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At least 289 records · Page 16

Some key issues in isotopic anomalies - Astrophysical history and aggregation

Astrophysical history, particularly that period extending from stellar nucleosynthesis events to the formation of meteorites, is discussed as the key element for the understanding of isotopic anomalies in meteorites. The bulk homogeneity of the interstellar medium is considered, and it is argued that, despite the presence of spatial inhomogeneities due to different nucleosynthesis rates in different parts of the galaxy and supernova ejecta, a cosmic chemical memory of nucleosynthesis patterns, rather than an inhomogeneous injection, is the source of isotopic anomalies. According to this view, volatility patterns and some isotopic patterns are mapped onto a grain-size spectrum, and the FUN systematics may be explained by interstellar sputtering. Furthermore, meteoritic He and Ne abundances are inferred to be presolar, and the ubiquitous titanium isotopic anomalies are explained by processes of chemical fixation and condensation in varying environments.

Clayton, D. D.↗

Singular perturbation, state aggregation and nonlinear filtering

Consideration is given to a state process evolving in R(n), whose motion is that of a pure jump process in R(n) in the 0(1) time scale, upon which is superimposed a continuous motion along the orbits of a gradient-like vector field g in R(n) in the 0(1/epsilon) time scale. The infinitesimal generator of the state process is, in other words, of the form L + (1/epsilon)g. It follows from the main results presented that the projected filters converge to the finite state Wonham filter corresponding to the problem of estimating the finite state process in the presence of additive white noise.

Hijab, O.↗

Aggregating available soil water holding capacity data for crop yield models

The total amount of water available to plants that is held against gravity in a soil is usually estimated as the amount present at -0.03 MPa average water potential minus the amount present at -1.5 MPa water potential. This value, designated available water-holding capacity (AWHC), is a very important soil characteristic that is strongly and positively correlated to the inherent productivity of soils. In various applications, including assessing soil moisture status over large areas, it is necessary to group soil types or series as to their productivity. Current methods to classify AWHC of soils consider only total capacity of soil profiles and thus may group together soils which differ greatly in AWHC as a function of depth in the profile. A general approach for evaluating quantitatively the multidimensional nature of AWHC in soils is described. Data for 902 soil profiles, representing 184 soil series, in Indiana were obtained from the Soil Characterization Laboratory at Purdue University. The AWHC for each of ten 150-mm layers in each soil was established, based on soil texture and parent material. A multivariate clustering procedure was used to classify each soil profile into one of 4, 8, or 12 classes based upon ten-dimensional AWHC values. The optimum number of classes depends on the range of AWHC in the population of oil profiles analyzed and on the sensitivity of a crop to differences in distribution of water within the soil profile.

Seubert, C. E.↗

Photon interaction cross sections for aggregations of finite-dimensional leaves

The Ross (1981) plate turbid-medium theory, which abstracts the leaf canopy as a gaseous mixture of oriented planar nondimensional plates that are randomly distributed in the configuration space, does not account for the 'hot spot' effect typical of all layered media with finite-dimensional scattering centers. The concept of 'particle distribution functions' is presently used to derive the interaction cross sections. This formalism is statistical-mechanical in nature, since the radiative transfer equation is essentially a linearized form of the Boltzmann equation for N-body systems.

Myneni, Ranga B.↗

Titan's aerosols. I - Laboratory investigations of shapes, size distributions, and aggregation of particles produced by UV photolysis of model Titan atmospheres

Experiments in which C2H2, C2H4, and HCN were photolyzed separately and as a mixture in UV light have been conducted in order to ascertain the physical properties of model Titan atmosphere aerosols. Aerosols formed from photolysis of C2H4 were physically similar to those formed from C2H2; protolysis of HCN rapidly generated particles that did not grow to sizes greater than 0.09 microns. While the formation of particles from C4H2 was observed within minutes, formation was slowed by a factor of 4 when C2H2 and HCN were added.

Scattergood, Thomas W.↗

Comet Halley as an aggregate of interstellar dust and further evidence for the photochemical formation of organics in the interstellar medium

Photolysis of mixtures of CO:NH3:H2O at 12 K results in the formation of an organic residue which is not volatile in high vacuum at room temperature. Analysis of this fraction by GC-MS resulted in the detection of C2-C3 hydroxy acids and hydroxy amides, glycerol, urea, glycine, hexamethylene tetramine, formamidine and ethanolamine. Use of isotopically labeled gases made it possible to establish that the observed products were not contaminants. The reaction pathways for the formation of these products were determined from the position of the isotopic labels in the mass spectral fragments. The significance of these findings to the composition of comets and the origins of life is discussed.

Briggs, R.↗

Analysis of Monomer Aggregation and Crystal Growth Rates of Lysozyme

This project was originally conceived to analyze the extensive data of tetragonal lysozyme crystal growth rates collected at NASA/MSFC by Dr. Marc L. Pusey's research group. At that time the lack of analysis of the growth rates was hindering progress in understanding the growth mechanism of tetragonal lysozyme and other protein crystals. After the project was initiated our initial analysis revealed unexpected complexities in the growth rate behavior. This resulted in an expansion in the scope of the project to include a comprehensive investigation of the growth mechanisms of tetragonal lysozyme crystals. A discussion of this research is included as well a list of presentations and publications resulting from the research. This project contributed significantly toward the education of several students and fostered extensive collaborations between investigators.

Nadarajah, Arunan↗

Documenting, Understanding, and Predicting the Aggregate Surface Radiation Fluxes for SHEBA

This document serves as a final report for NASA grant NAG5-4903 at Boston University. The report covers the first two years of the three-year project. The third year's funding and tasks have been transferred to the University of Wisconsin-Madison (UW) where the Principal Investigator (J. Key) is now stationed. The new UW grant number is NAG5-8625. Plans for the final project year at UW were detailed in the Request to Transfer document, submitted to NASA in July 1999. This is a group project with the University of Colorado (CU) as the lead institution, where Judith Curry is the Principal Investigator. The overall project is jointly funded by NASA and NSF. The progress reported herein is that specific to Boston University, but no attempt has been made to separate NASA and NSF activities.

Key, Jeffrey R.↗

The Magnetic Properties Of Aggregate Polycrystalline Diamond: Implications For Carbonado Petrogenesis

Carbonados are a type of diamond, which are made up of many aggregrates of small crystalline diamonds or microdiamonds. The term "carbonado" comes from the Portuguese word carbonated. They are only found in sedimentary deposits in the Central African Republic (CAR) and the Bahia Province of Brazil. They were once the source of the world's supply of industrial diamonds. Their origin is uncertain but several mutually exclusive hypotheses have been proposed. This theories are: (1) extraterrestrial, that is they formed from the dust cloud of original solar nebulae; (2) produced by the high temperatures and pressures of the Earth's mantle; (3) or as the result of an extra-terrestrial impact into a carbon rich layer of sediment. Our study was done to further the understanding of their origin. We measured the magnetic properties on some twenty samples from the CAR. An earlier study was done on whole samples of carbonados and the "common" or kimberlitic diamond. Our work differed in that we started at the surface and subsequently removed the surface layers (by days of acid immersion) into the interior; measuring the magnetic properties at each interval. This procedure permits us to monitor the distribution of magnetic substances within the samples. Our results showed that the magnetic carriers are distributed on the surface including the open pores and that the carbonado interior is essentially non-magnetic. This result suggests that the initial formation environment was deficient in magnetic particles. Such a situation could indicate that their formation was the result of an extra-terrestrial body impacting carbon-rich sediment. Obviously, more work will be required on isotopic and chemical analyses before a more detailed ori-in can be determined.

Kleteschka, Gunther↗

Serpentine by Hydrogenation of Fe-rich Ferromagnesiosilica PCs in Aggregate IDPs

Condensed hydrogen-bearing magnesiosilica smokes support that hydrogenation at H2/H2O ratios may lead to the formation of rare Fe-rich serpentine plus metallic iron in ferromagnesiosilica PCs with appropriate (Mg,Fe)/Si ratios that were acquired during their formation. Additional information is contained in the original extended abstract.

Rietmeijer, F. J. M.↗

Documenting, Understanding, and Predicting the Aggregate Surface Radiation Fluxes for SHEBA

This document serves as a final report for NASA grant NAG5-8625 to the University of Wisconsin-Madison (UW). The report covers work done at Boston University for the first two years of the project (as NAG5-4903) and the third and final year of the project at the University of Wisconsin (NAG5-8625). In 1999 the third year's funding and tasks were transferred to UW where the Principal Investigator (J. Key) is now stationed. A no-cost extension period of the grant ended on June 15, 2001. This is a group project with the University of Colorado (CU) as the lead institution, where Judith Curry is the Principal Investigator. The overall project is jointly funded by NASA and NSF. The progress reported herein is specific to Boston University and the University of Wisconsin.

Key, Jeffrey R.↗

Hydrophobic Surfaces of Spacecraft Components Enhance the Aggregation of Microorganisms and May Lead to Higher Survival Rates on Mars

In order to minimize the forward contamination of Mars, spacecraft are assembled under clean-room conditions that often require several procedures to clean and sterilize components. Surface characteristics of spacecraft materials may contribute to microbial survival by protecting spores from sterilizing agents, including UV irradiation on the surface of Mars. The primary objective of this study was to evaluate the effects of surface characteristics of several spacecraft materials on the survival of Bacillus subtilis spores under simulated Martian conditions.

A C Schuerger↗

Hydrophobic Surfaces of Spacecraft Components Enhance the Aggregation of Microorganisms and May Lead to Higher Survival Rates of Bacteria on Mars Landers

In order to minimize the forward contamination of Mars, spacecraft are assembled under cleanroom conditions that require several procedures to clean and sterilize components. Surface characteristics of spacecraft materials may contribute to microbial survival on the surface of Mars by protecting spores from sterilizing agents, including UV irradiation. The primary objective of this study was to evaluate the effects of surface characteristics of several spacecraft materials on the survival of Bacillus subtilis spores under simulated Martian conditions.

Schuerger, Andrew C.↗

The ability of lens alpha crystallin to protect against heat-induced aggregation is age-dependent

Alpha crystallin was prepared from newborn and aged bovine lenses. SDS-PAGE and tryptic peptide mapping demonstrated that both preparations contained only the alpha-A and alpha-B chains, with no significant contamination of other crystallins. Compared with alpha crystallin from the aged lens, alpha crystallin from the newborn lens was much more effective in the inhibition of beta L crystallin denaturation and precipitation induced in vitro by heat. Together, these results demonstrate that during the aging process, the alpha crystallins lose their ability to protect against protein denaturation, consistent with the hypothesis that the alpha crystallins play an important role in the maintenance of protein native structure in the intact lens.

NASA Discipline Cell Biology↗