Calculation of ion-molecule reaction rate constants from ion cyclotron resonance spectra - Methyl fluoride
Methyl fluoride calculated for ion-molecule reaction rate constants from ion cyclotron resonance spectra
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Methyl fluoride calculated for ion-molecule reaction rate constants from ion cyclotron resonance spectra
Photoelectron spectra of methane, silane, germane, methyl fluoride, difluoromethane and trifluoromethane, describing electron spectrometer with double focusing electrostatic plates
Self lubricating fluoride-metal composite materials for outer space applications
High temperature friction and wear characteristics of self lubricating composite disks of sintered tungsten, molybdenum, and cobalt molybdenum, impregnated with fluoride eutectic
Photochromic calcium fluoride preparation by rare earth additive coloration techniques
Solid and fluid states oxalyl fluoride vibrational spectra and structure
Solid lubricant film consisting of polyimide varnish as binder and graphite fluoride as lubricant is described. Comparative wear tests with other solid lubricants were conducted and results are shown in graph form. Test equipment used in conducting wear tests is reported.
A friction and wear life study was conducted on the use of a polyimide (PI) varnish as a binder for the solid lubricant, graphite fluoride (CF(1.1))N. Also studied were the lubricating properties of PI thin films with no solid lubricant additives. For comparison, similar experiments on PI-bonded MoS2 and burnished films of MoS2 or (CF(li))N were conducted. The best results were obtained with the PI-bonded (CF(1.1))N films. The polyimide thin films (with no solid lubricant additives) did not lubricate well at 25 C; however, when heated to 100 C, low friction and long wear lives were obtained.
Clean criticality data were obtained from molybdenum-reflected cylindrical uranyl-fluoride-water solution reactors. Using ENDF/B molybdenum cross sections, a nine energy group two-dimensional transport calculation of a reflected reactor configuration predicted criticality to within 7 cents of the experimental value. For these reactors, it was necessary to compute the reflector resonance integral by a detailed transport calculation at the core-reflector interface volume in the energy region of the two dominant resonances of natural molybdenum.
Plasma-sprayed composites, which have good oxidation-resistance and self-lubricating characteritics to 900 C, were developed. The composites are a nichrome matrix containing dispersed glass for oxidation protection and calcium fluoride for lubrication; they are applied to bearing surfaces by plasma spraying layers about 0.050 centimeters thick which are then machined to 0.025 centimeters. Oscillating bearing tests were performed in air to 900 C at unit radial loads up to 3.5 x 10 to the 7th power N/sq M (5000 psi) and a thrust load of 1960N (440 lbs). Bearings with a composite liner in the bore were in good condition after over 50,000 oscillating cycles accumulated during repeated, bearing temperatures cycles between 25 and 900 C.
A friction and wear life study was conducted on the use of a polyimide (PI) varnish as a binder for the solid lubricant, graphite fluoride (CF sub 1.1) sub n. Also studied were the lubricating properties of PI thin films with no solid lubricant additives. For comparison, similar experiments on PI-bonded MoS2 and burnished films of MoS2 or (CF sub 1.1) sub n were conducted. The best results were obtained with the PI-bonded (CF sub 1.1) sub n films. The polyimide thin films (with no solid lubricant additives) did not lubricate well at 25 C; however, when heated to 100 C, low friction and long wear lives were obtained.
Plasma spray of Nichrome matrix composite contains dispersed glass for oxidation protection and calcium fluoride for lubrication. Coatings can be applied to bearing journals and bearing bores. Coating was easily machinable and had excellent bond strength on substrate metal.
Plasma-sprayed composites, which have good oxidation resistance and self-lubricating characteristics to 900 C, were developed. The composites are a nichrome matrix containing dispersed glass for oxidation protection and calcium fluoride for lubrication; they are applied to bearing surfaces by plasma spraying layers about 0.050 cm thick which are then machined to 0.025 cm. Oscillating bearing tests were performed in air to 900 C at unit radial loads up to 5000 psi and a thrust load of 440 lb. Bearings with a composite liner in the bore were in good condition after over 50,000 oscillating cycles accumulated during repeated bearing temperature cycles between 25 and 900 C.
A study was conducted on the lubricating properties of organopolysiloxane-bonded graphite fluoride (CF sub 1.1) sub n films. The effects of temperature, atmosphere, composition of organopolysiloxane, and burnishing additional (CF sub 1.1) sub n powder onto the film surface were studied. For comparison, similar experiments were conducted on organopolysiloxane-bonded MoS2 films. The results are equivalent for both films, except that in a moist air environment the wear lives of the films formulated with (CF sub 1.1) sub n are up to 10 times longer than the wear lives of the MoS2-formulated films. Comparison to other (CF sub 1.1) sub n films showed organopolysiloxane films to give better lubrication results than hand-burnished (CF sub 1.1) sub n films but not as good as polyimide-bonded (CF sub 1.1) sub n films.
An active optical technique (differential absorption lidar (DIAL)) for detecting, ranging, and quantifying the concentration of anhydrous HCl contained in the ground cloud emitted by solid rocket motors (SRM) is evaluated. Results are presented of an experiment in which absorption coefficients of HCl were measured for several deuterium fluoride (DF) laser transitions demonstrating for the first time that a close overlap exists between the 2-1 P(3) vibrational transition of the DF laser and the 1-0 P(6) absorption line of HCl, with an absorption coefficient of 5.64 (atm-cm) to the -1 power. These measurements show that the DF laser can be an appropriate radiation source for detecting HCl in a DIAL technique. Development of a mathematical computer model to predict the sensitivity of DIAL for detecting anhydrous HCl in the ground cloud is outlined, and results that assume a commercially available DF laser as the radiation source are presented.
Friction, wear life, rider wear, and film wear for a 440 C high-temperature-stainless-steel, hemispherically tipped rider sliding against polyimide-bonded graphite fluoride films were evaluated in a moist-air atmosphere at 25 C. Optical microscope and surface profilometry observations were made at various sliding intervals to determine how film thickness affected the lubricating and failure mechanisms of the films. Two lubrication regimes operated for the same load. In the first, the film supported the load and the lubricating mechanism consisted of the shear (plastic flow) of a thin layer of the lubricant between the metallic rider and the film surface. In the second, the film did not support the load (it was worn away) and the lubricating mechanism consisted of the shear of very thin lubricant films between flat areas generated on the rider and on sandblasted metallic asperities in the film wear track. Lubricant was supplied from the valleys between the asperities or from the sides of the wear track. With thicker films, wear life increased since a greater lubricant supply was available from the sides of the wear track.
The tribological properties of polyimide-bonded graphite fluoride films were studied with a pin-on-disk friction apparatus. A 440 C HT stainless steel rider with a 0.95 millimeter diameter flat area was slid against the film in order to achieve a light, closely controlled contact stress. A 1 kilogram load was applied to this flat to give a projected contact stress of 14 megapascals. Two stages of lubrication were operating. In the first stage, the film supported the load and the lubricating mechanism appeared to be the shear of a thin surface layer of the film between the rider and the bulk of the film. The second stage began after the original film was worn away, and the lubricating mechanism appeared to be the shear of very thin lubricant layers between the flat area on the rider and flat plateaus generated on the sandblasted asperities of the metallic substrate. The major difference between the lubricating mechanisms of the hemispherical and flat riders was that the flat wore through the film much more slowly than did the hemisphere.
High energy density capacitors made from metallized polyvinylidene fluoride film were built and tested. Terminations of aluminum-babbitt, tin-babbitt, and all-babbitt were evaluated. All-babbit terminations appeared to be better. The 0.1 microfarad and 2 microfarad capacitors were made of 6 micrometer material. Capacitance, dissipation factor, and insulation resistance measurements were made over the ranges -55 C to 125 C and 10 Hz to 100 kHz. Twelve of forty-one 0.1 microfarad capacitors survived a 5000 hour dc plus ac life test. Under the same conditions, the 2 microfarad capacitors exhibited overheating because of excessive power loss. Some failures occurred after low temperature exposures for 48 hours. No failures were caused by vibration or temperature cycling.