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NASA NTRS1996

On the Capabilities of Using AIRSAR Data in Surface Energy/Water Balance Studies

The capabilities of using remote sensing data, and in particular multifrequency/multipolarization SAR data, like AIRSAR, for the retrieval of surface parameters, depend considerably on the specificity of each application. The potentials, and limitations, of SAR data in ecological investigations are well known. Because the chemistry is a major component in such studies and because of the almost lacking chemical information at the wavelengths of SAR data, the capabilities of using SAR-derived information in such studies are considerably limited. However, in the case of surface energy/water balance studies, the determination of the amount of water content, both in the soil and in the plants, is a major component in all modeling approaches. As the information about water content is present in the SAR signal, then the role of SAR data in studies where water content is to be determined becomes clearly predominant. Another situation where the role of SAR data becomes dominant over other remote sensing systems is the case of dense canopies. Because of the penetration capabilities of microwave data, which is especially superior as compared to optical data, information about the canopy as a whole and even the underlying soil is contained in the SAR data, while only the top canopy provides the information content in the case of optical data. In the case of relatively dense canopies, as has been demonstrated in this study, such different penetration capabilities provide very different results in terms of the derived total canopy water content, for instance. However, although all such capabilities are well known, unfortunately there are also well known limitations. Apart from calibration-related aspects (that we will not consider in this study), and apart from other intrinsic problems (like image noise, topographic corrections, etc.) which also significantly affect the derived results, we will concentrate on the problem of extracting information from the data. Even at this level, methods are still not fully well established, especially over vegetation-covered areas. In this paper, an algorithm is described which allows derivation of three fundamental parameters from SAR data: soil moisture, soil roughness and canopy water content, accounting for the effects of vegetation cover by using optical (Landsat) data as auxiliary. Capabilities and limitations of the data and algorithms are discussed, as well as possibilities to use these data in energy/water balance modeling studies. All the data used in this study were acquired as part of the Intensive Observation Period in June-July 1991 (European Multisensor Aircraft Campaign-91), as part of the European Field Experiment in a Desertification- threatened Area (EFEDA), a European contribution to the global-change research sponsored by the IGBP program (Bolle et al., 1993).

Moreno, Jose F.↗

DOE OSTI2025

Development of an ERT‐Based Framework for Bentonite Buffers Monitoring From Laboratory Tests: 2. Quantitative Moisture Dynamics Estimation Model

Abstract The long‐term containment of high‐level radioactive waste in geological disposal repositories relies on Engineered Barrier Systems (EBS), with bentonite clay emerging as a candidate material due to its unique properties. Understanding moisture dynamics within bentonite buffers is crucial for EBS performance, as it directly influences the material's swelling capacity, thermal and hydraulic conductivity, mechanical properties, and long‐term evolution under complex thermal‐hydrological‐mechanical (THM) processes. This study develops an advanced Electrical Resistivity Tomography (ERT)‐based framework to quantitatively monitor moisture dynamics under THM conditions. Our framework extends the Waxman‐Smits model to incorporate the coupled effects of temperature, water content, fluid chemistry, and mechanical changes on bentonite's electrical properties. Utilizing HotBENT‐Lab data from our companion paper, which includes electrical conductivity, CT density, and thermocouple measurements, this study offers a novel methodological framework bridging different scales of the model. Our results show that the extended model can estimate water content from ERT data, capturing spatial and temporal variations in moisture distribution within bentonite columns. However, the model tends to overestimate water content compared to CT density‐derived measurements. We address this discrepancy by incorporating a simplified swelling effect model, which improves agreement between ERT and CT density‐based water content estimates. We also discuss model limitations, including simplified treatment of swelling and micropore effects, and propose a conceptual framework for transitioning from laboratory to field applications, addressing challenges such as parameter scalability, field validation methods, and integration of diverse data sources. This ERT‐based framework can potentially advance real‐world moisture monitoring of bentonite‐based EBS in nuclear waste repositories. Plain Language Summary Safely containing high‐level radioactive waste depends on barriers made from materials like bentonite clay, which is effective because it swells and seals in the waste. To ensure these barriers work well over time, it's important to understand how moisture moves through the clay. Our study developed a new method using ERT to monitor moisture levels in bentonite under conditions that mimic those in actual storage sites, including changes in temperature, water content, and mechanical stress. This study improved an existing model to better account for how these factors affect the clay, allowing us to create more accurate moisture maps. Initially, the proposed model overestimated the amount of water in the clay, but its accuracy was improved by factoring in how the clay swells when wet. This study also identified some limitations of the model and suggested ways to adapt it for use in real‐world waste storage sites. This new approach could lead to better monitoring and safety checks for nuclear waste storage systems, helping to ensure long‐term containment. Key Points This work develops an ERT‐based framework extending the Waxman‐Smits model to monitor bentonite moisture dynamics during coupled THM processes The extended model accurately estimates water content from Electrical Resistivity Tomography data, incorporating swelling effects to improve precision This work proposes a conceptual framework for transitioning from laboratory to field applications, advancing EBS monitoring in nuclear waste repositories

Chen, Hang↗

DOE OSTI2024

The Effect of Air Separations on Fast Pyrolysis Products for Forest Residue Feedstocks

This study investigates the intricate relationship between biomass preprocessing and pyrolysis product yields, employing the air classification technique for the treatment of loblolly pine residues with varying moisture content. A comprehensive exploration of the physicochemical properties of air-classified loblolly pine informs a sophisticated pyrolysis simulation model. Given the complex and multifaceted nature of biomass pyrolysis, operating across diverse temporal and spatial scales, a pyrolysis kinetics-based CFD–DEM simulation method is employed to predict product yields. Results showed that the elevated moisture content amplifies particle adhesiveness, necessitating augmented air velocities for effective separation, thereby influencing the efficiency of the separation process. While carbon and hydrogen contents exhibit relative stability across diverse moisture contents and blower frequencies, the oxygen content undergoes noticeable changes. For example, the oxygen contents were measured as 29.2 and 38.6 wt% in the light fraction of 30% moisture content sample at blower frequencies of 10 and 20 Hz, respectively. An intriguing finding emerges from pyrolysis simulation, indicating that a lower blower frequency in air classification moderately enhances bio-oil yield and significantly improves its quality, particularly in terms of water content. For instance, the water content in the bio-oil was about 1.5% and 10% in the heavy and light fractions, respectively from 10% moisture sample under 15 Hz blower frequency. In summary, a detailed understanding and strategic manipulation of critical material attributes in biomass through efficient fractionation techniques are imperative for advancing fast pyrolysis as a sustainable avenue for renewable energy and chemical production.

09 BIOMASS FUELS↗

NASA NTRS1981

Progress in radar snow research

Multifrequency measurements of the radar backscatter from snow-covered terrain were made at several sites in Brookings, South Dakota, during the month of March of 1979. The data are used to examine the response of the scattering coefficient to the following parameters: (1) snow surface roughness, (2) snow liquid water content, and (3) snow water equivalent. The results indicate that the scattering coefficient is insensitive to snow surface roughness if the snow is drv. For wet snow, however, surface roughness can have a strong influence on the magnitude of the scattering coefficient. These observations confirm the results predicted by a theoretical model that describes the snow as a volume of Rayleig scatterers, bounded by a Gaussian random surface. In addition, empirical models were developed to relate the scattering coefficient to snow liquid water content and the dependence of the scattering coefficient on water equivalent was evaluated for both wet and dry snow conditions.

Stiles, W. H.↗

NASA NTRS2014

A Thermal Analysis of a Hot-Wire Probe for Icing Applications

This paper presents a steady-state thermal model of a hot-wire instrument applicable to atmospheric measurement of water content in clouds. In this application, the power required to maintain the wire at a given temperature is used to deduce the water content of the cloud. The model considers electrical resistive heating, axial conduction, convection to the flow, radiation to the surroundings, as well as energy loss due to the heating, melting, and evaporation of impinging liquid and or ice. All of these parameters can be varied axially along the wire. The model further introduces a parameter called the evaporation potential which locally gauges the maximum fraction of incoming water that evaporates. The primary outputs of the model are the steady-state power required to maintain a spatially-average constant temperature as well as the variation of that temperature and other parameters along the wire. The model is used to understand the sensitivity of the hot-wire performance to various flow and boundary conditions including a detailed comparison of dry air and wet (i.e. cloud-on) conditions. The steady-state power values are compared to experimental results from a Science Engineering Associates (SEA) Multi-Element probe, a commonly used water-content measurement instrument. The model results show good agreement with experiment for both dry and cloud-on conditions with liquid water content. For ice, the experimental measurements under read the actual water content due to incomplete evaporation and splashing. Model results, which account for incomplete evaporation, are still higher than experimental results where the discrepancy is attributed to splashing mass-loss which is not accounted in the model.

Thermal Analysis↗

NASA NTRS2000

Near-Global Survey of Cloud Column Susceptibilities Using ISCCP Data

A new parameter, cloud column susceptibility, is introduced to study the aerosol indirect effect. There are several advantages of this new parameter in comparison with the traditional cloud susceptibility. First, no assumptions about constant liquid water content and cloud layer thickness are required in calculations so that errors caused by these assumptions can be avoided. Second, no a priori knowledge of liquid water content is necessary in remote sensing, which makes global survey by satellite data possible even though liquid water content may change significantly. Third, this new parameter can deal with variations of cloud geometrical thickness during cloud-aerosol interactions, which are evidenced by Without assuming how cloud droplet size will respond to changes of number concentration, this new parameter describes the aerosol indirect effect more directly. It addresses the question of how cloud albedo changes with increasing column number concentrations of cloud droplets, which is resulted from cloud-aerosol interactions. In this study, two approaches are used to retrieve cloud column susceptibility by satellite data. The results of both approaches show a striking contrast of cloud column susceptibilities between continental and maritime. Between the two approaches, the one that uses no assumption of constant liquid water content leads to smaller, some times even negative, cloud column susceptibilities. This finding suggests that the aerosol indirect effect may be overestimated if the assumption of constant liquid water content is used in model studies.

Han, Qingyuan↗

NASA NTRS1975

The utility of surface temperature measurements for the remote sensing of surface soil water status

Experiments carried out on an Avondale loam soil indicated that the thermal inertia concept of soil water content detection is reasonably sound. The volumetric water contents of surface soil layers between 2 and 4 cm thick were found to be linear functions of the amplitude of the diurnal surface soil temperature wave for clear day-night periods. They were also found to be linear functions of the daily maximum value of the surface soil-air-temperature differential. Tests on three additional soils ranging from sandy loam to clay indicated that the relations determined for Avondale loam could not be accurately applied to these other soil types. When the moisture characteristic curves of each soil were used to transform water contents into pressure potentials, however, it was found that soil water pressure potential could be determined without prior knowledge of soil type, and thus its value as a potential soil water status survey tool was significantly enhanced.

Idso, S. B.↗

DOE OSTI2021

Influence of fixed charge concentration and water uptake on ion sorption in AMPS/PEGDA membranes

Water content and charge density strongly influence ion sorption in charged membranes. However, isolating the individual effect of each parameter on ion sorption can be difficult due to experimental challenges associated with independently controlling these two variables during membrane synthesis. This frustrates development and validation of fundamental models and structure/property relationships. In this study, three series of uncharged and negatively charged hydrogel membranes were prepared using poly(ethylene glycol) diacrylate (PEGDA) as a cross-linker and 2-acrylamido-2-methylpropanesulfonic acid (AMPS) as an ionic monomer. Here, water content and charge density were controlled by varying AMPS content and PEGDA chain length. Ion sorption in these materials was measured using aqueous NaCl solutions at concentrations ranging from 0.01 to 1.0 M. At constant charge density, salt sorption increased as water content increased. At fixed water content, salt sorption decreased as charge density increased. Salt sorption in membranes with the highest water content and charge density was predicted using the Donnan/Manning model, which accounts for solution and membrane phase thermodynamic non-idealities. However, this approach could not predict sorption in weakly charged and uncharged membranes, presumably due to additional membrane phase thermodynamic non-idealities associated with ion solvation and uncharged polymer segments.

36 MATERIALS SCIENCE↗

NASA NTRS1980

Agricultural soil moisture experiment, Colby, Kansas 1978: Measured and predicted hydrological properties of the soil

Predictive procedures for developing soil hydrologic properties (i.e., relationships of soil water pressure and hydraulic conductivity to soil water content) are presented. Three models of the soil water pressure-water content relationship and one model of the hydraulic conductivity-water content relationship are discussed. Input requirements for the models are indicated, and computational procedures are outlined. Computed hydrologic properties for Keith silt loam, a soil typer near Colby, Kansas, on which the 1978 Agricultural Soil Moisture Experiment was conducted, are presented. A comparison of computed results with experimental data in the dry range shows that analytical models utilizing a few basic hydrophysical parameters can produce satisfactory data for large-scale applications.

Arya, L. M.↗

NASA NTRS2002

Hydrogen Concentrations on C-class Asteroids from Remote Sensing

We present spectroscopic observations of 16 asteroids from 1.9-3.6 microns, collected from the United Kingdom Infrared Telescope (UKIRT) from 1996-2000. Of these 16 asteroids, 11 show some evidence of a 3-micron hydrated mineral absorption feature greater than 2 sigma at 2.9 microns. Using relations first recognized for carbonaceous chondrite powders by Miyamoto and Zolensky (1994) and Sato et al. (1997), we have determined the hydrogen/silicon ratio for these asteroids and calculated their equivalent water contents, assuming all the hydrogen was in water. The asteroids split into two groups, roughly defined as equivalent water contents of greater than approx. 7% (eight asteroids) and less than approx. 3 % (the remaining eight asteroids). This latter group includes some asteroids for which there is a small but statistically significant 3-micron band of non-zero depth. The G-class asteroids in the survey have higher water contents, consistent with CM chondrites. This strengthens the connection between CM chondrites and G asteroids that was proposed by Burbine (1998). We find that the 0.7-micron and 3-micron band depths are correlated for the population of target objects.

Rivkin, A. S.↗

NASA NTRSDate not supplied

A Preliminary Study of Inter-Facility LWC Differences in Appendix C and Supercooled Large Drop Conditions due to Calibration Instruments

The simulation of clouds containing Supercooled Large Droplets has received increasing attention due to the introduction of Appendix O and future associated requirements for means of compliance. Supercooled Large Droplet conditions can cover four orders of magnitude in drop sizes, imposing a larger instrument measurement challenge than for Appendix C conditions. Wind tunnel facilities have adopted different instrumentation for liquid water content measurement, with fundamentally different principles of operation. In order to explore the comparability of the different instruments used for Appendix C and SLD measurement, and its impact on confidence in measurements used for means of compliance, a project was established to conduct a series of dedicated tests at three wind tunnel facilities. To date, liquid water content measurements have been completed using a Multi-Element sensor as the common instrument at two of the facilities. The data have provided preliminary information suggesting that substantial inter-facility differences likely exist in liquid water content estimates in Supercooled Large Droplet conditions that appear to be largely attributable to the choice of calibration instruments. These results are dependent on the assumption that the Multi-Element probe would produce equivalent measurements at the two facilities if the liquid water content were the same, regardless of other environmental differences that may exist between the two facilities. Planned further testing with other liquid water content measurement techniques may provide further information to confirm or refute the results of this study.

aircraft icing↗

NASA NTRSDate not supplied

A Preliminary Study of Inter-Facility LWC Differences in Appendix C and Supercooled Large Droplet Conditions due to Calibration Instruments

aircraft icing↗

NASA NTRS2003

Hydrogen Concentrations on C-Class Asteroids Derived from Remote Sensing

We present spectroscopic observations of 16 asteroids from 1.9-3.6 microns collected from the United Kingdom Infrared Telescope (UKIRT) from 1996-2000. Of these 16 asteroids, 11 show some evidence of a 3 microns hydrated mineral absorption feature greater than 2(sigma) at 2.9 microns. Using relations first recognized for carbonaceous chondrite powders by Miyamoto and Zolensky and Sato et al., we have determined the hydrogen to silicon ratio for these asteroids and calculated their equivalent water contents, assuming all the hydrogen was in water. The asteroids split into 2 groups, roughly defined as equivalent water contents approx. greater than 7% (8 asteroids, all with 3 microns band depths approx. greater than 20%) and approx. greater than 3% for the remaining 8 asteroids. This latter group includes some asteroids for which a weak but statistically significant 3 microns band of non-zero depth exists. The G-class asteroids in the survey have higher water contents, consistent with CM chondrites. This strengthens the connection between CM chondrites and G asteroids that was proposed by Burbine. We find that the 0.7 microns and 3 microns band depths are correlated for the population of target objects.

Rivkin, A. S.↗

NASA NTRS2003

Hydrogen Concentrations on C-class Asteroids Derived from Remote Sensing

We present spectroscopic observations of 16 asteroids from 1.9-3.6 microns collected from the United Kingdom Infrared Telescope (UKIRT) from 1996-2000. Of these 16 asteroids, 11 show some evidence of a 3 micron hydrated mineral absorption feature greater than 2 sigma at 2.9 microns. Using relations first recognized for carbonaceous chondrite powders by Miyamoto and Zolensky (1994) and Sato et al. (1997), we have determined the hydrogen to silicon ratio for these asteroids and calculated their equivalent water contents, assuming all the hydrogen was in water. The asteroids split into 2 groups, roughly defined as equivalent water contents greater than approximately 7% (8 asteroids, all with 3 micron band depths greater than approximately 20%) and less than approximately 3% for the remaining 8 asteroids. This latter group includes some asteroids for which a weak but statistically significant 3 micron band of non-zero depth exists. The G-class asteroids in the survey have higher water contents, consistent with CM chondrites. This strengthens the connection between CM chondrites and G asteroids that was proposed by Burbine (1998). We find that the 0.7 micron and 3 micron band depths are correlated for the population of target objects.

Rivkin, A. S.↗

NASA NTRS2018

Seasonal Monitoring of Melt and Accumulation Within the Deep Percolation Zone of the Greenland Ice Sheet and Comparison with Simulations of Regional Climate Modeling

Increasing melt over the Greenland Ice Sheet (GrIS) recorded over the past several years has resulted in significant changes of the percolation regime of the ice sheet. It remains unclear whether Greenland's percolation zone will act as a meltwater buffer in the near future through gradually filling all pore space or if near-surface refreezing causes the formation of impermeable layers, which provoke lateral runoff. Homogeneous ice layers within perennial firn, as well as near-surface ice layers of several meter thickness have been observed in firn cores. Because firn coring is a destructive method, deriving stratigraphic changes in firn and allocation of summer melt events is challenging. To overcome this deficit and provide continuous data for model evaluations on snow and firn density, temporal changes in liquid water content and depths of water infiltration, we installed an upward-looking radar system (upGPR) 3.4 m below the snow surface in May 2016 close to Camp Raven (66.4779 deg N, 46.2856 deg W) at 2120 m a.s.l. The radar is capable of quasi-continuously monitoring changes in snow and firn stratigraphy, which occur above the antennas. For summer 2016, we observed four major melt events, which routed liquid water into various depths beneath the surface. The last event in mid-August resulted in the deepest percolation down to about 2.3 m beneath the surface. Comparisons with simulations from the regional climate model MAR are in very good agreement in terms of seasonal changes in accumulation and timing of onset of melt. However, neither bulk density of near-surface layers nor the amounts of liquid water and percolation depths predicted by MAR correspond with upGPR data. Radar data and records of a nearby thermistor string, in contrast, matched very well for both timing and depth of temperature changes and observed water percolations. All four melt events transferred a cumulative mass of 56 kg/(sq. m) into firn beneath the summer surface of 2015. We find that continuous observations of liquid water content, percolation depths and rates for the seasonal mass fluxes are sufficiently accurate to provide valuable information for validation of model approaches and help to develop a better understanding of liquid water retention and percolation in perennial firn.

Heilig, Achim↗

NASA NTRS2009

Commercial off-the-Shelf (COTS) Refractory Material Evaluation

Fondu Fyre (FF) is currently the only refractory material qualified for use in the flame trench at KSC's Shuttle Launch Pads 39A and 39B. However, the material is not used as it was qualified and has undergone increasingly frequent and severe degradation due to the launch blasts. This degradation is costly as well as dangerous for launch infrastructure, crew and vehicle. FF is applied at the pad via the gunnite process, where wetted refractory material is sprayed onto a steel grid mounted on a support structure. The water content in this process can be manually adjusted by operators, causing distinct visual and physical discrepancies among repair areas. Since the application process is unlikely to change for new refractory materials, it is important to understand the effects of water content on commercial off-the-shelf (COTS) refractory materials. The purpose of this study was to evaluate the performance of the FF with respect to various water contents as well as heat treatments, to simulate aging and exposure to the blast. Initial results indicated that different water contents and heat treatments result in distinct differences in crushing strength, apparent porosity and bulk density. However, water content became an insignificant factor in both crush strength and porosity when FF was cured to at least 1500 deg. Additionally, inspection of the material's surface microstructure by scanning electron microscopy indicated distinguishable characteristics for different heat treatment levels. Results from this study will help guide future studies on the development and identification of new refractory materials.

Calle, Luz Marina↗

NASA NTRS2000

Water-Searchers: A Reconfigurable and Self Sustaining Army of Subsurface Exploration Robots Searching for Water/Ice Using Multiple Sensors

Perhaps the most promising site for extant life on Mars today is where subsurface water has been maintained. Therefore, searching for underground water will provide a good chance to find evidence of life on Mars. The following are scientific/engineering questions that we want to answer using our approach: (1) Is there subsurface water/ice? How deep is it? How much is there? Is it frozen? (2) What kinds of underground layers exist in the Martian crust? (3) What is the density of Martian soil or regolith? Can we dig into it? Should we drill into it? (4) Can a sudden release of underground water occur if a big asteroid hits Mars? Our approach provides essential information to answer these questions. Moreover, dependence on the water content and depth in soil, not only resultant scientific conclusions but also proper digging/drilling methods, are suggested. 'How much water is in the Martian soil?' There can be several possibilities: (1) high water content that is enough to form permafrost; (2) low water content that is not enough to form permafrost; or (3) different layers with different moisture contents. 'How deep should a rover dig into soil to find water/ice?' The exact size-frequency distribution has not been measured for the soil particles. On-board sensors can provide not only the water content but also the density (or porosity) of Martian soil as a function of depth.

Youk, G. U.↗

NASA NTRS2008

Arctic Mixed-phase Clouds Simulated by a Cloud-Resolving Model: Comparison with ARM Observations and Sensitivity to Microphysics Parameterizations

Single-layer mixed-phase stratiform (MPS) Arctic clouds, which formed under conditions of large surface heat flux combined with general subsidence during a subperiod of the Atmospheric Radiation Measurement (ARM) Program Mixed-Phase Arctic Cloud Experiment (M-PACE), are simulated with a cloud resolving model (CRM). The CRM is implemented with either an advanced two-moment (M05) or a commonly used one-moment (L83) bulk microphysics scheme and a state-of-the-art radiative transfer scheme. The CONTROL simulation, that uses the M05 scheme and observed aerosol size distribution and ice nulei (IN) number concentration, reproduces the magnitudes and vertical structures of cloud liquid water content (LWC), total ice water content (IWC), number concentration and effective radius of cloud droplets as suggested by the M-PACE observations. It underestimates ice crystal number concentrations by an order of magnitude and overestimates effective radius of ice crystals by a factor of 2-3. The OneM experiment, that uses the L83 scheme, produces values of liquid water path (LWP) and ice plus snow water path (ISWP) that were about 30% and 4 times, respectively, of those produced by the CONTROL. Its vertical profile of IWC exhibits a bimodal distribution in contrast to the constant distribution of IWC produced in the CONTROL and observations.

Xu, Kuan-Man↗