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At least 289 records · Page 16

DART: Recent Advances in Remote Sensing Data Modeling With Atmosphere, Polarization, and Chlorophyll Fluorescence

To better understand the life-essential cycles and processes of our planet and to further develop remote sensing (RS) technology, there is an increasing need for models that simulate the radiative budget (RB) and RS acquisitions of urban and natural landscapes using physical approaches and considering the three-dimensional (3-D) architecture of Earth surfaces. Discrete anisotropic radiative transfer (DART) is one of the most comprehensive physically based 3-D models of Earth-atmosphere radiative transfer, covering the spectral domain from ultraviolet to thermal infrared wavelengths. It simulates the optical 3-DRB and optical signals of proximal, aerial, and satellite imaging spectrometers and laser scanners, for any urban and/or natural landscapes and for any experimental and instrumental configurations. It is freely available for research and teaching activities. In this paper, we briefly introduce DART theory and present recent advances in simulated sensors (LiDAR and cameras with finite field of view) and modeling mechanisms (atmosphere, specular reflectance with polarization and chlorophyll fluorescence). A case study demonstrating a novel application of DART to investigate urban landscapes is also presented.

Gastellu-Etchegorry, Jean-Phil↗

Comparison of 2.8- and 21-cm microwave radiometer observations over soils with emission model calculations

An airborne experiment was conducted under NASA auspices to test the feasibility of detecting soil moisture by microwave remote sensing techniques over agricultural fields near Phoenix, Arizona at midday of April 5, 1974 and at dawn of the following day. Extensive ground data were obtained from 96 bare, sixteen hectare fields. Observations made using a scanning (2.8 cm) and a nonscanning (21 cm) radiometer were compared with the predictions of a radiative transfer emission model. It is shown that (1) the emitted intensity at both wavelengths correlates best with the near surface moisture, (2) surface roughness is found to more strongly affect the degree of polarization than the emitted intensity, (3) the slope of the intensity-moisture curves decreases in going from day to dawn, and (4) increased near surface moisture at dawn is characterized by increased polarization of emissions. The results of the experiment indicate that microwave techniques can be used to observe the history of the near surface moisture. The subsurface history must be inferred from soil physics models which use microwave results as boundary conditions.

Burke, W. J.↗

Water-ice Clouds on Mars: Location and Seasonal Variation

Water-ice clouds were located on Mars using Viking infrared thermal mapper (IRTM) broadband spectral observations. The IRTM instrument had 5 thermal bands centered at 7, 9, 11, 15, and 20 microns. Clouds and hazes were consistently observed in four northern hemisphere regions centered over Tharsis, Arabia, Elysium, and along the boundary between the crater uplands and the northern plains. During the northern spring and summer when the atmosphere is relatively free of dust, there is a distinct difference between the cloud abundance in the Northern and Southern Hemispheres, with clouds and hazes being rare in the south. A second important class of water-ice clouds are those observed along the boundary of the retreating north polar cap. These clouds occur at all longitudes around the cap and are generally confined to within +/- 5 deg of the cap boundary. The cloud opacities can be estimated using a delta-Eddington radiative transfer model which incorporates Mie scattering and the electrical properties of water-ice. Assuming realistic, but non-unique, values for the ice particle size and cloud temperature, the derived opacities range from near-zero to 1.

Christensen, P. R.↗

Electron transfer in nonpolar media

The Marcus theory of electron transfer views fluctuating orientations of permanent dipoles as the nuclear mode bringing the donor and acceptor into the tunneling resonance. Electronic polarization of the solvent is excluded as the fast mode adiabatically following the electronic density. This view, valid for solids, does not apply to molecular liquids where molecular translations (density fluctuations) modulate the induction interaction of the donor-acceptor complex with the solvent. This mechanism of promoting radiation-less electronic transitions is considered here in the framework of the perturbation liquid-state theory. The reorganization energy of electron transfer in nonpolar solvents is nonzero and reaches the values of 0.1–0.3 eV for typical molecular sizes and solvents used in applications. The reorganization energy scales quadratically with the molecular polarizability of the solvent and decays as the inverse fifth power with the size of the donor and acceptor. The combination of the entropic character of the density fluctuations, driven by re-packing of molecular cores, with the short range of induction solute–solvent interactions leads to the violation of the fluctuation–dissipation theorem for the variance of the donor-acceptor energy gap. An explicit, approximately hyperbolic, dependence of the reorganization energy on temperature is predicted. It leads to a non-Arrhenius kinetic law for the rate constant of electron transfer in nonpolar liquid solvents.

14 SOLAR ENERGY↗

Scattering from randomly oriented circular discs with application to vegetation

A vegetation layer is modeled by a collection of randomly oriented circular discs over a half space. The backscattering coefficient from such a half space is computed using the radiative transfer theory. It is shown that significantly different results are obtained from this theory as compared with some earlier investigations using the same modeling approach but with restricted disc orientations. In particular, the backscattered cross polarized returns cannot have a fast increasing angular trend which is inconsistent with measurements. By setting the appropriate angle of orientation to zero the theory reduces to previously published results. Comparisons are shown with measurements taken from milo, corn and wheat and good agreements are obtained for both polarized and cross polarized returns.

Karam, M. A.↗

Mapping H-band Scattered Light Emission in the Mysterious SR21Transitional Disk

We present the first near infrared (NIR) spatially resolved images of the circumstellar transitional disk around SR21. These images were obtained with the Subaru HiCIAO camera, adaptive optics, and the polarized differential imaging technique. We resolve the disk in scattered light at H-band for stellocentric 0.1 < or approx. r < or approx. 0.6 (12 < or approx. r < or approx. 75AU). We compare our results with previously published spatially resolved 880 micron continuum Submillimeter Array images that show an inner r < or approx. 36AU cavity in SR21. Radiative transfer models reveal that the large disk depletion factor invoked to explain SR21's sub-mm cavity cannot be "universal" for all grain sizes. Even significantly more moderate depletions (delta = 0.1, 0.01 relative to an undepleted disk) than those that reproduce the sub-mm cavity (delta approx. 10(exp −6) are inconsistent with our H-band images when they are assumed to carry over to small grains, suggesting that surface grains scattering in the NIR either survive or are generated by whatever mechanism is clearing the disk midplane. In fact, the radial polarized intensity profile of our H-band observations is smooth and steeply inwardly-increasing (r(sup −3), with no evidence of a break at the 36AU sub-mm cavity wall. We hypothesize that this profile is dominated by an optically thin disk envelope or atmosphere component.We also discuss the compatibility of our data with the previously postulated existence of a sub-stellar companion to SR21 at r approx. 10-20AU, and find that we can neither exclude nor verify this scenario. This study demonstrates the power of multiwavelength imaging of transitional disks to inform modeling efforts, including the debate over precisely what physical mechanism is responsible for clearing these disks of their large midplane grains.

SR21↗

Scattering from randomly oriented circular discs with application to vegetation

A vegetation layer is modeled by a collection of randomly oriented circular discs over a half space. The backscattering coefficient from such a half space is computed using the radiative transfer theory. It is shown that significantly different results are obtained from this theory as compared with some earlier investigations using the same modeling approach but with restricted disc orientations. In particular, the backscattered cross-polarized returns cannot have a fast increasing angular trend which is inconsistent with measurements. By setting the appropriate angle of orientation to zero the theory reduces to previously published results. Comparisons are shown with measurements taken from milo, corn and wheat and good agreements are obtained for both polarized and cross-polarized returns.

Karam, M. A.↗

The polarization properties of Fe II 614.9 nm

The anomalous Zeeman splitting of the Fe II line at 614.9 nm results in four unusual properties of the polarization signature of this line in the presence of magnetic fields: the absence of linear polarization, no magnetooptical effect, the independence of intensity at line center from the inclination of the field, and a depolarizing self-absorption. The origin of these properties is illustrated in terms of the transfer of line radiation in an idealized solar atmosphere.

Lites, Bruce W.↗

Non-linear effects of QED multiple-photon processes on cyclotron spectra

The relativistic magnetic resonant multiple-photon processes are discussed up to order alpha(f)exp 2, in particular two-photon scattering and two-photon emission. The latter also contributes to the opacity and photon production, although more weakly than the scattering. These processes are nonlinear in the radiation field, and therefore the transfer depends sensitively on the cross sections. We show model spectra including three cyclotron harmonics for the accreting pulsar Her X-1 and the gamma-ray burster GB880205. The lines are highly polarized, and their depth is sensitive to the polarization treatment.

Meszaros, P.↗

Satellite Mapping of the Earth's Ozone and Sulfur Dioxide

The Total Ozone Mapping Spectrometer (TOMS) instruments are spatially-scanning UV spectrometers that have produced daily global images of total ozone over the last 21 years since the launch of the Nimbus 7 satellite. The instruments use a total ozone retrieval algorithm pioneered by J.V. Dave and C. L. Mateer for the Nimbus 4 Backscatter Ultraviolet (BUV) instrument, designed by D.F. Heath. The TOMS ozone maps have revealed the relations between total ozone and atmospheric dynamics, and shown the dramatic losses of ozone in the Antarctic ozone hole and the Northern hemisphere. The accepted long-term trends in global, regional, and local ozone are derived from data from the Nimbus 7 TOMS and three successive TOMS flights on Russian, Japanese, and American satellites. The next TOMS flight will be launched in 2000. The contiguous mapping design and fortuitous choice of TOMS wavelengths bands also permitted imaging of a second atmospheric gas, sulfur dioxide, which is transient due to its short lifetime. The importance of this measurement was first realized after the eruption of El Chichon volcano in 1982. The extreme range of sizes of volcanic eruptions and the 'associated danger require observations from a distant observing platform. The first quantitative time series of the input of sulfur dioxide by explosive volcanic eruptions into the atmosphere thus was developed from the TOMS missions. Finally, the Rayleigh and aerosol scattering spectral characteristic and reflectivity complete the four dominant pieces of information in the near UV albedo of the Earth. The four parameters are derived with a linear algorithm, the absorption coefficients of the gases, and effective paths computed from radiative transfer tables. Absorbing aerosol clouds (smoke, dust, volcanic ash) are readily identified by their deviation from a Rayleigh signature. The greatest shortcoming of the TOMS dataset is the 24 hour time resolution that is produced by the polar orbit of the satellite. Dynamic phenomena, such as upper air fronts that modulate total ozone and volcanic eruptions of sulfur dioxide and ash, cannot be adequately resolved. It is hoped that UV observations from geostationary satellites will soon be made to test the value of this unique information in weather forecasting and aviation safety.

Krueger, Arlin↗

Satellite Mapping of the Earth's Ozone and Sulfur Dioxide

The Total Ozone Mapping Spectrometer (TOMS) instruments are spatially-scanning UV spectrometers that have produced daily global images of total ozone over the last 21 years since the launch of the Nimbus 7 satellite. The instruments use a total ozone retrieval algorithm pioneered by J.V. Dave and C. L. Mateer for the Nimbus 4 Backscatter Ultraviolet (BUV) instrument, designed by D.F. Heath. The TOMS ozone maps have revealed the relations between total ozone and atmospheric dynamics, and shown the dramatic losses of ozone in the Antarctic ozone hole and the Northern hemisphere. The accepted long-term trends in global, regional, and local ozone are derived from data from the Nimbus 7 TOMS and three successive TOMS flights on Russian, Japanese, and American satellites. The next TOMS flight will be launched in 2000. The contiguous mapping design and fortuitous choice of TOMS wavelengths bands also permitted imaging of a second atmospheric gas, sulfur dioxide, which is transient due to its short lifetime. The importance of this measurement was first realized after the eruption of El Chichon volcano in 1982. The extreme range of sizes of volcanic eruptions and the associated danger require observations from a distant observing platform. The first quantitative time series of the input of sulfur dioxide by explosive volcanic eruptions into the atmosphere thus was developed from the TOMS missions. Finally, the Rayleigh and aerosol scattering spectral characteristic and reflectivity complete the four dominant pieces of information in the near UV albedo of the Earth. The four parameters are derived with a linear algorithm, the absorption coefficients of the gases, and effective paths computed from radiative transfer tables. Absorbing aerosol clouds (smoke, dust, volcanic ash) are readily identified by their deviation from a Rayleigh signature. The greatest shortcoming of the TOMS dataset is the 24 hour time resolution that is produced by the polar orbit of the satellite. Dynamic phenomena, such as upper air fronts that modulate total ozone and volcanic eruptions of sulfur dioxide and ash, cannot be adequately resolved. It is hoped that UV observations from geostationary satellites will soon be made to test the value of this unique information in weather forecasting and aviation safety.

Krueger, Arlin↗

Parametric 3D Atmospheric Reconstruction in Highly Variable Terrain with Recycled Monte Carlo Paths and an Adapted Bayesian Inference Engine

We describe a method for accelerating a 3D Monte Carlo forward radiative transfer model to the point where it can be used in a new kind of Bayesian retrieval framework. The remote sensing challenge is to detect and quantify a chemical effluent of a known absorbing gas produced by an industrial facility in a deep valley. The available data is a single low resolution noisy image of the scene in the near IR at an absorbing wavelength for the gas of interest. The detected sunlight has been multiply reflected by the variable terrain and/or scattered by an aerosol that is assumed partially known and partially unknown. We thus introduce a new class of remote sensing algorithms best described as "multi-pixel" techniques that call necessarily for a 3D radaitive transfer model (but demonstrated here in 2D); they can be added to conventional ones that exploit typically multi- or hyper-spectral data, sometimes with multi-angle capability, with or without information about polarization. The novel Bayesian inference methodology uses adaptively, with efficiency in mind, the fact that a Monte Carlo forward model has a known and controllable uncertainty depending on the number of sun-to-detector paths used.

Monte Carlo↗

Comparison of results obtained by solving the radiative transfer equation with an iterative method and a spherical harmonics method

Fluxes and intensities of light scattered by a model atmosphere are computed by a spherical harmonics approximation and by an iterative method of solving the radiative transfer equation and are compared. The large differences in the net fluxes and intensities reported by Dave and Armstrong (1974) for the two methods are reduced here by making a few changes in the iterative routine. Decreasing the polar angle increment from 2 to 1 deg in the iterative method of computing the source function does not improve the results as suggested by Dave and Armstrong.

Bahethi, O. P.↗

The OMPS Limb Profiler Instrument: Two-Dimensional Retrieval Algorithm

The upcoming Ozone Mapper and Profiler Suite (OMPS), which will be launched on the NPOESS Preparatory Project (NPP) platform in early 2011, will continue monitoring the global distribution of the Earth's middle atmosphere ozone and aerosol. OMPS is composed of three instruments, namely the Total Column Mapper (heritage: TOMS, OMI), the Nadir Profiler (heritage: SBUV) and the Limb Profiler (heritage: SOLSE/LORE, OSIRIS, SCIAMACHY, SAGE III). The ultimate goal of the mission is to better understand and quantify the rate of stratospheric ozone recovery. The focus of the paper will be on the Limb Profiler (LP) instrument. The LP instrument will measure the Earth's limb radiance (which is due to the scattering of solar photons by air molecules, aerosol and Earth surface) in the ultra-violet (UV), visible and near infrared, from 285 to 1000 nm. The LP simultaneously images the whole vertical extent of the Earth's limb through three vertical slits, each covering a vertical tangent height range of 100 km and each horizontally spaced by 250 km in the cross-track direction. Measurements are made every 19 seconds along the orbit track, which corresponds to a distance of about 150km. Several data analysis tools are presently being constructed and tested to retrieve ozone and aerosol vertical distribution from limb radiance measurements. The primary NASA algorithm is based on earlier algorithms developed for the SOLSE/LORE and SAGE III limb scatter missions. All the existing retrieval algorithms rely on a spherical symmetry assumption for the atmosphere structure. While this assumption is reasonable in most of the stratosphere, it is no longer valid in regions of prime scientific interest, such as polar vortex and UTLS regions. The paper will describe a two-dimensional retrieval algorithm whereby the ozone distribution is simultaneously retrieved vertically and horizontally for a whole orbit. The retrieval code relies on (1) a forward 2D Radiative Transfer code (to model limb radiances within a non-uniform atmosphere and evaluate 2D analytical partial derivatives) and (2) an optimal estimator inversion routine. The algorithm uses the typically sparse nature of the kernel matrices as well as fast matrix inversion techniques to allow for fast inversion of limb data with efficient memory management (as was done for MIPAS data processing). While the method has so far only been developed in the context of Single Scatter, the paper will show how the CPU intensive Multiple Scatter modeling can be implemented using parallel CPU processing. Initial results will be presented in terms of retrieved ozone profiles and code performance.

Rault, Didier F.↗

Two-photon exchange from intermediate state resonances in elastic electron-proton scattering

In this paper, we use a recently developed dispersive approach to compute the two-photon exchange (TPE) correction to elastic electron-proton scattering, including contributions from hadronic $J^P=1/2^\pm$ and $3/2^\pm$ resonant intermediate states below~1.8~GeV. For the transition amplitudes from the proton ground state to the resonant excited states we employ new exclusive meson electroproduction data from CLAS at $Q^2 \lesssim 5$~GeV$^2$, and we explore the effects of both fixed and dynamic widths for the resonances. Among the resonant states, the $N(1520)~\!3/2^-$ becomes dominant for $Q^2 \gtrsim 2$~GeV$^2$, with a sign opposite to the comparably sized $\Delta(1232)~\!3/2^+$ contribution, leading to an overall increase in the size of the TPE correction to the cross section relative to the nucleon only contribution at higher $Q^2$ values. The results are in good overall agreement with recent $e^+ p$ to $e^- p$ cross section ratio and polarization transfer measurements, and provide compelling evidence for a resolution of the electric to magnetic form factor ratio discrepancy.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Parameterization of IR cooling in a middle atmosphere dynamics model. I - Effects on the zonally averaged circulation

A computationally efficient two-stream parameterization of IR cooling is developed for a middle atmosphere dynamics model. The parameterization combines the monochromatic feature of an emissivity formulation with the computational simplicity of a single spatial integral to evaluate the monochromatic transfer equation. Calculations show strong radiative control of the mesopause region and the need for substantial deceleration of the mean zonal winds. Calculated temperatures show good agreement in the summer hemisphere where planetary wave activity is negligible, but in the polar night of the winter hemisphere they are about 30 K too cold, which suggests planetary wave heating must make up the deficit. With observed ozone densities, globally averaged radiative equilibrium temperatures in the 65-75 km region are too cold and an additional heat source about 1 K/day is required.

Apruzese, J. P.↗

Preface to Special Section: Validation of Atmospheric Infrared Sounder Observations

The papers described below demonstrate that the AIRS calibrated radiances and retrieved geophysical products generally meet or exceed the prelaunch specifications. The retrieved quantities show little variation in uncertainty as a function of cloud amount. However, AIRS retrieval yield is a rapidly decreasing function of cloud amount; at about 80% cloudiness essentially no infrared radiances are used in the retrieval processes. Also, AIRS performance has not been demonstrated for all conditions and products. Calibrated and forward calculated radiances meet performance specifications for conditions varying from the cold poles to warm tropics. The retrieval system performs well over extrapolar land in the free troposphere (~2-15 km above the surface) and over extrapolar oceans at all tropospheric altitudes. The AIRS retrieval algorithms have not been optimized for polar winter conditions, so no such results are presented in these papers.

temperature↗

The Effect of Periodic Spatial Perturbations on the Emission Rates of Quantum Dots near Graphene Platforms

The quenching of fluorescence (FL) at the vicinity of conductive surfaces and, in particular, near a 2-D graphene layer has become an important biochemical sensing tool. The quenching is attributed to fast non-radiative energy transfer between a chromophore (here, a Quantum Dot, QD) and the lossy graphene layer. Increased emission rate is also observed when the QD is coupled to a resonator. Here, we combine the two effects in order to control the emission lifetime of the QD. In our case, the resonator was defined by an array of nano-holes in the oxide substrate underneath a graphene surface guide. At resonance, the surface mode of the emitted radiation is concentrated at the nano-holes. Thus, the radiation of QD at or near the holes is spatially correlated through the hole-array’s symmetry. We demonstrated an emission rate change by more than 50% as the sample was azimuthally rotated with respect to the polarization of the excitation laser. In addition to an electrical control, such control over the emission lifetime could be used to control Resonance Energy Transfer (RET) between two chromophores.

36 MATERIALS SCIENCE↗