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SAGE II Measurements of Stratospheric Aerosol Properties at Non-Volcanic Levels

Since 2000, stratospheric aerosol levels have been relatively stable and at the lowest levels observed in the historical record. Given the challenges of making satellite measurements of aerosol properties at these levels, we have performed a study of the sensitivity of the product to the major components of the processing algorithm used in the production of SAGE II aerosol extinction measurements and the retrieval process that produces the operational surface area density (SAD) product. We find that the aerosol extinction measurements, particularly at 1020 nm, remain robust and reliable at the observed aerosol levels. On the other hand, during background periods, the SAD operational product has an uncertainty of at least a factor of 2 during due to the lack of sensitivity to particles with radii less than 100 nm.

Thomason, Larry W.↗

Columnar Aerosol Single-Scattering Albedo and Phase Function Retrieved from Sky Radiance Over the Ocean: Measurements of African Dust

The single-scattering albedo and phase function of African mineral dust are retrieved from ground-based measurements of sky radiance collected in the Florida Keys. The retrieval algorithm employs the radiative transfer equation to solve by iteration for these two properties which best reproduce the observed sky radiance using an assumed aerosol vertical structure and measured aerosol optical depth. Thus, no assumptions regarding particle size, shape, or composition are required. The single-scattering albedo, presented at fourteen wavelengths between 380 and 870 nm, displays a spectral shape expected of iron-bearing minerals but is much higher than current dust models allow. This indicates the absorption of light by mineral dust is significantly overestimated in climate studies. Uncertainty in the retrieved albedo is less than 0.02 due to the small uncertainty in the solar-reflectance-based calibration (12.2%) method employed. The phase function retrieved at 860 nm is very robust under simulations of expected experimental errors, indicating retrieved phase functions at this wavelength may be confidently used to describe aerosol scattering characteristics. The phase function retrieved at 443 nm is very sensitive to expected experimental errors and should not be used to describe aerosol scattering. Radiative forcing by aerosol is the greatest source of uncertainty in current climate models. These results will help reduce uncertainty in the absorption of light by mineral dust. Assessment of the radiative impact of aerosol species is a key component to NASA's Earth System Enterprise.

Cattrall, Christopher↗

Extinction and Backscatter retrievals for High Spectral Resolution Lidar for high noise situations

High Spectral Resolution Lidars are uniquely valuable for characterizing atmospheric aerosol and clouds, both alone and in combination with passive instruments such as polarimeters. The benefits of HSRL are the ability to characterize the vertical variability of the atmosphere, to a greater degree than any passive instruments, and – compared to other lidar—additional channels of measurements that permit the direct retrieval of particulate extinction. HSRLs have been successfully deployed from both ground-based and airborne platforms, and will soon be included on satellites as well. From space, new challenges await, due to the need for fully au-tonomous cost-effective instrumentation and lower signal-to-noise ratios. Accordingly, algorithms for the retrieval of HSRL backscatter and extinction must also be reexamined and optimized for best performance in these more challenging circumstances. Motivated by the need for algorithms for the Clio lidar on the future Atmosphere Observing System polar platform, we explore and compare three methods of aerosol extinction retrieval for HSRL data: the direct differentiation method used in standard processing of LaRC airborne HSRL, optimal estimation, and Twomey-Tikhonov regularization. Pros and cons of each methodology will be dis-cussed and explored.

Sharon P. Burton↗

Satellite Optical Remote Sensing of Clouds and Aerosols: From Particle Single-Scattering and Gaseous Absorption Through Radiative Transfer to Retrieval Products

Clouds and aerosols are fundamental regulators of Earth’s radiation budget and climate system, influencing both solar and terrestrial radiation through scattering, absorption, and emission processes. Accurate characterization of their physical and radiative properties from space requires a rigorous understanding of particle single-scattering, gaseous absorption, and radiative transfer in the atmosphere, as well as reliable inversion methods. This review synthesizes the physical foundations and algorithmic implementations of satellite-based passive optical remote sensing of clouds and aerosols, spanning the ultraviolet to thermal infrared spectral range. Beginning with electromagnetic scattering theory and state-of-the-art methods for computing single-scattering by nonspherical particles and computationally efficient methods for accounting for atmospheric absorption, we discuss the radiative transfer framework underpinning cloud and aerosol retrievals. The connection between single-scattering and multiple-scattering is rigorously formulated. We then summarize operational and research-grade retrieval techniques, including cloud masking and thermodynamic phase determination, CO₂ slicing for cloud-top pressure, the Nakajima-King shortwave bi-spectral, and infrared split-window approaches for cloud optical thickness and effective particle size, inversion algorithms for determining aerosol properties from multi-spectral and/or multi-angle radiometric and polarimetric measurements, and active-passive sensing synergy. Examples of the global cloud and aerosol climatologies are illustrated using observations from the Moderate Resolution Imaging Spectroradiometer (MODIS) and the Multi-angle Imaging SpectroRadiometer (MISR). Furthermore, the unique strengths of active remote sensing techniques based on spaceborne lidar observations are briefly elaborated in the context of studying ice clouds composed of randomly and horizontally oriented ice crystals, which is a significant challenge for conventional passive remote sensing techniques. By connecting physical theory to practical retrievals, this review highlights both the maturity of current methodologies and the remaining challenges in reducing uncertainties in particle morphology, vertical structure, absorption, and aerosol-cloud interactions. Furthermore, the impact of artificial intelligence (AI) on atmospheric remote sensing is briefly addressed.

Aerosols↗

ACE Objectives, Current Status and the 2017 Decadal Survey

In this talk we present an overview of the Aerosol-Cloud-Ecosystems (ACE) preformulation studies, a tier-2 satellite mission recommended by the 2007 Decadal Survey. We discuss the current status of ACE measurement concepts and associated retrieval algorithms. We conclude with a brief discussion of the recommendations by the 2017 Decadal Survey and how ACE accomplishments can inform the future Aerosol and Cloud, Convection & Precipitation Designated Observables.

ACE↗

Evaluation of cloud height, optical thickness, and phase retrievals from the CHROMA algorithm applied to Sentinel-3 OLCI data

We previously developed the Cloud Height Retrieval from O 2 Molecular Absorption (CHROMA) algorithm for the Ocean Color Instrument (OCI) on the new NASA Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) mission. Here, we apply CHROMA to observations from the Ocean Land Colour Instrument (OLCI) to guide expectations for PACE, as it will take some time to obtain large-scale validation data for OCI. We use cloud top height (CTH), phase, and (for liquid clouds) cloud optical thickness (COT) data from the ground-based Atmospheric Radiation Measurement (ARM) network to evaluate the OLCI retrievals. We found that OLCI and Moderate Resolution Imaging Spectroradiometer (MODIS) CTH compare similarly well to the ARM reference. OLCI has a tendency to underestimate CTH as CTH increases, and algorithm assumptions about cloud geometric thickness may contribute to this. ARM COT from multifilter shadowband radiometers (MFRSR) and Sun photometers are well-correlated with one another, albeit with a roughly 30 % offset on average; OLCI and MODIS COT agree more closely with the MFRSR data. OLCI retrieval uncertainty estimates show skill at telling low-uncertainty cases from high-uncertainty ones, although CTH uncertainties are underestimated. Additionally, we compare the OLCI data to satellite retrievals based on thermal infrared measurements from MODIS and Sea and Land Surface Temperature Radiometer (SLSTR) data. Differences are broadly consistent with physical expectations based on the A-band vs. thermal techniques, although one key challenge in such aggregated comparisons is different cloud masking sensitivities and algorithm failure rates meaning additional sampling differences are introduced. We conclude by discussing the transition to and possible enhancements for PACE OCI.

Sayer, Andrew M. [Univ. of Maryland Baltimore Coun↗

Satellite aerosols retrieval over land surfaces using the structure functions

Remote sensing of aerosol optical thickness from space is difficult over continental surfaces. There are two retrieval algorithms, one based on the use of dark targets and a second based on contrast reduction between selected pixels. Improvements in the contrast reduction method are reported. A procedure is developed for using the satellite image to evaluate whether conditions for applying the structure method are met. The theoretical background is discussed, and the usefulness of the structure functions is demonstrated. The method is applied to NOAA Advanced Very High Resolution Radiometer (AVHRR) imagery where simultaneous ground measurements are used for validation.

Tanre, D.↗

Aerosol Observability and Predictability: From Research to Operations for Chemical Weather Forecasting. Lagrangian Displacement Ensembles for Aerosol Data Assimilation

A challenge common to many constituent data assimilation applications is the fact that one observes a much smaller fraction of the phase space that one wishes to estimate. For example, remotely sensed estimates of the column average concentrations are available, while one is faced with the problem of estimating 3D concentrations for initializing a prognostic model. This problem is exacerbated in the case of aerosols because the observable Aerosol Optical Depth (AOD) is not only a column integrated quantity, but it also sums over a large number of species (dust, sea-salt, carbonaceous and sulfate aerosols. An aerosol transport model when driven by high-resolution, state-of-the-art analysis of meteorological fields and realistic emissions can produce skillful forecasts even when no aerosol data is assimilated. The main task of aerosol data assimilation is to address the bias arising from inaccurate emissions, and Lagrangian misplacement of plumes induced by errors in the driving meteorological fields. As long as one decouples the meteorological and aerosol assimilation as we do here, the classic baroclinic growth of error is no longer the main order of business. We will describe an aerosol data assimilation scheme in which the analysis update step is conducted in observation space, using an adaptive maximum-likelihood scheme for estimating background errors in AOD space. This scheme includes e explicit sequential bias estimation as in Dee and da Silva. Unlikely existing aerosol data assimilation schemes we do not obtain analysis increments of the 3D concentrations by scaling the background profiles. Instead we explore the Lagrangian characteristics of the problem for generating local displacement ensembles. These high-resolution state-dependent ensembles are then used to parameterize the background errors and generate 3D aerosol increments. The algorithm has computational complexity running at a resolution of 1/4 degree, globally. We will present the result of assimilating AOD retrievals from MODIS (on both Aqua and TERRA satellites) from AERONET for validation. The impact on the GEOS-5 Aerosol Forecasting will be fully documented.

da Silva, Arlindo↗

Direct measurements of tropospheric ozone using TOMS data

Fishman and Larsen have proposed a new algorithm, called 'tropospheric residual method,' which retrieves the climatological tropospheric ozone by using SAGE (Stratospheric Aerosol and Gas Experiment) and TOMS (Total Ozone Mapping Spectrometer) data. In this paper, we will examine the feasibility of detection for tropospheric ozone using only TOMS data. From a case study over the Atlantic Ocean off the coast of west Africa, it has been found that total ozone in the archived TOMS data has been overestimated over a region of marine-stratocumulus clouds.

Hudson, Robert D.↗

Thermal Infrared Dust Optical Depth and Coarse-Mode Effective Diameter Over Oceans Retrieved From Collocated MODIS and CALIOP Observations

In this study, we developed a novel algorithm based on the collocated Moderate Resolution Imaging Spectroradiometer (MODIS) thermal infrared (TIR) observations and dust vertical profiles from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) to simultaneously retrieve dust aerosol optical depth at 10 µm (DAOD10μm) and the coarse-mode dust effective diameter (Deff) over global oceans. The accuracy of the Deff retrieval is assessed by comparing the dust lognormal volume particle size distribution (PSD) corresponding to retrieved Deff with the in-situ measured dust PSDs from the AER-D, SAMUM-2 and SALTRACE field campaigns through case studies. The new DAOD10μm retrievals were evaluated first through comparisons with the collocated DAOD10.6μm retrieved from the combined Imaging Infrared Radiometer (IIR) and CALIOP observations from our previous study (Zheng et al. 2022). The pixel-to-pixel comparison of the two DAOD retrievals indicates a good agreement (R~0.7) and a significant reduction of (~50%) retrieval uncertainties largely thanks to the better constraint on dust size. In a climatological comparison, the seasonal and regional (5°×2°) mean DAOD10um retrievals based on our combined MODIS and CALIOP method are in good agreement with the two independent Infrared Atmospheric Sounding Interferometer (IASI) products over three dust transport regions (i.e., North Atlantic (NA; R = 0.9), Indian Ocean (IO; R = 0.8) and North Pacific (NP; R = 0.7)). Using the new retrievals from 2013 to 2017, we performed a climatological analysis of coarse mode dust Deff over global oceans. We found that dust Deff over IO and NP are up to 20% smaller than that over NA. Over NA in summer, we found a ~50% reduction of the number of retrievals with Deff > 5 μm from 15°W to 35°W and a stable trend of Deff average at 4.4 μm from 35°W throughout the Caribbean Sea (90°W). Over NP in spring, only ~5% of retrieved pixels with Deff > 5 μm are found from 150°E to 180°, while the mean Deff remains stable at 4.0 μm throughout eastern NP. To our best knowledge, this study is the first to retrieve both DAOD and coarse-mode dust particle size over global oceans for multiple years. This retrieval dataset provides insightful information for evaluating dust long-wave radiative effects and coarse mode dust particle size in models.

dust optical depth↗

CALIGOLA: A New Multidisciplinary Spaceborne Lidar Mission (Cloud Aerosol Lidar for Global scale Observations of the ocean-Land-Atmosphere system)

Spaceborne lidars provide unique and valuable insight into the vertical structure of clouds and aerosols over the globe as well as insight into their microphysical and optical properties. Over the past two decades, lidar observations from CALIPSO, ICESAT-2 and CATS fundamentally advanced our understanding of the roles of clouds and aerosols play in weather, climate and air quality. The measurement records further served as important references for validating and improving retrieval algorithms of cloud/aerosol properties from operational weather satellites. A more recent development is the emerging awareness on how spaceborne lidar profile observations can also enhance knowledge of Earth’s coupled atmosphere-ocean-land system. Here we report on a new and powerful spaceborne lidar mission concept known as CALIGOLA (Cloud Aerosol Lidar for Global Scale Observations of the Ocean-Land Atmosphere System). The mission is multidisciplinary and will provide new insights into atmospheric processes with advance measurement capabilities beyond CALIPSO and the recently launched EarthCARE mission. CALIGOLA will further provide the first profiling of the world’s oceans to reveal unprecedented observations on the health and productivity of marine biology (phytoplankton and zooplankton) as well as provide unique observations of surface vegetation, ice, and snow. The mission will feature an innovative three-wavelength lidar, that will simultaneously acquire elastic backscatter, Raman, and fluorescence measurements, with polarization sensitivity on the elastic channels. The instrument is further designed with greater sensitivity than CALIOP and with vertical resolution on the order of a few meters near the surface. The mission is planned for launch early next decade and is baselined to fly in a polar orbit that is compatible with the previous A-Train constellation to extend the long-term measurement record. CALIGOLA is being developed through a partnership between Agenzia Spaziale Italiana (ASI) and National Aeronautics and Space Administration (NASA).

Lidar Aerosols Clouds Ocean Biology↗

Aerosol Optical Depth as Observed by the Mars Science Laboratory REMS UV Photodiodes

Systematic observations taken by the REMS UV photodiodes on a daily basis throughout the landed Mars Science Laboratory mission provide a highly useful tool for characterizing aerosols above Gale Crater. Radiative transfer modeling is used to model the approximately two Mars Years of observations taken to date taking into account multiple scattering from aerosols and the extended field of view of the REMS UV photodiodes. The retrievals show in detail the annual cycle of aerosol optical depth, which is punctuated with numerous short timescale events of increased optical depth. Dust deposition onto the photodiodes is accounted for by comparison with aerosol optical depth derived from direct imaging of the Sun by Mastcam. The effect of dust on the photodiodes is noticeable, but does not dominate the signal. Cleaning of dust from the photodiodes was observed in the season around Ls=270deg, but not during other seasons. Systematic deviations in the residuals from the retrieval fit are indicative of changes in aerosol effective particle size, with larger particles present during periods of increased optical depth. This seasonal dependence of aerosol particle size is expected as dust activity injects larger particles into the air, while larger aerosols settle out of the atmosphere more quickly leading to a smaller average particle size over time. A full description of these observations, the retrieval algorithm, and the results can be found in Smith et al. (2016).

Aerosol↗

Aerosol and Surface Parameter Retrievals for a Multi-Angle, Multiband Spectrometer

This software retrieves the surface and atmosphere parameters of multi-angle, multiband spectra. The synthetic spectra are generated by applying the modified Rahman-Pinty-Verstraete Bidirectional Reflectance Distribution Function (BRDF) model, and a single-scattering dominated atmosphere model to surface reflectance data from Multiangle Imaging SpectroRadiometer (MISR). The aerosol physical model uses a single scattering approximation using Rayleigh scattering molecules, and Henyey-Greenstein aerosols. The surface and atmosphere parameters of the models are retrieved using the Lavenberg-Marquardt algorithm. The software can retrieve the surface and atmosphere parameters with two different scales. The surface parameters are retrieved pixel-by-pixel while the atmosphere parameters are retrieved for a group of pixels where the same atmosphere model parameters are applied. This two-scale approach allows one to select the natural scale of the atmosphere properties relative to surface properties. The software also takes advantage of an intelligent initial condition given by the solution of the neighbor pixels.

Broderick, Daniel↗

A Seasonal Trend of Single Scattering Albedo in Southern African Biomass-burning Particles: Implications for Satellite Products and Estimates of Emissions for the World's Largest Biomass-burning Source

As a representative site of the southern African biomass-burning region, sun-sky data from the 15 year Aerosol Robotic Network (AERONET) deployment at Mongu, Zambia, was analyzed. For the biomass-burning season months (July-November), we investigate seasonal trends in aerosol single scattering albedo (SSA), aerosol size distributions, and refractive indices from almucantar sky scan retrievals. The monthly mean single scattering albedo at 440 nm in Mongu was found to increase significantly from approx.. 0.84 in July to approx. 0.93 in November (from 0.78 to 0.90 at 675 nm in these same months). There was no significant change in particle size, in either the dominant accumulation or secondary coarse modes during these months, nor any significant trend in the Angstrom exponent (440-870 nm; r(exp 2) = 0.02). A significant downward seasonal trend in imaginary refractive index (r(exp 2) = 0.43) suggests a trend of decreasing black carbon content in the aerosol composition as the burning season progresses. Similarly, burning season SSA retrievals for the Etosha Pan, Namibia AERONET site also show very similar increasing single scattering albedo values and decreasing imaginary refractive index as the season progresses. Furthermore, retrievals of SSA at 388 nm from the Ozone Monitoring Instrument satellite sensor show similar seasonal trends as observed by AERONET and suggest that this seasonal shift is widespread throughout much of southern Africa. A seasonal shift in the satellite retrieval bias of aerosol optical depth from the Moderate Resolution Imaging Spectroradiometer collection 5 dark target algorithm is consistent with this seasonal SSA trend since the algorithm assumes a constant value of SSA. Multi-angle Imaging Spectroradiometer, however, appears less sensitive to the absorption-induced bias.

aerosol absorption↗

Multi-Band Atmospheric Correction Algorithm for Ocean Color Retrievals

NASA's current Atmospheric Correction (AC) algorithm for ocean color utilizes two bands and their ratio in the Near Infrared (NIR) to estimate aerosol reflectance and aerosol type. The algorithm then extrapolates the spectral dependence of aerosol reflectance to the visible wavelengths based on modeled spectral dependence of the identified aerosol type. Future advanced ocean color sensors, such as the Ocean Color Instrument (OCI) that will be carried on the Plankton, Aerosol, Cloud, and ocean Ecosystem (PACE) satellite, will be capable of measuring the hyperspectral radiance from 340 to 890 nm at 5-nm spectral resolution and at 7 discrete Short-wave Infrared (SWIR) channels: 940, 1038,1250, 1378, 1615, 2130, and 2260 nm. To optimally employ this unprecedented instrument capability, we propose an improved AC algorithm that utilizes all atmospheric-window channels in the NIR to SWIR spectral range to reduce the uncertainty in the AC process. A theoretical uncertainty analysis of this, namely Multi-Band AC (MBAC), indicates that the algorithm can reduce the uncertainty in remote sensing reflectance (Rrs) retrievals of the ocean caused by sensor random noise. Furthermore, in optically complex waters, where the NIR signal is affected by contributions from highly-reflective turbid waters, the MBAC algorithm can be adaptively weighted to the strongly-absorbing SWIR channels to enable improved ocean color retrievals in coastal waters. We provide here a description of the algorithm and demonstrate the improved performance in ocean color retrievals, relative to the current NASA standard AC algorithm, through comparison with field measurements and assessment of propagated uncertainties in applying the MBAC algorithm to MODIS and simulated PACE OCI data.

PACE↗

Spaceborne Remote Sensing of Aerosol Type: Global Distribution, Model Evaluation and Translation into Chemical Speciation

It is essential to evaluate and refine aerosol classification methods applied to passive satellite remote sensing. We have developed an aerosol classification algorithm (called Specified Clustering and Mahalanobis Classification, SCMC) that assigns an aerosol type to multi-parameter retrievals by spaceborne, airborne or ground-based passive remote sensing instruments [1]. The aerosol types identified by our scheme are pure dust, polluted dust, urban-industrialdeveloped economy, urban-industrialdeveloping economy, dark biomass smoke, light biomass smoke and pure marine. We apply the SCMC method to inversions from the ground-based AErosol RObotic NETwork (AERONET [2]) and retrievals from the space-borne Polarization and Directionality of Earths Reflectances instrument (POLDER, [3]). The POLDER retrievals that we use differ from the standard POLDER retrievals [4] as they make full use of multi-angle, multispectral polarimetric data [5]. We analyze agreement in the aerosol types inferred from both AERONET and POLDER and evaluate GEOS-Chem [6] simulations over the globe. Finally, we use in-situ observations from the SEAC4RS airborne field experiment to bridge the gap between remote sensing-inferred qualitative SCMC aerosol types and their corresponding quantitative chemical speciation. We apply the SCMC method to airborne in-situ observations from the NASA Langley Aerosol Research Group Experiment (LARGE, [7]) and the Differential Aerosol Sizing and Hygroscopicity Spectrometer Probe (DASH-SP, [8]) instruments; we then relate each coarsely defined SCMC type to a sum of percentage of individual aerosol species, using in-situ observations from the Particle Analysis by Laser Mass Spectrometry (PALMS, [9]), the Soluble Acidic Gases and Aerosol (SAGA, [10]), and the High - Resolution Time - of - Flight Aerosol Mass Spectrometer (HR ToF AMS, [11]).

airborne↗

Evaluating the SAGE III/ISS Version 5.2 Water Vapor Retrieval in the Presence of Aerosol Loading

The Stratospheric Aerosol and Gas Experiment operating on the International Space Station (SAGE III/ISS) is an occultation instrument that retrieves aerosol extinction and ozone, water vapor, and other trace gas concentrations. Water vapor in the stratosphere plays a role in ozone depletion and global temperature regulation making it an important species to monitor. The SAGE III/ISS instrument provides high quality, vertically resolved profiles of water vapor throughout the stratosphere and upper troposphere. In previous versions of SAGE water vapor products, a dry bias was noted in comparison to other satellite retrievals in the presence of elevated aerosol optical depth. Several updates for the version 5.2 water vapor algorithm will be presented and compared with previous versions of the data and other satellite products during different periods of aerosol loading.

M Heitz↗

Coupled Retrieval of Aerosol Properties and Surface Reflection Using the Airborne Multi-Angle SpectroPolarimetric Imager (AirMSPI)

The Airborne Multi-angle SpectroPolarimetric Imager (AirMSPI) has been flying aboard the NASA ER-2 high altitude aircraft since October 2010. In step-and-stare operation mode, AirMSPI acquires radiance and polarization data at 355, 380, 445, 470*, 555, 660*, 865*, and 935 nm (* denotes polarimetric bands). The imaged area covers about 10 km by 10 km and is observed from 9 view angles between ±67° off of nadir. We have developed an efficient and flexible code that uses the information content of AirMSPI data for a coupled retrieval of aerosol properties and surface reflection. The retrieval was built based on the multi-pixel optimization concept, with the use of a hybrid radiative transfer model that combines the Markov Chain and adding/doubling methods. The convergence and robustness of our algorithm is ensured by applying constraints on (a) the spectral variation of the Bidirectional Polarization Distribution Function (BPDF) and angular shape of the Bidirectional Reflectance Distribution Function (BRDF); (b) the spectral variation of aerosol optical properties; and (c) the spatial variation of aerosol parameters across neighboring image pixels. Our retrieval approach has been tested using over 20 AirMSPI datasets having low to moderately high aerosol loadings (~0.02<AOD550-nm<~0.45) and acquired during several field campaigns. Results are compared with AERONET aerosol reference data. We also explore the benefits of AirMSPI’s ultraviolet and polarimetric bands as well as the use of multiple view angles.

Xu, Feng↗