Search NASA⌕ Search

SEARCH · Search NASA

Results for “electronic hybridization”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 289 records · Page 16

An assessment of plasma instabilities or planetary lightning as a source for the VLF bursts detected at Venus

Very low frequency (VLF) signals detected in the nightside ionosphere of Venus have generally been attributed to atmospheric lightning. However it has recently been suggested that these bursts could be generated by either whistler-mode or lower hybrid drift instabilities. It has previously been shown that the growth rate for whistler-mode instabilities in the nightside ionosphere is too small for appreciable growth at altitudes less than 200 km, where the VLF burst rate is highest. We show that the bursts are usually observed in regions of low electron beta, where whistler-mode attenuation is small. We further show that many of the bursts are detected in regions of high collision frequency, which stabilizes the lower hybrid drift instability. Lastly, the waves are also detected in regions where the wavelength required for Doppler-shift of lower hybrid waves to 100 Hz is shorter than the electron Larmor radius, which also argues against a lower hybrid drift instability. Planetary lightning is consequently a more likely source for the VLF bursts.

Strangeway, R. J.↗

Modified Iterative Extended Hueckel. 1: Theory

Iterative Extended Huekel is modified by inclusion of explicit effective internuclear and electronic interactions. The one electron energies are shown to obey a variational principle because of the form of the effective electronic interactions. The modifications permit mimicking of aspects of valence bond theory with the additional feature that the energies associated with valence bond type structures are explicitly calculated. In turn, a hybrid molecular, orbital valence, bond scheme is introduced which incorporates variant total molecular electronic density distributions similar to the way that Iterative Extended Hueckel incorporates atoms.

Aronowitz, S.↗

Mixed Cu-simple metal dimers and trimers - CuLi, CuLi2, CuNa, CuK, CuBe, CuBe2, Cu2Be, CuAl, and CuAl2

Theoretical studies of selected diatomic and triatomic molecules containing copper and the simple metals Li, Na, K, Be, and Al are presented, with emphasis on elucidating the nature of the bonding in mixed transition metal-simple metal systems. Large Gaussian basis sets are used in the diatomic calculations, and are used to calibrate the triatomic calculations, in which somewhat smaller Gaussian basis sets are employed. Electron correlation is incorporated using both the single-reference singles plus doubles configuration interaction and coupled pair functional methods. It is found that alkali atoms form very polar sigma bonds with copper, and that the ionicity increases with the inclusion of higher excitations because they improve the electron affinity of copper, which in turn allows a larger negative charge on copper. Aluminum is found to form stronger bonds than beryllium, since it does not have to undergo sp hybridization. Some of the trimers bond by forming three-center three-electron bonds. These multicenter bonds are quite strong even when compared to the two-electron bonds in the dimers or to other bonding mechanisms in the trimers.

Bauschlicher, Charles W., Jr.↗

Lower-hybrid turbulence in a nonuniform magnetoplasma

An experimental study of a pressure-gradient-driven instability in a large discharge plasma is presented. When the electron diamagnetic drift exceeds the sound speed, ion-acoustic-like waves are driven unstable. The growth rate maximizes near the lower-hybrid frequency and the waves propagate essentially across B. The sound waves grow to large amplitudes and saturate by wave steepening and refraction away from the destabilizing drift. Magnetic fluctuations result from electron diamagnetic currents and opposing Hall currents associated with the wave density fluctuations. Ions are essentially unmagnetized and slow compared to the magnetized electrons. In spite of the large amplitude waves little acceleration of electrons or ions is observed.

Stenzel, R. L.↗

ISIS Topside-Sounder Plasma-Wave Investigations as Guides to Desired Virtual Wave Observatory (VWO) Data Search Capabilities

Many plasma-wave phenomena, observed by space-borne radio sounders, cannot be properly explained in terms of wave propagation in a cold plasma consisting of mobile electrons and infinitely massive positive ions. These phenomena include signals known as plasma resonances. The principal resonances at the harmonics of the electron cyclotron frequency, the plasma frequency, and the upper-hybrid frequency are well explained by the warm-plasma propagation of sounder-generated electrostatic waves, Other resonances have been attributed to sounder-stimulated plasma instability and non-linear effects, eigenmodes of cylindrical electromagnetic plasma oscillations, and plasma memory processes. Data from the topside sounders of the International Satellites for Ionospheric Studies (ISIS) program played a major role in these interpretations. A data transformation and preservation effort at the Goddard Space Flight Center has produced digital ISIS topside ionograms and a metadata search program that has enabled some recent discoveries pertaining to the physics of these plasma resonances. For example, data records were obtained that enabled the long-standing question (several decades) of the origin of the plasma resonance at the fundamental electron cyclotron frequency to be explained [Muldrew, Radio Sci., 2006]. These data-search capabilities, and the science enabled by them, will be presented as a guide to desired data search capabilities to be included in the Virtual Wave Observatory (VWO).

Benson, Robert F.↗

Topside sounders as mobile ionospheric heaters

There is evidence that satellite-borne RF sounders can act as mobile ionospheric heaters in addition to performing topside sounding. The main objective of topside sounding is to use sounder-generated electromagnetic (em) waves to obtain ionospheric topside vertical electron-density (N(sub e) profiles. These profiles are obtained from mathematical inversions of the frequency vs. delay-time ionospheric reflection traces. In addition to these em reflection traces, a number of narrowband intense signals are observed starting at zero delay times after the transmitted pulses. Some of these signals, termed plasma resonances, appear at characteristic frequencies of the ambient medium such as at the electron cyclotron frequency f(sub ce), the harmonics nf(sub ce), the electron plasma frequency f(sub pe) and the upper-hybrid frequency f(sub uh), where (f(sub uh))(exp 2) = (f(sub ce))(exp 2) + (f(sub pe))(exp 2) . These signals have been attributed to the oblique echoes of sounder-generated electrostatic (es) waves. These resonances provide accurate in situ f(sub pe) and f(sub ce) values which, in turn, lead to accurate N(sub e) and [B] values where B is the ambient magnetic field. Resonances are also observed between the nf(sub ce) harmonics both above and below f(sub uh). The former, known as the Qn plasma resonances, are mainly attributed to the matching of the wave group velocity of sounder-generated (Bernstein-mode) es waves to the satellite velocity. The frequency spectrum of these waves in the magnetosphere can be used to detect non-Maxwellian electron velocity-distributions. In addition, these resonances also exhibit components that appear to be the result of plasma emissions stimulated by the sounder pulses. The plasma resonances observed between the nf(sub ce) harmonics and below f(sub uh), known as the Dn plasma resonances, are entirely attributed to such sounder-stimulated plasma emissions. There are other sounder-stimulated plasma phenomena that also fall into this category, e.g., ion affects on electron-resonant phenomena, proton-cyclotron echoes and N(sub e) field-aligned irregularities (FAI). Some of these phenomena are more pronounced when f(sub pe)/f(sub ce) approx. = n where n is an integer significantly greater than one. The observations suggest that the sounder-stimulated plasma phenomena are stimulated, or enhanced, on a time scale much less than one second. The purpose of this presentation is to review the above topics with particular emphasis on the sounder-stimulated plasma phenomena.

Benson, R. F.↗

Organic-Inorganic Hybrids Using Novel Phenylethynyl Imide Silanes

In this presentation, polyimide-silica hybrids using novel phenylethynyl imide silanes are reported. The phenylethynyl group is present in the organic precursor as either a pendent or an end group to bond chemically with the polyimide adhesive containing phenylethynyl groups during processing, while the silane group of the organic precursor would chemically react with the inorganic precursor through oxane bond formation. The chemical compositions of these novel hybrids were examined using X-ray mapping modes of scanning electron microscopy (SEM), which revealed a silicon gradient interphase between the high surface energy substrate and the polyimide adhesive. Novel aromatic phenylethynyl imide silanes (APEISs) and pendent phenylethynyl imide oligomeric disilanes (PPEIDSs) have been synthesized, and sol-gel solutions containing the new silanes, a phenylethynyl terminated imide oligomer (PETI-5), and an inorganic precursor were formulated to develop a gradient hybrid interphase between a titanium alloy and the adhesive. Two different sol-gel systems were investigated to develop organic-inorganic hybrids. Hybrid I was composed of an organic precursor containing both phenylethynyl and silane groups (PPEIDS) and an inorganic precursor. Functional group concentrations were controlled by the variation of the molecular weight of the imide backbone of PPEIDS. Hybrid II was composed of organic and inorganic precursors and a coupling agent containing both phenylethynyl and silane groups. Morphology and chemical composition of the hybrid interphase between the inorganic substrate and the adhesive were investigated, and the bond strength and durability were evaluated using lap shear tests at various conditions. The assessment of how the bonding at an interface is affected by various sol-gel solution compositions and environments is reported.

Park, C.↗

Harmonic H(+) gyrofrequency structures in auroral hiss observed by high-altitude auroral sounding rockets

Two recent sounding rocket experiments have yielded VLF wave data with spectral structures ordered by the hydrogen gyrofrequency. The spectral structures occur near and above the lower hybrid frequency in association with auroral hiss. These structures are observed within and near regions of auroral electron precipitation and transverse ion acceleration. They are accompanied by auroral hiss but are anticorrelated with spectral peaks at the lower hybrid frequency. They are typically found above 500 km altitude, have no measurable magnetic component, and are at least occasionally short wavelength. Because the spectral structures appear to be electrostatic, are ordered by the hydrogen gyrofrequency, and are short wavelength, the structures are interpreted as modes which connect the lower hybrid mode with the hydrogen Bernstein modes. A study of the plasma wave mode structure in the vicinity of the lower hybrid frequency is presented to substantiate this interpretation. These results imply that these waves are a common feature of the auroral zone ionsphere above 500 km altitude and exist any time that auroral hiss exists. The absence of previous satellite observations of this phenomenon can be explained by Doppler broadening.

Kintner, P. M.↗

The FIELDS Instrument Suite on MMS: Scientific Objectives, Measurements, and Data Products

The FIELDS instrumentation suite on the Magnetospheric Multiscale (MMS) mission provides comprehensive measurements of the full vector magnetic and electric fields in the reconnection regions investigated by MMS, including the dayside magnetopause and the night-side magnetotail acceleration regions out to 25 Re. Six sensors on each of the four MMS spacecraft provide overlapping measurements of these fields with sensitive cross-calibrations both before and after launch. The FIELDS magnetic sensors consist of redundant flux-gate magnetometers (AFG and DFG) over the frequency range from DC to 64 Hz, a search coil magnetometer (SCM) providing AC measurements over the full whistler mode spectrum expected to be seen on MMS, and an Electron Drift Instrument (EDI) that calibrates offsets for the magnetometers. The FIELDS three-axis electric field measurements are provided by two sets of biased double-probe sensors (SDP and ADP) operating in a highly symmetric spacecraft environment to reduce significantly electrostatic errors. These sensors are complemented with the EDI electric measurements that are free from all local spacecraft perturbations. Cross-calibrated vector electric field measurements are thus produced from DC to 100 kHz, well beyond the upper hybrid resonance whose frequency provides an accurate determination of the local electron density. Due to its very large geometric factor, EDI also provides very high time resolution (∼1 ms) ambient electron flux measurements at a few selected energies near 1 keV. This paper provides an overview of the FIELDS suite, its science objectives and measurement requirements, and its performance as verified in calibration and cross-calibration procedures that result in anticipated errors less than 0.1 nT in B and 0.5 mV/m in E. Summaries of data products that result from FIELDS are also described, as well as algorithms for cross-calibration. Details of the design and performance characteristics of AFG/DFG, SCM, ADP, SDP, and EDI are provided in five companion papers.

Electromagnetic field measurements↗

Si:Bi switched photoconducttor infrared detector array

A multiplexed infrared detector array is described. The small demonstration prototype consisted of two cryogenically cooled, bismuth doped silicon, extrinsic photoconductor pixels multiplexed onto a single output channel using an on focal plane switch integration sampling technique. Noise levels of the order of 400 to 600 rms electrons per sample were demonstrated for this chip and wire hybrid version.

Eakin, C. E.↗

Analytic evaluation of two-center molecular integrals

By using the Fourier-transform technique, the explicit expressions for the one-electron - two-center overlap integrals of Slater-type atomic orbitals up to 3d are derived. The final expressions are analytic, simple, and independent of local coordinates. Furthermore, they do not contain the nonclosed-form of exponential integrals which were presented in expressions given in earlier work. It is shown that the two-electron - two-center Coulomb integrals, as well as the hybrid integrals, can simply be expressed in terms of these integrals. The numerical instability arising from the situation in which the exponents of the two orbitals are almost equal is discussed, and a solution for this problem based on a Taylor-series expansion of the integral is suggested.

Tai, H.↗

Interaction of a neutral cloud moving through a magnetized plasma

Current collection by outgassing probes in motion relative to a magnetized plasma may be significantly affected by plasma processes that cause electron heating and cross field transport. Simulations of a neutral gas cloud moving across a static magnetic field are discussed. The authors treat a low-Beta plasma and use a 2-1/2 D electrostatic code linked with the authors' Plasma and Neutral Interaction Code (PANIC). This study emphasizes the understanding of the interface between the neutral gas cloud and the surrounding plasma where electrons are heated and can diffuse across field lines. When ionization or charge exchange collisions occur a sheath-like structure is formed at the surface of the neutral gas. In that region the crossfield component of the electric field causes the electron to E times B drift with a velocity of the order of the neutral gas velocity times the square root of the ion to electron mass ratio. In addition a diamagnetic drift of the electron occurs due to the number density and temperature inhomogeneity in the front. These drift currents excite the lower-hybrid waves with the wave k-vectors almost perpendicular to the neutral flow and magnetic field again resulting in electron heating. The thermal electron current is significantly enhanced due to this heating.

Goertz, C. K.↗

Development of a High Resolution Liquid Xenon Imaging Telescope for Medium Energy Gamma Ray Astrophysics

In the third year of the research project, we have (1) tested a 3.5 liter prototype of the Liquid Xenon Time Projection Chamber, (2) used a prototype having a 4.4 cm drift gap to study the charge and energy resolution response of the 3.5 liter chamber, (3) obtained an energy resolution as good as that previously measured by us using chambers with drift gaps of the order of millimeters, (4) observed the induction signals produced by MeV gamma rays, (4) used the 20 hybrid charge sensitive preamplifiers for a nondestructive readout of the electron image on the induction wires, (5) performed extensive Monte Carlo simulations to obtain results on efficiency, background rejection capability, and source flux sensitivity, and (6) developed a reconstruction algorithm for events with multiple interaction points.

Aprile, Elena↗

Photonics: Technology project summary

Photonics involves the use of light (photons) in conjunction with electronics for applications in communications, computing, control, and sensing. Components used in photonic systems include lasers, optical detectors, optical wave guide devices, fiber optics, and traditional electronic devices. The goal of this program is to develop hybrid optoelectronic devices and systems for sensing, information processing, communications, and control. It is hoped that these new devices will yield at least an order of magnitude improvement in performance over existing technology. The objective of the program is to conduct research and development in the following areas: (1) materials and devices; (2) networking and computing; (3) optical processing/advanced pattern recognition; and (4) sensing.

Depaula, Ramon P.↗

A hybrid simulation of contact discontinuity

Contact discontinuities in a collisionless plasma are studied by hybrid simulations, in which ions are treated as particles and electrons are considered as a fluid. It is demonstrated that contact discontinuity with a stable density ramp can exist in cases with a finite electron temperature. An electron pressure gradient is present across the contact discontinuity, leading to the presence of a parallel electric field and hence field-aligned potential increase (Delta Phi (sub parallel)) in the transition region. By reflecting ions at the discontinuity, this parallel electric potential peak reduces the interpenetration between hot and cold ions and maintains a stable density ramp across the contact discontinuity. The ratio of the field-aligned electric potential energy to ion thermal energy, e(Delta) Phi(sub parallel)/kT(sub i), is found to be an increasing function of T(sub e)/T(sub i), where T(sub e) and T(sub i) are respectively the electron and ion temperature.

Wu, B. H.↗

Electrostatic Electron Cyclotron Waves Observed by the Plasma Wave Instrument on Board Polar

We report the results of an investigation of waves observed by the Polar spacecraft at high altitudes and latitudes and at frequencies just above the cyclotron frequency. These observations are made frequently when the spacecraft is over the polar cap as well as near the dayside cusp and near the nightside auroral region, and observations are made for ratios of plasma frequency to cyclotron frequency, f(sub p)/f(sub c) = 1. Using the six-channel high-frequency waveform receiver (HFWR) on board the spacecraft, which can provide three-axis electric and three-axis magnetic field measurements, we attempt to identify the wavemode of these emissions and investigate possible source mechanisms including low-energy electron beams. We further observe electromagnetic emission associated with upper hybrid waves near and within the plasmasphere. This emission is consistent with both Z and O modes.

Menietti, J. D.↗

Heating and Acceleration of Solar Wind Ions by Turbulent Wave Spectrum in Inhomogeneous Expanding Plasma

Near the Sun (< 10Rs) the acceleration, heating, and propagation of the solar wind are likely affected by the background inhomogeneities of the magnetized plasma. The heating and the acceleration of the solar wind ions by turbulent wave spectrum in inhomogeneous plasma is studied using a 2.5D hybrid model. The hybrid model describes the kinetics of the ions, while the electrons are modeled as massless neutralizing fluid in an expanding box approach. Turbulent magnetic fluctuations dominated by power-law frequency spectra, which are evident from in-situ as well as remote sensing measurements, are used in our models. The effects of background density inhomogeneity across the magnetic field on the resonant ion heating are studied. The effect of super- Alfvenic ion drift on the ion heating is investigated. It is found that the turbulent wave spectrum of initially parallel propagating waves cascades to oblique modes, and leads to enhanced resonant ion heating due to the inhomogeneity. The acceleration of the solar wind ions is achieved by the parametric instability of large amplitude waves in the spectrum, and is also affected by the inhomogeneity. The results of the study provide the ion temperature anisotropy and drift velocity temporal evolution due to relaxation of the instability. The non-Maxwellian velocity distribution functions (VDFs) of the ions are modeled in the inhomogeneous solar wind plasma in the acceleration region close to the Sun.

Ofman, Leon↗

Marshall Space Flight Center Faculty Fellowship Program

The 2018 Marshall Faculty Fellowship Program involved 16 faculty in the laboratories and departments at Marshall Space Flight Center. These faculty engineers and scientists worked with NASA collaborators on NASA projects, bringing new perspectives and solutions to bear. This Technical Memorandum is a compilation of the research reports of the 2018 Marshall Faculty Fellowship program, along with the Program Announcement (Appendix A) and the Program Description (Appendix B). The research affected the following five areas: (1) Materials (2) Propulsion (3) Spacecraft systems (4) Vehicle systems (5) Space science The materials investigations includes Lunar Regolith for habitats, friction stir welding, and composite joints. Propulsion studies included cryogenic tank pressurization, transmitted torque in a cryogenic environment, and condensation in presence of noncondensables, Europa Lander Deorbit Stage, and catalyst development for a hybrid rocket. Spacecraft systems include wireless sensor networks and printed electronic inks. Vehicle systems studies were performed on Mars ascent vehicle analysis, architecture models, and Space Launch System manual steering. Space science studies included planetary lava flow. Our goal is to continue the Marshall Faculty Fellowship Program funded by Center internal project offices. Faculty Fellows in this 2018 program represented the following minority-serving institutions: Alabama A&M University, Southern University, Delgado Community College, and Dillard University.

Six, N. F.↗