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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

Predicted High-Pressure Hot Superconductivity in Li 2 CaH 16 and Li 2 CaH 17 Phases that Resemble the Type-II Clathrate Structure

High-temperature high-pressure superconducting hydrides are typically characterized by cage-like hydrogenic lattices filled with electropositive metal atoms. Here, density functional theory based evolutionary crystal structure searches find two phases that possess these geometric features and are related to the Type-II clathrate structure. In these Fd$\overline{3}$m Li 2 CaH 16 and R$\overline{3}$m Li 2 CaH 17 phases the calcium atom occupies the larger cage and the lithium atom the smaller one. The highest superconducting critical temperatures predicted within the isotropic Eliashberg formalism, 330 K at 350 GPa for Fd$\overline{3}$m Li 2 CaH 16 and 370 K at 300 GPa for R$\overline{3}$m Li 2 CaH 17 , suggest these structures are another example of hot superconducting hydrides. As pressure is lowered the cage-like lattices distort with the emergence of quasimolecular hydrogenic motifs; nonetheless Li 2 CaH 17 is predicted to be superconducting down to 160 GPa at 205 K.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Nuclear reactor radiation and temperature effects on piezoelectric surface acoustic wave devices

Surface acoustic wave (SAW) resonators were characterized in-situ in a nuclear reactor environment at high temperature. Devices based on lithium niobate (LiNbO 3 ), aluminum nitride (sc-AlN), and thin-film aluminum nitride on sapphire substrate (AlN/sapphire) were tested up to 400 °C temperature and 1.9 × 10 12 n/cm 2 s neutron flux. Shifts in device resonant frequency were detected in response to temperature and neutron flux. Devices undergo a frequency change when exposed to neutron flux. At 300 °C, AlN/sapphire produced the strongest neutron flux response about 1.02 ppm at 1.27 × 10 12 n/cm 2 s neutron flux (5.7 × 10 4 rad-Si/hr neutron dose rate), compared to 0.30 ppm for LiNbO 3 and 0.17 ppm for sc-AlN. While the transient kinetics in response to step change in neutron flux support the defect-accumulation mechanism, the concurrent measurement of device temperature using resistive temperature sensor suggests additional heating caused by absorption of gamma rays can also play a role. These results make SAW devices attractive candidates for sensor applications in extreme environments.

Aluminum nitride↗

Nanoscale Magnetic Ordering Dynamics in a High Curie Temperature Ferromagnet

Thermally driven transitions between ferromagnetic and paramagnetic phases are characterized by critical behavior with divergent susceptibilities, long-range correlations, and spin dynamics that can span kHz to GHz scales as the material approaches the critical temperature T c , but it has proven technically challenging to probe the relevant length and time scales with most conventional measurement techniques. In this study, we employ scanning nitrogen-vacancy center based magnetometry and relaxometry to reveal the critical behavior of a high-T c ferromagnetic oxide near its Curie temperature. Cluster analysis of the measured temperature-dependent nanoscale magnetic textures points to a 3D universality class with a correlation length that diverges near T c . Meanwhile, the temperature-dependent spin dynamics, measured through all optical relaxometry suggest that the phase transition is in the XY universality class. In conclusion, our results capture both static and dynamic aspects of critical behavior, providing insights into universal properties that govern phase transitions in magnetic materials.

36 MATERIALS SCIENCE↗

High-Temperature Extensometry and PdCr Temperature-Compensated Wire Resistance Strain Gages Compared

A detailed experimental evaluation is underway at the NASA Lewis Research Center to compare and contrast the performance of the PdCr/Pt dual-element temperature-compensated wire resistance strain gage with that of conventional high-temperature extensometry. The advanced PdCr gage, developed by researchers at Lewis, exhibits desirable properties and a relatively small and repeatable apparent strain to 800 C. This gage represents a significant advance in technology because existing commercial resistance strain gages are not reliable for quasi-static strain measurements above approx. 400 C. Various thermal and mechanical loading spectra are being applied by a high-temperature thermomechanical uniaxial testing system to evaluate the two strain-measurement systems. This is being done not only to compare and contrast the two strain sensors, but also to investigate the applicability of the PdCr strain gage to the coupon-level specimen testing environment typically employed when the high-temperature mechanical behavior of structural materials is characterized. Strain measurement capabilities to 800 C are being investigated with a nickel-base superalloy, Inconel 100 (IN 100), substrate material and application to TMC's is being examined with the model system, SCS-6/Ti-15-3. Furthermore, two gage application techniques are being investigated in the comparison study: namely, flame-sprayed and spot welding. The apparent strain responses of both the weldable and flame-sprayed PdCr wire strain gages were found to be cyclically repeatable on both IN 100 and SCS-6/Ti-15-3 [0]_8. In general, each gage exhibited some uniqueness with respect to apparent strain behavior. Gages mounted on the IN 100 specimens tended to show a repeatable apparent strain within the first few cycles, because the thermal response of IN 100 was stable. This was not the case, however, for the TMC specimens, which typically required several thermal cycles to stabilize the thermal strain response. Thus, progressive changes in the apparent strain behavior were corroborated by the extensometer, which unlike the mounted gage can distinguish quantitative changes in the material's thermal strain response. One specimen was instrumented with both a fixed and floating gage. From the difference in output of these two gages, the thermal expansion strains were calculated. These data, which are given in the figure, show excellent agreement with the values measured by the high-temperature extensometry.

Source record↗

Department of Transportation PHMSA Aerosol Spray Project: Phase-0

This report discusses the work conducted at Sandia National Laboratories during the preliminary phase (Phase-0) of the Department of Transportation (DOT) Pipeline and Hazardous Materials Safety Administration (PHMSA) project tasked to better understand what happens to a high-pressure liquid canister or vessel during a fire in which an accidental instantaneous release occurs. Phase 0 had two main objects: (1) to establish a methodology for the high temperature and pressure spray vessel release and (2) to characterize the spray droplet formation. For this test series, diagnostic equipment such as the Malvern Spraytec, high-speed photometric cameras, pencil gauges, and thermocouples were used. Additionally, the effect of surface tension on the particle size distribution was evaluated with 1-liter of distilled water and with the same including the addition of 0.5% soap/water mixture. Results from this effort indicated that the plume formed from the instantaneous release in all conditions primarily included two distinct particle size distributions including 217-312µm and 0.53µm on average. Soapy water formed a higher concentration of smaller mist (0.53µm) than distilled water, potentially due to decreased surface tension with the added surfactant. Though results showed good correlation to certain particle size distributions it is encouraged to conduct additional tests like this with a wider range of liquids with different properties, which could affect the overall particle size distribution when released.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Empirical Study of the Multiaxial, Thermomechanical Behavior of NiTiHf Shape Memory Alloys

An empirical study was conducted to characterize the multiaxial, thermomechanical responses of new high temperature NiTiHf alloys. The experimentation included loading thin walled tube Ni(sub 50.3)Ti(sub 29.7)Hf(sub 20) alloy samples along both proportional and nonproportional axial-torsion paths at different temperatures while measuring surface strains using stereo digital image correlation. A Ni(sub 50.3)Ti(sub 33.7)Hf(sub 16) alloy was also studied in tension and compression to document the effect of slightly depleting the Hf content on the constitutive responses of NiTiHf alloys. Samples of both alloys were made from nearly texture free polycrystalline material processed by hot extrusion. Analysis of the data shows that very small changes in composition significantly alter NiTiHf alloy properties, as the austenite finish (Af) temperature of the 16-at Hf alloy was found to be approximately 60 C less than the 20-at Hf alloy (approximately 120 C vs. 180 C). In addition, the 16-at Hf alloy exhibited smaller compressive transformation strains (2 vs. 2.5 percent). Multi-axial characterization of the 20-at % Hf alloy showed that while the random polycrystal transformation strains in tension (4 percent) and compression (2.5 percent) are modest in comparison with binary NiTi (6 percent, 4 percent), the torsion performance is superior (7 vs. 4 shear strain width to the pseudoelastic plateau).

tensile deformation↗

Application of thermal life prediction model to high-temperature aerospace alloys B1900+Hf and Haynes 188

The results of the application of a newly proposed thermomechanical fatigue (TMF) life prediction method to a series of laboratory TMF results on two high-temperature aerospace engine alloys are presented. The method, referred to as TMF/TS-SRP, is based on three relatively recent developments: the total strain version of the method of Strainrange Partitioning (TS-SRP), the bithermal testing technique for characterizing TMF behavior, and advanced viscoplastic constitutive models. The high-temperature data reported in a companion publication are used to evaluate the constants in the model and to provide the TMF verification data to check its accuracy. Predicted lives are in agreement with the experimental lives to within a factor of approximately 2.

Halford, Gary R.↗

The violent interstellar medium

Observational evidence for high-velocity and high-temperature interstellar gas is reviewed. The physical processes that characterize this gas are described, including the ionization and emissivity of coronal gas, the behavior and appearance of high-velocity shocks, and interfaces between coronal gas and cooler interstellar gas. Hydrodynamical models for the action of supernova explosions and stellar winds on the interstellar medium are examined, and recent attempts to synthesize all the processes considered into a global model for the interstellar medium are discussed.

Mccray, R.↗

Attachment of Free Filament Thermocouples for Temperature Measurements on CMC

Ceramic Matrix Composites (CMC) are being developed for use as enabling materials for advanced aeropropulsion engine and high speed civil transport applications. The characterization and testing of these advanced materials in hostile, high-temperature environments require accurate measurement of the material temperatures. Commonly used wire Thermo-Couples (TC) can not be attached to this ceramic based material via conventional spot-welding techniques. Attachment of wire TC's with commercially available ceramic cements fail to provide sufficient adhesion at high temperatures. While advanced thin film TC technology provides minimally intrusive surface temperature measurement and has good adhesion on the CMC, its fabrication requires sophisticated and expensive facilities and is very time consuming. In addition, the durability of lead wire attachments to both thin film TC's and the substrate materials requires further improvement. This paper presents a newly developed attachment technique for installation of free filament wire TC's with a unique convoluted design on ceramic based materials such as CMC's. Three CMC's (SiC/SiC CMC and alumina/alumina CMC) instrumented with type IC, R or S wire TC's were tested in a Mach 0.3 burner rig. The CMC temperatures measured from these wire TC's were compared to that from the facility pyrometer and thin film TC's. There was no sign of TC delamination even after several hours exposure to 1200 C. The test results proved that this new technique can successfully attach wire TC's on CMC's and provide temperature data in hostile environments. The sensor fabrication process is less expensive and requires very little time compared to that of the thin film TC's. The same installation technique/process can also be applied to attach lead wires for thin film sensor systems.

Lei, Jih-Fen↗

Application of a thermal fatigue life prediction model to high-temperature aerospace alloys B1900 + Hf and Haynes 188

The results of the application of a newly proposed thermomechanical fatigue (TMF) life prediction method to a series of laboratory TMF results on two high-temperature aerospace engine alloys are presented. The method, referred to as TMF/TS-SRP, is based on three relatively recent developments: the total strain version of the method of Strain Range Partitioning (TS-SRP), the bithermal testing technique for characterizing TMF behavior, and advanced viscoplastic constitutive models. The high-temperature data reported in a companion publication are used to evaluate the constants in the model and to provide the TMF verification data to check its accuracy. Predicted lives are in agreement with the experimental lives to within a factor of approximately 2.

Halford, G. R.↗

Experimental and Numerical Characterization of a Cylindrical Blackbody Cavity

During hypersonic flight, high temperatures and high heat fluxes are generated on the surfaces of vehicles. The Flight Loads Laboratory (FLL) at Dryden Flight Research Center (DFRC) is equipped with a calibration furnace, capable of calibrating heat flux gages up to 1100kW per square meters, and temperature sensors up to 2600 C. One heating configuration of the calibration furnace is a cylindrical blackbody cavity. Throughout the blackbody there are temperature gradients due to various boundary conditions. These boundary conditions include resistance heating, radiant heat transfer, and conduction to water-cooled electrodes. Also, an inert gas is purged through the graphite blackbody to prevent it from oxidizing. Consequently, the various modes of heat transfer present during operation of the blackbody cavity must be well understood in order to produce accurate heat flux gage and temperature sensor calibrations for use in ground testing or flight testing of hypersonic vehicles. The first step towards understanding the heat transfer in the blackbody cavity was to perform experiments at 1100 C, with and without outer surface insulation, while taking detailed temperature measurements inside the blackbody cavity. Steady state thermal models of the blackbody cavity were then developed. These models included detailed thermal analysis using commercial thermal analysis software. Conduction, radiation, and convection were considered in the thermal models for two cases: one with the outside of the blackbody cavity insulated and the second without insulation. This paper describes the experimental and numerical efforts used to characterize the steady state operation of the blackbody cavity. It describes the analysis of the test measurements, the boundary conditions used in the numerical models, and how the models were calibrated to fit the experimental data. Effects of various uncertainties, such as material properties, and convection are discussed.Initial thermal models predicted temperatures in the deepest part of the blackbody cavity within 7 C of the measured value and produced trends comparable to the experimental data, throughout the models. Adjustment of the boundary conditions, which were included in the thermal models, produced good agreement with measured temperatures. Free and forced convection of the purge gas inside the blackbody was found to be insignificant.

Abdelmessih, Amanie N.↗

Solar Thermochemical Redox Cycling Using Ga- and Al-Doped LSM Perovskites for Renewable Hydrogen Production

Solar thermochemical hydrogen production using redox-active metal oxides is a promising pathway for the production of green hydrogen and synthetic fuel precursors. Herein, the perovskite material (La 0.6 Sr 0.4 ) 0.95 Mn 0.8 Ga 0.2 O 3–δ (LSMG6482) is identified as a promising metal oxide for thermochemical water splitting. LSMG6482, along with more-established water splitters ceria and (La 0.6 Sr 0.4 ) 0.95 Mn x Al 1–x O 3–δ (LSMA) perovskites, is experimentally characterized via thermogravimetric (TGA) analysis and high-temperature water splitting in a reactor simulating solar concentrating conditions. TGA analysis demonstrated that LSMG6482 has high and stable oxygen exchange capacity under controlled pO 2 redox cycling, demonstrated by large changes in oxygen nonstoichiometry (δ) relative to ceria. Water splitting experiments using laser heating (T red = 1400 °C, T ox = 1200 °C) resulted in H 2 yields of 165.1 μmol g –1 for the candidate LSMG6482 composition, exceeding that of all benchmark materials tested. Under high conversion oxidation conditions, where H 2 is cointroduced with H 2 O (150 ≤ nH 2 O/nH 2 ≤ 500), H 2 yields were greatest for LSMG6482 and LSMA6482, up to four times that of ceria at the highest nH 2 O/nH 2 conditions. Crystallographic analysis showed that over the course of experimentation, there is some secondary phase growth for all perovskite compositions, except for LSMA6482, but there was no observable degradation in H 2 yields.

08 HYDROGEN↗

Observation of deuteron and antideuteron formation from resonance-decay nucleons

High-energy hadronic collisions generate environments characterized by temperatures above 100 MeV (refs.), about 100,000 times hotter than the centre of the Sun. At present, it is therefore unclear how light (anti)nuclei with mass number A of a few units, such as the deuteron, 3 He or 4 He, each bound by only a few MeV, can emerge from these collisions. Here, the ALICE Collaboration reports that deuteron–pion momentum correlations in proton–proton (pp) collisions provide model-independent evidence that about 90% of the observed (anti)deuterons are produced in nuclear reactions following the decay of short-lived resonances, such as the Δ(1232). These findings, obtained by the ALICE Collaboration at the Large Hadron Collider, resolve a gap in our understanding of nucleosynthesis in ultrarelativistic hadronic collisions. Apart from offering insights on how (anti)nuclei are formed in hadronic collisions, the results can be used in the modelling of the production of light and heavy nuclei in cosmic rays and dark-matter decays.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Magnetic Materials Research at SRNL

Introduction – What are Magnetic Materials? Magnetic materials are crystalline solids which below a certain temperature, known as the ordering temperature, display spontaneous order in their magnetic moments. Results • Enhanced thermal stability and saturation magnetization with Y substitution in Ce2Fe14B based permanent magnets • Discovered a new ferromagnetic phase transition at TC = 62.9 K in (Dy1/3Mo2/3)2AlC and validated the two previously reported low temperature magnetic phases Characterization of Magnetic Materials Raw high purity materials are melted together to synthesize a crystalline sample using an arc melter at Savannah River National Laboratory (SRNL). Use high energy ball milling to form a hard/soft magnetic composite using Y substituted Ce2Fe14B. Finish structural characterization on γ- irradiated (RE1/3Mo2/3)2AlC (RE = Rare Earth) MAX samples. Unit Cell Lattice Points

Bretana, Alex↗

Flow control valve

A flow control valve for high temperature fluids is disclosed. The valve is characterized by an all-metal flow control unit including a tubular conduit, terminating in a valve seat, a throttling cone having an internal, truncated conical surface coaxially related to the valve seat and supported for axial motion relative to the seat, and an axially reciprocable, flow-control plug supported in coaxial relation with the cone. The plug is provided with a truncated conical surface configured to be mated with the surface of the throttling cone for regulating a flow of fluid established through the unit and a curved shut-off surface.

Hays, L. G.↗

An overview of high temperature metal fatigue: Aspects covered by the 1973 International Conference on Creep and Fatigue

A summary of papers is presented which covers the following broad aspects of high temperature metal fatigue: (1) materials development and characterization; (2) environmental factors, including air, vacuum, helium, iodine, sodium, and radiation environments; (3) general fatigue life relationships; (4) crack growth laws; (5) design code activities; and (6) design and service experience. Illustrative tables accompany the summary.

Manson, S. S.↗

Space processing of composite materials

Materials and processes for the testing of aluminum-base fiber and particle composites, and of metal foams under extended-time low-g conditions were investigated. A wetting and dispersion technique was developed, based on the theory that under the absence of a gas phase all solids are wetted by liquids. The process is characterized by a high vacuum environment and a high temperature cycle. Successful wetting and dispersion experiments were carried out with sapphire fibers, whiskers and particles, and with fibers of silicon carbide, pyrolytic graphite and tungsten. The developed process and facilities permit the preparation of a precomposite which serves as sample material for flight experiments. Low-g processing consists then merely in the uniform redistribution of the reinforcements during a melting cycle. For the preparation of metal foams, gas generation by means of a thermally decomposing compound was found most adaptable to flight experiments. For flight experiments, the use of compacted mixture of the component materials limits low-g processing to a simple melt cycle.

Steurer, W. H.↗