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NASA NTRS2014

Water: A Critical Material Enabling Space Exploration

Water is one of the most critical materials in human spaceflight. The availability of water defines the duration of a space mission; the volume of water required for a long‐duration space mission becomes too large, heavy, and expensive for launch vehicles to carry. Since the mission duration is limited by the amount of water a space vehicle can carry, the capability to recycle water enables space exploration. In addition, water management in microgravity impacts spaceflight in other respects, such as the recent emergency termination of a spacewalk caused by free water in an astronaut's spacesuit helmet. A variety of separation technologies are used onboard spacecraft to ensure that water is always available for use, and meets the stringent water quality required for human space exploration. These separation technologies are often adapted for use in a microgravity environment, where water behaves in unique ways. The use of distillation, membrane processes, ion exchange and granular activated carbon will be reviewed. Examples of microgravity effects on operations will also be presented. A roadmap for future technologies, needed to supply water resources for the exploration of Mars, will also be reviewed.

Pickering, Karen D.↗

NASA NTRS2013

Toward Global Drought Early Warning Capability - Expanding International Cooperation for the Development of a Framework for Monitoring and Forecasting

Drought has had a significant impact on civilization throughout history in terms of reductions in agricultural productivity, potable water supply, and economic activity, and in extreme cases this has led to famine. Every continent has semiarid areas, which are especially vulnerable to drought. The Intergovernmental Panel on Climate Change has noted that average annual river runoff and water availability are projected to decrease by 10 percent-13 percent over some dry and semiarid regions in mid and low latitudes, increasing the frequency, intensity, and duration of drought, along with its associated impacts. The sheer magnitude of the problem demands efforts to reduce vulnerability to drought by moving away from the reactive, crisis management approach of the past toward a more proactive, risk management approach that is centered on reducing vulnerability to drought as much as possible while providing early warning of evolving drought conditions and possible impacts. Many countries, unfortunately, do not have adequate resources to provide early warning, but require outside support to provide the necessary early warning information for risk management. Furthermore, in an interconnected world, the need for information on a global scale is crucial for understanding the prospect of declines in agricultural productivity and associated impacts on food prices, food security, and potential for civil conflict. This paper highlights the recent progress made toward a Global Drought Early Warning Monitoring Framework (GDEWF), an underlying partnership and framework, along with its Global Drought Early Warning System (GDEWS), which is its interoperable information system, and the organizations that have begun working together to make it a reality. The GDEWF aims to improve existing regional and national drought monitoring and forecasting capabilities by adding a global component, facilitating continental monitoring and forecasting (where lacking), and improving these tools at various scales, thereby increasing the capacity of national and regional institutions that lack drought early warning systems or complementing existing ones. A further goal is to improve coordination of information delivery for drought-related activities and relief efforts across the world. This is especially relevant for regions and nations with low capacity for drought early warning. To do this requires a global partnership that leverages the resources necessary and develops capabilities at the global level, such as global drought forecasting combined with early warning tools, global real-time monitoring, and harmonized methods to identify critical areas vulnerable to drought. Although the path to a fully functional GDEWS is challenging, multiple partners and organizations within the drought, forecasting, agricultural, and water-cycle communities are committed to working toward its success.

GDEWS↗

DOE OSTI2025

Enhancing heat pump water heater performance with embedded phase change materials thermal energy storage: First hour rating improvement and demand response operation

The increasing global emphasis on energy efficiency and sustainability has put heat pump water heaters (HPWHs) in the spotlight as an energy-efficient alternative to traditional water heating systems. However, their widespread adoption is limited by challenges such as insufficient First Hour Rating (FHR), suboptimal control mechanisms, and limited flexibility for demand response operations. Here, to address these limitations, this study proposes an innovative HPWH system integrated with embedded phase change material (PCM)-based thermal energy storage (TES). The research introduces a novel design and control strategy that leverages optimized PCM integration to enhance thermal storage capacity, improve hot water delivery during peak demand, and increase load-shifting potential. A combination of system modeling, performance simulation, and demand response control strategy evaluation was employed to quantify the benefits of PCM integration. Results demonstrate that the proposed PCM-TES HPWH system significantly enhances FHR, with an optimal 7.0 lb. of PCM increasing FHR by over 26 %—from 62 to 78 gal—for a standard 50-gal HPWH. Additionally, under advanced demand response operation using a preheat strategy, the system reduces the percentage of control temperature out-of-band time from 65 % (conventional HPWH) to just 11.6 %, enabling a more stable and efficient hot water supply. This research contributes a novel PCM-embedded HPWH design and control framework that addresses both performance and grid-interactivity challenges. The findings offer a viable pathway to enhancing the operational efficiency, flexibility, and grid responsiveness of residential water heating systems.

Demand response control↗

DOE OSTI2022

Non-Powered Dam Retrofit Exemplary Design for Hydropower Applications

Non-powered dams (NPDs) represent complex systems, situated at the intersection of natural stream environments and the built environment. The presence and operations of NPDs affect stream constituents (e.g., fish, recreational craft, sediment, water) and serve one or more engineered purposes (e.g., recreation, flood control, water supply, irrigation, tailings and debris control, navigation). By definition, NPDs do not provide hydropower generation. However, every NPD contains some untapped hydropower resource potential, represented by the pre-existing hydraulic head created by the dam and presence of flowing water. Adding power generation to an NPD requires retrofitting the NPD, which could involve the addition of any new component or function beyond that currently installed. Because this research is funded by the US Department of Energy Water Power Technologies Office, adding hydropower to NPDs is among the primary objectives for research investment. However, NPD retrofitting extends beyond the purview of hydropower additions. This report provides background information regarding NPD development in the United States, including an overview of the US NPD population, development potential, and recent development. It also summarizes challenges and opportunities facing NPD retrofit development, highlights the importance of maintaining or improving stream and dam functionality, notes key NPD characteristics, describes NPD retrofit methods, and identifies innovation areas for spurring future NPD retrofit development. Section 4 describes retrofit exemplary design principles and concepts that could apply to a wide range of NPD projects. These principles and concepts inform an NPD Retrofit Exemplary Design Specification (REDS), as included in Appendix A. The NPD REDS is heavily influenced by prior work under the standard modular hydropower technology acceleration research initiative, especially the work documented in the Exemplary Design Envelope Specification for Standard Modular Hydropower Technology (Witt et al., 2017). Whereas this prior work focuses on a particular technology class that applies most intentionally for new stream-reach development (i.e., greenfield sites), the NPD REDS contained herein applies more broadly to the NPD resource class and is technology-agnostic (i.e., the specific technologies intended to be described are not explicitly prescribed). This report serves as a part of early-phase research on NPD retrofit development, aimed toward spurring additional, follow-on efforts to specifically address development challenges, capitalize on development opportunities, and inspire innovation. As documented in the landmark “Hydropower Vision” report (DOE 2016), “transformative technical innovations able to meet the co-objectives of environmental sustainability and low-carbon energy will be critical to enabling additional hydropower growth.” This report serves as an important step in steering transformation of US non-powered dam infrastructure.

13 HYDRO ENERGY↗

DOE OSTI2021

Molecular Engineering of 2D Nanomaterial Field-Effect Transistor Sensors: Fundamentals and Translation across Innovation Spectrum

We report over the last decade, 2D layered nanomaterials have attracted significant attention across the scientific community due to their rich and exotic properties. Various nanoelectronic devices based on these 2D nanomaterials have been explored and demonstrated, including those for environmental applications. Here, the fundamental attributes of 2D layered nanomaterials for field-effect transistor (FET) sensors and tunneling FET (TFET) sensors, which provide versatile detection of water contaminants such as heavy-metal ions, bacteria, nutrients, and organic pollutants, are discussed. The major challenges and opportunities are also outlined for designing and fabricating 2D nanomaterial FET/TFET sensors with superior performance. Translation of these FET/TFET sensors from fundamental research to applied technology is illustrated through a case study on graphene-based real-time FET water sensors. A second case study centers on large-scale sensor networks for water-quality monitoring to enable intelligent drinking water and river-water systems. Overall, 2D nanomaterial FET sensors have significant potential for enabling a human-centered intelligent water system that can likely be applied to other precarious water supplies around the globe.

2D nanomaterials↗

DOE OSTI2024

How Rains and Floods Become Groundwater: Understanding Recharge Pathways With Stable and Cosmogenic Isotopes

Anthropogenic climate change leads to increased precipitation intensity and exacerbated droughts in California, challenging the reliability and drought resiliency of water supply. Storing floodwater underground via managed aquifer recharge can mitigate these effects through direct infiltration or streambed infiltration. Seasonally dry streams (arroyos) already play an important part in managing groundwater recharge to the Livermore basin (CA). Understanding how, when and where stormwater and arroyo water infiltrate is critical to effectively utilise this strategy. To track water from recent storms (water year 2022–2023, WY23) into the Livermore Valley Groundwater Basin, we analysed stable water isotopes (δ 18 O and δ 2 H) in combination with naturally occurring radioactive isotopic tracers, sulphur-35 ( 35 S, t ½ = 87 days) and tritium ( 3 H, t ½ = 12.3 years). By comparing measurements of δ 18 O, 35 S and 3 H in arroyos to precipitation and groundwater, we classified the relative age and identified source of recharge to 16 wells near two arroyos. Two wells contained water with recent recharge (from WY23) from local precipitation. One well had recent recharge from variable (precipitation and imported water) sources. One well contained imported water recharge. Three wells contained water from mixed recent and older (pre-WY23) waters, from local precipitation sources. Two wells contained recent recharge from local mine settling ponds. Seven wells had older recharge from local precipitation sources. This combination of isotopes allows us to delineate where local and imported water recharges in this highly managed basin and identify locations where managed aquifer recharge is contributing to rapid groundwater infiltration. Our combined interpretation of isotopic water ages and sources in the context of land use shows that local infiltration of precipitation in open spaces is an important recharge mechanism, in addition to the managed arroyo recharge. Finally, a broader familiarity with 35 S will enable more extensive research on the infiltration of urban floodwaters.

58 GEOSCIENCES↗

DOE OSTI2023

Assessing residential activity in a home plumbing system simulator: monitoring the occurrence and relationship of major opportunistic pathogens and phagocytic amoebas

Opportunistic premise plumbing pathogens (OPPPs) have been detected in buildings’ plumbing systems causing waterborne disease outbreaks in the United States. In this study, we monitored the occurrence of OPPPs along with free-living amoeba (FLA) and investigated the effects of residential activities in a simulated home plumbing system (HPS). Water samples were collected from various locations in the HPS and analyzed for three major OPPPs: Legionella pneumophila, nontuberculous mycobacterial species (e.g., Mycobacterium avium, M. intracellulare, and M. abscessus), and Pseudomonas aeruginosa along with two groups of amoebas (Acanthamoeba and Vermamoeba vermiformis). A metagenomic approach was also used to further characterize the microbial communities. Results show that the microbial community is highly diverse with evidence of spatial and temporal structuring influenced by environmental conditions. L. pneumophila was the most prevalent pathogen (86% of samples), followed by M. intracellulare (66%) and P. aeruginosa (21%). Interestingly, M. avium and M. abscessus were not detected in any samples. The data revealed a relatively low prevalence of Acanthamoeba spp. (4%), while V. vermiformis was widely detected (81%) across all the sampling locations within the HPS. Locations with a high concentration of L. pneumophila and M. intracellulare coincided with the highest detection of V. vermiformis, suggesting the potential growth of both populations within FLA and additional protection in drinking water. After a period of stagnation lasting at least 2-weeks, the concentrations of OPPPs and amoeba immediately increased and then decreased gradually back to the baseline. Furthermore, monitoring the microbial population after drainage of the hot water tank and partial drainage of the entire HPS demonstrated no significant mitigation of the selected OPPPs. This study demonstrates that these organisms can adjust to their environment during such events and may survive in biofilms and/or grow within FLA, protecting them from stressors in the supplied water.

59 BASIC BIOLOGICAL SCIENCES↗

NASA NTRS1995

The circum-Chryse region as a possible example of a hydrologic cycle on Mars: Geologic observations and theoretical evaluation

Moore, Jeffrey M.↗

NASA NTRS1995

The circum-Chryse region as a possible example of a hydrologic cycle on Mars: Geologic observations and theoretical evaluation

The transection and superposition relationships among channels, chaos, surface materials units, and other features in the circum-Chryse region of Mars were used to evaluate relative age relationships and evolution of flood events. Channels and chaos in contact (with one another) were treated as single discrete flood-carved systems. Some outflow channel systems form networks and are inferred to have been created by multiple flood events. Within some outflow channel networks, several separate individual channel systems can be traced to a specific chaos which acted as flood-source area to that specific flood channel. Individual flood-carved systems were related to widespread materials units or other surface features that served as stratigraphic horizons. Chryse outflow channels are inferred to have formed over most of the perceivable history of Mars. Outflow channels are inferred to become younger with increasing proximity to the Chryse basin. In addition, outflow channels closer to the basin show a greater diversity in age. The relationship of subsequent outflow channel sources to the sources of earlier floods is inferred to disfavor episodic flooding due to the progressive tapping of a juvenile near-surface water supply. Instead, we propose the circum-Chryse region as a candidate site of past hydrological recycling. The discharge rates necessary to carve the circum-Chryse outflow channels would have inevitably formed temporary standing bodies of H2O on the Martian surface where the flood-waters stagnated and pooled (the Chryse basin is topographically enclosed). These observations and inferences have led us to formulate and evaluate two hypotheses: (1) large amounts of the sublimated H2O off the Chryse basin flood lakes precipitated (snowed) onto the flood-source highlands and this H2O was incorporated into the near surface, recharging the H2O sources, making possible subsequent deluges; and (2) ponded flood-water in Chryse basin drained back down an anti basinward dipping subsurface layer accessed along the southern edge of the lake, recharging the flood-source aquifers. H2O not redeposited in the flood-source region was largely lost to the hydrologic cycle. This loss progressively lowered the vitality of the cycle, probably by now killing it. Our numerical evaluations indicate that of the two hypotheses we formulated, the groundwater seep cycle seems by far the more viable. Optimally, approx. 3/4 of the original mass of an ice-covered cylindrical lake (albedo 0.5, 1 km deep, 100-km radius, draining along its rim for one quarter of its circumference into substrata with a permeability of 3000 darcies) can be modeled to have moved underground (on timescales of the order of 10(exp 3) years) before the competing mechanisms of sublimation and freeze down choked off further water removal. Once underground, this water can travel distances equal to the separation between Chryse basin and flood-source sites in geologically short (approx. 10(exp 6) year-scale) times. Conversely, we calculate that optimally only approx. 40% of the H2O carried from Chryse can condense at the highlands, and most of the precipitate would either collect at the base of the highlands/lowlands scarp or sublimate at rates greater than it would accumulate over the flood-source sites. Further observations from forthcoming missions may permit the determination of which mechanisms may have operated to recycle the Chryse flood-waters.

Moore, Jeffrey M.↗

NASA NTRS1995

The Circum-Chryse Region as a Possible Example of a Hydrologic Cycle on Mars: Geologic Observations and Theoretical Evaluation

The transection and superposition relationships among channels, chaos, surface materials units, and other features in the circum-Chryse region of Mars were used to evaluate relative age relationships and evolution of flood events. Channels and chaos in contact (with one another) were treated as single discrete flood-carved systems. Some outflow channel systems form networks and are inferred to have been created by multiple flood events. Within some outflow channel networks, several separate individual channel systems can be traced to a specific chaos which acted as flood-source area to that specific flood channel. Individual flood-carved systems were related to widespread materials units or other surface features that served as stratigraphic horizons. Chryse outflow channels are inferred to have formed over most of the perceivable history of Mars. Outflow channels are inferred to become younger with increasing proximity to the Chryse basin. In addition, outflow channels closer to the basin show a greater diversity in age. The relationship of subsequent outflow channel sources to the sources of earlier floods is inferred to disfavor episodic flooding due to the progressive tapping of a juvenile near-surface water supply. Instead, we propose the circum-Chryse region as a candidate site of past hydrological recycling. The discharge rates necessary to carve the circum-Chryse outflow channels would have inevitably formed temporary standing bodies of H2O on the Martian surface where the flood-waters stagnated and pooled (the Chryse basin is topographically enclosed). These observations and inferences have led us to formulate and evaluate two hypotheses: (1) large amounts of the sublimated H2O off the Chryse basin flood lakes precipitated (snowed) onto the flood-source highlands and this H2O was incorporated into the near surface, recharging the H2O sources, making possible subsequent deluges; and (2) ponded flood-water in Chryse basin drained back down an anti basinward dipping subsurface layer accessed along the southern edge of the lake, recharging the flood-source aquifers. H2O not redeposited in the flood-source region was largely lost to the hydrologic cycle. This loss progressively lowered the vitality of the cycle, probably by now killing it. Our numerical evaluations indicate that of the two hypotheses we formulated, the groundwater seep cycle seems by far the more viable. Optimally, approximately 3/4 of the original mass of an ice-covered cylindrical lake (albedo 0.5, 1 km deep, 100-km radius, draining along its rim for one quarter of its circumference into substrata with a permeability of 3000 darcies) can be modeled to have moved underground (on timescales of the order of 10(exp 3) years) before the competing mechanisms of sublimation and freeze down choked off further water removal. Once underground, this water can travel distances equal to the separation between Chryse basin and flood-source sites in geologically short (approximately 10(exp 6) year-scale) times. Conversely, we calculate that optimally only approximately 40% of the H2O carried from Chryse can condense at the highlands, and most of the precipitate would either collect at the base of the highlands/lowlands scrap or sublimate at rates greater than it would accumulate over the flood-source sites. Further observations from forthcoming missions may permit the determination of which mechanisms may have operated to recycle the Chryse flood-waters.

Moore, Jeffrey M.↗

NASA NTRS2017

Developing Reliable Life Support for Mars

A human mission to Mars will require highly reliable life support systems. Mars life support systems may recycle water and oxygen using systems similar to those on the International Space Station (ISS). However, achieving sufficient reliability is less difficult for ISS than it will be for Mars. If an ISS system has a serious failure, it is possible to provide spare parts, or directly supply water or oxygen, or if necessary bring the crew back to Earth. Life support for Mars must be designed, tested, and improved as needed to achieve high demonstrated reliability. A quantitative reliability goal should be established and used to guide development t. The designers should select reliable components and minimize interface and integration problems. In theory a system can achieve the component-limited reliability, but testing often reveal unexpected failures due to design mistakes or flawed components. Testing should extend long enough to detect any unexpected failure modes and to verify the expected reliability. Iterated redesign and retest may be required to achieve the reliability goal. If the reliability is less than required, it may be improved by providing spare components or redundant systems. The number of spares required to achieve a given reliability goal depends on the component failure rate. If the failure rate is under estimated, the number of spares will be insufficient and the system may fail. If the design is likely to have undiscovered design or component problems, it is advisable to use dissimilar redundancy, even though this multiplies the design and development cost. In the ideal case, a human tended closed system operational test should be conducted to gain confidence in operations, maintenance, and repair. The difficulty in achieving high reliability in unproven complex systems may require the use of simpler, more mature, intrinsically higher reliability systems. The limitations of budget, schedule, and technology may suggest accepting lower and less certain expected reliability. A plan to develop reliable life support is needed to achieve the best possible reliability.

life support↗

NASA NTRSDate not supplied

Radiocatalyst for Radiation Protection and Microbial Control

Radiocatalysts are materials that reduce the activation energy required to split water into hydrogen and reactive oxygen species (ROS). They are activated by radiation and can be used to improve the ability of water to act as a radiation barrier. This paper reports the results of an experimental evaluation of a gold radiocatalyst. This work provides a preliminary evaluation of the ability of these types of catalysts to increase the efficiency of water hydrolysis when exposed to different types of radiation (GCR). Although the radiation exposure devices used in this testing were not capable of generating radiation as diverse as is commonly found in space, the testing is useful in evaluating the function of these radiocatalytic nanoparticles when exposed to a a subset of the types of radiation that are found in GCR. The results are relevant to evaluating the use of this material for both space radiation protection and the production of useful byproducts, such as ROS, which can be used to maintain the sterility of stored water supplies. Radiocatalysts are materials typically used in radiation cancer therapy to improve the kill rate of tumors. These nanoparticles can be directly injected into tumors or functionalized to enter tumor cells via the blood stream. When they are exposed to radiation, they produce ROS. ROS are water hydrolysis products such as OH¯, O¯, O3, H2O2. This study used radiocatalytic 1.8 nm gold nanoparticles functionalized with citrate. These nanoparticles were tested through exposure to Xrays, 56Fe particles and gamma rays to demonstrate activity to a variety of radiation sources. The results demonstrate that radiocatalysts can improve the radiation absorption of water by a factor of 3 to 8 and can effectively kill bacteria at radiation levels above 1 Gy.

radiocatalyst radiation protection biocide↗

DOE OSTI2026

Case Study of Integrating High-Temperature Heat Pump with LiBr-H2O Absorption Chiller for Data Center Liquid Cooling

Data centers (DCs) are physical infrastructures that support artificial intelligence workloads. The rapid growth of artificial intelligence is putting substantial pressure on the US power grid. Most of electricity consumed by IT equipment, accounting for 50%-60% of total DC power, ultimately becomes waste heat. This heat is dissipated by DC’s cooling facilities, accounting for an additional 30%-40% of total DC power. Recovering and repurposing this waste heat offers a significant opportunity to enhance energy efficiency and reduce operating costs of DCs. One potential pathway is converting heat to cold using thermal-driven absorption chillers, therefore, reducing the power consumption in DC cooling facilities. Existing studies mainly demonstrate the technical and economic feasibility of repurposing DC’s waste heat for cooling applications but provide limited technical details on how to integrate the thermal-driven absorption chillers with DC cooling systems. In addition, the low-grade waste heat available from DCs must be upgraded to higher temperatures suitable for absorption chillers. This paper presents a case study on integrating high-temperature heat pumps with a LiBr-H2O absorption chiller to use DC waste heat for cooling. A thermodynamic model of single-effect, LiBr-H2O absorption chiller and an empirical model of high-temperature heat pumps were built. The case study considers ASHRAE W17 liquid-cooled DC, with facility service water supplied at 17.0℃ and returned at 25.3℃. The thermal behaviors of absorption chiller components were predicted for the generation temperature ranging from 75.0℃ to 115.0℃. Based on the available waste heat in the integrated system, two waste heat recovery strategies were evaluated: a facility service water-based strategy and cooling water-based strategy. Results indicated that the cooling water-based strategy achieves higher Coefficient of Performance (COPs) than the facility service water-based strategy. The relatively low cooling COPs of single-effect LiBr-H2O absorption chillers could be offset by high heating COP of high temperature heat pumps. The maximum cooling COP of absorption chiller and the overall COP of integrated systems occur at lower generation temperatures, but these conditions also yield lower cooling capacities. In practice, system operation should balance the trade-off between the COP and cooling capacity

Wang, Pengtao [ORNL] (ORCID:0000000214713429)↗

NASA NTRS1979

Preliminary results of passive microwave snow experiment during February and March 1978

The purpose of the experiment was to determine if remote microwave sensing of snowpack data could be used to predict runoff, thereby allowing more efficient management of the water supply. A four-frequency microwave radiometer system was attached to a truck-mounted aerial lift and was used to gather data on snowpacks at three different sites in the Colorado Rocky Mountains. Ground truth data measurements (density, temperature, grain size, hardness, and free-liquid water content) were taken at each site corresponding to each microwave scan.

Chang, A. T. C.↗

DOE OSTI2022

Causes of Missing Snowmelt Following Drought

Abstract Water management in snowy mountainous regions hinges on forecasting snowmelt runoff. However, droughts are altering snowpack‐runoff relationships with ongoing debate about the driving mechanisms. For example, in 2021 in California, less than half of predicted streamflow arrived. Mechanisms proposed for this “missing” streamflow included changes in evapotranspiration ( ET ), rainfall, and subsurface moisture conditions. Here, we demonstrate that ET in drought years generates dry subsurface conditions that reduce runoff in subsequent years. A model including this legacy of depleted moisture storage reduced median error in 2021 forecasts from 60% to 20% at 15 minimally disturbed basins and from 18% to 2% at 6 water supply basins in the Sierra Nevada (basins range in area from 5 to 23,051 km 2 and mean annual precipitation from 814 to 1,549 mm). Our findings indicate that the relationship between snowpack and runoff will evolve as plant ecosystems respond to climate change and alter subsurface water storage dynamics.

Lapides, Dana A.↗

DOE OSTI2024

New insights into the flow dynamics of a deep freshwater aquifer in the semi-arid and saline Cuvelai-Etosha Basin, Northern Namibia: Results of a multi-environmental tracer study

Study region A paleo-megafan system of the Cubango River in the northern parts of the semi-arid Cuvelai-Etosha Basin, shared by Angola and Namibia. It hosts a deep freshwater aquifer, the so-called Kalahari-Ohangwena 2 (KOH-2), with the potential to resolve the imminent regional water supply shortages. Study focus Hydrogeochemical and multi-environmental tracer studies incorporating the use of age tracers 14 C, 36 Cl, 81 Kr and 4 He to determine the age of groundwater and provide insights into the flow dynamics of the KOH-2. New hydrological insights for the region Stable water isotopes and noble gas thermometry show that in a period with higher rainfall and recharge, temperatures were at least 3 – 4 °C lower than today. Several arguments led to the conclusion that younger groundwater, possibly of an age of 35,000 years, is mixed with ancient saline pore water. These include: 1) the correlation of measured 36 Cl and 81 Kr ratios, as well as 4 He concentrations, using a binary mixing model, and 2) the substantial variation in 81 Kr ages, ranging from 40,000 to 170,000 years, over relatively short distances—a phenomenon challenging to explain by advective groundwater flow equations. Consequently, the ages derived from 81 Kr measurements serve as indicators of the extent of freshening and therefore describe mixing ages rather than absolute travel times.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1975

Development of an automated potable water bactericide monitoring unit

A monitor unit has been developed that permits the direct determination of the level of elemental iodine, used for microbiological control, in a spacecraft potable water supply system. Salient features of unit include low weight, volume and maintenance requirements, complete automatic operation, no inflight calibration, no expendables (except electrical current) and high accuracy and precision. This unit is capable of providing a signal to a controller that, in turn, automatically adjusts the addition rate of iodine to the potable water system so that a predetermined level of iodine can be maintained. In addition, the monitor provides a reading whereby the crewman can verify that the proper amount of iodine (within a range) is present in the water. A development history of the monitor is presented along with its design and theory of operation. Also presented are the results generated through testing of the unit in a simulated Shuttle potable water system.

Walsh, J. M.↗

DOE OSTI2024

statemodify: a Python framework to facilitate accessible exploratory modeling for discovering drought vulnerabilities

The Colorado River Basin (CRB) is experiencing an unprecedented water shortage crisis brought upon by a combination of factors arising from interactions across the region’s coupled human and natural systems. Allocation of water to the seven states that rely on the Colorado River was settled in the Colorado River Compact of 1922 during a period now known to be characterized by atypically high flows (Christensen et al., 2004). Since then, aridification due to anthropogenic-driven warming has steadily reduced the overall water supply available in the basin, with a 10% decrease in the river’s flow occurring over just the past two decades (Bass et al., 2023). The river is further strained by increasing demands associated with a growing population and diverse multi-sectoral demands. Navigating these challenges also requires accounting for the complex prior appropriation water rights system governing water allocation across the region’s diverse users.

54 ENVIRONMENTAL SCIENCES↗