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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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DOE OSTI2021

Opportunities for Industry to Provide Flexibility While Increasing Profitability

Supply and demand flexibility will both be needed to ensure the electricity system functions properly as the share from variable renewable generation continues to grow. Industrial manufacturing currently consumes about a third of primary energy worldwide, and electricity is projected to supply an increasing share of this demand as the global economy decarbonizes. Therefore, the ability for industry to flex demand poses an enticing opportunity to enable grid flexibility. However, large capital outlays prevent industry from voluntarily altering demand. Here we show that as battery costs continue to fall, industry will soon be able to profitably alter demand in accordance with electricity price variations. Focusing on two established industries– chlor-alkali and electric arc furnaces – and two industries with large future potential – methane pyrolysis and atmospheric CO 2 capture, we use a linear program (LP) optimization to assess the technoeconomic feasibility of flexible industrial demand across both historical and future-looking wholesale day-ahead marginal prices for the Electricity Reliability Council of Texas (ERCOT). We find positive net present values (NPV) from $\$$400K to $\$$50M using projected 2050 battery prices for industrial purchase of behind-the-meter batteries, using only arbitrage as a source of value. These results indicate that, with projected battery prices, profit-seeking industrial players could voluntarily play a future role in stabilizing a high-renewables grid where electricity prices act as accurate signals of grid needs.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2021

Sensor enabled data-driven predictive analytics for modeling and control with high penetration of DERs in distribution systems

The electric power grid is undergoing a tremendous transformation due to the increasing penetration of renewable energy resources beginning with wind and more recently with the distributed energy resources (DERs) such as solar and battery storage. DERs have dramatically changed the role of the distribution systems in the overall power grid, and they are expected to contribute a significant portion of power generation in the future. If current trends for DERs continue, system operation and control will need to change dramatically for improved grid reliability and resiliency. As renewable resources increase in penetration, new and challenging operational, planning, and design problems are expected to emerge. Some of the key challenges that arise in the planning and operation of the future grid are: 1) Quantifying the impact of high DER penetration in distribution systems on bulk grid behavior over multiple time scales. 2) Identifying whether a particular DER configuration/settings have a large impact on the overall grid behavior. These challenges can be addressed in an offline manner using detailed T&D grid models and they can also be addressed in an online manner using sensor measurements. In particular, the advancement and planned growth in sensor technology in power grid over various voltage levels provide us with a unique opportunity to tackle these challenges from a data analytic perspective without needing detailed T&D grid models. A few questions that naturally arise when addressing the challenges from DERs using sensor data are: 1) How can we use limited sensor measurements to monitor & control voltage stability and small signal stability of the bulk system? 2) How can we ensure that the developed data analytic methods are robust to data availability and quality issues? 3) How can we compute the developed analytics in a scalable manner using streaming measurements? In this project, we addressed the aforementioned challenges arising from DERs and answered the questions raised above on how to effectively use the sensor measurements to enhance the reliability and performance of the electric grid. Thus, the overarching goal of this project is to develop effective reduced/representative system models from data that make the computational complexity sufficiently manageable so as to be useful to simulate, analyze, and even control complex non-linear power systems dynamics with large penetrations of DERs. In order to achieve the objective, the project team established a four-fold technical approach 1) Formulated a combined transmission-distribution co-simulation framework for data generation and validation, 2) Derived reduced/representative models of power systems based on data-driven methods for efficient computation and appropriate representation of system behavior, 3) Developed data driven characterization of power system behavior based on transfer operator theory, machine learning and optimization for model estimation, 4) Incorporated a scalable data management and processing architecture using distributed Kafka streaming applications that coordinate input data streams to the developed data analytics. The key accomplishments of the project are: 1) Development of a scalable multi-timescale T&D co-simulation framework (both for steady state and for dynamic co-simulation) using commercial solvers (PSSE and GridLAB-D). The steady-state T&D co-simulation interface is shared with our industry partner (PJM). 2) A structured reduced order dynamic model of distribution systems that can represent partial motor stalling along with a systematic procedure to derive the model parameters. 3) A PMU based online method to monitor, localize and mitigate fault-induced delayed voltage recovery using DER reactive support and load control in distribution systems. 4) Development of linear operator based robust methodologies for dynamic state estimation, uncertainty quantification, system identification and trajectory prediction for power system dynamics. 5) An adaptive damping control for utilizing wind energy resources to provide oscillation damping and system stability. 6) Implementation of Kafka-based framework for efficient processing of streaming data using Linux-based local virtual environment.

DER integration↗
DOE OSTI2025

Customizable Technical Specifications for Lithium-Ion Battery Storage Projects

Learn how to navigate the FEMP Lithium-ion Battery Storage Technical Specifications, a key resource for federal agencies developing onsite energy storage projects. This webinar, led by technical experts, will provide a step-by-step walkthrough of the specifications, supplemented with a real-world case study. Gain practical insights to support successful battery storage project development and implementation.

25 ENERGY STORAGE↗
DOE OSTI2026

West Africa Battery Energy Storage Systems (BESS) Capacity Building - Discussion of BESS Tariffs: Payment Structures and Case Studies [Slides]

Battery Energy Storage Systems (BESS) are emerging as critical assets for enhancing grid reliability, integrating renewable energy, and enabling system flexibility. Yet, the regulatory and financial frameworks that determine how BESS projects are compensated vary widely across jurisdictions. This presentation explores international case studies - from Honduras, Costa Rica, Chile, South Africa, Mexico, and Brazil - to illustrate how tariff design and payment structures are evolving to support large-scale BESS deployment. The cases highlight a range of ownership and revenue models, including cost-of-service mechanisms, energy and capacity payments, and market-based arbitrage, as well as hybrid approaches under development. The discussion will examine key challenges such as defining remuneration for ancillary services, addressing double charging, and accounting for efficiency losses and degradation over time. By comparing experiences across markets, the presentation identifies emerging best practices for valuing BESS and designing tariffs that align technical performance with economic incentives, providing insights for regulators, utilities, and policymakers pursuing storage integration.

25 ENERGY STORAGE↗
DOE OSTI2025

Process design and techno-economic analysis for bio-based graphite and liquid hydrocarbons production from lignocellulosic biomass

The worldwide demand for graphite, as the main anode material for Li-ion batteries, is expected to double by 2028 since it supports the use of electricity, including transient renewable sources, for energy storage, sustainable mobility, and automation. However, the dependence on non-renewable and external resources jeopardizes the world supply chain. This study explores the technical and economic performance of transforming lignocellulosic biomass into biographite and fuel-grade hydrocarbons through pyrolysis bio-oil upgrading. According to simulation results, the total power demand for the biorefinery reached 10,784 kWh per tonne of biographite, of which 36 % can be supplied by the heat integration network and power plant. Sensitivity and risk analyses were conducted to evaluate the economics, with process yields identified as the most relevant indicators to the minimum selling price (MSP). The analysis revealed a promising cost-competitive range for biographite MSP against fossil-based graphite (medium quality synthetic graphite Chinese market price ~$\$$4.2/kg). Case D, which includes biofuels as a byproduct, presents the best metrics, reaching a MSP of $\$$3.3/kg of anode-grade biographite with a profit margin of 27 %. While including biofuels in the product slate provides the best economic performance, the uncertainty associated with the big capital investment makes its risk 13 % higher to attain an IRR >20 % than the case in which biographite is produced as a standalone product. Overall, this study demonstrates that integrated biorefineries can produce a cost-competitive bio-based anode material for Li-ion batteries.

09 BIOMASS FUELS↗
DOE OSTI2025

Microstructure Scale Lithium-Ion Battery Modeling: Part II. On In-Plane Heterogeneities and the Mechanisms that Regulate Them

Li-ion batteries performance and degradation are typically modeled at the macroscopic scale, that is neglecting in-plane heterogeneities that can arise from non-uniform electrode microstructures. Herein, a microstructure scale electrochemical model is used to quantify the impact of microstructure heterogeneity on cell performance during fast charging. The model predicts the electrolyte and solid concentration in-plane standard deviation can reach, respectively, ≈200 mol·m −3 and 6–7 kmol·m −3 locally. Further, the intercalation current density in-plane relative standard deviation can reach extremely high values, around 100% in the cathode and well above 100% in the anode graphite. These denote highly non-uniform lithiation rates and material utilization within each slice of the microstructure along the cell thickness. Non-uniform curvatures, at the particle scale (surface roughness) and between particles (size distribution), were found to initiate these in-plane heterogeneities, while an OCP-induced mechanism subsequently regulates them. The present model provides new insights into small length scale heterogeneity impact on battery performance not available with standard macro-scale/P2D modeling.

25 ENERGY STORAGE↗
DOE OSTI2024

Lifespan Impacts to Infrastructure, Renewable Energy Components and Energy Storage Components Related to Fluoropolymer Use

This report focuses on the use of fluoropolymers in infrastructure materials (building construction materials, transportation, and electrical transmission and distribution); renewable energy generation components (specifically wind and solar); and energy storage components (lithium-ion batteries and fuel cells) and product lifespan impacts if fluoropolymers were no longer available or allowed in commerce. Additionally, environmental considerations for fluoropolymer manufacture, use, and end-of-life disposal are discussed. This document is the second of two companion reports. The first report, Assessment of Fluoropolymer Production and Use With Analysis of Alternative Replacement Materials, contained an analysis of use of fluoropolymers and their potential replacement technologies in aerospace, automotive, battery, building construction, chemical processing, electronics, infrastructure, semiconductor, solar panel, and wind energy industries sectors, along with qualitative life cycle assessment (LCA) and cost-benefit analysis of replacing fluoropolymers. This report does not focus on the lifecycle aspects of use of fluoropolymer or alternatives in the designated applications. For more information on those topics, see aforementioned report.

25 ENERGY STORAGE↗
DOE OSTI2022

Innovative Thermal Strategies: Electrification's Best Friend

Because transportation and heat are the most significant contributors to greenhouse gas (GHG) emissions in the northern U.S., electrification of transport and heat are prominent elements of many decarbonization plans, such as that of New York State (NYS). A key challenge is then to decarbonize the electric supply and distribution system ("the grid") that supplies electricity, a process colloquially known as "greening the grid", so that the saved direct carbon emissions are not offset by additional indirect emissions from electrical generation on the grid. Applying this "simple" decarbonization plan to locations with high winter heating loads and modest renewable resources is challenging. Understanding the impact of thermal system design to grid demands in these locations and the related marginal power source for electrification options is critical to allocating proper resources to solve decarbonization challenges and quantifying the resultant carbon emissions impact.

battery storage↗
DOE OSTI2025

How to Model Batteries (with PV, Stand-Alone, or Hybrids) in SAM and PySAM

This tutorial will be a deep dive into considerations for battery modeling and demonstrating how to model them in SAM, including battery chemistry, thermal modeling, degradation/lifetime, dispatch, interconnection limits and curtailment, and their associated impacts on project profits and battery lifetime. By the end of the tutorial attendees will know how to size and model both behind-the-meter and front-of-meter battery systems, including financial analysis and pairing with other PV models (including pvlib) via PySAM.

25 ENERGY STORAGE↗
DOE OSTI2020

Degradation of Commercial Lithium-Ion Cells as a Function of Chemistry and Cycling Conditions

Energy storage systems with Li-ion batteries are increasingly deployed to maintain a robust and resilient grid and facilitate the integration of renewable energy resources. However, appropriate selection of cells for different applications is difficult due to limited public data comparing the most commonly used off-the-shelf Li-ion chemistries under the same operating conditions. This article details a multi-year cycling study of commercial LiFePO 4 (LFP), LiNi x Co y Al 1–x–y O 2 (NCA), and LiNi x Mn y Co 1–x–y O 2 (NMC) cells, varying the discharge rate, depth of discharge (DOD), and environment temperature. The capacity and discharge energy retention, as well as the round-trip efficiency, were compared. Even when operated within manufacturer specifications, the range of cycling conditions had a profound effect on cell degradation, with time to reach 80% capacity varying by thousands of hours and cycle counts among cells of each chemistry. The degradation of cells in this study was compared to that of similar cells in previous studies to identify universal trends and to provide a standard deviation for performance. All cycling files have been made publicly available at batteryarchive.org, a recently developed repository for visualization and comparison of battery data, to facilitate future experimental and modeling efforts.

25 ENERGY STORAGE↗
DOE OSTI2020

High-temperature thermal energy storage with thermophotovoltaic energy conversion (Final Report)

This project began with a simple concept: that thermal energy storage paired with thermophotovoltaic power conversion could be a cost-effective solution to the challenge of renewables variability. Renewable energy sources such as solar and wind energy are clean, affordable, and abundant worldwide, but their variability presents a major problem for the incorporation of a large amount of these resources in global power systems. Systems with high penetrations of renewables frequently see periods of overproduction, where renewable energy is thrown away, and periods of underproduction, where expensive and polluting fossil fuel resources must be used to fill in the gaps. While energy storage technologies such as lithium ion batteries can help store energy from times of overproduction to times the energy is needed, current and projected future prices for these technologies are not low enough to support very renewables-heavy power grids. The research also focused on the techno-economics of using thermal energy storage and thermophotovoltaics to store the energy from solar and wind energy sources when they are available and release this energy back to the grid when it is needed. One of the biggest outcomes of this research was the conclusion that battery prices must drop 10x from their current values in order to meet this need, and this is unlikely to happen with current technologies such as lithium ion batteries.

14 SOLAR ENERGY↗
DOE OSTI2023

Optimizing Renewable Ammonia Production for a Sustainable Fertilizer Supply Chain Transition

Local renewable ammonia production using electrolytic hydrogen is an emerging approach to alleviate emissions attributed to synthetic nitrogen fertilizer production while also insulating against fluctuations in fertilizer prices and mitigating transportation costs and emissions. However, replacing ammonia currently produced using fossil fuels will not be immediate. To this end, we develop a supply chain transition model, which first optimizes the design and hourly operation of new renewable ammonia facilities to minimize production costs and then optimizes the annual installation timing, production scale, and location of these new renewable facilities along with ammonia transportation to meet county resolution demands. The objective is to augment and eventually replace conventional ammonia market imports in an economically competitive manner. We performed a case study for Minnesota's ammonia supply chain and found that a full transition to in-state renewable production by 2032 is optimal. This is incentivized by the U.S. federal government's clean hydrogen production credits. This transition results in 99 % reduction in carbon intensity along with stable supply costs below $475 per metric tonne. New renewable production facilities are an order of magnitude smaller than existing conventional plants. They use both wind and solar resources and operate dynamically to minimize expensive battery and hydrogen storage capacities.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Investigation of Nonflammable Electrolytes for Behind-the-Meter Storage Batteries

Behind-the-Meter Storage (BTMS) is a battery-based, stationary energy storage system that is connected to the residential or industrial customer's side of the electrical grid utility service meter. BTMS systems enable consumers to (A) economically schedule charging and usage of stored energy, (B) store and use energy from on-site generation, especially from inconstant, renewable sources like solar and wind, and (C) avoid overloading the grid during peak hours via supplementation with stored energy. BTMS battery performance requirements and general priorities differentiate from other applications, like EVs, which has prompted the development of batteries with tailored electrode and electrolyte materials. These materials prioritize low cost, avoiding critical materials; longevity, achieving 8000 cycle and 20-year shelf lives; and importantly, high safety. Nonflammable electrolytes show promise to improve safety by mitigating thermal runaway, yet often come with sacrifices to battery performance. In this presentation (1) primary categories of nonflammable electrolytes will be discussed; (2) a rational design of experiment will be presented for efficient performance evaluation of several nonflammables electrolyte in BTMS-relevant battery chemistry, Li4Ti5O12- and LiNi0.90Mn0.10O2; and (3) preliminary results will be presented.

battery↗
DOE OSTI2024

Machine learning for the redox potential prediction of molecules in organic redox flow battery

Here, organic redox flow batteries (ORFB) are recognized as an innovative technology for the large-scale storage of renewable energy. The redox potential of organic redox-active molecules plays a vital role in their performance. Advanced screening techniques like high-throughput experiment and machine learning (ML) have significantly enhanced organic material performance and transformed the field of ORFB. However, the scarcity of experimental data poses a considerable challenge for ML model development in this domain. In our study, we developed lightweight graph-based Gaussian process regression (GPR) models with GPU-accelerated marginalized graph kernel and hybrid kernel to predict the redox potentials of organic redox-active molecules for ORFBs, specifically focusing on small datasets. To evaluate model accuracy, we created a new experimental database of organic redox-active molecules by the data from hundreds of published papers and assembled previous computational datasets. We also considered some key parameters, such as pH conditions and solvent type, to assess their impact on redox potential prediction. Our GPR model predicted redox potentials with high accuracy across all datasets using minimal training data. The study provides powerful tools for molecule screening and design and delivers valuable guidance on designing training datasets for costly experiments.

25 ENERGY STORAGE↗
DOE OSTI2023

Cathode regeneration and upcycling of spent LIBs: toward sustainability

‘Green ambition towards sustainability’ is one of the hot research topics of the 21st century. With the sharp steering of the energy infrastructure toward fulfilling this radical expectation, the last decade has seen a global trend toward diversified sustainable renewable energy sources (such as solar, wind, and hydroelectric power) and electrification. Lithium-ion batteries (LIBs) are playing a significant role in this energy revolution. However, with the massive scale of the production of LIBs and their eventual retirement, attention has been turned to the erratic supply of raw materials used to manufacture these batteries and their disposal. Cathode regeneration technology is likely to be an optimal solution for the disposal of waste cathodes, aimed at non-destructively repairing and straightforwardly reusing degraded cathode materials for re-manufacturing LIBs with a shortened circular process, reasonable profits, and excellent efficiency. Additionally, cathode upcycling technology, aimed at upgrading the electrochemical performance of degraded materials, can be well adapted to the upgrading of battery chemistry and show excellent flexibility and potential for transforming the LIB industry from a resource-based to a circular economy. Thus, a holistic perspective based on the complete life cycle of LIBs is encouraged, and sustainability must be at the forefront regarding battery and pack design, raw material acquisition, materials synthesis, manufacturing, operating, retiring, and recycling processes of LIBs.

25 ENERGY STORAGE↗
DOE OSTI2025

On Rate-Limiting Mechanisms in NMC Cathodes: The Interplay of Low and High Current Constraints

In this study, we investigate the rate performance limits in LiNi 0.6 Mn 0.2 Co 0.2 O 2 cathodes for lithium-ion batteries, focusing on how cathode thickness, porosity, and threshold voltage impact discharge capacity. By conducting galvanostatic discharge experiments across a wide range of current densities using cathodes of varying thicknesses and porosities, we identify two distinct rate-limiting mechanisms: ionic liquid-diffusion and Ohmic/charge-transfer limitations. Our findings show that thick, dense cathodes are primarily limited by lithium diffusion in the electrolyte, while thinner and more porous cathodes are dominated by Ohmic/charge-transfer limitations, particularly at higher lower cutoff voltages. Crucially, these results allow us to identify the rate-limiting mechanisms in different cathode configurations, offering clear insights into how cathode design can be optimized for improved performance. Understanding these mechanisms is essential for designing next-generation batteries with enhanced rate performance, which is critical for applications such as electric vehicles and renewable energy storage systems.

Brischetto, Martin (ORCID:0000000339865813)↗
DOE OSTI2022

Wind and Solar Hybrid Power Plants for Energy Resilience

Wind-solar-storage hybrid power plants represent a significant and growing share of new proposed projects in the United States (U.S.). Their uptake is supported by increasing renewable energy market share, technical abilities for dispatch and control, and decreasing wind, solar, and battery storage costs. Simultaneously, generation and storage resources are increasingly used in distributed power systems. While concerns around the reliability of the aging, transforming U.S. electric grid are growing, diversifying energy resources through hybridization or spatial distribution provides an opportunity to enhance power system resilience compared to single-source generation. Understanding where to build hybrids for resilience value, rather than bulk power supply, has not been fully explored in previous studies. Therefore, in this study, we complete a national complementarity analysis to identify areas in the U.S. that are particularly suited for wind-solar hybrid power plant development. We show the importance of seasonal and diurnal patterns in assessing complementarity, and identify that regions in the Great Plains, Midwest, and Southeast are particularly suited for hybrid power plants. We demonstrate the resilience value of hybridization for a reference system based near Memphis, Tennessee, and show optimal sizing of wind, solar, and storage assets given 1.0 and 0.9 critical load factors. Results indicate that pairing wind and solar assets better meet constant load demand and reduce storage requirements compared to solar alone. These results enable future work integrating complementarity metrics in resilience frameworks and indicate a need for more finer resolution of local resource, demand, and hazard data.

14 SOLAR ENERGY↗