripping, to catalytic conversion. Use of this type of reactor in terrestrial applications has been rather extensive because of its simplicity and relative ease of operation. Developing similar reactors for use in microgravity is critical to many space-based advanced life support systems. However, the hydrodynamics of two-phase flow packed bed reactors in this new environment and the effects of one physiochemical process on another has not been adequately assessed. Surface tension or capillary forces play a much greater role which results in a shifting in flow regime transitions and pressure drop. Results from low gravity experiments related to flow regimes and two-phase pressure drop models are presented in this paper along with a description of plans for a flight experiment on the International Space Station (ISS). Understanding the packed bed hydrodynamics and its effects on mass transfer processes in microgravity is crucial for the design of packed bed chemical or biological reactors to be used for water reclamation and other life support processes involving water purification.

Motil, Brian J.↗

Powdered aluminum and oxygen rocket propellants: Subscale combustion experiments

Aluminum combined with oxygen has been proposed as a potential lunar in situ propellant for ascent/descent and return missions for future lunar exploration. Engine concepts proposed to use this propellant have not previously been demonstrated, and the impact on performance from combustion and two-phase flow losses could only be estimated. Therefore, combustion tests were performed for aluminum and aluminum/magnesium alloy powders with oxygen in subscale heat-sink rocket engine hardware. The metal powder was pneumatically injected, with a small amount of nitrogen, through the center orifice of a single element O-F-O triplet injector. Gaseous oxygen impinged on the fuel stream. Hot-fire tests of aluminum/oxygen were performed over a mixture ratio range of 0.5 to 3.0, and at a chamber pressure of approximately 480 kPa (70 psia). The theoretical performance of the propellants was analyzed over a mixture ratio range of 0.5 to 5.0. In the theoretical predictions the ideal one-dimensional equilibrium rocket performance was reduced by loss mechanisms including finite rate kinetics, two-dimensional divergence losses, and boundary layer losses. Lower than predicted characteristic velocity and specific impulse performance efficiencies were achieved in the hot-fire tests, and this was attributed to poor mixing of the propellants and two-phase flow effects. Several tests with aluminum/9.8 percent magnesium alloy powder did not indicate any advantage over the pure aluminum fuel.

Meyer, Mike L.↗

Microgravity fluid management requirements of advanced solar dynamic power systems

The advanced solar dynamic system (ASDS) program is aimed at developing the technology for highly efficient, lightweight space power systems. The approach is to evaluate Stirling, Brayton and liquid metal Rankine power conversion systems (PCS) over the temperature range of 1025 to 1400K, identify the critical technologies and develop these technologies. Microgravity fluid management technology is required in several areas of this program, namely, thermal energy storage (TES), heat pipe applications and liquid metal, two phase flow Rankine systems. Utilization of the heat of fusion of phase change materials offers potential for smaller, lighter TES systems. The candidate TES materials exhibit large volume change with the phase change. The heat pipe is an energy dense heat transfer device. A high temperature application may transfer heat from the solar receiver to the PCS working fluid and/or TES. A low temperature application may transfer waste heat from the PCS to the radiator. The liquid metal Rankine PCS requires management of the boiling/condensing process typical of two phase flow systems.

Migra, Robert P.↗

The Effects of Sooting and Radiation on Droplet Combustion

The burning of liquid hydrocarbon fuels accounts for a significant portion of global energy production. With predicted future increases in demand and limited reserves of hydrocarbon fuel, it is important to maximize the efficiency of all processes that involve conversion of fuel. With the exception of unwanted fires, most applications involve introduction of liquid fuels into an oxidizing environment in the form of sprays which are comprised of groups of individual droplets. Therefore, tremendous benefits can result from a better understanding of spray combustion processes. Yet, theoretical developments and experimental measurements of spray combustion remains a daunting task due to the complex coupling of a turbulent, two-phase flow with phase change and chemical reactions. However, it is recognized that individual droplet behavior (including ignition, evaporation and combustion) is a necessary component for laying the foundation for a better understanding of spray processes. Droplet combustion is also an ideal problem for gaining a better understanding of non-premixed flames. Under the idealized situation producing spherically-symmetric flames (produced under conditions of reduced natural and forced convection), it represents the simplest geometry in which to formulate and solve the governing equations of mass, species and heat transfer for a chemically reacting two phase flow with phase change. The importance of this topic has promoted extensive theoretical investigations for more than 40 years.

Lee, Kyeong-Ook↗

Synthesis of results for Brine Availability Test in Salt (BATS) DECOVALEX-2023 Task E

In the 2023 phase of the international collaborative DECOVALEX modeling project, Task E focused on understanding thermal, hydrological, and mechanical (THM) processes related to predicting brine migration in the excavation damaged zone around a heated excavation in salt. Salt is attractive as a disposal medium for radioactive waste because it is self-healing and is essentially impermeable and non-porous in the far field. Investigation of the short-term, near-field behavior is important for radioactive waste disposal because this early period strongly controls the amount of inflowing brine. Brine leads to corrosion of waste forms and waste packages, and possible dissolution of radionuclides with brine transport being a potential transport vector to the accessible environment.The Task was divided into steps. Step 0 included matching unheated brine inflow data from boreholes at the Waste Isolation Pilot Plant (WIPP) and matching temperature observations during a Brine Availability Test in Salt (BATS) heater test. Step 1 included validation of models against a thermo-poroelastic analytical solution, and two-phase flow around an excavation. Finally, Step 2 required all the individual components covered in steps 0 and 1 to come together to match observed brine inflow behavior during the same BATS heater test.There were a range of approaches from the teams, from mechanistic to prescriptive. Given the uncertainties in the problem, some teams used one- or two-dimensional models of the processes, while other teams included more geometrical complexity in three-dimensional models. Task E was a learning experience for the teams involved, and feedback from the modeling teams has led to changes in follow-on BATS experiments at WIPP. The primary Task E lessons learned were the impact of hydrologic initialization methods (wetting up vs. drying down), the difference between confined and unconfined thermal expansion, and the large changes in permeability associated with heating and cooling.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Small-droplet spray measurements with a scattered-light scanner

Interacting two-phase flow through pneumatic two-fluid nozzles was investigated to determine the effect of nitrogen gas mass-velocity on the Sauter mean diameter of water sprays produced by the breakup of small diameter liquid-jets in high velocity gas streams. Tests were conducted primarily in the aerodynamic-stripping regime of liquid-jet atomization. It was found that the loss of droplets due to vaporization and dispersion had a marked effect on drop size measurements. A scattered-light scanner, developed at NASA Lewis Research Center was used to measure Sauter mean diameters, D sub 32, as small as 5 microns, which were correlated with nitrogen gas mass-velocity to give the following expression: D(sup -1)(sub 32) = 11.7(rho (sub n) V(sub n))(sup 1.33) where D sub 32 and p(sub n)V(sub n) are given in centimeters and g/sq cm-sec, respectively. The exponent 1.33 is the same as that predicted by atomizing theory for liquid-jet breakup in high velocity gas streams.

Ingebo, Robert D.↗

Gas density effect on dropsize of simulated fuel sprays

Two-phase flow in pneumatic two-fluid fuel nozzles was investigated experimentally to determine the effect of atomizing-gas density and gas mass-flux on liquid-jet breakup in sonic-velocity gas-flow. Dropsize data were obtained for the following atomizing-gases: nitrogen; argon; carbon dioxide; and helium. They were selected to cover a gas molecular-weight range of 4 to 44. Atomizing-gas mass-flux ranged from 6 to 50 g/sq cm-sec and four differently sized two-fluid fuel nozzles were used having orifice diameters that varied from 0.32 to 0.56 cm. The ratio of liquid-jet diameter to SMD, D sub o/D sub 32, was correlated with aerodynamic and liquid-surface forces based on the product of the Weber and Reynolds number, We*Re, and gas-to-liquid density ratio, rho sub g/rho sub l. To correlate spray dropsize with breakup forces produced by using different atomizing-gases, a new molecular-scale dimensionless group was derived. The derived dimensionless group was used to obtain an expression for the ratio of liquid-jet diameter to SMD, D sub o/D sub 32. The mathematical expression of this phenomenon incorporates the product of the Weber and Reynolds number, liquid viscosity, surface tension, acoustic gas velocity, the RMS velocity of gas molecules, the acceleration of gas molecules due to gravity, and gas viscosity. The mathematical expression encompassing these parameters agrees well with the atomization theory for liquid-jet breakup in high velocity gas flow. Also, it was found that at the same gas mass-flux, helium was considerably more effective than nitrogen in producing small droplet sprays with SMD's in the order of 5 micrometers.

Ingebo, Robert D.↗

Gas density effect on dropsize of simulated fuel sprays

Two-phase flow in pneumatic two-fluid fuel nozzles was investigated experimentally to determine the effect of atomizing-gas density and gas mass-flux on liquid-jet breakup in sonic-velocity gas-flow. Dropsize data were obtained for the following atomizing-gases: nitrogen; argon; carbon dioxide; and helium. They were selected to cover a gas molecular-weight range of 4 to 44. Atomizing-gas mass-flux ranged from 6 to 50 g/sq cm-sec and four differently sized two-fluid fuel nozzles were used having orifice diameters that varied from 0.32 to 0.56 cm. The ratio of liquid-jet diameter to SMD, D sub o/D sub 32, was correlated with aerodynamic and liquid-surface forces based on the product of the Weber and Reynolds number, and gas-to-liquid density ratio, rho sub g/rho sub 1. To correlate spray dropsize with breakup forces produced by using different atomizing-gases, a new molecular-scale dimensionless group was derived. The derived dimensionless group was used to obtain an expression for the ratio of liquid-jet diameter to SMD, D sub o/D sub 32. The mathematical expression of this phenomenon incorporates the product of the Weber and Reynolds number, liquid viscosity, surface tension, acoustic gas velocity, the RMS velocity of gas molecules, the acceleration of gas molecules due to gravity, and gas viscosity. The mathematical expression encompassing these parameters agrees well with the atomization theory for liquid-jet breakup in high velocity gas flow. Also, it was found that at the same gas mass-flux, helium was considerably more effective than nitrogen in producing small droplet sprays with SMD's in the order of 5 micrometers.

Ingebo, Robert D.↗

Performance assessment of low pressure nuclear thermal propulsion

An increase in Isp for nuclear thermal propulsion systems is desirable for reducing the propellant requirements and cost of future applications, such as the Mars Transfer Vehicle. Several previous design studies have suggested that the Isp could be increased substantially with hydrogen dissociation/recombination. Hydrogen molecules (H2), at high temperatures and low pressures, will dissociate to monatomic hydrogen (H). The reverse process (i.e., formation of H2 from H) is exothermic. The exothermic energy in a nozzle increases the kinetic energy and therefore, increases the Isp. The low pressure nuclear thermal propulsion system (LPNTP) system is expected to maximize the hydrogen dissociation/recombination and Isp by operating at high chamber temperatures and low chamber pressures. The process involves hydrogen flow through a high temperature, low pressure fission reactor, and out a nozzle. The high temperature (approximately 3000 K) of the hydrogen in the reactor is limited by the temperature limits of the reactor material. The minimum chamber pressure is about 1 atm because lower pressures decrease the engines thrust to weight ratio below acceptable limits. This study assumes that hydrogen leaves the reactor and enters the nozzle at the 3000 K equilibrium dissociation level. Hydrogen dissociation in the reactor does not affect LPNTP performance like dissociation in traditional chemical propulsion systems, because energy from the reactor resupplies energy lost due to hydrogen dissociation. Recombination takes place in the nozzle due primarily to a drop in temperature as the Mach number increases. However, as the Mach number increases beyond the nozzle throat, the static pressure and density of the flow decreases and minimizes the recombination. The ideal LPNTP Isp at 3000 K and 10 psia is 1160 seconds due to the added energy from fast recombination rates. The actual Isp depends on the finite kinetic reaction rates which affect the amount of monatomic hydrogen recombination before the flow exits the nozzle. A LPNTP system has other technical issues (e.g. flow instability and two-phase flow) besides hydrogen dissociation/recombination which affect the systems practicality. In this study, only the effects of hydrogen dissociation/recombination are examined.

Gerrish, Harrold P., Jr.↗