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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

Technical Program Plan for INL Advanced Reactor Technologies Advanced Gas Reactor Fuel Development and Qualification Program

High-temperature gas cooled reactors (HTGRs) are graphite moderated nuclear reactors cooled with helium. Their high outlet temperatures and thermal energy conversion efficiency enable efficient and cost effective integration with non electricity generating applications. These applications include process heat and hydrogen production for petrochemical and other industrial processes that require operating temperatures between 300 and 900°C. HTGRs will supplement the use of premium fossil fuels such as oil and natural gas, improve overall energy security in the United States by reducing dependence on foreign fuels, and reduce carbon dioxide (CO2)/greenhouse gas emissions. The HTGR design uses helium as a coolant, graphite as a neutron moderator, and ceramic particle fuel. Helium is chemically inert and neutronically transparent. The graphite core slows down the neutrons, retains its strength at high temperatures, provides structural stability, and acts as a substantial heat sink during transient conditions. The ceramic particle fuel is extremely robust and retains the radioactive by products of the fission reaction within the coated particle under normal and off normal conditions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Technical Program Plan for INL Advanced Reactor Technologies Advanced Gas Reactor Fuel Development and Qualification Program

High-temperature gas cooled reactors (HTGRs) are graphite moderated nuclear reactors cooled with helium. Their high outlet temperatures and thermal energy conversion efficiency enable efficient and cost effective integration with non electricity generating applications. These applications include process heat and hydrogen production for petrochemical and other industrial processes that require operating temperatures between 300 and 900°C. HTGRs will supplement the use of premium fossil fuels such as oil and natural gas, improve overall energy security in the United States by reducing dependence on foreign fuels, and reduce carbon dioxide (CO2)/greenhouse gas emissions. The HTGR design uses helium as a coolant, graphite as a neutron moderator, and ceramic particle fuel. Helium is chemically inert and neutronically transparent. The graphite core slows down the neutrons, retains its strength at high temperatures, provides structural stability, and acts as a substantial heat sink during transient conditions. The ceramic particle fuel is extremely robust and retains the radioactive by products of the fission reaction within the coated particle under normal and off normal conditions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Technical Program Plan for INL Advanced Reactor Technologies Advanced Gas Reactor Fuel Development and Qualification Program

High-temperature gas cooled reactors (HTGRs) are graphite moderated nuclear reactors cooled with helium. Their high outlet temperatures and thermal energy conversion efficiency enable efficient and cost effective integration with non electricity generating applications. These applications include process heat and hydrogen production for petrochemical and other industrial processes that require operating temperatures between 300 and 900°C. HTGRs will supplement the use of premium fossil fuels such as oil and natural gas, improve overall energy security in the United States by reducing dependence on foreign fuels, and reduce carbon dioxide (CO2)/greenhouse gas emissions. The HTGR design uses helium as a coolant, graphite as a neutron moderator, and ceramic particle fuel. Helium is chemically inert and neutronically transparent. The graphite core slows down the neutrons, retains its strength at high temperatures, provides structural stability, and acts as a substantial heat sink during transient conditions. The ceramic particle fuel is extremely robust and retains the radioactive by products of the fission reaction within the coated particle under normal and off normal conditions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

NanoStructured bulk thermoelectric generator for efficient power harvesting for self-powered sensor network

The goal of the Nuclear Energy Enabling Technology Research Project is to develop efficient and reliable thermoelectric (TE) generators for self-powered wireless sensor nodes (WSNs) for nuclear applications. The power harvesting technology has crosscutting significance to all United States Department of Energy Office of Nuclear Energy research and development programs, as it will enable self-powered WSNs in multiple nuclear reactor designs and spent fuel storage facilities using thermal energy available in a nuclear power plant or spent fuel storage facility. This project addresses an important technology gap that exists in truly realizing WSNs due to the need for cables to connect to external power supplies and develop TE power harvesting devices to deliver sufficient power to drive the WSNs. The outcomes of the project will lead to significant advancement in sensors and instrumentation technology, reducing cost, improving monitoring reliability, and therefore enhancing safety. The self-powered WSNs could support the long-term safe and economical operation of all reactor designs and fuel cycle concepts, as well as spent fuel storage and many other nuclear science and engineering applications. The research is based on recent breakthroughs in high-performance nanostructured bulk (nanobulk) half-Heusler and bismuth telluride thermoelectric materials that enable high-efficiency and high-power-density direct heat-to-electricity conversion over a wide temperature range. The nanobulk TE materials that the research team has already developed yield up to a 50% increase in the TE figure of merit, ZT, compared with state-of-the-art bulk counterparts. In addition to increased efficiency, the nanostructured materials are of potentially enhanced radiation tolerance due to the increased interface densities at the nanoscale grain boundaries that serves as efficient sinks to annihilate radiation-induced, freely-migrating structural defects. This report summarizes major technical results the team achieved in this three-year project, with a focus on the results obtained in the third year of the project. The report includes results on thermoelectric materials fabrication and optimization, irradiation effect on thermoelectric materials performance, thermoelectric device simulation, fabrication and testing, wireless sensor node system simulation, and the demonstration of a wireless sensor node powered by thermoelectric generators.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Tandem concentrator solar cells with 30 percent (AMO) power conversion efficiency

Very high efficiency concentrator solar panels are envisioned as economical and reliable electrical power subsystems for space based platforms of the future. GaAs concentrator cells with very high efficiencies and good sub-bandgap transmissions can be fabricated on standard wafers. GaSb booster cell development is progressing very well; performance characteristics are still improving dramatically. Consistent GaAs/GaSb stacked cell AMO efficiencies greater than 30 percent are expected.

Avery, J. E.↗

The Effects of Hydrogen Iodide Back Surface Treatment on CdTe Solar Cells

An appropriate electrical back contact in CdTe solar cells is crucial to achieving high power conversion efficiency. In this work, we develop a facile back surface treatment method for CdTe solar cells using hydroiodic acid (HI) and investigate the effects of HI etching on the CdTe surfaces. The electrical properties of the CdTe absorber and interfaces are characterized by current-voltage, capacitance-voltage, admittance spectroscopy, and complex capacitance spectroscopy measurements. Here, the HI-etched devices show slightly higher apparent carrier concentrations than the control devices, suggesting an increased copper doping in the CdTe absorber. The potential barrier height of the back contact is reduced from 0.430 to 0.368 eV after the HI-treatment, accompanied by reduced contact resistance and carrier recombination. Additionally, the HI-treatment eliminates a defect signature at 0.409 eV. All of these HI-treatment effects lead to improved power conversion efficiency of CdTe solar cells through enhancement of the fill factor, the short circuit current, and open circuit voltage in order of significance.

14 SOLAR ENERGY↗

Design and characterization of a solar-enhanced microwave plasma reactor for atmospheric pressure carbon dioxide decomposition

The decomposition of carbon dioxide (CO 2 ) is a main step in carbon re-utilization approaches aimed to fulfill fuels and chemicals demands and mitigate environmental emissions. Plasmachemical CO 2 decomposition processes can be highly efficient; however, their reliance on electrical energy can limit their economic viability and sustainability advantage. In contrast, solar thermochemical CO 2 decomposition approaches can have limited efficiency, but their direct use of the most abundant form of renewable energy affords them the greatest sustainability potential. Solar-Enhanced Microwave Plasma (SEMP) chemical synthesis, based on the direct interaction between microwave plasma and concentrated solar radiation, is investigated as a novel approach to combine the advantages of plasmachemical and solar thermochemical processes. SEMP is motivated by the potential for synergistic effects between solar photons and plasma species, implied by the markedly greater spectral absorption of nonequilibrium CO 2 plasma compared to that of equilibrium CO 2 , to lead to enhanced chemical decomposition. The design, development, and characterization of a SEMP reactor for atmospheric pressure CO 2 decomposition is presented. The reactor is powered by a 1.25 kW magnetron and by up to 525 W of incident radiative power from a high-flux solar simulator. Experimental results reveal that the microwave plasma absorbs up to 20% of concentrated solar radiation at a solar-to-electrical power ratio of 0.5, and that relative absorption decreases with increasing solar input power. Yet, conversion efficiency and plasma energy efficiency increase with increasing solar power, up to 9% and 25% respectively, for a solar-to-electrical power ratio of 0.75. The enhanced process performance appears to be a consequence of the greater power density in the plasma caused by the direct absorption of solar radiation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Carbon-Nanotube-Based Thermoelectric Materials and Devices

Conversion of waste heat to voltage has the potential to significantly reduce the carbon footprint of a number of critical energy sectors, such as the transportation and electricity-generation sectors, and manufacturing processes. Thermal energy is also an abundant low-flux source that can be harnessed to power portable/wearable electronic devices and critical components in remote off-grid locations. As such, a number of different inorganic and organic materials are being explored for their potential in thermoelectric-energy-harvesting devices. Carbon-based thermoelectric materials are particularly attractive due to their use of nontoxic, abundant source-materials, their amenability to high-throughput solution-phase fabrication routes, and the high specific energy (i.e., W g-1) enabled by their low mass. Single-walled carbon nanotubes (SWCNTs) represent a unique 1D carbon allotrope with structural, electrical, and thermal properties that enable efficient thermoelectric-energy conversion. Here, the progress made toward understanding the fundamental thermoelectric properties of SWCNTs, nanotube-based composites, and thermoelectric devices prepared from these materials is reviewed in detail. This progress illuminates the tremendous potential that carbon-nanotube-based materials and composites have for producing high-performance next-generation devices for thermoelectric-energy harvesting.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Efficient far-infrared thermal bremsstrahlung radiation from a heterojunction bipolar transistor

We investigate the far-infrared thermal radiation properties of a heterojunction bipolar transistor. The device conveniently provides a high electric field for electrons to heat the lattice and the electron gas in a background with ions embedded. Because of very high effective temperature of the electron gas in the collector, the electron-ion bremsstrahlung makes efficient the thermal radiation in the far-infrared region. The transistor can yield a radiation power of 0.1 mW with the spectral region between 2 and 75 THz and a power conversion efficiency of 6 × 10{sup −4}. Such output contains a power of 20 μW in the low-frequency part (2–20 THz) of the spectrum.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Phase 1 Space Fission Propulsion Energy Source Design

Fission technology can enable rapid, affordable access to any point in the solar system. If fission propulsion systems are to be developed to their full potential; however, near-term customers must be identified and initial fission systems successfully developed, launched, and operated. Studies conducted in fiscal year 2001 (IISTP, 2001) show that fission electric propulsion (FEP) systems with a specific mass at or below 50 kg/kWjet could enhance or enable numerous robotic outer solar system missions of interest. At the required specific mass, it is possible to develop safe, affordable systems that meet mission requirements. To help select the system design to pursue, eight evaluation criteria were identified: system integration, safety, reliability, testability, specific mass, cost, schedule, and programmatic risk. A top-level comparison of four potential concepts was performed: a Testable, Passive, Redundant Reactor (TPRR), a Testable Multi-Cell In-Core Thermionic Reactor (TMCT), a Direct Gas Cooled Reactor (DGCR), and a Pumped Liquid Metal Reactor.(PLMR). Development of any of the four systems appears feasible. However, for power levels up to at least 500 kWt (enabling electric power levels of 125-175 kWe, given 25-35% power conversion efficiency) the TPRR has advantages related to several criteria and is competitive with respect to all. Hardware-based research and development has further increased confidence in the TPRR approach. Successful development and utilization of a "Phase I" fission electric propulsion system will enable advanced Phase 2 and Phase 3 systems capable of providing rapid, affordable access to any point in the solar system.

Houts, Mike↗

Phase 1 Space Fission Propulsion System Design Considerations

Fission technology can enable rapid, affordable access to any point in the solar system. If fission propulsion systems are to be developed to their full potential; however, near-term customers must be identified and initial fission systems successfully developed, launched, and operated. Studies conducted in fiscal year 2001 (IISTP, 2001) show that fission electric propulsion (FEP) systems operating at 80 kWe or above could enhance or enable numerous robotic outer solar system missions of interest. At these power levels it is possible to develop safe, affordable systems that meet mission performance requirements. In selecting the system design to pursue, seven evaluation criteria were identified: safety, reliability, testability, specific mass, cost, schedule, and programmatic risk. A top-level comparison of three potential concepts was performed: an SP-100 based pumped liquid lithium system, a direct gas cooled system, and a heatpipe cooled system. For power levels up to at least 500 kWt (enabling electric power levels of 125-175 kWe, given 25-35% power conversion efficiency) the heatpipe system has advantages related to several criteria and is competitive with respect to all. Hardware-based research and development has further increased confidence in the heatpipe approach. Successful development and utilization of a "Phase 1" fission electric propulsion system will enable advanced Phase 2 and Phase 3 systems capable of providing rapid, affordable access to any point in the solar system.

Houts, Mike↗

Photochemical charges separation and photoelectric properties of flexible solar cells with two types of heterostructures

Photochemical charges generation, separation, and transport at nanocrystal interfaces are central to energy conversion for solar cells. Here, Zn{sub 2}SnO{sub 4} nanowires/Cu{sub 4}Bi{sub 4}S{sub 9} (ZTO/CBS), ZTO nanowires/CBS-reduced graphene oxide (ZTO/CBS-RGO), and bulk heterojunction (BHJ) solar cells were measured. The signals of steady state and electric field-induced surface photovoltage indicate that RGO with high electron mobility can evidently improve the photovoltaic response. Besides, ZTO/CBS and ZTO/CBS-RGO cells exhibit the excellent performance and the highest efficiencies of 1.2% and 2.8%, respectively. The internal relations of photoelectric properties to some factors, such as film thickness, direct paths, RGO conductive network, energy level matching, etc., were discussed in detail. Qualitative and quantitative analyses further verified the comprehensive effect of RGO and other factors. Importantly, the fine bendable characteristic of BHJ solar cells with excellent efficiency and facile, scalable production gives the as-made flexible solar cells device potential for practical application in future.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Thermoelectrics with a twist

Thermoelectrics convert heat into electricity by enabling electron flow across a temperature gradient, but internal electrical resistance from Joule heating is a key limiting factor to conversion efficiency. In the pursuit of material platforms for the next generation of thermoelectrics, topological materials with high electron mobility, including topological insulators and topological semimetals, have attracted substantial attention. Topological insulators support protected current-carrying electron states that are robust to perturbations, reducing electrical resistance.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Boosting Thermal Management & Reliability of Vehicle Power Electronics

Electric vehicles rely heavily on power electronics—including inverters, converters, and chargers—to control the flow of electricity between the battery, the motor, and other powertrain components. NREL is helping boost the performance of power electronics components and systems, while driving down size, weight, and cost. In electric vehicles, these components need to operate at higher temperatures, voltages, switching frequencies, and power conversion efficiencies. That’s where NREL’s thermal management and reliability research comes in.

33 ADVANCED PROPULSION SYSTEMS↗

Chloride ion-doped polypyrrole nanocomposite as cathode material for rechargeable magnesium battery

Highlights: • Chloride ion-doped polypyrrole nanocomposite is firstly developed as new cathode for rechargeable magnesium battery. • Reversible redox reactions of nitrogen species in nanostructured polypyrrole in RMB system are proved. • More than 95 mAh g{sup −1} capacity and a high Coulombic efficiency of about 96% are delivered. - Abstract: We report a chloride ion-doped polypyrrole/carbon nanotube (PPyCl/CNTs) nanocomposite as new cathode material for rechargeable magnesium battery. The PPyCl/CNTs nanocomposite with amorphous structure, uniform chlorine distribution and large specific surface area shows reversible electrochemical energy storage upon redox reaction of nitrogen species. The structural configuration of PPyCl by the incorporation of CNTs contributes to significant improvement in the electrochemical performance. More than 95 mAh g{sup −1} capacity and a high Coulombic efficiency of about 96% are delivered. This study offers a promising way for designing new cathode for rechargeable magnesium batteries.

25 ENERGY STORAGE↗

Power processing and control requirements of dispersed solar thermal electric generation systems

Power Processing and Control requirements of Dispersed Receiver Solar Thermal Electric Generation Systems are presented. Kinematic Stirling Engines, Brayton Engines and Rankine Engines are considered as prime movers. Various types of generators are considered for ac and dc link generations. It is found that ac-ac Power Conversion is not suitable for implementation at this time. It is also found that ac-dc-ac Power Conversion with a large central inverter is more efficient than ac-dc-ac Power Conversion using small dispersed inverters. Ac-link solar thermal electric plants face potential stability and synchronization problems. Research and development efforts are needed in improving component performance characteristics and generation efficiency to make Solar Thermal Electric Generation economically attractive.

Das, R. L.↗