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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Reaction Diffusion Modelling of 3D Pillar Electrodes in Single-Catalyst CO 2 Reduction Cascades

Effective electrochemical CO 2 reduction to liquid fuels requires that the local catalytic environment facilitates the desired reactivity, yet a microscopic understanding of this environment is difficult to achieve from experiment alone. In this work, a 3D reaction-diffusion model was developed to explore the effects of electrode surface area and local geometry on the performance of a heterogeneous catalyst that performs a two-step CO 2 reduction cascade reaction to CO and then CH 3 OH under aqueous conditions. Kinetic parameters for the model were inspired by experimental results using a cobalt phthalocyanine (CoPc) catalyst. Three-dimensional architectures composed of arrays of square pillars with varying dimensions and either smooth or periodically modulated surfaces were tested, revealing the extent to which geometry modulates the performance of the cascade reactions. Although structural variations modulate local concentration gradients, we find that electrochemically active surface area predominantly governs the overall cascade reaction. Moreover, the results suggest that supersaturation of CO, with concentrations up to ten-fold higher than the equilibrium solubility limit, might be critical for more efficient conversion to CH 3 OH. For any given geometry, the spatially averaged ratio of [CO] to [CO 2 ] is dictated by the electrochemically active surface area and determines the yield of CH 3 OH. For a fixed surface area, geometries that spatially confine the electrolyte yield moderate local [CO] to [CO 2 ] ratios within small volumes. In contrast, less confining geometries result in a broader distribution of local ratios spread over larger volumes, with both configurations yielding the same spatially averaged [CO] to [CO 2 ] ratio. These insights provide valuable design principles—highlighting the critical importance of surface area and possibly CO supersaturation—for engineering advanced electrode architectures that leverage intermediate trapping and CO supersaturation to enhance overall performance in tandem CO 2 reduction systems.

COMSOL↗
NASA NTRS1979

The space transportation system

Design features of the Space Shuttle orbiter vehicle, main engine, solid rocket booster, external tank, and inertial and spinning solid upper stages are presented. Space Shuttle facilities at Kennedy Space Center are discussed, together with the long duration exposure facility, a reusable, unmanned gravity-gradient stabilized, free-flying structure which can accomodate both active and passive experiments requiring long-term space exposure. Standard and optional Shuttle services are outlined, and preliminary flight assignments are described.

Hamon, W. J.↗
NASA NTRS1980

Spherical harmonic analysis of a synoptic climatology generated with a global general circulation model

Spherical harmonic analysis was used to analyze the observed climatological (C) fields of temperature at 850 mb, geopotential height at 500 mb, and sea level pressure. The spherical harmonic method was also applied to the corresponding "model climatological" fields (M) generated by a general circulation model, the "GISS climate model." The climate model was initialized with observed data for the first of December 1976 at 00. GMT and allowed to generate five years of meteorological history. Monthly means of the above fields for the five years were computed and subjected to spherical harmonic analysis. It was found from the comparison of the spectral components of both sets, M and C, that the climate model generated reasonable 500 mb geopotential heights. The model temperature field at 850 mb exhibited a generally correct structure. However, the meridional temperature gradient was overestimated and overheating of the continents was observed in summer.

Christidis, Z. D.↗
NASA NTRS1980

Development of a composite geodetic structure for space construction, phase 1A

The development of a geodetic beam and beam builder for on orbit construction of large truss type space structures is discussed. The geodetic beam is a lightweight, open lattice structure composed of an equilateral gridwork of crisscrossing rods. The beam provides a high degree of stiffness and minimizes structural distortion, due to temperature gradients, through the incorporation of a new graphite and glass reinforced thermoplastic composite material with a low coefficient of thermal expansion. A low power consuming, high production rate, beam builder automatically fabricates the geodetic beams in space using rods preprocessed on Earth. Three areas of the development are focused upon; (1) geodetic beam designs for local attachment of equipment or beam to beam joining in a parallel or crossing configurations, (2) evaluation of long life pultruded rods capable of service temperatures higher than possible with the HMS/P1700 rod material, and (3) evalaution of high temperature joint encapsulant materials.

Source record↗
NASA NTRS1981

Organized motion in turbulent flow

A review of organized motion in turbulent flow indicates that the transport properties of most shear flows are dominated by large-scale vortex nonrandom motions. The mean velocity profile of a turbulent boundary layer consists of a viscous sublayer, buffer layer, and a logarithmic outer layer; an empirical formula of Coles (1956) applies to various pressure gradients. The boundary layer coherent structure was isolated by the correlation methods of Townsend (1956) and flow visualization by direct observations of complex unsteady turbulent motions. The near-wall studies of Willmart and Wooldridge (1962) used the space-time correlation for pressure fluctuations at the wall under a thick turbulent boundary layer; finally, organized motion in free shear flows and transition-control of mixing demonstrated that the Reynolds number invariance of turbulence shows wide scatter.

Cantwell, B. J.↗
NASA NTRS1984

A Research Program in Active Control/aeroelasticity

Research activities concerning active control aeroelasticity are discussed. In aeroservoelastic system design of a flexible aircraft, it is often necessary to obtain specified steady state structural dynamic response and to maintain stability margins at both the plant (aircraft) input and output. The research during the present period is discussed. Steady state structural dynamic response constraints and gradients were formulated. Incorporation of the design software as an update to the PADLOCS synthesis software was examined. The stability margin improvement technique at both the plant input and output using singular value properties and constrained optimization method was validated.

Source record↗
NASA NTRS1986

MHD waves detected by ICE at distances greater than or = 28 million km from Comet Halley: Cometary or solar wind origin?

Spectral analyses of the high resolution magnetic field data are employed to determine if there is evidence of cometary heavy ion pickup when ICE was closest to Halley. No evidence for the presence of heavy ion cyclotron waves is found. However, two wave modes are discovered in the solar wind: electromagnetic ion cyclotron waves and drift mirror mode waves. Both modes have scales of 10 to 60 s (1 to 6 Tp) in the spacecraft frame. The possibility of wave generation by cometary hydrogen pickup is explored. Theoretical and experimental evidence indicates that cometary origin is improbable. The most likely source is plasma instabilities associated with solar wind stream-stream interactions. Very low frequency electrostatic emissions occur in field minima or at gradients of the drift mirror structures. Possible generation mechanisms of drift mirror mode waves, cyclotron waves, and electrostatic waves are discussed.

Tsurutani, B. T.↗
NASA NTRS1989

A Survey of Measurements and Measuring Techniques in Rapidly Distorted Compressible Turbulent Boundary Layers

A wide range of recent work on compressible turbulent boundary layers is described. Special attention was paid to flows with rapid changes in pressure including flows with shock waves, curved walls, and expansions. The application of rapid distortion theory to flows transversing expansion and shock waves is reviewed. This is followed by an account of experiments aimed at elucidating the large scale structures present in supersonic boundary layers. The current status of laser-Doppler and hot-wire anemometry in supersonic flow is discussed, and a new interferometric technique for the determination of wall-stress is described. The use of small pressure transducers to deduce information about the structure of zero pressure-gradient and severely perturbed boundary layers is investigated. Finally, there is an extension of the data presentation of AGARDographs 223, 253 and 263 to cover rapidly distorted boundary layers.

Fernholz, H. H.↗
NASA NTRS1996

Stratospheric Meteorological Conditions for the 3-12 Nov. 1994 ATMOS/ATLAS-3 Measurements

During the ATLAS-3 mission (3-12 Nov 1994), United Kingdom Meteorological Office fields show that the SH vortex was still strong below about 700 K (approximately 16 hPa), with coherent vortex fragments apparent up to about 1300 K (approximately 3 hPa). The SH vortex was shifted off the pole toward 270 deg E throughout ATLAS-3, although its shape varied from day to day. SH temperatures were increasing during ATLAS-3; temperatures below 188 K were last seen 35-45 days before the mission, but were below 195 K as late as 2 Nov 1994. The NH polar vortex had developed at levels above about 550 K (approximately 35 hPa). Simulated high-resolution potential vorticity (PV) fields clearly show low latitude air being drawn up around the polar vortices in both hemispheres. These fields indicate that meteorological analyses underestimate the amount of atmospheric variability, including the strength of local PV gradients, and small-scale structure. Structure such as that in the simulated fields can result in apparent discrepancies between tracer measurements and PV fields.

Manney, G. L.↗
NASA NTRS1998

Low Dissipative High Order Shock-Capturing Methods using Characteristic-Based Filters

An approach which closely maintains the non-dissipative nature of classical fourth or higher- order spatial differencing away from shock waves and steep gradient regions while being capable of accurately capturing discontinuities, steep gradient and fine scale turbulent structures in a stable and efficient manner is described. The approach is a generalization of the method of Gustafsson and Olsson and the artificial compression method (ACM) of Harten. Spatially non-dissipative fourth or higher-order compact and non-compact spatial differencings are used as the base schemes. Instead of applying a scalar filter as in Gustafsson and Olsson, an ACM like term is used to signal the appropriate amount of second or third-order TVD or ENO types of characteristic based numerical dissipation. This term acts as a characteristic filter to minimize numerical dissipation for the overall scheme. For time-accurate computations, time discretizations with low dissipation are used. Numerical experiments on 2-D vortical flows, vortex-shock interactions and compressible spatially and temporally evolving mixing layers showed that the proposed schemes have the desired property with only a 10% increase in operations count over standard second-order TVD schemes. Aside from the ability to accurately capture shock-turbulence interaction flows, this approach is also capable of accurately preserving vortex convection. Higher accuracy is achieved with fewer grid points when compared to that of standard second-order TVD or ENO schemes. To demonstrate the applicability of these schemes in sustaining turbulence where shock waves are absent, a simulation of 3-D compressible turbulent channel flow in a small domain is conducted.

Yee, H. C.↗
NASA NTRS1998

Low Dissipative High Order Shock-Capturing Methods Using Characteristic-Based Filters

An approach which closely maintains the non-dissipative nature of classical fourth or higher- order spatial differencing away from shock waves and steep gradient regions while being capable of accurately capturing discontinuities, steep gradient and fine scale turbulent structures in a stable and efficient manner is described. The approach is a generalization of the method of Gustafsson and Oisson and the artificial compression method (ACM) of Harten. Spatially non-dissipative fourth or higher-order compact and non-compact spatial differencings are used as the base schemes. Instead of applying a scalar filter as in Gustafsson and Olsson, an ACM like term is used to signal the appropriate amount of second or third-order TVD or ENO types of characteristic based numerical dissipation. This term acts as a characteristic filter to minimize numerical dissipation for the overall scheme. For time-accurate computations, time discretizations with low dissipation are used. Numerical experiments on 2-D vortical flows, vortex-shock interactions and compressible spatially and temporally evolving mixing layers showed that the proposed schemes have the desired property with only a 10% increase in operations count over standard second-order TVD schemes. Aside from the ability to accurately capture shock-turbulence interaction flows, this approach is also capable of accurately preserving vortex convection. Higher accuracy is achieved with fewer grid points when compared to that of standard second-order TVD or ENO schemes. To demonstrate the applicability of these schemes in sustaining turbulence where shock waves are absent, a simulation of 3-D compressible turbulent channel flow in a small domain is conducted.

Yee, H. C.↗
DOE OSTI2021

Test Results of a High-Gradient 2.856-GHz Negative Harmonic Accelerating Waveguide

We report the high-gradient tests results of a novel traveling wave accelerating structure for β=0.3 based on a novel approach of operating at the first negative spatial harmonic. Accelerating gradients of 50 MV/m and peak electric fields of 160 MV/m were achieved in a single structure consisting of 15 coupled cells during tests at the advanced photon source. This work was performed by RadiaBeam, in collaboration with the Argonne National Laboratory, as a part of a Research and Development Program for the development of an ultrahigh-gradient linear accelerator, the Advanced Compact Carbon Ion Linac, for hadron therapy.

42 ENGINEERING↗
DOE OSTI2023

Correlating Rate-Dependent Transition Metal Dissolution between Structure Degradation in Li-Rich Layered Oxides

Understanding the mechanism of the rate-dependent electrochemical performance degradation in cathodes is crucial to developing fast charging/discharging cathodes for Li-ion batteries. Here, in this work, taking Li-rich layered oxide Li 1.2 Ni 0.13 Co 0.13 Mn 0.54 O 2 as the model cathode, the mechanisms of performance degradation at low and high rates are comparatively investigated from two aspects, the transition metal (TM) dissolution and the structure change. Quantitative analyses combining spatial-resolved synchrotron X-ray fluorescence (XRF) imaging, synchrotron X–ray diffraction (XRD) and transmission electron microscopy (TEM) techniques reveal that low-rate cycling leads to gradient TM dissolution and severe bulk structure degradation within the individual secondary particles, and especially the latter causes lots of microcracks within secondary particles, and becomes the main reason for the fast capacity and voltage decay. In contrast, high-rate cycling leads to more TM dissolution than low-rate cycling, which concentrates at the particle surface and directly induces the more severe surface structure degradation to the electrochemically inactive rock-salt phase, eventually causing a faster capacity and voltage decay than low-rate cycling. These findings highlight the protection of the surface structure for developing fast charging/discharging cathodes for Li-ion batteries.

25 ENERGY STORAGE↗
DOE OSTI2025

Dual‐Gradient Construction on Li‐Rich Cathodes for High Stability Lithium Battery

Abstract The practical applications of high‐energy Li‐rich layered oxides (LLOs) have been hindered by the severe performance degradation including voltage decay and capacity fading. The gradient construction toward high‐activity interior and high‐stability exterior, typically realized by gradually changed transition metal (TM) gradient in LLOs, can alleviate the performance degradation to certain degrees. In this study, a gradient design of Al/Mg dopants is demonstrated for the TM‐gradient LLOs to further harmonize the high‐activity interior and high‐stability exterior, thereby forming the dual (TM and doping) gradient. As a result, superior capacity retention of 86% and a minor voltage decay of 0.54 mV cycle −1 are achieved at 1 C after 300 cycles. The improved electrochemical stability of the dual‐gradient LLO is attributed to the enhanced surface stability and suppressed bulk structure degeneration of LLOs upon electrochemical cycling. The dual‐gradient design serves as an important approach to fabricate high‐performance bulk LLOs toward applications.

Wu, Tianhao↗
DOE OSTI2020

Bulk and Nanocrystalline Cesium Lead-Halide Perovskites as Seen by Halide Magnetic Resonance

Lead-halide perovskites increasingly mesmerize researchers because they exhibit a high degree of structural defects and dynamics yet nonetheless offer an outstanding (opto)electronic performance on par with the best examples of structurally stable and defect-free semiconductors. This highly unusual feature necessitates the adoption of an experimental and theoretical mindset and the reexamination of techniques that may be uniquely suited to understand these materials. Surprisingly, the suite of methods for the structural characterization of these materials does not commonly include nuclear magnetic resonance (NMR) spectroscopy. The present study showcases both the utility and versatility of halide NMR and NQR (nuclear quadrupole resonance) for probing the structure and structural dynamics of CsPbX 3 (X = Cl, Br, I), in both bulk and nanocrystalline forms. The strong quadrupole couplings, which originate from the interaction between the large quadrupole moments of, e.g., the 35 Cl, 79 Br, and 127 I nuclei, and the local electric-field gradients, are highly sensitive to subtle structural variations, both static and dynamic. The quadrupole interaction can resolve structural changes with accuracies commensurate with synchrotron X-ray diffraction and scattering. It is shown that space-averaged site-disorder is greatly enhanced in the nanocrystals compared to the bulk, while the dynamics of nuclear spin relaxation indicates enhanced structural dynamics in the nanocrystals. The findings from NMR and NQR were corroborated by ab initio molecular dynamics, which point to the role of the surface in causing the radial strain distribution and disorder. These findings showcase a great synergy between solid-state NMR or NQR and molecular dynamics simulations in shedding light on the structure of soft lead-halide semiconductors.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Topological Dirac Semimetal Phase in Bismuth Based Anode Materials for Sodium-Ion Batteries

Bismuth has recently attracted interest in connection with Na-ion battery anodes due to its high volumetric capacity. It reacts with Na to form Na 3 Bi which is a prototypical Dirac semimetal with a nontrivial electronic structure. Density-functional-theory based first-principles calculations are playing a key role in understanding the fascinating electronic structure of Na 3 Bi and other topological materials. In particular, the strongly-constrained-and-appropriately-normed (SCAN) meta-generalized-gradient-approximation (meta-GGA) has shown significant improvement over the widely used generalized-gradient-approximation (GGA) scheme in capturing energetic, structural, and electronic properties of many classes of materials. Here, we discuss the electronic structure of Na 3 Bi within the SCAN framework and show that the resulting Fermi velocities and s-band shift around the Γ point are in better agreement with experiments than the corresponding GGA predictions. SCAN yields a purely spin-orbit-coupling (SOC) driven Dirac semimetal state in Na 3 Bi in contrast with the earlier GGA results. Our analysis reveals the presence of a topological phase transition from the Dirac semimetal to a trivial band insulator phase in Na 3 Bi x Sb 1-x alloys as the strength of the SOC varies with Sb content, and gives insight into the role of the SOC in modulating conduction properties of Na 3 Bi.

36 MATERIALS SCIENCE↗
NASA NTRS1978

LDEF/Shuttle capabilities for environmental testing in space

The Long Duration Exposure Facility (LDEF) is being developed to accommodate experiments which require a free-flying exposure in space and which benefit from postflight laboratory analysis of the retrieved experiment hardware. The first LDEF mission, which is planned for a 6- to 12-month stay in space is scheduled in the late 1970s during the Shuttle Orbital Flight Test Program. The LDEF is a simple reusable structure which is three-axis gravity gradient stabilized when free flying in space. The experiments on the LDEF are totally self-contained in trays mounted to the structure. After the LDEF is either revisited or retrieved by the Shuttle, the trays with experiments will be returned to the experimenters for postflight inspection. Attention is given to the fabrication of a second LDEF for a long-term mission planned in 1979, aspects of LDEF orbit life time, the radiation environment, questions of solar exposure, the thermal environment, and the vacuum (atomic particle) environment.

Clark, L. G.↗