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The Origin of Carbon-bearing Volatiles in Surprise Valley Hot Springs in the Great Basin: Carbon Isotope and Water Chemistry Characterizations

There are numerous hydrothermal fields within the Great Basin of North America, some of which have been exploited for geothermal resources. With methane and other carbon-bearing compounds being observed, in some cases with high concentrations, however, their origins and formation conditions remain unknown. Thus, studying hydrothermal springs in this area provides us an opportunity to expand our knowledge of subsurface (bio)chemical processes that generate organic compounds in hydrothermal systems, and aid in future development and exploration of potential energy resources as well. While isotope measurement has long been used for recognition of their origins, there are several secondary processes that may generate variations in isotopic compositions: oxidation, re-equilibration of methane and other alkanes with CO2, mixing with compounds of other sources, etc. Therefore, in addition to isotopic analysis, other evidence, including water chemistry and rock compositions, are necessary to identify volatile compounds of different sources. Surprise Valley Hot Springs (SVHS, 41 deg 32'N, 120 deg 5'W), located in a typical basin and range province valley in northeastern California, is a terrestrial hydrothermal spring system of the Great Basin. Previous geophysical studies indicated the presence of clay-rich volcanic and sedimentary rocks of Tertiary age beneath the lava flows in late Tertiary and Quaternary. Water and gas samples were collected for a variety of chemical and isotope composition analyses, including in-situ pH, alkalinity, conductivity, oxidation reduction potential (ORP), major and trace elements, and C and H isotope measurements. Fluids issuing from SVHS can be classified as Na-(Cl)-SO4 type, with the major cation and anion being Na+ and SO4(2-), respectively. Thermodynamic calculation using ORP and major element data indicated that sulfate is the most dominant sulfur species, which is consistent with anion analysis results. Aquifer temperatures at depth estimated by both dissolved SiO2 and Na-K-Ca geothermometers are in the range of 125.0 to 135.4 C, and higher than the values measured at orifices (77.3 to 90.0 C). CO2 and homologs of straight chain alkanes (C1-C5) were identified in gas samples. Carbon isotope values of alkanes increase with carbon numbers. The C-13 fractionation between CO2 and dissolved inorganic carbon suggests they are out of carbon isotope equilibrium. The hypothesis regarding the formation of carbon-bearing compounds in SVHS may involve two processes: 1) Under high heat flow conditions which are caused by regional faulting and crustal extension, original high molecular weight organic compounds (kerogens) in clay-rich rocks decomposed to generate methane and other alkane homologs. 2) The SVHS area is associated with outflow structures, and distant from the heat source. Anaerobic oxidation of methane (AOM) with sulfate at shallow depth (< 90 C) is suggested as being responsible for the generation of CO2 in SVHS.

Fu, Qi↗

SelenITA: A Dual Point Lunar Mission to Characterize the Near Surface Dust and Electromagnetic Plasma Environment

SelenITA is a dual CubeSat mission that will provide the first multi-point dust, plasma, and magnetic field measurements in lunar orbit. This mission will advance the understanding of the electromagnetic space environment at the Moon in support of the Artemis program, exploration, and the geosciences. Here we present the science rationale motivating the mission. The candidate mission science objectives include: (1) constrain the origins of crustal magnetic fields; (2) determine the nature of plasma interactions with crustal magnetic fields; (3) characterize plasma waves and turbulence at the Moon; (4) characterize the lunar surface electric potential in varying plasma environments; (5) constrain the composition, thermal state, and structure of the lunar upper mantle and crust; (6) characterize the ionizing radiation in lunar orbit; and lastly, (7) determine the density of the dust exosphere as a function of latitude, longitude, and altitude, including the lunar polar space environment. The measurement requirements include simultaneous two-point observations of the 3-component vector magnetic field, plasma distribution (flux, energy, density, temperature), and single-point observations of energetic particles (protons, electrons, gamma rays), and dust. These measurements are important because it helps us understand how future astronauts, robots, and space hardware will live and work on the lunar surface.

space weather↗

SelenITA: A Dual Point Lunar Mission to Characterize the Near Surface Dust and Electromagnetic Plasma Environment

SelenITA is a dual CubeSat mission that will provide the first multi-point dust, plasma, and magnetic field measurements in lunar orbit. This mission will advance the understanding of the electromagnetic space environment at the Moon in support of the Artemis program, exploration, and the geosciences. Here we present the science rationale motivating the mission. The candidate mission science objectives include: (1) constrain the origins of crustal magnetic fields; (2) determine the nature of plasma interactions with crustal magnetic fields; (3) characterize plasma waves and turbulence at the Moon; (4) characterize the lunar surface electric potential in varying plasma environments; (5) constrain the composition, thermal state, and structure of the lunar upper mantle and crust; (6) characterize the ionizing radiation in lunar orbit; and lastly, (7) determine the density of the dust exosphere as a function of latitude, longitude, and altitude, including the lunar polar space environment. The measurement requirements include simultaneous two-point observations of the 3-component vector magnetic field, plasma distribution (flux, energy, density, temperature), and single-point observations of energetic particles (protons, electrons, gamma rays), and dust. These measurements are important because it helps us understand how future astronauts, robots, and space hardware will live and work on the lunar surface.

space weather↗

Fourier analysis of planimetric lunar crater shape - Possible guide to impact history and lunar geology

If the lithology of lunar crust influences impact crater morphology, a method of analysis that is sensitive to small-scale changes in crater shape is required. In the present paper, it is shown that Fourier analysis in closed form can provide detailed information regarding planimetric crater shape. Preliminary analysis of the rim crest outline of 247 nearside lunar craters (larger than 18 km in diam) led to the following information: Imbrian and pre-Imbrian craters are more elongate than younger craters, possibly as a result of widespread crustal deformation early in the moon's history. Crater size does not affect the planimetric shape of craters. Highland craters are less circular than mare craters, probably due to the greater structural and lithologic complexity of the highland crust. Craters comprising each shape family of the eleventh harmonic typically are located in the same general geographic region of the moon.

Eppler, D. T.↗

The magnetic field of the earth - Performance considerations for space-based observing systems

Basic problems inherent in carrying out observations of the earth magnetic field from space are reviewed. It is shown that while useful observations of the core and crustal fields are possible at the peak of the solar cycle, the greatest useful data volume is obtained during solar minimum. During the last three solar cycles, the proportion of data with a planetary disturbance index of less than 2 at solar maximum was in the range 0.4-0.8 in comparison with solar minimum. It is found that current state of the art orbit determination techniques should eliminate orbit error as a problem in gravitational field measurements from space. The spatial resolution obtained for crustal field anomalies during the major satellite observation programs of the last 30 years are compared in a table. The relationship between observing altitude and the spatial resolution of magnetic field structures is discussed. Reference is made to data obtained using the Magsat, the Polar Orbiting Geophysical Observatory (POGO), and instruments on board the Space Shuttle.

Webster, W. J., Jr.↗

Deep crustal deformation by sheath folding in the Adirondack Mountains, USA

As described by McLelland and Isachsen, the southern half of the Adirondacks are underlain by major isoclinal (F sub 1) and open-upright (F sub 2) folds whose axes are parallel, trend approximately E-W, and plunge gently about the horizontal. These large structures are themselves folded by open upright folds trending NNE (F sub 3). It is pointed out that elongation lineations in these rocks are parallel to X of the finite strain ellipsoid developed during progressive rotational strain. The parallelism between F sub 1 and F sub 2 fold axes and elongation lineations led to the hypothesis that progressive rotational strain, with a west-directed tectonic transport, rotated earlier F sub 1-folds into parallelism with the evolving elongation lineation. Rotation is accomplished by ductile, passive flow of F sub 1-axes into extremely arcuate, E-W hinges. In order to test these hypotheses a number of large folds were mapped in the eastern Adirondacks. Other evidence supporting the existence of sheath folds in the Adirondacks is the presence, on a map scale, of synforms whose limbs pass through the vertical and into antiforms. This type of outcrop pattern is best explained by intersecting a horizontal plane with the double curvature of sheath folds. It is proposed that sheath folding is a common response of hot, ductile rocks to rotational strain at deep crustal levels. The recognition of sheath folds in the Adirondacks reconciles the E-W orientation of fold axes with an E-W elongation lineation.

Mclelland, J. M.↗

A proposal to conduct a Caribbean plate project involving the application of space technology to the study of Caribbean geology

The Caribbean plate project is designed to improve current understanding of geological resources and geological hazards within the Caribbean region. Models of mineral occurrence and genesis (including energy resources) on a regional scale, which contribute to nonrenewable resource investigations. Models of lithospheric stress and strain on a regional scale, which contribute to forecasting geological hazards such as earthquakes and major volcanic eruptions are developed. Geological information is synthesize, and research tools provided by space technology the study of the Earth's crust are used. The project was organized in a thematic fashion, to focus on specific geological aspects of the Caribbean plate which are considered to be key factors in developing the types of models described. The project adopts a synoptic perspective in seeking to characterize the three dimensional structure, composition, state of stress, and evolution of the entire Caribbean plate. Geological information derived from analysis of space acquired data is combined with information provided by conventional methods to obtain insight into the structure, composition, and evolution of the Earth's crust. In addition, very long baseline interferometry and laser ranging techniques, which are also based upon the use of space technology, obtain information concerning crustal motion that, in turn, provides insight into the distribution and localization of crustal stress.

Wadge, G.↗

Correlations and contrasts in structural history and style between an Archaean greenstone belt and adjacent gneiss belt, NE Minnesota

An analysis of the deformation along the boundary between the Vermilion Granitic Complex (VGC) and the Vermilion district indicates that the two terranes have seen a similar deformation history since the earliest stages of folding in the area. Despite this common history, variations in structural style occur between the two terranes, such as the relative development of D sub 1 fabrics and D sub 2 shear zones, and these can be attributed to differences in the crustal levels of the two terranes during the deformation. Similarly, the local development of F sub 3 folds in the VGC, but not in the Vermilion district, is interpreted to be a result of later-D sub 2 pluton emplacement which was not significant at the level of exposure of ther Vermilion district.

Bauer, R. L.↗

Postseismic Rebound in Fault Step-Overs Caused by Pore Fluid Flow

Near-field strain induced by large crustal earthquakes results in changes in pore fluid pressure that dissipate with time and produce surface deformation. Synthetic Aperture Radar (SAR) interferometry revealed several centimeters of postseismic uplift in pull-apart structures and subsidence in a compressive jog along the Landers, California, 1992 earthquake surface rupture, with a relaxation time of 270 +/- 45 days. Such a postseismic rebound may be explained by the transition of the Poisson's ratio of the deformed volumes of rock from undrained to drained conditions as pore fluid flow allows pore pressure to return to hydrostatic equilibrium.

Peltzer, Gilles↗

Constraining the Mean Crustal Thickness on Mercury

The topography of Mercury is poorly known, with only limited radar and stereo coverage available. However, radar profiles reveal topographic contrasts of several kilometers over wavelengths of approximately 1000 km. The bulk of Mercury's geologic activity took place within the first 1 Ga of the planet's history), and it is therefore likely that these topographic features derive from this period. On Earth, long wavelength topographic features are supported either convectively, or through some combination of isostasy and flexure. Photographic images show no evidence for plume-like features, nor for plate tectonics; I therefore assume that neither convective support nor Pratt isostasy are operating. The composition and structure of the crust of Mercury are almost unknown. The reflectance spectrum of the surface of Mercury is similar to that of the lunar highlands, which are predominantly plagioclase. Anderson et al. used the observed center-of-mass center-of-figure offset together with an assumption of Airy isostasy to infer a crustal thickness of 100-300 km. Based on tidal despinning arguments, the early elastic thickness (T(sub e)) of the (unfractured) lithosphere was approximately equal to or less than 100 km. Thrust faults with lengths of up to 500 km and ages of about 4 Ga B.P. are known to exist on Mercury. Assuming a semicircular slip distribution and a typical thrust fault angle of 10 degrees, the likely vertical depth to the base of these faults is about 45 km. More sophisticated modelling gives similar or slightly smaller answers. The depth to the base of faulting and the elastic layer are usually similar on Earth, and both are thought to be thermally controlled. Assuming that the characteristic temperature is about 750 K, the observed fault depth implies that the heat flux at 4 Ga B.P. is unlikely to be less than 20 mW m(exp -2) for a linear temperature gradient. For an elastic thickness of 45 km, topography at 1000 km wavelength is likely to be about 60% compensated. There are thus likely to be considerable lateral variations in crustal thickness. Additional information is contained in the original extended abstract.

Nimmo, F.↗

Comparison of Os and Cr Isotopic Methods for the Detection of Meteoritic Components in Impact Melt Rocks from the Morokweng and Vredefort Impact Structures, South Africa

The verification of an extraterrestrial component in impact-derived melt rocks or breccias can be of diagnostic value to provide confirming evidence for an impact origin of a geological structure. Geochemical methods are used to determine the presence of the traces of such a component. In the absence of actual meteorite fragments, it is necessary to search for traces of meteoritic material that is mixed in with the target rocks in breccias and melt rocks. Meteoritic components have been identified for just over 40 impact structures (out of more than 160 known on Earth), which reflects also the detail in which these structures were studied. The identification of a meteoritic component can be achieved by determining the concentrations and interelement ratios of siderophile elements, especially the platinum group elements (PGE), which are several orders of magnitude more abundant in meteorites than in terrestrial upper crustal rocks. The usage of platinum group element abundances and ratios avoids some of the ambiguities that may result if only common siderophile elements (e.g., Cr, Co, Ni) are considered. However, problems may arise if the target rocks have high abundances of siderophile elements, or if the siderophile element concentrations in the impactites are very low. In such cases, the Os and Cr isotopic systems have recently been used for establishing the presence of a meteoritic component in a number of impact melt rocks and breccias. In the past it was attempted to use PGE data to determine the type or class of meteorite for the impactor, but these attempts were not always successful. It is difficult to decide between chondrite types based on PGE abundances, which has led to conflicting identifications for a number of impact structures. Clearly, the identification of a meteoritic component in impactites is not a trivial problem. In this study, we are using a combination of trace element (PGE) analyses and the results from both, Os and Cr isotopic studies, to illustrate the pros and cons of each method on two case studies, namely the Vredefort and Morokweng impact structures. Additional information is contained in the original extended abstract.

Koeberl, Christian↗

Support of long-wavelength loads on Venus and implications for internal structure

The development of a thin-shell formulation to compute stress in a planetary lithosphere is discussed. The formulation uses spherical harmonic representations of the gravity field and topography as boundary conditions to produce lateral density anomalies at two depths. The stress fields for displacement, crustal thickness anomaly, and mantle density anomaly, which are required for the boundary conditions, are calculated. The computed stresses are compared to the tectonic features of Venus. The data reveal that the highland areas are formed in a state of isostasy or uplift and are supported by dynamic processes in the mantle. Lithospheric models predict low-density mantle beneath Alta, Beta, Eisila, Thetis, and Thetus Regiones, and thick crust accompanied by higher-density mantle under Ishtar Terra and Ovda Regio.

Banerdt, W. B.↗

Structure, composition and thermal state of the crust in Brazil

Aeromagnetic survey data of the Minas Gerais areas were analyzed and compared with MAGSAT anomaly data. Initially the data set was used to determine the thickness of the magnetized crust. The value obtained is in agreement with crustal models derived from deep seismic sounding and gravity data, indicating that the bottom of the magnetized layer occurs close to the Moho transition. An analysis of the long wavelength pattern indicates that the anomalies form a series of lineations along the magnetic E-W. These are shown to be the result of attenuation. On the MAGSAT total intensity map localized anomalies are superimposed onto an anomaly background formed by alternating positive and negative patches. Implementation and testing of analysis software for MAGSAT data are also discussed.

Pacca, I. I. G.↗

Identification of geostructures of continental crust particularly as they relate to mineral resource evaluation

The author has identified the following significant results. New mineral deposits have recently been discovered in eastern Alaska through application of a hypothesis very similar to one developed in interpretation of Nimbus and ERTS-1 imagery in this investigation, that mineral deposits may be spatially related to a set of crustal linears. The discovery affirms the validity of this hypothesis and provides an additional exploration rationale to the mineral industry. A regional lineation in lakes near Umiat in northern Alaska, suspected to reflect structures in basement and suggesting areas of possible potential for new petroleum exploration, is found to cover a much larger area than previously suspected east of the Colville River, increasing the area of interest. Further application of this same imagery exists in that environmental scars to the tundra resulting from previous ground exploration, if of large size, can be recognized and their natural revegetation monitored by use of ERTS imagery. New geologic data obtained from ERTS-1 images of lowland areas of western northern Alaska facilitates assessing the petroleum potential of this area. Use of the images in field mapping permitted extrapolation of field observations. Mosaics of ERTS-1 images have provided additional data on regional linear sets and on other regional fault trends possibly related to mineralized areas.

Gryc, G.↗

Do large impact basins in the Southern Hemisphere of Mars control the distribution of polar structures and deposits?

Among the problems in Martian geology are the cause of the off-axis and asymmetric distribution of the southern polar layered terrain and residual ice deposits and the cause of the orientation of scarps, valleys, and reentrant canyons that occur. A problem region is the small number of large (D greater than 500) impact basins seen in the relatively well preserved cratered terrain of the south polar region. This region was mapped in detail, searching for evidence of ancient, highly degraded impact basins for two reasons: To determine whether the apparent absence of large impact basins is due to incomplete mapping and recognition or a fundamental characteristic of the Martian crust related to the origin of the Martian crustal dichotomy, and whether ancient impact basins exert some control on the distribution of volcanic and polar deposits in the Southern Hemisphere and on the topography on which these deposits lie. The possible influence is examined of the candidate basins in localizing the asymmetric distribution of polar deposits and in controlling the orientation of structures found within these deposits.

Frey, Herbert↗

On the relationship between isostatic elevation and the wavelengths of tectonic surface features on Venus

Venus lithospheric structure models are presently formulated in which regional isostatic elevation, d, and the spacing wavelength, lambda, of tectonic features formed due to horizontal extension and compression are functions of both surface thermal gradient and crustal thickness c. It is shown that, in areas of Venus where the upper mantle is stronger than the upper crust, the spacings of short-wavelength features should increase with increasing d, if that change in turn is due to increasing c, but should decrease with increasing d, if this change is in turn due to increasing surface thermal gradient.

Zuber, M. T.↗

The earth's geoid and the large-scale structure of mantle convection

It is shown that most of the earth's low-degree geoid power is derived from density heterogeneity in the lower mantle. Much of the remaining geoid power is due to high-density slabs in active subduction zones. The compensated topography and lithospheric or crustal thickness variations contribute significantly to the observed geoid only for harmonic degrees greater than or equal to 6.

Richards, Mark A.↗

Reconciliation of stress and structural histories of the Tharsis region of Mars

New information is presented on the structural and stratigraphic evolution of the Tharsis region of Mars, along with a lithospheric deformation model that can account for the observations. According to this model, the lithosphere beneath Tharsis consists of a thin elastic crustal cap on the rise, which is mechanically detached from the strong upper mantle by a volcanically thickened, hot, weak lower crust; these layers merge into a single cooler strong lithospheric layer around the edges of the rise. It is suggested that the nonuniform distribution of tectonic features and strain around Tharsis is due to the concentration of regional stresses near weaker volcanotectonic centers.

Tanaka, Kenneth L.↗