Search NASA⌕ Search

SEARCH · Search NASA

Results for “atomization energies”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 289 records · Page 16

Atmosphere Explorer set for launch

The Atmosphere Explorer-D (Explorer-54) is described which will explore in detail an area of the earth's outer atmosphere where important energy transfer, atomic and molecular processes, and chemical reactions occur that are critical to the heat balance of the atmosphere. Data are presented on the mission facts, launch vehicle operations, AE-D/Delta flight events, spacecraft description, scientific instruments, tracking, and data acquisition.

Source record↗

The structure of ion plated films in relation to coating properties

Ion plating is an ion assisted or glow discharge deposition technique, where ions or energetic atoms transfer energy, momentum and charge to the substrate and the growing film in a manner which can be controlled to favorably modify surface, subsurface chemistry, and microstructure. The glow discharge energizing effects from the initial nucleation stages to the final film growth are discussed. As a result, adherence, coherence, internal stresses, density and morphology of the coatings are significantly improved, over the conventional (nonion-assisted) techniques which in turn favorably affect the surface initiated failures caused by friction, wear, erosion, corrosion and fatigue. Ion plated films because of their graded coating/substrate interface, fine, uniform, densely packed film structure also induce a surface strengthening effect which improved the mechanical properties such as yield, tensile strength and fatigue life. Since a uniform, continuous film can be obtained at lower nominal film thickness, this effect is of great importance in solid film lubrication and in corrosion protection.

Spalvins, T.↗

Ion-Plated Soft Metallic Films Reduce Friction and Wear

Ion plating is ion-assisted or glow-discharge surface-deposition technique. In this process, ions or energetic atoms transfer energy, momentum, and charge to substrate and deposited surface film. Process controlled to modify physical characteristics of surface, subsurface chemical conditions, and surface and subsurface microstructures as well. Ion plating with such soft, thin metallic films as gold, silver, or lead has great potential for producing self-contained lubricating surfaces. Such films reduce friction, wear, and corrosion on sliding or rotating mechanical surfaces used in wide range of environments.

Spalvins, T.↗

Inversion of chalcogen defect levels in silicon - An MNDO study

MNDO (modified neglect of diatomic overlap) calculations have been carried out for substitutional oxygen and sulfur impurities in silicon. The calculations of the gap levels reveal a reversal of trend with atomic ionization energies in agreement with self-consistent Green function results, and analysis of the MNDO charge distribution supports the view that the electronegativity difference between oxygen and sulfur gives rise to this shallower energy level.

Singh, R. K.↗

The dependence of solar modulation on the sign of the cosmic ray particle charge

ISEE-3 spacecraft cosmic ray telescope data on the modulation of cosmic ray electrons are compared with IMP-8 spacecraft data on low energy He atoms to evaluate the effects of solar maxima on cosmic ray modulation. The investigation is constrained to the modulation of 70-95 MeV He-4 nuclei and 600-1000 MeV electrons over the period 1965-1984, an interval covering solar maxima in 1970 and 1981. It is shown that the occurrences of solar maxima are associated with magnetic field polarity reversals. When the interplanetary magnetic field reverses polarity, oppositely charged particles flow in different directions, thereby permitting studies of drift effects and modulation. Data on the recovery periods after the solar maxima show that the He-4 nuclei recovered before the electron population in 1970, while the situation was reversed in 1981. Actual flux ratio reversals were recorded in the years surrounding the maxima. Although the data support a connection between modulation of cosmic rays and the sign of charged particles, current models cannot account for the deviation of electron intensities from the nuclei intensities.

Garcia-Munoz, M.↗

Martin Marietta atomic oxygen Low Earth Orbit (LEO) simulation

An atomic oxygen beam apparatus that produces flux levels and atomic kinetic energy similar to that encountered by spacecraft in low Earth orbit (LEO) is described. The beam apparatus consists of an electric discharge ion source, mass filter, decelerator, and neutralizer. Specific design goals include a 1.3 cm beam diameter, a 5 eV beam energy, and a flux density on the order of 10(15) cm(-2) s(-1). The total fluence will be on the order of 10(19) cm(-2) for an 8 hour test. The neutral oxygen beam will expose various materials contained within a large target chamber. Within the chamber will be a rather complex suite of instrumentation that will allow real-time studies of material mass loss and reactant species spatial distribution. In addition, a UV solar simulator will aid in the understanding of various synergistic effects.

Sjolander, Gary W.↗

Collisional excitation of an asymmetric rotor, silicon dicarbide

Rotational excitation rates have been computed for the asymmetric top molecule SiC2 in collisions with low-energy He atoms. The intermolecular forces were obtained from an electron gas model, and collision dynamics were treated within the infinite-order sudden approximation. Total excitation rates, i.e., summed over final levels, are expected to be accurate to about 50 percent, and the larger state-to-state rates are likely to be within a factor of about 2 of the correct values, although some of the smaller (and less important) rates may be less accurate. These rates are also thought to reflect, within this level of accuracy, rates for excitation by collisions with H2 molecules.

Palma, Amedeo↗

Collisional excitation of interstellar sulfur dioxide

State-to-state rotational excitation rates for the asymmetric top molecule SO2 in collisions with low-energy He atoms have been computed. The intermolecular forces were obtained from an electron gas model, and collision dynamics were treated with the finite-order sudden approximation. The total excitation rate is probably accurate to better than 50 percent; however, individual state-to-state rates may be in error by factors of 2 or 3, and some smaller rates may be accurate only to an order of magnitude. Present results are expected to reflect within the same level of accuracy rates for excitation by collisions with H2 molecules.

Palma, Amedeo↗

Particle radiation near the orbit of the Vacuum Wake Shield

The particle populations that are expected to inflict the most damage on thin film materials grown on the vacuum Wake Shield Facility (WSF) are ions and energetic neutral atoms with energies in the range of 100 eV to 20 keV. The production of films that have an order of magnitude fewer defects than are now available requires that the 1-keV particle flux be kept lower than 1000 particles/(sq cm s sr keV) (assuming a reasonable spectral shape). WSF will be flown on orbits with an inclination of 28 deg at altitudes of 300-700 km. Because of the background counting rate produced by the about 100 MeV trapped protons in the inner belt, obtaining accurate measurements of the particles of interest is very difficult. The quiet-time background fluxes of the relevant particles are not presently known. At times of magnetic activity, fluxes of 0.1-17 keV O(+) ions as great as 10 million ions/(sq cm s sr keV) have been observed flowing out of the ionosphere at these latitudes. It appears that instrumentation for detailed assessment is essential for the proof-of-concept flight(s) and that real-time monitoring of low-energy ion and energetic neutral radiation will be required for the production flights.

Bering, Edgar A., III↗

A photoionization instability in the early intergalactic medium

It is argued that any fairly uniform source of ionizing photons can be the cause of an instability in the pregalactic medium on scales larger than a photon path length. Underdense regions receive more ionizing energy per atom and reach higher temperature and entropy, driving the density down still further. Fluctuations created by this instability can lead to the formation of structures resembling protogalaxies and intergalactic clouds, obviating the need for gas clouds or density perturbations of earlier cosmological provenance, as is usually assumed in theories of galaxy and structure formation. Characteristic masses for clouds produced by the instability, with log mass in solar units plotted against log radius in kpc, are illustrated.

Hogan, Craig J.↗

Modeling of InP metalorganic chemical vapor deposition

The growth of InP by metalorganic chemical vapor deposition (MOCVD) in a horizontal reactor is being modeled with a commercially available computational fluid dynamics modeling code. The mathematical treatment of the MOCVD process has four primary areas of concern: 1) transport phenomena, 2) chemistry, 3) boundary conditions, and 4) numerical solution methods. The transport processes involved in CVD are described by conservation of total mass, momentum, energy, and atomic species. Momentum conservation is described by a generalized form of the Navier-Stokes equation for a Newtonian fluid and laminar flow. The effect of Soret diffusion on the transport of particular chemical species and on the predicted deposition rate is examined. Both gas-phase and surface chemical reactions are employed in the model. Boundary conditions are specified at the inlet and walls of the reactor for temperature, fluid flow and chemical species. The coupled set of equations described above is solved by a finite difference method over a nonuniform rectilinear grid in both two and three dimensions. The results of the 2-D computational model is presented for gravity levels of zero- and one-g. The predicted growth rates at one-g are compared to measured growth rates on fused silica substrates.

Black, Linda R.↗

Electronic characterization of defects in narrow gap semiconductors

The study of point defects in semiconductors has a long and honorable history. In particular, the detailed understanding of shallow defects in common semiconductors traces back to the classic work of Kohn and Luttinger. However, the study of defects in narrow gap semiconductors represents a much less clear story. Here, both shallow defects (caused by long range potentials) and deep defects (from short range potentials) are far from being completely understood. In this study, all results are calculational and our focus is on the chemical trend of deep levels in narrow gap semiconductors. We study substitutional (including antisite), interstitial and ideal vacancy defects. For substitutional and interstitial impurities, the efects of relaxation are included. For materials like Hg(1-x)Cd(x)Te, we study how the deep levels vary with x, of particular interest is what substitutional and interstitial atoms yield energy levels in the gap i.e. actually produce deep ionized levels. Also, since the main technique utilized is Green's functions, we include some summary of that method.

Patterson, James D.↗

Optical luminescence spectroscopy as a probe of the surface mineralogy of Mars

Optical luminescence (OpL) spectroscopy is an attractive use of a visible-near-IR spectrometer on a Mars lander because mineral products of atmosphere-surface interactions on Mars will probably have characteristic OpL spectra. Optical luminescence spectra would be taken at night, when a spectrometer might otherwise sit idle. Also needed would be a source of exciting radiation, which could be shared with other experiments. Optical luminescence is emission of nonthermal optical photons (near-UV through near-IR) as a response to energy input. On absorption of energy, an atom (or ion) will enter an excited state. The favored decay of many such excited states involving valence-band electrons is emission of an optical photon. Optical luminescence spectra can be useful in determining mineralogy and mineral composition. Optical luminescence in crystals can arise from essential elements (or ions), trace-element substituents (activators), or defects. Common activators in salts of alkali and alkaline earth elements include Mn(2+)(VI), other transition metals, the rare earths, and the actinides. Trace substituents of other species can enhance or quench OpL (e.g., Pb(2+) vs. Fe(3+)). Optical luminescence can also arise from defects in crystal structures, including those caused by radiation and shock.

Treiman, A. H.↗

The Far Ultraviolet (FUV) auroral imager for the Inner Magnetospheric Imager (IMI) mission: Options

The change from an intermediate mission (cost ceiling of $300 million) to a solar-terrestrial probe class mission (cost ceiling of $150 million) will require some major changes in the configuration of the IMI mission. One option being considered is to move to a small spin-stabilized spacecraft (with no despun platform) which could be launched with a smaller Taurus or Conestoga class booster. Such a change in spacecraft type would not present any fundamental problems (other than restrictions on mass and power) for the He plus 304 A plasmasphere imager, the high and low energy neutral atom imagers, and the geocoronal imager, but would present a challenge for the FUV auroral imager since the original plan called for this instrument to operate from a despun platform. Since the FUV instrument is part of the core payload it cannot be dropped from the instrument complement without jeopardizing the science goals of the mission. A way must be found to keep this instrument and to allow it to accomplish most, if not all, of its science objectives. One of the subjects discussed are options for building an FUV instrument for a spinning spacecraft. Since a number of spinning spacecraft have carried auroral imagers, a range of techniques exists. In addition, the option of flying the FUV imager on a separate micro-satellite launched with the main IMI spacecraft or with a separate pegasus launch, was considered and is discussed.

Wilson, Gordon R.↗

Middle- and low-latitude emissions from energetic neutral atom precipitation seen from ATLAS 1 under quiet magnetic conditions

During the ATLAS 1 mission spectral observations were made at middle and low latitudes of features expected from the precipitation of energetic neutral atoms. The Imaging Spectrometric Observatory was used at night in the UV and visible with maximum gain. The tangent ray heights of the look directions ranged from near 100 km to near 200 km, and the geomagnetic conditions were quiet during the observations, which were made March 28 to April 3, 1992. The N2(+) 1N 391.4-nm and O I 130.4 and 135.6-nm emissions were observed at all latitudes, with lower emission rates at lower magnetic dip latitudes, except that enhancements in the O I lines were seen within 30 deg of the dip equator to radiative recombination of ionospheric plasma. The latitude profile observed for the N2(+) 1N emission did not show an equatorial or midlatitude peak. This implies that the source of energetic neutrals is more consistent with prompt charge exchange loss of freshly injected trapped ions with relatively low mirror heights (i.e., ions on higher L shells with equatorial pitch angle distributions nearly isotropic to the loss cone) than loss of highly eroded populations of particles with high mirror heights (i.e., ions on lower L shells with pancake equatorial pitch angle distributions). The N2(+) 1N emission rates have been compared with models of atmospheric emission due to fluxes of O/O(+) and H/H(+) in the thermosphere, as produced by energetic neutral oxygen or hydrogen atom precipitation. Energy deposition rates are inferred.

Tinsley, B. A.↗

A Three-Year Program of Micro- and Nano-System Technology Development for X-Ray Astronomy

For many years the work at MIT aimed at the development of new concepts and technologies for space experiments in high-energy astrophysics, but not explicitly supported by flight programs, has been supported. This work has yielded new devices and techniques for X-ray astronomy, primarily low-noise, deep-depletion charge-coupled devices (CCDS) for spectrally-resolved X-ray imaging, and high-performance transmission gratings for high-resolution X-ray spectroscopy. Among the most significant recent achievements have been the development by G. Ricker and associates of the X-ray CCD camera flying on ASCA, and currently in development for AXAF and Astro-E, and the development by C. Canizares and associates of thick, 200 nm-period transmission gratings employing the phenomenon of phase shifting for high-resolution X-ray spectroscopy up to energies of 8- 1 0 keV that is essential for the operation of the AXAF High Energy Transmission Grating Spectrometer (HETGS). Through the current SR&T grant, the latter technology is now being extended successfully to the fabrication of 100 nm-period transmission gratings, which have twice the dispersion of the AXAF gratings. We note that, among other outcomes, the modest investments of past SR&T Grants at MIT resulted in the development of the key technologies for fully one-half of the scientific instrumentation on AXAF. In addition, NASA flight programs that have benefited from previous SR&T support at MIT include the SAS 3 X-ray Observatory, which carried the first rotation modulation collimator, the Focal Plane Crystal Spectrometer (FPCS) on the Einstein Observatory, the CCD cameras on ASCA and planned for Astro-E, the High Energy Transient Experiment (HETE), the Solar EUV Monitor on the Solar and Heliospheric Observatory (SOHO), the Medium Energy Neutral Atom imager (MENA) on the Image for Magnetopause-to-aurora Global Exploration (IMAGE) mission, and the recently-approved Two Wide-Angle Imaging Neutral-atom Spectrometers (TWINS) Mission of Opportunity.

Canizares, Claude R.↗

Using Model-Based Reasoning for Autonomous Instrument Operation

Multiprobe missions are an important part of NASA's future: Cluster, Magnetospheric Multi Scale, Global Electrodynamics and Magnetospheric Constellation are representatives from the Sun-Earth Connections Theme. To make such missions robust, reliable, and affordable, ideally the many spacecraft of a constellation must be at least as easy to operate as one spacecraft is today. To support this need for scalability, science instrumentation must become increasingly easy to operate, even as this same instrumentation becomes more capable and advanced. Communication and control resources will be at a premium for future instruments. Many missions will be out of contact with ground operators for extended periods either to reduce operations cost or because of orbits that limit communication to weekly perigee transits. Autonomous capability is necessary if such missions are to effectively achieve their operational objectives. An autonomous system is one that acts given its situation in a mission appropriate manner without external direction to achieve mission goals. To achieve this capability autonomy must be built into the system through judicious design or through a built-in intelligence that recognizes system state and manages system response. To recognize desired or undesired system states, the system must have an implicit or explicit understanding of its expected states given its history and self observations. The systems we are concerned with, science instruments, can have stringent requirements for system state knowledge in addition to requirements driven by health and safety concerns. Without accurate knowledge of the system state, the usefulness of the science instrument may be severely limited. At the same time, health and safety concerns often lead to overly conservative instrument operations further reducing the effectiveness of the instrument. These requirements, coupled with overall mission requirements including lack of communication opportunities and tolerance of environmental hazards, frame the problem of constructing autonomous science instruments. we are developing a model of the Low Energy Neutral Atom instrument (LENA) that is currently flying on board the Imager for Magnetosphere-to-Aurora Global Exploration (IMAGE) spacecraft. LENA is a particle detector that uses high voltage electrostatic optics and time-of-flight mass spectrometry to image neutral atom emissions from the denser regions of the Earth's magnetosphere. As with most spacecraft borne science instruments, phenomena in addition to neutral atoms are detected by LENA. Solar radiation and energetic particles from Earth's radiation belts are of particular concern because they may help generate currents that may compromise LENA's long term performance. An explicit model of the instrument response has been constructed and is currently in use on board IMAGE to dynamically adapt LENA to the presence or absence of energetic background radiations. The components of LENA are common in space science instrumentation, and lessons learned by modelling this system may be applied to other instruments. This work demonstrates that a model-based approach can be used to enhance science instrument effectiveness. Our future work involves the extension of these methods to cover more aspects of LENA operation and the generalization to other space science instrumentation.

Johnson, Mike↗

Using Model-Based Reasoning for Autonomous Instrument Operation - Lessons Learned From IMAGE/LENA

Model-based reasoning has been applied as an autonomous control strategy on the Low Energy Neutral Atom (LENA) instrument currently flying on board the Imager for Magnetosphere-to-Aurora Global Exploration (IMAGE) spacecraft. Explicit models of instrument subsystem responses have been constructed and are used to dynamically adapt the instrument to the spacecraft's environment. These functions are cast as part of a Virtual Principal Investigator (VPI) that autonomously monitors and controls the instrument. In the VPI's current implementation, LENA's command uplink volume has been decreased significantly from its previous volume; typically, no uplinks are required for operations. This work demonstrates that a model-based approach can be used to enhance science instrument effectiveness. The components of LENA are common in space science instrumentation, and lessons learned by modeling this system may be applied to other instruments. Future work involves the extension of these methods to cover more aspects of LENA operation and the generalization to other space science instrumentation.

Johnson, Michael A.↗