Results for “fuel oxidation testing” — Page 16

NASA NTRS2018

Orion European Structural Test Article Propellant Tank Fill and Drain Carts

Environmental testing of the Orion European Structural Test Article (E-STA), which contains the Orion European Service Module (ESM), required that the onboard propellant tanks be filled and drained with fuel and oxidizer simulant fluids as well as pressurized and depressurized with an ullage gas. This conference paper will elaborate on how these objectives were fulfilled by presenting the development of derived requirements definition, initial fill and drain concepts, selection of simulant fluids, finalization of pump and pressurization design, selection of components, and selection of transfer hoses and interface connections as well as development and maintenance of budgets, schedules, reviews, construction, documentation, and test procedures. This paper also describes the implementation of checkout and commissioning activities leading to successful fluid cart pumping and pressurization operations for the test campaign. The development, construction, and operation of the fluid cart pumping and pressurization systems for the environmental testing of the Orion E-STA, took place at NASA's Plum Brook Station Space Environments Complex (SEC) during 2015 and 2016.

FLUID TRANSFER↗

NASA NTRS2018

Orion European Structural Test Article Propellant Tank Fill and Drain Carts

Environmental testing of the Orion European Structural Test Article (E-STA), which contains the Orion European Service Module (ESM), required that the onboard propellant tanks be filled and drained with fuel and oxidizer simulant fluids as well as pressurized and de-pressurized with an ullage gas. This conference paper will elaborate on how these objectives were fulfilled by presenting the development of derived requirements definition, initial fill and drain concepts, selection of simulant fluids, finalization of pump and pressurization design, selection of components, selection of transfer hoses and interface connections, as well as development and maintenance of budgets, schedules, reviews, construction, documentation, and test procedures. This paper also describes implementation of checkout and commissioning activities leading to successful fluid cart pumping and pressurization operations for the test campaign. The development, construction, and operation of the fluid cart pumping and pressurization systems for the Environmental testing of the Orion European Structural Test Article (E-STA), took place at the NASA Glenn Research Center's Plum Brook Station Space Environments Complex (SEC) during 2015 and 2016.

Pressurization↗

NASA NTRS1997

Space Shuttle Main Engine Start with Off-Nominal Propellant Inlet Pressures

This paper describes Rocketdyne's successful analysis and demonstration of the Space Shuttle Main Engine (SSME) operation at off-nominal propellant inlet conditions during the Reusable Launch Vehicle (RLV) evaluation tests. The nominal inlet condition range is: 103 to 111 psia and 170.5 to 178 deg. R for the oxidizer and 43 to 47 psia and 37 to 40 deg. R for the fuel. The SSME start was successfully demonstrated with engine inlet pressures of 50 psia liquid oxygen (LOX) with subcooled LOX at 160 deg R and 38 psia fuel at 38 deg. R. Four tests were used to incrementally modify the start sequence to demonstrate the final goal.

Bradley, Michael↗

NASA NTRS2004

New Screening Test Developed for the Blanching Resistance of Copper Alloys

NASA's extensive efforts towards more efficient, safer, and more affordable space transportation include the development of new thrust-cell liner materials with improved capabilities and longer lives. For rocket engines fueled with liquid hydrogen, an important metric of liner performance is resistance to blanching, a phenomenon of localized wastage by cycles of oxidation-reduction due to local imbalance in the oxygen-fuel ratio. The current liner of the Space Shuttle Main Engine combustion chamber, a Cu-3Ag-0.5Zr alloy (NARloy-Z) is degraded in service by blanching. Heretofore, evaluating a liner material for blanching resistance involved elaborate and expensive hot-fire tests performed on rocket test stands. To simplify that evaluation, researchers at the NASA Glenn Research Center developed a screening test that uses simple, in situ oxidation-reduction cycling in a thermogravimetric analyzer (TGA). The principle behind this test is that resistance to oxidation or to the reduction of oxide, or both, implies resistance to blanching. Using this test as a preliminary tool to screen alloys for blanching resistance can improve reliability and save time and money. In this test a small polished coupon is hung in a TGA furnace at the desired (service) temperature. Oxidizing and reducing gases are introduced cyclically, in programmed amounts. Cycle durations are chosen by calibration, such that all copper oxides formed by oxidation are fully reduced in the next reduction interval. The sample weight is continuously acquired by the TGA as usual.

Thomas-Ogbuji, Linus U.↗

DOE OSTI2024

Testing of Materials and Coatings at up to 1150°C and 300 bar for use in Oxy-Combustion Turbine

Various materials that may be used in a supercritical carbon dioxide (sCO2) oxy-fuel turbine in the 150-300 MWe size range are being evaluated in various environments of interest. The inlet of the turbine must be capable of 1,150 °C at 300 bar and the exhaust temperature is expected to be within the 725-775 °C range. The design requirements are pushing the known limits of high temperature materials. Little is known about the oxidation of the metallic alloys considered for turbine nozzles and blades or about the resilience of thermal management solutions, such as thermal barrier coatings (TBC), required to accommodate these high temperatures. The combinations of high temperature resistant materials and coatings must be tested in sCO2 to evaluate their reliability in an oxy-fuel turbine environment. A total of 13 alloys were chosen to be tested. They included bare samples, with nano deposited MCrAlY bond coat only, or with the addition of a TBC. A unique test facility was developed to expose those materials in sCO2 at up to 300 bar and 1150 °C for up to 5,000 hours. This was accomplished by placing an induction heater inside an autoclave to achieve those high temperature locally while the pressurized vessel is cooled externally. The specimens are weighed before and after exposure to determine the oxidation rate. The integrity, morphology, and composition of some of the coatings and thermally grown oxide will be investigated by scanning electron microscopy (SEM). This paper presents the up-to-date results of the testing coated and uncoated superalloys in sCO2 at up to 1150 °C and up to 300 bar performed at Southwest Research Institute.

Bocher, Florent↗

NASA NTRS2023

High-Pressure, Normal-Gravity Droplet Combustion Experimental Hardware

The High-Pressure, Trans-Critical (HPTC) 1-g Liquid Droplet Combustion Experiments will assess the autoignition and combustion of liquid fuel droplets at elevated temperatures and pressures. These experiments are being conducted at the NASA Glenn Research Center in a manner similar to experiments performed in Glenn’s Zero Gravity Research Facility (ZGF) using the B drop vehicle. The modification to the test capabilities of the ZGF experiments in the new experimental configuration will allow researchers to continue performing normal-gravity liquid droplet combustion experiments without requiring the use of the ZGF test equipment. These normal-gravity experiments will be conducted at lower pressures than in the ZGF because the pressure vessel for this setup is limited to a maximum working pressure of 7.74 atm (99.1 psig) at 366.5 K (200 °F). This experimental configuration will enable development of a similar capability for conducting high-pressure combustion and supercritical oxidation research on the International Space Station. Experiments will be conducted with the capability of altering the ambient pressure, temperature, and gas concentrations, as well as the fuel type for each test. For these experiments, the test vessel operates at pressures up to 7.5 atm (95.5 psig), temperatures up to 1,073 K (1,472 °F) inside the insulated oven, and oxygen concentrations up to 30 percent.

Droplet Combustion↗

DOE OSTI2020

Evaluation of Radiolysis Data for Hydrogen Gas Generation During Gamma Irradiation of Pre-Corroded and Pristine Aluminum Samples - An Aluminum SNF Dry Storage Study Interim Report

Information and data from radiolysis testing to measure hydrogen (H₂) generated from hydrated oxides on aluminum exposed to ⁶⁰Co radiation were reviewed to evaluate hydrogen generation with radiation dose. Hydrogen generation rate is a primary input to the coupled thermal-chemical system model of the performance of aluminum-clad spent nuclear fuel in a dry storage canister (ASNF-in-canister) over its storage life. Hydrogen generation data and hydrogen generation rate (hydrogen generated per absorbed radiation dose, $\Delta$(H₂)/$\Delta$(dose)) were reported in two reports for radiolysis testing [1, 2]. The testing involved first-time data¹ for radiolytic yield of hydrogen from hydrated-oxides-on-aluminum substrates, and from pristine (non-corroded) aluminum substrates. The laboratory-grown hydrated-oxides-on-aluminum substrates contained a ~ 5 μm film consisting of the trihydroxide bayerite (Al(OH)₃) with amounts of the oxyhydroxide boehmite (AlOOH). These specimens were assumed to also contain physisorbed water (unquantified). The pristine substrates were flat coupons of aluminum that were ground to a 600-grit finish but were not immersed in water to grow a hydrated oxide. The pristine substrates were tested as companion specimens to provide information on hydrogen generation from material without chemisorbed water and were assumed to contain physisorbed water (unquantified).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2020

Re-Additization of Commercial Biodiesel Blends During Long-Term Storage

Commercial biodiesel blends representative of the U.S. market were aged following procedure ASTM D4625, Standard Test Method for Middle Distillate Fuel Storage Stability at 43°C (110°F), with periodic monitoring of fuel properties indicative of oxidation. The oxidation stability—or oxidation reserve expressed as Rancimat induction period (IP)—gradually decreased from its initial value, as expected. At a predetermined IP threshold, an antioxidant was used to restore IP to the ASTM D7467 specification minimum of 6 six hours, referred to as re-additization. At lower IP values, the amount of antioxidant required increased significantly, and the effectiveness tended to be reduced. Once IP fell to essentially zero, the acid content increased to above the allowable limit. Insoluble material was detectable after the acid number increased out of specification. Storage life was increased with re-additization relative to the as-received fuels, as evidenced by longer time to produce acids. Experience in the field may vary based on storage conditions; however, these results indicate re-additization can significantly increase the storage life of biodiesel blends when used with regular monitoring of IP and acid number. An assessment of property changes during long-term storage showed the initial IP did not predict storage behavior, although fuels above the specification minimum remained stable for greater than 12 weeks of D4625 accelerated aging (1 one year simulated).

09 BIOMASS FUELS↗

DOE OSTI2024

Status report on HFIR irradiation of optimized alumina forming alloys

Properties of FeCrAl alloys under neutron irradiation are of interest because of these materials’ potential application as accident-tolerant fuel cladding in nuclear systems. In parallel, alumina-forming austenitic (AFA) alloys are of interest for use as structural materials in advanced nuclear systems for their potential higher resistance to embrittlement and high-temperature steam oxidation resistance. An irradiation campaign for fiscal year 2024 has been developed under the Advanced Fuels Campaign to perform irradiation testing of various FeCrAl and AFA alloys in Oak Ridge National Laboratory’s High Flux Isotope Reactor (HFIR). The goals of this irradiation campaign are to (1) study the impact of minor alloying elements on the neutron-irradiated mechanical properties of FeCrAl alloys and (2) collect neutron-irradiated mechanical properties on AFA alloys for comparison with those of FeCrAl alloys. This campaign will include both tensile and fracture toughness specimens tested following HFIR irradiation at temperatures representative of normal operating conditions in light-water reactors. The pre-irradiation characterization to date, the irradiation plan for the FeCrAl and AFA specimens, and the subsequent post-irradiation experimental test plan are presented in this report, along with the status of HFIR builds and scheduled insertion dates.

36 MATERIALS SCIENCE↗

NASA NTRS1972

Space simulation experiments on reaction control system thruster plumes.

A space simulation procedure was developed for studying rocket plume contamination effects using a 5-lb bipropellant reaction control system thrustor. Vacuum chamber pressures of 0.00003 torr (70 miles altitude) were achieved with the thrustor firing in pulse trains consisting of eight pulses - 50 msec on, 100 msec off, and seven minutes between pulse trains. The final vacuum was achieved by cooling all vacuum chamber surfaces to liquid-helium temperature and by introducing a continuous argon leak of 48 std. cc/sec into the test chamber. Fast time response liquid flow rate measurements showed that large variations occurred in the ratio of oxidizer to fuel flow for pulse-on times up to 120 msec. These variations could lead to poor combustion efficiency and the production of contamination.

Cassidy, J. F.↗

NASA NTRS1981

Space Shuttle main engine performance assessment - Columbia's first flight

Design features and performance of the Shuttle main engines first flight are presented. Each of the three engines produces 470,000 lb of thrust, operates at 3,012 psia, and has a 77.5 to 1 nozzle expansion ratio. The engines are designed for a 7.5 hr operational life, and will be tested at 109% capacity in future Shuttle flights. The developmental program is outlined, and includes 127,000 sec of operational testing on 19 engines. Engine operations and components are described, noting 100% burning of the hydrogen and oxidizer, high pressure fuel turbopumps, the controller assembly, etc.; details of solutions to fatigue failures and subsequent certification are provided. The nine minute first flight firing revealed a radiant heating of a control sensor transducer, which was shielded for succeeding flights. Alternatives are given for thrust augmentation, for which each 1% yields an additional 800 lb payload increase capability, and can be implemented by 1987.

Thompson, J. R., Jr.↗

NASA NTRS1986

Long term deposit formation in aviation turbine fuel at elevated temperature

An experimental characterization is conducted for the relationships between deposit mass, operating time, and temperature, in coking associated with aviation fuels under conditions simulating those typical of turbine engine fuel systems. Jet A and Suntech A fuels were tested in stainless steel tubing heated to 420-750 K, over test durations of between 3 and 730 hr and at fuel velocities of 0.07-1.3 m/sec. Deposit rates are noted to be a strong function of tube temperature; for a given set of test conditions, deposition rates for Suntech A exceed those of Jet A by a factor of 10. Deposition rates increased markedly with test duration for both fuels. The heated tube data obtained are used to develop a global chemical kinetic model for fuel oxidation and carbon deposition.

Giovanetti, A. J.↗

NASA NTRS2022

Liquid Nitrogen Testing of an Integrated Reaction Control System

Integrated Reaction Control Systems (IRCS) are considered an enabling technology for future human exploration of the solar system. An IRCS uses the same fuel and oxidizer as the main propulsion system, allowing for increased performance and simplified cryogenic fluid management operations. The IRCS team at Marshall Spaceflight Center is currently evaluating an IRCS system that uses a combination of electric pumps and pressure-regulation devices to provide a constant flow of conditioned propellant to a thruster bank during operation. In contrast to accumulator and gasifier designs, the recirculation loop design is less massive and can provide large, sustained flowrates to the thruster inlet. In the summer 2021 test series presented herein, the feasibility of this concept was evaluated using liquid nitrogen as a simulant for liquid oxygen. The goals of this test series were to demonstrate the ability of the pump and pressure regulator to maintain adequate thruster inlet conditions during transient operation, and to demonstrate the ability for the system to operate in an “idle mode” that maintains system chill between activations. During test operations, the back-pressure regulator responded more slowly than the opening/closing of valves in the thruster simulant, but it was still able to attenuate the pressure fluctuation at the pump discharge and ensure a stable flowrate through the pump. Similarly, the pump was able to be run far below its nominal operating point and successfully flow sufficient fluid to maintain chill conditions.

RCS↗

NASA NTRSDate not supplied

Liquid Nitrogen Testing of An Integrated Reaction Control System

Integrated Reaction Control Systems (IRCS) are considered an enabling technology for future human exploration of the solar system. An IRCS uses the same fuel and oxidizer as the main propulsion system, allowing for increased performance and simplified cryogenic fluid management operations. The IRCS team at Marshall Spaceflight Center is currently evaluating an IRCS system that uses a combination of electric pumps and pressure-regulation devices to provide a constant flow of conditioned propellant to a thruster bank during operation. In contrast to accumulator and gasifier designs, the recirculation loop design is less massive and can provide large, sustained flowrates to the thruster inlet. In the summer 2021 test series presented herein, the feasibility of this concept was evaluated using liquid nitrogen as a simulant for liquid oxygen. The goals of this test series were to demonstrate the ability of the pump and pressure regulator to maintain adequate thruster inlet conditions during transient operation, and to demonstrate the ability for the system to operate in an “idle mode” that maintains system chill between activations. During test operations, the back-pressure regulator responded more slowly than the opening/closing of valves in the thruster simulant, but it was still able to attenuate the pressure fluctuation at the pump discharge and ensure a stable flowrate through the pump. Similarly, the pump was able to be run far below its nominal operating point and successfully flow sufficient fluid to maintain chill conditions.

RCS↗

NASA NTRSDate not supplied

Liquid Nitrogen Testing of an Integrated Reaction Control System

Integrated Reaction Control Systems (IRCS) are considered an enabling technology for future human exploration of the solar system. An IRCS uses the same fuel and oxidizer as the main propulsion system, allowing for increased performance and simplified cryogenic fluid management operations. The IRCS team at Marshall Spaceflight Center is currently evaluating an IRCS system that uses a combination of electric pumps and pressure-regulation devices to provide a constant flow of conditioned propellant to a thruster bank during operation. In contrast to accumulator and gasifier designs, the recirculation loop design is less massive and can provide large, sustained flowrates to the thruster inlet. In the summer 2021 test series presented herein, the feasibility of this concept was evaluated using liquid nitrogen as a simulant for liquid oxygen. The goals of this test series were to demonstrate the ability of the pump and pressure regulator to maintain adequate thruster inlet conditions during transient operation, and to demonstrate the ability for the system to operate in an “idle mode” that maintains system chill between activations. During test operations, the back-pressure regulator responded more slowly than the opening/closing of valves in the thruster simulant, but it was still able to attenuate the pressure fluctuation at the pump discharge and ensure a stable flowrate through the pump. Similarly, the pump was able to be run far below its nominal operating point and successfully flow sufficient fluid to maintain chill conditions.

integrated RCS↗

NASA NTRSDate not supplied

Liquid Nitrogen Testing of an Integrated Reaction Control System

Integrated Reaction Control Systems (IRCS) are considered an enabling technology for future human exploration of the solar system. An IRCS uses the same fuel and oxidizer as the main propulsion system, allowing for increased performance and simplified cryogenic fluid management operations. The IRCS team at Marshall Spaceflight Center is currently evaluating an IRCS system that uses a combination of electric pumps and pressure-regulation devices to provide a constant flow of conditioned propellant to a thruster bank during operation. In contrast to accumulator and gasifier designs, the recirculation loop design is less massive and can provide large, sustained flowrates to the thruster inlet. In the summer 2021 test series presented herein, the feasibility of this concept was evaluated using liquid nitrogen as a simulant for liquid oxygen. The goals of this test series were to demonstrate the ability of the pump and pressure regulator to maintain adequate thruster inlet conditions during transient operation, and to demonstrate the ability for the system to operate in an “idle mode” that maintains system chill between activations. During test operations, the back-pressure regulator responded more slowly than the opening/closing of valves in the thruster simulant, but it was still able to attenuate the pressure fluctuation at the pump discharge and ensure a stable flowrate through the pump. Similarly, the pump was able to be run far below its nominal operating point and successfully flow sufficient fluid to maintain chill conditions.

integrated RCS↗

NASA NTRS2013

Wireless Integrated Microelectronic Vacuum Sensor System

NASA Stennis Space Center's (SSC's) large rocket engine test facility requires the use of liquid propellants, including the use of cryogenic fluids like liquid hydrogen as fuel, and liquid oxygen as an oxidizer (gases which have been liquefied at very low temperatures). These fluids require special handling, storage, and transfer technology. The biggest problem associated with transferring cryogenic liquids is product loss due to heat transfer. Vacuum jacketed piping is specifically designed to maintain high thermal efficiency so that cryogenic liquids can be transferred with minimal heat transfer. A vacuum jacketed pipe is essentially two pipes in one. There is an inner carrier pipe, in which the cryogenic liquid is actually transferred, and an outer jacket pipe that supports and seals the vacuum insulation, forming the "vacuum jacket." The integrity of the vacuum jacketed transmission lines that transfer the cryogenic fluid from delivery barges to the test stand must be maintained prior to and during engine testing. To monitor the vacuum in these vacuum jacketed transmission lines, vacuum gauge readings are used. At SSC, vacuum gauge measurements are done on a manual rotation basis with two technicians, each using a handheld instrument. Manual collection of vacuum data is labor intensive and uses valuable personnel time. Additionally, there are times when personnel cannot collect the data in a timely fashion (i.e., when a leak is detected, measurements must be taken more often). Additionally, distribution of this data to all interested parties can be cumbersome. To simplify the vacuum-gauge data collection process, automate the data collection, and decrease the labor costs associated with acquiring these measurements, an automated system that monitors the existing gauges was developed by Invocon, Inc. For this project, Invocon developed a Wireless Integrated Microelectronic Vacuum Sensor System (WIMVSS) that provides the ability to gather vacuum-gauge measurements automatically and wirelessly, in near-real time - using a low-maintenance, lowpower sensor mesh network. The WIMVSS operates by using a self-configuring mesh network of wireless sensor units. Mesh networking is a type of networking where each sensor or node can capture and disseminate its own data, but also serve as a relay to receive and transmit data from other sensors. Each sensor node can synchronize with adjacent sensors, and propagate data from one sensor to the next, until the destination is reached. In this case, the destination is a Network Interface Unit (NIU). The WIMVSS sensors are mounted on the existing vacuum gauges. Information gathered by the sensors is sent to the NIU. Because of the mesh networking, if a sensor cannot directly send the data to the NIU, it can be propagated through the network of sensors. The NIU requires antenna access to the sensor units, AC power, and an Ethernet connection. The NIU bridges the sensor network to a WIMVSS server via an Ethernet connection. The server is configured with a database, a Web server, and proprietary interface software that makes it possible for the vacuum measurements from vacuum jacketed fluid lines to be saved, retrieved, and then displayed from any Web-enabled PC that has access to the Internet. Authorized users can then simply access the data from any PC with Internet connection. Commands can also be sent directly from the Web interface for control and maintenance of the sensor network. The technology enabled by the WIMVSS decreases labor required for gathering vacuum measurements, increases access to vacuum data by making it available on any computer with access to the Internet, increases the frequency with which data points can be acquired for evaluating the system, and decreases the recurring cost of the sensors by using off-the-shelf components and integrating these with heritage vacuum gauges.

Krug, Eric↗

NASA NTRS1992

Low thrust chemical rocket technology

An on-going technology program to improve the performance of low thrust chemical rockets for spacecraft on-board propulsion applications is reviewed. Improved performance and lifetime is sought by the development of new predictive tools to understand the combustion and flow physics, introduction of high temperature materials and improved component designs to optimize performance, and use of higher performance propellants. Improved predictive technology is sought through the comparison of both local and global predictions with experimental data. Predictions are based on both the RPLUS Navier-Stokes code with finite rate kinetics and the JANNAF methodology. Data were obtained with laser-based diagnostics along with global performance measurements. Results indicate that the modeling of the injector and the combustion process needs improvement in these codes and flow visualization with a technique such as 2-D laser induced fluorescence (LIF) would aid in resolving issues of flow symmetry and shear layer combustion processes. High temperature material fabrication processes are under development and small rockets are being designed, fabricated, and tested using these new materials. Rhenium coated with iridium for oxidation protection was produced by the Chemical Vapor Deposition (CVD) process and enabled an 800 K increase in rocket operating temperature. Performance gains with this material in rockets using Earth storable propellants (nitrogen tetroxide and monomethylhydrazine or hydrazine) were obtained through component redesign to eliminate fuel film cooling and its associated combustion inefficiency while managing head end thermal soakback. Material interdiffusion and oxidation characteristics indicated that the requisite lifetimes of tens of hours were available for thruster applications. Rockets were designed, fabricated, and tested with thrusts of 22, 62, 440 and 550 N. Performance improvements of 10 to 20 seconds specific impulse were demonstrated. Higher performance propellants were evaluated: Space storable propellants, including liquid oxygen (LOX) as the oxidizer with nitrogen hydrides or hydrocarbon as fuels. Specifically, a LOX/hydrazine engine was designed, fabricated, and shown to have a 95 pct theoretical c-star which translates into a projected vacuum specific impulse of 345 seconds at an area ratio of 204:1. Further performance improvment can be obtained by the use of LOX/hydrogen propellants, especially for manned spacecraft applications, and specific designs must be developed and advanced through flight qualification.

Schneider, Steven J.↗