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At least 289 records · Page 16

Toward Improved Land Surface Initialization in Support of Regional WRF Forecasts at the Kenya Meteorological Department

Flooding and drought are two key forecasting challenges for the Kenya Meteorological Department (KMD). Atmospheric processes leading to excessive precipitation and/or prolonged drought can be quite sensitive to the state of the land surface, which interacts with the boundary layer of the atmosphere providing a source of heat and moisture. The development and evolution of precipitation systems are affected by heat and moisture fluxes from the land surface within weakly-sheared environments, such as in the tropics and sub-tropics. These heat and moisture fluxes during the day can be strongly influenced by land cover, vegetation, and soil moisture content. Therefore, it is important to represent the land surface state as accurately as possible in numerical weather prediction models. Enhanced regional modeling capabilities have the potential to improve forecast guidance in support of daily operations and high-end events over east Africa. KMD currently runs a configuration of the Weather Research and Forecasting (WRF) model in real time to support its daily forecasting operations, invoking the Nonhydrostatic Mesoscale Model (NMM) dynamical core. They make use of the National Oceanic and Atmospheric Administration / National Weather Service Science and Training Resource Center's Environmental Modeling System (EMS) to manage and produce the WRF-NMM model runs on a 7-km regional grid over eastern Africa. Two organizations at the National Aeronautics and Space Administration Marshall Space Flight Center in Huntsville, AL, SERVIR and the Short-term Prediction Research and Transition (SPoRT) Center, have established a working partnership with KMD for enhancing its regional modeling capabilities. To accomplish this goal, SPoRT and SERVIR will provide experimental land surface initialization datasets and model verification capabilities to KMD. To produce a land-surface initialization more consistent with the resolution of the KMD-WRF runs, the NASA Land Information System (LIS) will be run at a comparable resolution to provide real-time, daily soil initialization data in place of interpolated Global Forecast System soil moisture and temperature data. Additionally, real-time green vegetation fraction data from the Visible Infrared Imaging Radiometer Suite will be incorporated into the KMD-WRF runs, once it becomes publicly available from the National Environmental Satellite Data and Information Service. Finally, model verification capabilities will be transitioned to KMD using the Model Evaluation Tools (MET) package, in order to quantify possible improvements in simulated temperature, moisture and precipitation resulting from the experimental land surface initialization. The transition of these MET tools will enable KMD to monitor model forecast accuracy in near real time. This presentation will highlight preliminary verification results of WRF runs over east Africa using the LIS land surface initialization.

Case. Jonathan↗

Brown Dwarf Variability: What's Varying and Why?

Surveys by ground based telescopes, HST, and Spitzer have revealed that brown dwarfs of most spectral classes exhibit variability. The spectral and temporal signatures of the variability are complex and apparently defy simplistic classification which complicates efforts to model the changes. Important questions include understanding if clearings are forming in an otherwise uniform cloud deck or if thermal perturbations, perhaps associated with breaking gravity waves, are responsible. If clouds are responsible how long does it take for the atmospheric thermal profile to relax from a hot cloudy to a cooler cloudless state? If thermal perturbations are responsible then what atmospheric layers are varying? How do the observed variability timescales compare to atmospheric radiative, chemical, and dynamical timescales? I will address such questions by presenting modeling results for time-varying partly cloudy atmospheres and explore the importance of various atmospheric processes over the relevant timescales for brown dwarfs of a range of effective temperatures. Regardless of the origin of the observed variability, the complexity seen in the atmospheres of the field dwarfs hints at the variability that we may encounter in the next few years in directly imaged young Jupiters. Thus understanding the nature of variability in the field dwarfs, including sensitivity to gravity and metallicity, is of particular importance for exoplanet characterization.

brown dwarfs↗

Wind Profiling With the Airborne Doppler Aerosol Wind Lidar During the 2022 Convective Processes Experiment

The 2017 Decadal Survey for Earth Science and Applications from Space (ESAS 2017) identifies a critical need for improving our understanding of Planetary Boundary Layer (PBL) processes and air-surface fluxes as well as why clouds, convection, and heavy precipitation occur when and where they do. Lidars are uniquely capable of collecting high precision and high spatio-temporal observations that have been used for atmospheric process studies from the ground, aircraft, and space. The wind lidar team at the NASA Langley Research Center (LaRC) started the development of Doppler wind lidar more than a decade ago to demonstrate technologies required for an Earth-orbiting system to globally measure wind profiles. Since then, an airborne Doppler Aerosol WiNd (DAWN) lidar system has been developed and participated in a series of field campaigns. The Doppler Aerosol WiNd (DAWN) lidar uses atmospheric aerosol motion to derive vertical profiles of horizontal wind speed and direction beneath the aircraft. In September 2022, DAWN, along with a suite of other instruments, was flown on a NASA DC-8 as part of The Convective Processes EXperiment – Cabo Verde (CPEX-CV) field campaign. A main objective of CPEX was to obtain a comprehensive set of temperature, humidity and, particularly, wind observations over tropical waters in undisturbed conditions, Saharan dust outbreaks, and in the vicinity of scattered through organized deep convection in all phases of the convective life cycle. DAWN collected data for approximately 90 hours across 13 CPEX-CV science flights. Airborne Vertical Atmospheric Profiling System (AVAPS) dropsondes were dropped throughout the flight for profiling the atmosphere and validating the DAWN instrument. DAWN had co-located data with 347 AVAPS NRD41 dropsondes, providing 32,117 vertical levels for a comprehensive validation of DAWN wind retrievals. DAWN showed very good agreement with dropsondes of ~0.2 m/s bias and ~1.8 m/s RMS. Given this agreement, DAWN is considered to be a worthy reference dataset, and its retrievals have been compared to winds derived from GOES Atmospheric Motion Vectors (AMVs), Advanced Scatterometer winds (ASCAT), and model data from GFS, GEOS, and MERRA-2 to better understand the quality of our current models and satellite wind observations. The proposed presentation will provide a brief description of the DAWN instrument, discuss the synergistic observations collected across a wide range of atmospheric conditions sampled during the CPEX-CV flights, and a summary of comparisons between DAWN, GOES AMV, ASCAT, and model analyses/predictions, with an emphasis on the PBL.

DAWN↗

Possible role of oceanic heat transport in early Eocene climate

Increased oceanic heat transport has often been cited as a means of maintaining warm high-latitude surface temperatures in many intervals of the geologic past, including the early Eocene. Although the excess amount of oceanic heat transport required by warm high latitude sea surface temperatures can be calculated empirically, determining how additional oceanic heat transport would take place has yet to be accomplished. That the mechanisms of enhanced poleward oceanic heat transport remain undefined in paleoclimate reconstructions is an important point that is often overlooked. Using early Eocene climate as an example, we consider various ways to produce enhanced poleward heat transport and latitudinal energy redistribution of the sign and magnitude required by interpreted early Eocene conditions. Our interpolation of early Eocene paleotemperature data indicate that an approximately 30% increase in poleward heat transport would be required to maintain Eocene high-latitude temperatures. This increased heat transport appears difficult to accomplish by any means of ocean circulation if we use present ocean circulation characteristics to evaluate early Eocene rates. Either oceanic processes were very different from those of the present to produce the early Eocene climate conditions or oceanic heat transport was not the primary cause of that climate. We believe that atmospheric processes, with contributions from other factors, such as clouds, were the most likely primary cause of early Eocene climate.

NASA Discipline Number 52-30↗

PolarMERRA: A Polar-Focused Global Reanalysis Project for Scientific and Stakeholder Needs

The adequate modeling of physical processes in the Arctic and Antarctic is vital for developing prediction capabilities and for obtaining an understanding of rapidly evolving polar conditions, including their potential global impacts. These processes are often poorly represented in global models and reanalyses, owing to a legacy modeling focus on midlatitude processes, as well as a scarcity of observations needed for model development in polar regions. The polarMERRA initiative, a joint effort between NASA’s Cryospheric Sciences and Modeling and Prediction programs, seeks to improve the representation of cryospheric and polar atmospheric processes and to develop an open-source framework for a quantitively evaluation of polar-relevant variables against current and future satellite and in-situ observations, models, and reanalyses. Here, we evaluate the impacts of spatial resolution and modifications to sea ice, ice sheet, and atmospheric parameterizations on the representation of high latitude conditions by using a quantitative scorecard approach that leverages NASA’s extensive satellite record. Investigations are conducted using the NASA Goddard Earth Observing System model (GEOS) and its data assimilation system (GEOS DAS). Through a quantitative identification of process deficiencies, bias reductions in key surface variables, including temperature and precipitation over cryospheric surfaces, may be achieved. The polarMERRA project additionally seeks to identify additional data sources for use in the GEOS DAS, and to incorporate data and parameterization improvements into future model and reanalysis products for scientific and stakeholder use.

Lauren C Andrews↗

Model Hierarchies for Understanding Atmospheric Circulation

In this review, we highlight the complementary relationship between simple and comprehensive models in addressing key scientific questions to describe Earth's atmospheric circulation. The systematic representation of models in steps, or hierarchies, connects our understanding from idealized systems to comprehensive models and ultimately the observed atmosphere. First, we define three interconnected principles that can be used to characterize the model hierarchies of the atmosphere. We explore the rich diversity within the governing equations in the dynamical hierarchy, the ability to isolate and understand atmospheric processes in the process hierarchy, and the importance of the physical domain and resolution in the hierarchy of scale. We center our discussion on the large-scale circulation of the atmosphere and its interaction with clouds and convection, focusing on areas where simple models have had a significant impact. Our confidence in climate model projections of the future is based on our efforts to ground the climate predictions in fundamental physical understanding. This understanding is, in part, possible due to the hierarchies of idealized models that afford the simplicity required for understanding complex systems.

58 GEOSCIENCES↗

Climate and Environmental Sciences Division, North Slope of Alaska Priorities Workshop, September 10–12, 2014

The U.S. Department of Energy (DOE) Climate and Environmental Sciences Division (CESD) within the Office of Biological and Environmental Research (BER), is hosting a series of workshops to solicit community feedback on how key scientific needs, gaps, and priorities in process model understanding and climate model prediction could be addressed through strategic deployment and operation of instruments and routine high resolution modeling. In particular, the use of the Atmospheric Radiation Measurement (ARM) Climate Research Facility—a DOE Office of Science user facility— is being reconfigured to better support the integration of observations and high-resolution modeling and to address these types of emerging science questions. As part of ARM’s reconfiguration, instruments are being concentrated to produce denser observational capabilities at fewer sites. In September 2014, the North Slope of Alaska (NSA) Priorities Workshop was held to obtain scientific input on priorities for observational and scientific research activities related to atmospheric processes in the North Slope region and to identify gaps or needs that limit the ability of the research community to address these scientific priorities. Topics of discussion included capabilities at the existing ARM NSA facilities in Barrow and Oliktok Point, additional observations that may supplement and/or link these facilities (e.g., aircraft, unmanned aerial systems, tethered balloons, scanning radar systems, surface stations), and modeling activities.

54 ENVIRONMENTAL SCIENCES↗

An imaging spectrometric observatory for Spacelab

The large payload capacity of the Space Shuttle Orbiter offers the first opportunity to launch into space an instrument able to simultaneously measure the entire spectrum of atmospheric emission, from the extreme UV to the near-IR, with high spectral resolution and high sensitivity while obtaining global and altitude coverage. This capability would provide a database for atmospheric process studies. The Spacelab Imaging Spectrometric Observatory (ISO) comprises an array of five spectrometers designed to make full use of the Space Shuttle as an observing platform for atmosphere remote sensing, and covers the 300-12,000-A wavelength range with a 2-7 A resolution. Area array detectors can scan the entire wavelength range in less than 20 sec and, being two-dimensional, permit spectral imaging in one direction and spatial imaging on the other.

Torr, M. R.↗

CROCUS High-Frequency Measurements of CO₂, H₂O, Wind, and Temperature at University of Illinois Chicago

As of April 9, 2026: this dataset is currently being versioned to include data up to March 31, 2026. Once the versioning process is complete, new data files will be available for access. The dataset metadata will also be updated to reflect the data availability of the new data being versioned. Raw atmospheric measurements collected at the University of Illinois Chicago (UIC) as part of the Community Research on Climate and Urban Science (CROCUS) project. The data includes high-frequency measurements of carbon dioxide (CO₂) concentration, water vapor (H₂O) concentration, wind speed (U, V, W components), temperature, and atmospheric pressure. These raw data are recorded by the LI-7500DS Open Path CO₂/H₂O Analyzer and a sonic anemometer at a 10 Hz acquisition frequency, providing the necessary inputs for calculating fluxes of CO₂, H₂O, heat, and momentum. In addition to gas concentration measurements, the dataset includes diagnostic information from the instruments, including absorptance, sample and reference signals, and diagnostic values. The data were collected to study urban atmospheric conditions and contribute to flux calculations for urban climate research. These measurements form the basis for calculating 30-minute average fluxes of key atmospheric variables using the eddy covariance method. This dataset provides critical raw input data for researchers interested in atmospheric fluxes, urban air quality, and the interaction between the urban environment and atmospheric processes. The data is part of the U.S. Department of Energy’s Biological and Environmental Research (BER) program, under the CROCUS Urban Integrated Field Laboratory (UIFL) project.

54 ENVIRONMENTAL SCIENCES↗

Toward Improved Land Surface Initialization in Support of Regional WRF Forecasts at the Kenya Meteorological Service (KMS)

Flooding and drought are two key forecasting challenges for the Kenya Meteorological Service (KMS). Atmospheric processes leading to excessive precipitation and/or prolonged drought can be quite sensitive to the state of the land surface, which interacts with the planetary boundary layer (PBL) of the atmosphere providing a source of heat and moisture. The development and evolution of precipitation systems are affected by heat and moisture fluxes from the land surface, particularly within weakly-sheared environments such as in the tropics and sub-tropics. These heat and moisture fluxes during the day can be strongly influenced by land cover, vegetation, and soil moisture content. Therefore, it is important to represent the land surface state as accurately as possible in land surface and numerical weather prediction (NWP) models. Enhanced regional modeling capabilities have the potential to improve forecast guidance in support of daily operations and high-impact weather over eastern Africa. KMS currently runs a configuration of the Weather Research and Forecasting (WRF) NWP model in real time to support its daily forecasting operations, making use of the NOAA/National Weather Service (NWS) Science and Training Resource Center's Environmental Modeling System (EMS) to manage and produce the KMS-WRF runs on a regional grid over eastern Africa. Two organizations at the NASA Marshall Space Flight Center in Huntsville, AL, SERVIR and the Shortterm Prediction Research and Transition (SPoRT) Center, have established a working partnership with KMS for enhancing its regional modeling capabilities through new datasets and tools. To accomplish this goal, SPoRT and SERVIR is providing enhanced, experimental land surface initialization datasets and model verification capabilities to KMS as part of this collaboration. To produce a land-surface initialization more consistent with the resolution of the KMS-WRF runs, the NASA Land Information System (LIS) is run at a comparable resolution to provide real-time, daily soil initialization data in place of data interpolated from the National Centers for Environmental Prediction (NCEP) Global Forecast System (GFS) model soil moisture and temperature fields. Additionally, realtime green vegetation fraction (GVF) data from the Visible Infrared Imaging Radiometer Suite (VIIRS) on the Suomi National Polar-orbiting Partnership (Suomi- NPP) satellite will be incorporated into the KMS-WRF runs, once it becomes publicly available from the National Environmental Satellite Data and Information Service (NESDIS). Finally, model verification capabilities will be transitioned to KMS using the Model Evaluation Tools (MET; Brown et al. 2009) package in conjunction with a dynamic scripting package developed by SPoRT (Zavodsky et al. 2014), to help quantify possible improvements in simulated temperature, moisture and precipitation resulting from the experimental land surface initialization. Furthermore, the transition of these MET tools will enable KMS to monitor model forecast accuracy in near real time. This paper presents preliminary efforts to improve land surface model initialization over eastern Africa in support of operations at KMS. The remainder of this extended abstract is organized as follows: The collaborating organizations involved in the project are described in Section 2; background information on LIS and the configuration for eastern Africa is presented in Section 3; the WRF configuration used in this modeling experiment is described in Section 4; sample experimental WRF output with and without LIS initialization data are given in Section 5; a summary is given in Section 6 followed by acknowledgements and references.

Case, Johnathan L.↗

Strong Dependence of Atmospheric Feedbacks on Mixed-Phase Microphysics and Aerosol-Cloud Interactions in HadGEM3

We analyze the atmospheric processes that explain the large changes in radiative feed-backs between the two latest climate configurations of the Hadley Centre Global Environmental model. We use a large set of atmosphere-only climate-change simulations (amip and amip-p4K) to separate the contributions to the differences in feedback parameter from all the atmospheric model developments between the two latest model configurations. We show that the differences are mostly driven by changes in the shortwave cloud radiative feedback in the midlatitudes, mainly over the Southern Ocean. Two new schemes explain most of the differences: the introduction of a new aerosol scheme; and the development of a new mixed-phase cloud scheme. Both schemes reduce the strength of the pre-existing shortwave negative cloud feedback in the midlatitudes. The new aerosol scheme dampens a strong aerosol-cloud interaction, and it also suppresses a negative clear-sky shortwave feedback. The mixed-phase scheme increases the amount of cloud liquid water path (LWP) in the present-day, thereby reducing the radiative effciency of the increase of LWP in the warmer climate. It also enhances a strong, pre-existing, positive cloud fraction feedback. We assess the realism of the changes by comparing present-day simulations against observations, and discuss avenues that could help constrain the relevant processes.

HadGEM3↗

An Overview of Snow Photochemistry: Evidence, Mechanisms and Impacts

It has been shown that sunlit snow and ice plays an important role in processing atmospheric species. Photochemical production of a variety of chemicals has recently been reported to occur in snow/ice and the release of these photochemically generated species may significantly impact the chemistry of the overlying atmosphere. Nitrogen oxide and oxidant precursor fluxes have been measured in a number of snow covered environments, where in some cases the emissions significantly impact the overlying boundary layer. For example, photochemical ozone production (such as that occurring in polluted mid-latitudes) of 3-4 ppbv/day has been observed at South Pole, due to high OH and NO levels present in a relatively small boundary layer. Field and laboratory experiments have determined that the origin of the observed NOx flux is the photochemistry of nitrate within the snowpack, however some details of the mechanism have not yet been elucidated. A variety of low molecular weight organic compounds have been shown to be emitted from sunlit snowpacks, the source of which has been proposed to be either direct or indirect photo-oxidation of natural organic materials present in the snow. Although myriad studies have observed active processing of species within irradiated snowpacks, the fundamental chemistry occurring remains poorly understood. Here we consider the nature of snow at a fundamental, physical level; photochemical processes within snow and the caveats needed for comparison to atmospheric photochemistry; our current understanding of nitrogen, oxidant, halogen and organic photochemistry within snow; the current limitations faced by the field and implications for the future.

Grannas, A. M.↗

Study of internal gravity waves in the meteor zone

An important component of the dynamical regime of the atmosphere at heights near 100 km are internal gravity waves (IGW) with periods from about 5 min to about 17.5 hrs which propagate from the lower atmospheric layers and are generated in the uppermost region of the atmosphere. As IGW propagate upwards, their amplitudes increase and they have a considerable effect on upper atmospheric processes: (1) they provide heat flux divergences comparable with solar heating; (2) they influence the gaseous composition and produce wave variations of the concentrations of gaseous components and emissions of the upper atmosphere; and (3) they cause considerable acceleration of the mean stream. It was concluded that the periods, wavelengths, amplitudes and velocities of IGW propagation in the meteor zone are now measured quite reliably. However, for estimating the influence of IGW on the thermal regime and the circulation of the upper atmosphere these parameters are not as important as the values of wave fluxes of energy, heat, moment and mass.

Gavrilov, N. M.↗

A Mineralogy–Based Anthropogenic Combustion–Iron Emission Inventory

Atmospheric supply of iron can modulate ocean biogeochemistry, due to its key role in global nitrogen and carbon cycles. Current estimates predict up to 20% of global ocean net primary productivity depends on an atmospheric iron source. Using a technology–based methodology, we revise total and soluble anthropogenic iron emissions and resolve iron into its mineral components, which allows modeling mineral–specific atmospheric reactions. We compare different methodologies for representing anthropogenic iron solubility: measured in mild and strong leaches and estimated using a mineralogy basis and identify the emissions that are most affected by such assumptions. The inclusion of metal smelting as an iron source increases iron emissions by up to 10 times higher in the fine aerosol fraction (smaller than 1 μm) than most previous inventories. Different solubility assumptions alter anthropogenic soluble iron emissions and deposition by a factor of 20 and 10, respectively. Using solubilities measured in mild leaches and calculated by mineralogy give 20–30 Gg/yr anthropogenic emissions and 40–50 Gg/yr deposition, while those measured in strong leaches give 80–440 Gg/yr emissions and 200–450 Gg/yr deposition. Here, this range of anthropogenic soluble iron deposition leads to global soluble iron deposition of 1,900–2,300 Gg/yr when dust, wildfires, and atmospheric processing are included, indicating such assumptions can affect global soluble iron supply by about 30%. In regions where marine primary productivity is iron limited, anthropogenic combustion–iron contributes up to half of the atmospheric soluble iron flux to the North Pacific Ocean but supplies less than 5% to the Southern Ocean.

54 ENVIRONMENTAL SCIENCES↗

High-Resolution Image Products Acquired from Mid-Sized Uncrewed Aerial Systems for Land–Atmosphere Studies

We assess the viability of deploying commercially available multispectral and thermal imagers designed for integration on small uncrewed aerial systems (sUASs, <25 kg) on a mid-size Group-3-classification UAS (weight: 25–600 kg, maximum altitude: 5486 m MSL, maximum speed: 128 m/s) for the purpose of collecting a higher spatial resolution dataset that can be used for evaluating the surface energy budget and effects of surface heterogeneity on atmospheric processes than those datasets traditionally collected by instrumentation deployed on satellites and eddy covariance towers. A MicaSense Altum multispectral imager was deployed on two very similar mid-sized UASs operated by the Atmospheric Radiation Measurement (ARM) Aviation Facility. This paper evaluates the effects of flight on imaging systems mounted on UASs flying at higher altitudes and faster speeds for extended durations. We assess optimal calibration methods, acquisition rates, and flight plans for maximizing land surface area measurements. We developed, in-house, an automated workflow to correct the raw image frames and produce final data products, which we assess against known spectral ground targets and independent sources. We intend this manuscript to be used as a reference for collecting similar datasets in the future and for the datasets described within this manuscript to be used as launching points for future research.

47 OTHER INSTRUMENTATION↗

AIRS - the Atmospheric Infrared Sounder

The Atmospheric Infrared Sounder (AIRS) was launched in 2002, along with two companion microwave sounders. This AIRS sounding suite is the most advanced atmospheric sounding system to date, with measurement accuracies far surpassing those of current weather satellites. From its sun synchronous polar orbit, the AIRS system provides more than 90% of the globe every 24 hours. Much of the post-launch period has been devoted to optimizing the 'retrieval' system used to derive atmospheric and other parameters from the observations and to validate those parameters. The geophysical parameters have been produced since the beginning of 2003 - the first data were released to the public in mid-2003, and future improved versions will be released periodically. The ongoing calibration/validation effort has confirmed that the system is very accurate and stable. There are a number of applications for the AIRS products, ranging from numerical weather prediction - where positive impact on forecast accuracy has already been demonstrated, to atmospheric research - where the AIRS water vapor products near the surface and in the mid and upper troposphere as well as in the stratosphere promise to make it possible to characterize and model phenomena that are key for short-term atmospheric processes, from weather patterns to long-term processes, such as interannual variability and climate change.

Aqua↗

Evaluating the strength of the land$-$atmosphere moisture feedback in Earth system models using satellite observations

The relationship between terrestrial water storage (TWS) and atmospheric processes has important implications for predictability of climatic extremes and projection of future climate change. In places where moisture availability limits evapotranspiration (ET), variability in TWS has the potential to influence surface energy fluxes and atmospheric conditions. Where atmospheric conditions, in turn, influence moisture availability, a full feedback loop exists. Here we developed a novel approach for measuring the strength of both components of this feedback loop, i.e., the forcing of the atmosphere by variability in TWS and the response of TWS to atmospheric variability, using satellite observations of TWS, precipitation, solar radiation, and vapor pressure deficit during 2002–2014. Our approach defines metrics to quantify the relationship between TWS anomalies and climate globally on a seasonal to interannual timescale. Metrics derived from the satellite data were used to evaluate the strength of the feedback loop in 38 members of the Community Earth System Model (CESM) Large Ensemble (LENS) and in six models that contributed simulations to phase 5 of the Coupled Model Intercomparison Project (CMIP5). We found that both forcing and response limbs of the feedback loop in LENS were stronger than in the satellite observations in tropical and temperate regions. Feedbacks in the selected CMIP5 models were not as strong as those found in LENS, but were still generally stronger than those estimated from the satellite measurements. Consistent with previous studies conducted across different spatial and temporal scales, our analysis suggests that models may overestimate the strength of the feedbacks between the land surface and the atmosphere. Lastly, we describe several possible mechanisms that may contribute to this bias, and discuss pathways through which models may overestimate ET or overestimate the sensitivity of ET to TWS.

54 ENVIRONMENTAL SCIENCES↗

Rapid Measurements of Aerosol Ionic Composition and 3-10 nm Particle Size Distributions On The NASA P3 To Better Quantify Processes Affecting Aerosols Advected From East Asia

The Particle Into Liquid Sample (PILS) was deployed on the NASA P3 for airborne measurements of fine particle ionic chemical composition. The data have been quality assured and reside in the NASA data archive. We have analyzed our data to characterize the sources and atmospheric processing of fine aerosol particles advected from the region during the experiments. Fine particle water-soluble potassium was found to serve as a useful aerosol tracer for biomass smoke. Ratios of PILS potassium to sulfate are used as a means of estimating the percent contribution of biomass burning to fine particle mass in mixed plumes advecting from Asia. The high correlations between K+ and NO3(sup -) and NH4(sup +)' indicated that biomass burning was a significant source of these aerosol compounds in the region. It is noteworthy that the air mass containing the highest concentrations of fine particles recorded in all of ACE-Asia and TRACE-P appeared to be advecting from the Bejing/Tientsin urban region and also had the highest K(+), NO3(sup -) and NH4(sup +) concentrations of both studies. Based on K+/SO4(sup 2-) ratio's, we estimated that the plume was composed of approx. 60% biomass burning emissions, possibly from the use of bio-fuels in the urban regions.

Weber, Rodney J.↗