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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Latest Developments in PM Systems and Methods and their Application to WM Projects - 20364

How do you improve on an industry that is well established yet often misses the mark on key metrics demonstrating effective planning and execution of project scope, schedule and budget? With the increased complexity of DOE projects relative to either poorly kept records of what wastes are stored or the lack of specific knowledge relative to the waste concentrations/quantities, this is a question continually asked and investigated by many. In fact, in 2017, the GAO's report to Congress indicated that although the DOE has made some progress on its monitoring effectiveness and demonstrating progress criteria, these goals were not met and there needs to be more improvement and monitoring. This paper will offer some insights into the latest developments in project management methodologies and the possible application of these to waste management projects. Traditional data generated via a project schedule that utilizes critical path methodology (CPM) and additional earned value management (EVM) data needs to be accurate and enable the project manager to better understand the probability of project success. Although this data has readily been available on most large-scale projects, success as measured by various stakeholder groups including the client, project team, regulators, etc. is less than optimal. Therefore, an urgent need exists to explore how traditional project data (CPM and EVM) coupled with new methodologies allows for better planning and execution by the project team. Many new approaches/methodologies can even be used to predict the success of options prior to full implementation on the actual project. Three approaches/methodologies will be discussed: - Artificial Intelligence; - Change Management; - Blend of Traditional Management (Gantt chart) and Agile Methodologies. As market forces change, so will the direction of project management. The days of 'one size fits all' are no longer valid. A combination of predictive and adaptive approaches in the management of projects is essential to enable execution of project deliverables on time, under budget, and within the contractual scope. This paper is intended to provide the reader with insight to the close relationship of project management trends and business management trends, and to provoke critical thinking about what it means to align project management strategy with an environment of non-stop innovation. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Distributed power generation via gasification of biomass and municipal solid waste: A review

The access to electricity has increased worldwide, growing from 60 million additional consumers per year in 2000-2012 to 100 million per year in 2012-2016. Despite this growth, approximately 675 million people will still lack access to electricity in 2030, indicating that electricity demand will continue to increase. Unfortunately, traditional large fossil power technologies based on coal, oil and natural gas lead to a major concern in tackling worldwide carbon dioxide emissions, and nuclear power remains unpopular due to public safety concerns. Distributed power generation utilizing CO 2 -neutral sources, such as gasification of biomass and municipal solid wastes (MSW), can play an important role in meeting the world energy demand in a sustainable way. Furthermore, this review focuses on the recent technology developments on seven power generation technologies (i.e. internal combustion engine, gas turbine, micro gas turbine, steam turbine, Stirling engine, organic rankine cycle generator, and fuel cell) suitable for distributed power applications with capability of independent operation using syngas derived from gasification of biomass and MSW. Technology selection guidelines is discussed based on criteria, including hardware modification required, size inflexibility, sensitivity to syngas contaminants, operational uncertainty, efficiency, lifetime, fast ramp up/down capability, controls and capital cost. Major challenges facing further development and commercialization of these power generation technologies are discussed.

09 BIOMASS FUELS↗
DOE OSTI2023

Application of Particle Accelerators to Mitigate Energy and Climate Change Problems Facing America

Reliable CO 2 -free baseload power is needed to address ever-increasing demands for electricity while minimizing adverse climate change. Diversified power supply provided by solar, wind, geothermal, and nuclear reactors can displace the use of fossil fuels. The United States (U.S.) is taking a new look at nuclear power as a source of electrical energy and the nuclear industry is proposing new approaches which may minimize capital costs. However, nuclear power comes with a variety of technical problems. Chief among those is managing the used fuel from nuclear reactors. No long-term, practicable solution to this problem is available. The lack of progress on a comprehensive waste management strategy restricts growth in the nuclear power industry and minimizes the role that nuclear energy may serve as part of a zero-carbon future (Bahr, 2021). According to the Nuclear Waste Policy Act of 1982, as amended, the U.S. Government has possession of the used reactor fuel and incurs large annual storage fees paid to utilities to store and safeguard the accumulated used fuel. In effect, short term on-site storage of nuclear waste is the current waste management plan. The amount of used reactor fuel in the U.S. is approximately 80,000 metric tons. While no geologic repository exists within the U.S., the potential site at Yucca Mountain, NV would accommodate 70,000 metric tons, which fails to meet current and future needs. Given the technical and political challenges associated with establishing a single geological storage site, it is necessary for the U.S. to implement technologies that improve the suitability of geological storage by reducing the volume and radiotoxicity of stored material. No extant technology meets this need. Accelerator driven waste burners have been proposed as a scalable method to process used nuclear fuel, however considerable technical challenges remain which impede commercialization. Innovations in design require investigation of novel materials, development of accurate models and simulations, and a comprehensive assessment of safety and performance. This proposal elaborates how LANL is uniquely positioned to make key contributions to this area of research.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2026

Waste-to-Energy Potential in Guam [Slides]

This report presents an overview of the potential applications and associated costs of implementing waste-to-energy technologies in Guam. It examines how these systems could contribute to the island’s energy portfolio by converting waste materials into usable power or heat.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2026

Treatment of Lagoon Dairy Manure Wastewater via Iron Electrocoagulation, Microfiltration, and Adsorption

Dairy manure wastewater generated by flushing barn cow waste contains nutrients, pathogens, and organic and inorganic contaminants. This study utilized a process consisting of iron electrocoagulation (Fe-EC), microfiltration (MF), and activated carbon (AC) adsorption to treat farm wastewater and explore the reclamation of clean water for irrigation and livestock consumption. Significant removal (>99.9%) of chemical oxygen demand (COD), total organic carbon (TOC), phosphorus (P), turbidity, and microorganisms, as well as ions including magnesium, calcium, sulfur, and silica was achieved by the combined EC-MF-AC process. Specifically, a charge loading of ∼37,500 C/L in a continuous-flow EC configuration, followed by MF, achieved more than 95% removal of TOC and COD. Characterization of produced flocs and foam via scanning-electron microscopy with energy-dispersal spectroscopy and Fourier transform infrared spectroscopy confirmed the removal of ions, including calcium, sulfur, and silica. A key finding was the electrocatalytic conversion of nitrogen species to ammonia gas through the intermediate reduction of nitrate/nitrite, which led to ∼60% total nitrogen (TN) removal. AC treatment further improved TN removal to ∼70%. The Fe-EC process also eradicated >99.9% of bacteria. Preliminary process cost assessment, based on recycled materials for EC electrodes, showed significant cost savings (∼2 times) compared to commercial electrodes.

Dutta, Swapnamoy [ORNL]↗
DOE OSTI2020

Preliminary Determination of the Impact of Alkaline Earth Metals on Crystalline Silicotitanate

Savannah River Remediation (SRR) recently deployed the Tank Closure Cesium Removal (TCCR) system which utilizes an ion exchange process to remove 137 Cs from tank waste supernate. In TCCR, salt solution is filtered and then passed through ion exchange columns containing crystalline silicotitanate (CST) media, commercially known as UOP IONSIV™ R9120-B, which is highly selective for removing cesium. The current process focuses on dissolving salt in Savannah River Site (SRS) Tank 10H, followed by processing in the TCCR skid located near the tank. Prior to processing each batch of waste generated in Tank 10H, the projected maximum cesium loading on the CST is determined using an in-tank batch contact equilibrium test. This involves placing a small amount (~0.1 g) of CST in a “teabag” device and submerging it in the tank waste for a period of 10 days. Results from those earlier teabag tests had indicated much lower cesium loading than predicted by the equilibrium sorption model (ZAM). There are numerous possible explanations for this result; however, based on the observed loadings of Ca (and other metals) on the CST from the teabag tests, it was hypothesized that competition from these other ions may be limiting the cesium loadings.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2022

Radiological Considerations Supporting the American Medical Isotope Producer Niowave

This report provides a summary of work performed by Savannah River National Laboratory (SRNL) during FY22 in support of Niowave, an American Medical Isotope Production (AMIP) facility. SRNL served in a technical support role, funded by NA-231, supporting Niowave in the beginning of non radiological functional testing of their airport facility in FY22. Through this agreement, SRNL provides Niowave access to subject matter experts (SMEs) for questions that may arise during the drafting of engineering plans, facility policies, and/or response procedures. This report summarizes discussions between SRNL and Niowave about guidance concerning issues with the floor of the hot cells, dispersible removable contamination (beta emitting fission product), hot cell operation specifically utilization of cameras or mirrors, and the process for removing contaminated waste from the hot cell. Lessons learned and other various resources provided to Niowave by SRNL during FY22 are referenced in this report. This work was funded through NNSA’s Office of Material Management and Minimization, Conversion Office (NA-231).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2024

Tank Closure Cesium Removal Ion Exchange Column CST Characterization: SRNL-STI-2024-00072 (Rev.0) pdf

Savannah River Mission Completion (SRMC) recently suspended operation of the Tank Closure Cesium Removal (TCCR) system which utilized an ion exchange (IX) process to remove radioactive cesium from waste supernate. During the demonstration phase, a total of three batches of Tank 10H dissolved salt waste were processed through the original TCCR columns. Subsequently, dissolved salt waste from Tank 9H was processed through TCCR in a phase referred to as TCCR 1A with four new IX columns. All eight columns have now been moved to Interim Safe Storage (ISS). For each batch processed through the TCCR IX columns, SRNL performed a number of analyses on surface and variable depth samples as well as batch equilibrium contact tests (BECT) to determine equilibrium loadings of Cs on the crystalline silicotitanate (CST) IX media. The BECTs were performed by lowering “teabags” containing ~0.1 g of CST each into the tank for a period of at least 10 days. The teabags were then retrieved and sent to SRNL for digestion and analysis.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Technical Feasibility of Recovering Critical Minerals from Oil and Gas Industry Produced Water

Economic recovery of critical minerals from solid and liquid streams produced from natural resource extraction operations including Oil and Gas production, Mining, geothermal, and other industries can help alleviate shortage of the minerals important to industry. It is important to develop techniques for extraction that can be utilized at large scale to be economically viable, and to minimize waste products that require special disposal procedures. NETL and Participant will collaborate to develop and evaluate at the lab-scale, a process to recover and concentrate critical minerals from oil and gas industry produced water using a combination of physical and chemical methods, so that it may be converted into a valuable product. This effort promotes a circular economy by converting a waste stream into marketable products.

02 PETROLEUM↗
DOE OSTI2023

Release of a High Temperature Engineering Test Reactor (HTTR) Steady State Multiphysics Model to the Virtual Test Bed

In response to climate change, global governments and private industry have established a common goal of achieving net-zero emissions by 2050 \cite{osti_1865910}. This goal requires a reassessment of current energy demands and production methods. Reducing emissions at an affordable cost while maintaining grid reliability requires a nationwide collaborative effort among government and industry in the United States. Nuclear power is the leading low-carbon electricity generation method. In the past 50 years, the use of nuclear power has reduced carbon dioxide emissions by over 60 gigatons and has played a crucial role in the security of energy supply~\cite{IEA}. In the U.S., nuclear power accounts for 20\% of the electrical supply and provides energy reliably. Advanced reactors will operate at higher temperatures, operate more efficiently, utilize more energy stored within fuel, and reduce the amount of waste produced \cite{osti_1616270}. To face these challenges and goals, the U.S. Department of Energy has created an initiative to focus on the modeling and simulation tools to support future nuclear power plant design, licensing, and operations. The Virtual Test Bed (VTB)~\cite{vtb2023} was launched by the National Reactor Innovation Center (NRIC) in collaboration with the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program to support the advanced nuclear reactor community. The VTB involves teams from both Idaho National Laboratory and Argonne National Laboratory and aims to provide example models for a broad range of both current and future advanced reactor designs. A feature of the VTB is the automatic testing of these models to ensure continued functionality as simulation tools are further developed. The VTB and the advanced reactor models documented there are important resources for this initiative. This work describes the inclusion of a new model on the VTB---a High Temperature Engineering Test Reactor (HTTR) steady-state model \cite{LABOURE2023109838}.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2023

Sustainable Wood-Waste-Based Thermal Insulation Foam for Building Energy Efficiency

Wood is one of the most abundant biomaterials on Earth, which has been used for centuries in construction applications including furniture, roofing, flooring, and cabinetry. However, wood chips—which are a low-quality and plentiful waste byproduct of lumber milling, woodworking, and shipping operations—have low economic value and complicated disposal methods. In this paper, we propose a strategy for wood chip reuse through the fabrication of bio-based building insulation foam. Through a high-temperature chemical treatment delignification process, we introduced additional small pores within the wood chips, effectively lowering their thermal conductivity, and used them in combination with a binding agent to produce a porous insulation foam. The porous insulation foam achieved a low thermal conductivity of 0.038 W/(m·K) and a high compressive strength of 1.1 MPa (70% strain). These characteristics demonstrate that wood waste can be repurposed into an effective building material, addressing challenges in both waste management and sustainable construction.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2024

Innovating the next generation of commercial smart building software

Nearly 30% of commercial building energy use is wasted due to equipment faults and HVAC controls problems. The result is increased emissions, compromised comfort and productivity, and less reliable coordination of building power needs with a clean grid. The energy impact alone represents $17 billion in potential savings. Today’s smart building software provides a robust solution to address these operational deficiencies. Energy management and information systems (EMIS) are saving up to 9% on average, with two-year paybacks. They are being incorporated into energy management processes, commissioning services, and utility programs. As effective as they are, two barriers prevent even deeper benefits; limited personnel to fix problems once they are identified, and the expense and time to manually implement changes in control systems. In partnership with the research community, the EMIS industry is developing new capabilities to overcome these barriers. Moving beyond siloed products for either fault detection and diagnostics, or optimal control, these new capabilities empower users to not only automatically identify faults, but also to push corrective action, and control improvements to their buildings. In this paper, several areas for enhancements are documented: ‘one-time’ correction of faults such as setpoints, schedules, and economizer lockouts; short-term active testing for automated proportional integral derivative (PID) loop tuning and functional testing; and continuous supervisory control for demand flexibility and year-round efficiency. Results are presented from a pair of partner implementations out of a dozen providers integrating these enhancements into their products, including field tests from across the country, and insights into operator acceptance and integration into operations and maintenance practices.

Casillas, Armando↗
DOE OSTI2024

Iodine solid sorbent design: a literature review of the critical criteria for consideration

Designing sorbents for iodine capture in different conditions requires selection and optimization of a large and diverse range of variables. These variables fall into general categories (or features) of sorbent activity, sorbent stability, and the fate of the loaded material in terms of the disposal (waste form) options available. To illustrate, silver-loaded, high-porosity sorbents make for maximized iodine capture and less pressure drop in a column-based sorption system approach, however, this high porosity can lead to less mechanically stable sorbents. Additionally, waste forms containing silver must also be compliant with additional criteria for hazardous waste disposal. Thus, all these aspects must be considered simultaneously when selecting a sorbent for utilization under specific conditions. Information is given for different types of sorbent design considerations for different operating conditions and some emphasis is also given on promising alternatives for silver as the active (chemisorption-based) getter metal. Discussion is given around demonstrated options for waste forms for different metal-iodide compounds.

36 MATERIALS SCIENCE↗
DOE OSTI2022

MSW Variability Mapping and Conversion to Biofuel

MSW (Municipal Solid Waste) is a form of biomass which consists of categorized components of waste/trash. The general categories are paper, yard trash, construction & debris, appliances, tires, glass, metals, aluminum & steel cans, plastics, organics, inorganics, and HHW (Household Hazardous Waste). This project focuses on the factors within a region or population that contribute to variability in the composition of MSW and in turn MSW’s convertibility to biofuel. A list of contributors was determined (Social Vulnerability Index, Access to Public Transportation, Racial Distribution, GDP, Personal Income) and then JMP was used to perform a Multivariate analysis to determine correlations and a Partial Least-Squares regression to determine Variable Importance Plots for each MSW category. In addition to data analysis, the convertibility of MSW to biofuel was studied via microwave pyrolysis system in order to separate and characterize the various gaseous and bio-oil products.

09 BIOMASS FUELS↗
DOE OSTI2021

Raman Spectroscopy Based On-Line, Real-Time Monitoring to Reduce Composition Uncertainties: Enhanced sensitivity through optimization of Raman Parameters

Optical spectroscopy-based on-line monitoring of Hanford processing streams can enable real-time characterization of chemical composition of process streams and batches, ultimately enabling and enhancing process control. It can provide immediate feedback on process conditions and has the potential to reduce the needed number of grab sample collections, thereby reducing times and costs associated with laboratory processing. Here we discuss the utilization of Raman spectroscopy to quantify multiple target analytes that are common within Hanford tanks and waste processing streams. Analytes include: nitrate, nitrite, carbonate, chromate, sulfate, phosphate, hydroxide, oxalate, ammonia, and aluminate. Most notably in this work, Raman applications to low-concentration streams are explored and optimized. Raman instrument specifications are compared; specifically, the impact of utilizing three different Raman excitation wavelengths, 405, 532, and 671 nm, is discussed. Also, Raman data collection parameters such as collection time and spectral averaging are measured and discussed. Finally, optical libraries of chemical targets were collected using optimized collection parameters and chemometric models were built to automate quantification of chemical targets. These models were validated through application to simulants and real Hanford process samples. Chemometric models performed well on both training and validation sets, suggesting these approaches can be successfully applied to on-line and real-time monitoring of low concentration Hanford processing streams. The use of the combine Raman wave lengths with the enhanced chemometric models for the low concentration streams significantly improved the chemical detection levels and significantly reduced uncertainties of those measurements.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

Cryogenic Carbon Capture™ (CCC) Status Report

The Cryogenic Carbon Capture™ (CCC) process separates CO2 from light gases in essentially any continuous process. CCC cools the gases to the frost or desublimation point of CO2 (-100 to -135 °C), separates and pressurizes the solids, and warms all streams to produce a CO2-depleted stream at ambient pressure and a pure (99+%) pressurized liquid CO2 stream typically to about 150 bar, both at ambient temperature. The process also recovers all gas moisture and most gas impurities less volatile than CO2 (NOx, SOx, Hg, PM, UHC, CCC, etc.) in separable streams. CCC nearly eliminates refrigeration energy for sensible temperature changes through heat integration. CCC does require energy to change the CO2 phase from a mixed vapor to a pressurized fluid, which represents the minimum energy required of any process for this separation. CCC uses additional energy for turbomachinery inefficiencies, heat losses, moisture removal and overall process pressure drop. Aside from these real-world energy demands, CCC operates near the minimum energy required to perform this gas separation by minimizing stream recycling. CCC compresses CO2 as a liquid, which is one of several reasons it costs about about half as much and consumes about half as much energy as an amine process when using flue gases with about 15% CO2. The process also has several major additional advantages, including (a) it is a bolt-on retrofit technology that does not need steam or any modification of existing equipment, (b) it recovers water and nearly all pollutants in addition to CO2 from the flue gas, (c) it enables highly efficient and cost effective energy storage at grid scale and on time scales of minutes, (d) it enables NG storage if the energy storage option is used, and (d) it has a small footprint and is minimally disruptive to existing plants, requiring only electrical power and a gas source to operate. Sustainable Energy Solutions (SES) has scaled this technology through several levels, the largest of which captures nominally 1 tonne of CO2/day and is called the skid system. Skid system field tests include utility-scale power plants, cement plants, heating plants, and other utility or industrial sites that burn natural gas, biomass, coal, shredded tires, municipal waste, and combinations of these fuels. These field tests produced 95-99% CO2 capture with CO2 purities of 99+% and initial CO2 contents that range from 4 to 28%. SES currently seeks to scale the system to merchant scale (10-80 tonnes of CO2 per day). In the process of doing so, SES has demonstrated the potential for CCC to contribute to energy storage and direct air capture in innovative and cost-effective ways. This presentation discusses the overall process and highlights results from field and in-house tests. These include (a) measured CO2 capture rates and operating conditions from in-house and field tests, and (b) predicted utility-scale costs and energy demands. This discussion also includes the application of the CCC technology to energy storage and direct air capture.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2020

E-Area Low-Level Waste Facility GoldSim System Model

This report documents the development of the E-Area Low-Level Waste Facility (ELLWF) trench system model. The GoldSim® Monte Carlo simulation software is utilized to model the release and transport of radiological inventory disposed (both currently and in the future) within Engineered and Slit Trenches. This model is in support of the sensitivity and uncertainty analysis for the ELLWF Performance Assessment. The ELLWF system model utilizes a hybrid-approach to accurately describe the disposal system. The Hydrologic Evaluation of Landfill Performance model provides the infiltration data to both PORFLOW and GoldSim. PORFLOW is used to calibrate the GoldSim model to ensure confidence in the stochastic results. Finally, the concentrations from GoldSim transport simulations are fed into the SRNL Dose Toolkit to calculate dose impacts and assess plume interaction

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗