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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Space observations of the variability of solar irradiance in the near and far ultraviolet.

Satellite observations of UV solar irradiance in selected wavelength bands between 1200 and 3000 A have been made continuously by photometers consisting of broadband sensors operated on Nimbus 3 and 4, which were launched in April 1969 and April 1970, respectively. In addition, on Nimbus 4, spectrophotometer measurements of solar irradiance have been made with a dispersive instrument at 12 selected wavelengths from 2550 to 3400 A with a 10-A bandpass. Variations of solar irradiance associated with the solar rotational period have been observed since the launch of Nimbus 3. These variations are apparently associated with two source regions separated by about 180 deg in solar longitude. The change in irradiance with solar rotation was found to increase with decreasing wavelengths. Different types of observed variations in UV solar irradiance can be classified in accordance with characteristic times. In order of increasing periods, they are (1) flare-associated enhancements, (2) 27-day variations due to solar rotation, (3) a possible biennial effect, and (4) long-term variations associated with the 11-year solar cycle.

Heath, D. F.↗
NASA NTRS1990

A status report on the analysis of the NOAA-9 SBUV/2 sweep mode solar irradiance data

Monitoring of the near ultraviolet (UV) solar irradiance is important because the solar UV radiation is the primary energy source in the upper atmosphere. The solar irradiance at wavelengths shortward of roughly 300 nm heats the stratosphere via photodissociation of ozone in the Hartley bands. Shortward of 242 nm the solar UV flux photodissociates O2, which is then available for ozone formation. Upper stratosphere ozone variations coincident with UV solar rotational modulation have been previously reported (Gille et al., 1984). Clearly, short and long term solar irradiance observations are necessary to separate solar-forced ozone variations from anthropogenic changes. The SBUV/2 instrument onboard the NOAA-9 spacecraft has made daily measurements of the solar spectral irradiance at approximately 0.15 nm intervals in the wavelength region 160-405 nm at 1 nm resolution since March 1985. These data are not needed to determine the terrestrial ozone overburden or altitude profile, and hence are not utilized in the NOAA Operational Ozone Product System (OOPS). Therefore, assisted by the ST System Corporation, NASA has developed a scientific software system to process the solar sweep mode data from the NOAA-9 instrument. This software will also be used to process the sweep mode solar irradiance data from the NOAA-11 and later SBUV/2 instruments. An overview of the software system and a brief discussion of analysis findings to date are provided. Several outstanding concerns/problems are also presented.

Cebula, R. P.↗
DOE OSTI2022

A Polymer Canvas with the Stiffness of the Bone Matrix to Study and Control Mesenchymal Stem Cell Response

Reproducing in vitro the complex multiscale physical features of human tissues creates novel biomedical opportunities and fundamental understanding of cell–environment interfaces and interactions. While stiffness has been recognized as a key driver of cell behavior, systematic studies on the role of stiffness have been limited to values in the KPa–MPa range, significantly below the stiffness of bone. Here, in this work, a platform enabling the tuning of the stiffness of a biocompatible polymeric interface up to values characteristic of human bone is reported, which are in the GPa range, by using extremely thin polymer films on glass and cross-linking the films using ultraviolet (UV) light irradiation. It is shown that a higher stiffness is related to better adhesion, proliferation, and osteogenic differentiation, and that it is possible to switch on/off cell attachment and growth by solely tuning the stiffness of the interface, without any surface chemistry or topography modification. Since the stiffness is tuned directly by UV irradiation, this platform is ideal for rapid and simple fabrication of stiffness patterns and gradients, thus representing an innovative tool for combinatorial studies of the synergistic effect of tissue environmental cues on cell behavior, and creates new opportunities for next-generation biosensors, single-cell patterning, and lab-on-a-chip devices.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2022

Photoinitiator Selection and Concentration in Photopolymer Formulations towards Large-Format Additive Manufacturing

Photopolymers are an attractive option for large-format additive manufacturing (LFAM), because they can be formulated from structural thermosets and cure rapidly in ambient conditions under low-energy ultraviolet light-emitting diode (UV LED) lamps. Photopolymer cure is strongly influenced by the depth penetration of UV light, which can be limited in the 2–4 mm layer thicknesses typical of LFAM. Photoinitiator (PI) systems that exhibit photobleaching have proven useful in thick-section cure applications, because they generate a photoinitiation wavefront, but this effect is time-dependent. This study investigates the light transmission and through-thickness cure behavior in (meth)acrylate photopolymer formulations with the photobleaching initiator bis(2,4,6-trimethylbenzoyl)-phenylphosphine oxide (BAPO). Utilizing an optical model developed by Kenning et al., lower concentrations (0.1 wt% to 0.5 wt%) of BAPO were predicted to yield rapid onset of photoinitiation. In situ cure measurements under continuous UV LED irradiation of 380 mW/cm2 showed that a 0.1 wt% concentration of BAPO achieved peak polymerization rate within 2.5 s at a 3-mm depth. With only 1 s of irradiation at 1.7 W/cm2 intensity, the 0.1 wt% BAPO formulation also achieved the highest level of cure of the formulas tested. For an irradiation dose of 5.5 J/cm2 at a duration of 3.7 s, cured polymer specimens achieved a flexural strength of 108 MPa and a flexural modulus of 3.1 GPa. This study demonstrates the utility of optical modeling as a potential screening tool for new photopolymer formulations, primarily in identifying an upper limit to PI concentration for the desired cure depth. The results also show that photobleaching provides only a limited benefit for LFAM applications with short (1.0 s to 3.7 s) UV irradiation times and indicate that excess PI concentration can inhibit light transmission even under extended irradiation times up to 60 s.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Accurate and Simple Parametrization to Estimate Solar UV from GHI and Other Accessible Variables

This study is part of a broader program that aims to generate reliable ultraviolet (UV) data for several applications. This work presents a simple and fast parametrization to estimate UV solar irradiation at the ground level from global horizontal irradiance (GHI) information. The work focuses on UVB (280-315 nm) and erythemic UV (UVE) irradiance weighted by the average skin response.

GHI↗
NASA NTRS1981

Protective mechanisms and acclimation to solar ultraviolet-B radiation in Oenothera stricta

Plant adaptations ameliorating or repairing the damaging effects of ultraviolet-B (UV-B) radiation on plant tissue were investigated. The degree of phenotype plasticity in UV protective mechanisms and acclimation in relation to the natural solar UV-B radiation flux and in an enhanced UV-B irradiance environment was also examined. Mechanisms by which plants avoid radiation, adaptations altering the path of radiation incident on the leaf, and repair processes were considered. Attenuation of UV-B by tissues, UV-B irradiation into the leaf, and the effects of UV-B on photosynthesis were investigated.

Robberecht, R.↗
NASA NTRS1994

UV-B radiation amplification factor determined based on the simultaneous observation of total ozone and global spectral irradiance

The Japan Meteorological Agency started the spectral observation of solar ultraviolet (UV) irradiance on 1 January 1990 at Tateno, Aerological Observatory in Tsukuba (35 deg N, 140 deg E). The observation has been carried out using the Brewer spectrophotometer for the wavelengths from 290 to 325 nm with a 0.5 nm interval every hour from 30 minutes before sunrise to 30 minutes after sunset throughout a year. Because of remarkable similarity within observed spectra, an observed spectrum can be expressed by a simple combination of a reference spectrum and two parameters expressing the deformation of the observed spectrum from the reference. By use of the relation between one of the deformation parameters and the total ozone simultaneously observed with the Dobson spectrophotometer, the possible increase of UV irradiance due to ozone depletion is estimated. For damaging UV, the irradiance possibly increases about 19 percent with the ozone depletion of 10 percent at noon throughout the year in the northern midlatitudes. DUV at noon on the summer solstice possibly increases about 5.6 percent with the ozone depletion of 10 m atm-cm for all latitudes in the Northern Hemisphere.

Ito, T.↗
NASA NTRS1987

UV-B radiation and photosynthetic irradiance acclimate eggplant for outdoor exposure

Treatment of greenhouse-grown eggplant (Solanum melongena L. var. esculentum Nees. 'Burpee's Black Beauty') seedlings with supplemental photosynthetically active radiation from cool-white fluorescent lamps increased growth of plants subsequently transferred outdoors relative to growth of plants that received no supplemental radiation or were shaded to 45% of solar irradiation in the greenhouse before transfer outdoors. Eggplant seedlings transferred outdoors were placed under plastic tarps either to provide relative protection from solar ultraviolet-B (UV-B) radiation (280-315 nm) using Mylar film or to allow exposure to UV-B using cellulose acetate. Protection of seedlings from UV-B radiation resulted in greater leaf expansion than for UV-B-exposed seedlings, but no change in leaf or shoot dry weight occurred after 9 days of treatment. Specific leaf weight increased in response to UV-B exposure outdoors. Exposure of eggplant to UV-B radiation from fluorescent sunlamps in the greenhouse also decreased leaf expansion and leaf and shoot dry weight gain after 5 days of treatment. However, there were no differences in leaf or shoot dry weight relative to control plants after 12 days of UV-B treatment, indicating that UV-B treated plants had acclimated to the treatment and actually had caught up with non-UV-B-irradiated plants in terms of growth.

NASA Program Space Biology↗
NASA NTRS1978

Cloud effects on ultraviolet photoclimatology

The purpose of this study is to quantify for the needs of photobiology the influence of clouds upon the ultraviolet spectral irradiance reaching the ground. Towards this end, analytic formulas are developed which approximately characterize the influence of clouds upon total solar radiation. These may be used in conjunction with a solar pyranometer to assign an effective visual optical depth for the cloud cover. A formula is also developed which characterizes the influence of the optical depth of clouds upon the UV spectral irradiance in the 280-340 nm region. Thus total solar energy observations to assign cloud optical properties can be used to calculate the UV spectral irradiance at the ground in the presence of these clouds. As incidental by-products of this effort, convenient formulas are found for the direct and diffuse components of total solar energy.

Green, A. E. S.↗
NASA NTRS1991

Evaluation of optically transparent polyetherimide films for applications in space

Several series of aromatic polyetherimide films have been synthesized and characterized with the objective of obtaining maximum optical transparency for applications in space. Incorporation of phenoxy groups into aromatic polyimides has resulted in a reduction in the color intensity of these films compared to commercial polyimide film by reducing electronic interactions between polymer chains. The resulting lightly colored to colorless polyetherimide films have been characterized by UV-visible and infrared spectroscopy before and after exposure to varying doses of UV and electron irradiation designed to simulate use as second-surface mirror thermal control coatings. After exposure to 300 equivalent solar hours UV irradiation and 1 MeV electron irradiation, the polyetherimides were 2.2 to 2.6 times more transparent than commercial polyimide film of the same thickness.

St. Clair, Anne K.↗
NASA NTRS1988

Absolute solar spectral irradiance 120 nm-400 nm (Results from the Solar Ultraviolet Spectral Irradiance Monitor-SUSIM-Experiment on board Spacelab 2)

The Solar UV Spectral Irradiance Monitor experiment flown on the Spacelab-2 mission measured the absolute solar spectral irradiance in the ultraviolet spectral range 120 nm-400 nm with two spectral passbands, 0.15 and 5 nm. The photometric error was + or - 5.0 percent relative to three different absolute calibration standards. Calibration procedures and error budget are discussed. The results are reported and compared with other measurements.

Vanhoosier, Michael E.↗
DOE OSTI2023

Enhanced Photoluminescence and Prolonged Carrier Lifetime through Laser Radiation Hardening and Self-Healing in Aged MAPbBr3 Perovskites Encapsulated in NiO Nanotubes

Organic-inorganic perovskites hold great promise as optoelectronic semiconductors for pure color light emitting and photovoltaic devices. However, challenges persist regarding their photostability and chemical stability, which limit their extensive applications. This paper investigates the laser radiation hardening and self-healing-induced properties of aged MAPbBr3 perovskites encapsulated in NiO nanotubes (MAPbBr3@NiO) using photoluminescence (PL) and fluorescence lifetime imaging (FLIM). After deliberately subjecting the MAPbBr3@ NiO to atmospheric conditions for two years, the sample remains remarkably stable. It exhibits no changes in PL wavelength during UV laser irradiation and self-healing. Furthermore, exposure to UV light at 375 nm enhances the PL of the self-healed MAPbBr3@NiO. FLIM analysis sheds light on the mechanism behind photodegradation, self-healing, and PL enhancement. The results indicate the involvement of many carrier-trapping states with low lifetime events and an increase in peak lifetime after self-healing. The formation of trapping states at the perovskite/nanotube interface is discussed and tested. This study provides new insights into the dynamics of photo-carriers during photodegradation and self-healing in organic-inorganic perovskites.

36 MATERIALS SCIENCE↗
DOE OSTI2025

UV-Enabled Defect Engineering in Multilayer GaSe and InSe and UV Writing of the Grating Pattern

III–VI post-transition-metal chalcogenides are layered semiconductor materials that exhibit direct band gaps in multilayers. Defect engineering is essential in 2D layered semiconductors for functional devices. Here, in this work, we report defect engineering in multilayer gallium selenide (GaSe) and indium selenide (InSe), where defects generated by ultraviolet (UV, 325 nm) laser irradiation result in an additional photoluminescence (PL) line. The additional PL line is due to defect-bound excitons. Characteristics of the defect emission are similar in GaSe and InSe samples subjected to UV irradiation, air annealing, and hydrostatic pressure. Two-beam UV interference was applied to create grating patterns with a periodic array of low and high densities of defects in GaSe. Density functional theory has identified the defect type in GaSe. The results provide valuable insights into defect generation and UV scribing of photonic circuits in 2D Se-based multilayers for optical integration in a 2D platform.

2D multilayered materials↗
NASA NTRS2014

Laboratory Investigations of the Complex Refractory Organic Material Produced from Irradiation of Pluto Ice Analogs

Much of Pluto's surface consists of N2 ice with smaller amounts of CH4 and CO ices. Despite the low temperature (approximately 45K), chemistry can be driven in the surface ices by radiation processing such as cosmic ray bombardment. When cosmic rays strike the surface, much of their energy is dispersed in the form of secondary electrons, which in turn drive much of the resulting chemical reactions. Laboratory experiments designed to simulate the conditions on these icy bodies may provide insight into this chemistry. Significant progress has been made in the laboratory toward understanding the smaller, simple compounds produced in the solid phase by radiation processing of (N2, CH4, CO) ices (Bohn et al. 1994; Moore & Hudson 2003; Hodyss et al. 2011; Kim and Kaiser 2012). Recently Materese et al. (2014) used a variety of techniques to better characterize the refractory materials produced from the UV photo-irradiation of N2:CH4:CO ices. However, because Pluto's atmosphere is optically thick to Lyman-alpha UV radiation it is important to re-examine the results using an alternate radiation source. Our latest work has consisted of the analysis of refractory materials produced from the electron bombardment of low temperature N2(‐), CH4(‐), and CO(‐)containing ices (100:1:1). The ice mixture was chosen to be analogous to the known surface ices on Pluto and the radiation source was chosen to mimic the secondary electrons produced by cosmic rays bombardment. The residues were studied using multiple chemical techniques including, infrared (IR) spectroscopy, X‐ray absorption near‐edge structure (XANES) spectroscopy, and gas chromatography coupled with mass spectrometry (GC‐MS). The organic residues produced in these experiments can be seen as an analog for the refractory component of the surface of Pluto, and are compared with the residues previously obtained from UV photo‐irradiation. UV and near‐ IR spectroscopy of the surfaces of Pluto and Charon during the encounter with NASA's New Horizons spacecraft in 2015, will give the first close‐up measurements of ices and their photoproducts. Laboratory measurements and experiments will provide a better context for the data returned by the spacecraft.

organics↗
NASA NTRS1983

Differences in the temporal variations of solar UV flux, 10.7-cm solar radio flux, sunspot number, and Ca-K plage data caused by solar rotation and active region evolution

Attention is given to two types of temporal variations in the solar UV spectral irradiance caused by solar rotation and active region evolution. It is noted that the first type of dissimilar temporal behavior occurs when concentrations of solar active regions evolve at solar longitudes nearly 180 deg apart. Both the UV observations and modeled UV fluxes based on Ca-K plage data then exhibit pronounced 13-day periodicity, whereas the 10.7-cm solar radio flux and sunspot number exhibit quite dissimilar temporal variations. This type of dissimilarity is related to the modeled UV flux and has a dependence on the solar central meridian distance that is narrower than that for the 10.7-cm radio flux or for sunspot numbers. A second case of marked dissimilarity is seen when major new solar active regions arise and dominate the full-disk fluxes for several rotations. It is found that the strongest peaks in 10.7 cm and sunspot numbers tend to occur on their first rotation, for example, during major dips in the total solar irradiance, whereas the Ca-K plages and UV enhancements peak on the next rotation and then decay more slowly on subsequent rotations.

Donnelly, R. F.↗
NASA NTRS1972

Space observations of the variability of solar irradiance in the near and far ultraviolet

Satellite observations of the ultraviolet solar irradiance in selected wavelength bands between 1200 and 3000 a were made continuously by photometers consisting of broad-band sensors operated on Numbus 3 and 4 which were launched in April 1969 and 1970. In addition, spectrophotometer measurements of the solar irradiance were made with a dispersive instrument at 12 selected wavelengths from 2550 to 3400 a with a 10 a bandpass on Nimbus 4. Variations of the solar irradiance associated with the solar rotational period were observed since the launch of Nimbus 3. These variations are apparently associated with two source regions separated by about 180 deg in solar longitude. The change in irradiance with solar rotation was found to increase with decreasing wavelengths. Different types of the observed variations in uv solar irradiance can be classified in accordance with characteristics times, e.g. in the order of increasing periods as follows: (1)flare associated enhancements (2) 27-day variations due to solar rotation; (3) a possible biennial effect; and (4) long term variations associated with the 11-year solar cycle.

Heath, D. F.↗